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Records with Keyword: Biomass
Showing records 26 to 50 of 382. [First] Page: 1 2 3 4 5 6 Last
Factors for Bioeconomy Development in EU Countries with Different Overall Levels of Economic Development
Andrzej Czyżewski, Andrzej Grzyb, Anna Matuszczak, Mariola Michałowska
April 20, 2023 (v1)
Keywords: agriculture, bioeconomy, Biomass, EU countries, Renewable and Sustainable Energy
The aim of this article is to indicate the rationale for the development of the bioeconomy in selected EU countries depending on their overall level of economic development. The research was based on four highly developed countries, i.e., Germany, France, Finland and Denmark, and four medium-developed countries, i.e., Poland, Hungary, Czech Republic, and Slovakia for the period 2001−2018. Renewable energy consumption, biomass and agricultural production were analysed as determinants of the bioeconomy development. The question was also answered whether differences in terms of measures determining the level of bioeconomy development between countries with different levels of economic development during the studied period are decreasing or increasing, using sigma (σ)-convergence coefficients. It is shown that the development of the bioeconomy of the studied countries is related to their level of economic development. In the middle economically developed countries, real opportunities for t... [more]
Non-Parametric Computational Measures for the Analysis of Resource Productivity
Christina Bampatsou, George Halkos
April 20, 2023 (v1)
Subject: Environment
Keywords: Biomass, CO2 emissions, energy use, recycled municipal waste, sustainable development, total factor productivity
In this study, we assumed that 28 European countries (Decision Making Units (DMUs)) aimed to accomplish higher economic outputs, using fewer resources and producing fewer emissions in the form of environmental degradation. In this context, we studied the drivers of total factor productivity change (TFPCH) in DMUs, associated with either managerial capabilities (efficiency change (EC)) or innovations (technical change (TC)) in resource-saving production methods, before and after the integration of CO2 (carbon dioxide) emissions as an additional variable (undesirable output) in the initial model of one output (gross domestic product (GDP)) and five inputs (labor, capital, energy, domestic material consumption and recycled municipal waste). The primary focus of this study is to identify best practices that policymakers can adopt as they attempt to reduce productivity loss. Our results highlight the weak areas of individual countries and seem to indicate the action that should be taken to... [more]
Impacts of Long- and Short-Term of Irrigation with Treated Wastewater and Synthetic Fertilizers on the Growth, Biomass, Heavy Metal Content, and Energy Traits of Three Potential Bioenergy Crops in Arid Regions
Mahmoud F. Seleiman, Nasser Al-Suhaibani, Salah El-Hendawy, Kamel Abdella, Majed Alotaibi, Ali Alderfasi
April 20, 2023 (v1)
Subject: Environment
Keywords: bioenergy crops, Biomass, heavy metals, synthetic fertilizer, Wastewater
The availability of suitable water is an important factor for increasing the cultivated areas and sustainability in arid (i.e., less than 200 mm precipitation per year) and semiarid regions (i.e., 200−700 mm precipitation per year). Therefore, this study aimed to analyze the impact of treated wastewater (TWW) and groundwater (GW) as well as synthetic fertilizers (50% and 100% of the recommended NPK dose; 150−150−60 kg N−P2O5−K2O ha−1) on the growth, biomass, energy traits, and macro and trace elements of maize (Zea mays L.), sorghum (Sorghum bicolor L.), and pearl millet (Pennisetum glaucum L) grown in old cultivated (first location; L1) and virgin soil (L2 and L3) as potential bioenergy crops. The soil in L1 has been irrigated with treated wastewater for the last 15 years and continued to be irrigated with treated wastewater in this investigation. The virgin soil was divided into two parts: the first part was irrigated with TWW, and the second part was irrigated with GW. The experimen... [more]
Towards Engineered Hydrochars: Application of Artificial Neural Networks in the Hydrothermal Carbonization of Sewage Sludge
Theodoros N. Kapetanakis, Ioannis O. Vardiambasis, Christos D. Nikolopoulos, Antonios I. Konstantaras, Trinh Kieu Trang, Duy Anh Khuong, Toshiki Tsubota, Ramazan Keyikoglu, Alireza Khataee, Dimitrios Kalderis
April 20, 2023 (v1)
Keywords: artificial neural networks, Biomass, hydrochar, hydrothermal carbonization, Machine Learning, sewage sludge, waste management
Sewage sludge hydrochars (SSHs), which are produced by hydrothermal carbonization (HTC), offer a high calorific value to be applied as a biofuel. However, HTC is a complex processand the properties of the resulting product depend heavily on the process conditions and feedstock composition. In this work, we have applied artificial neural networks (ANNs) to contribute to the production of tailored SSHs for a specific application and with optimum properties. We collected data from the published literature covering the years 2014−2021, which was then fed into different ANN models where the input data (HTC temperature, process time, and the elemental content of hydrochars) were used to predict output parameters (higher heating value, (HHV) and solid yield (%)). The proposed ANN models were successful in accurately predicting both HHV and contents of C and H. While the model NN1 (based on C, H, O content) exhibited HHV predicting performance with R2 = 0.974, another model, NN2, was also able... [more]
Operational Testing of a Solid Fuel Boiler with Different Fuels
Norbert Érces, László Kajtár
April 20, 2023 (v1)
Subject: Environment
Keywords: air pollutant, Biomass, biomass boiler, CO emission, flue gas
In the course of our investigations, we burned high-quality logs as well as wood briquettes in a conventional, manually fed mixed-fired boiler, under different operating parameters. Based on the evaluation of the measurement results, there is a significant difference in terms of recoverable energy and carbon monoxide emissions for the two fuels burned in the same device at different air supply parameters. Studies have shown that a constantly changing position of the draft control door has an adverse effect on carbon monoxide emissions as well as the energy produced. In the case of a constant draft door setting, the preset values that can be considered ideal for energy yield and CO emissions were determined for the two fuel types. The obtained results were compared with the requirements according to the MSZ EN 303-5 standard.
Applying Artificial Intelligence to Predict the Composition of Syngas Using Rice Husks: A Comparison of Artificial Neural Networks and Gradient Boosting Regression
Hung-Ta Wen, Jau-Huai Lu, Mai-Xuan Phuc
April 20, 2023 (v1)
Keywords: artificial neural network, Biomass, gasification, gradient boosting regression, hydrogen production, rice husk, steam-air updraft gasifier
The purpose of this study is to utilize two artificial intelligence (AI) models to predict the syngas composition of a fixed bed updraft gasifier for the gasification of rice husks. Air and steam-air mixtures are the gasifying agents. In the present work, the feeding rate of rice husks is kept constant, while the air and steam flow rates vary in each case. The consideration of various operating conditions provides a clear comparison between air and steam-air gasification. The effects of the reactor temperature, steam-air flow rate, and the ratio of steam to biomass are investigated here. The concentrations of combustible gases such as hydrogen, carbon monoxide, and methane in syngas are increased when using the steam-air mixture. Two AI models, namely artificial neural network (ANN) and gradient boosting regression (GBR), are applied to predict the syngas compositions using the experimental data. A total of 74 sets of data are analyzed. The compositions of five gases (CO, CO2, H2, CH4,... [more]
ANN Prediction of Performance and Emissions of CI Engine Using Biogas Flow Variation
Adhirath Mandal, Haengmuk Cho, Bhupendra Singh Chauhan
April 20, 2023 (v1)
Keywords: ANN modeling, biogas, Biomass, Diesel, dual fuel, emissions
Compression ignition (CI) engines are popular in the transport sector because of their high compression ratio. However, in recent years, it has become a major concern from an environmental point of view because of the emission and depleting fossil fuel. The advanced combustion concept has been a popular research topic in the CI engine. Low-temperature combustion with alternate fuel has helped in reducing the oxides of nitrogen (NOx) and soot emission of the engine. Biogas is a popular substitute of energy especially deduced from biomass because of its clean combustion properties, as well it being a renewable energy source compared to non-renewable diesel resources. In experiments with dual fuel, i.e., conventional diesel and alternate fuel (biogas) were carried out through them. In the present study, an artificial neural network model was used to estimate emissions and check the attributes of performance. Different algorithms and training functions were used to train the models. Howeve... [more]
A System Dynamics Approach to Comparative Analysis of Biomass Supply Chain Coordination Strategies
Shohre Khoddami, Fereshteh Mafakheri, Yong Zeng
April 20, 2023 (v1)
Keywords: bioenergy, Biomass, communities, cost sharing, Optimization, quantity discounts, Simulation, supply chain coordination, system dynamics
Biomass is an abundant energy source, particularly in Canada, as an alternative or primary source for electricity generation. However, low economy of scale could cause a loss of efficiency for bioenergy adoption in small remote communities. In this sense, coordination among the players could promote the efficiency and profitability of bioenergy supply chains for these communities. There are different coordination strategies with varying impacts on supply chain players’ profit or cost. Therefore, analyzing and comparing them could provide insights on how to decide about the choice of coordination strategy. In doing so, this study considers the coordination strategies of quantity discounts and cost-sharing. The study adopts a system dynamics approach for simulating these coordination scenarios, obtaining their corresponding optimal supply chain decisions, followed by a comparative analysis. For a case study, the study considers multiple suppliers providing biomass for electricity generat... [more]
Effects of Oxygen and Steam Equivalence Ratios on Updraft Gasification of Biomass
Nadia Cerone, Francesco Zimbardi
April 19, 2023 (v1)
Keywords: Biomass, equivalence ratio, gasification, tar, torrefaction, updraft
Several experimental datasets available on the gasification of different lignocellulosic feedstocks were used to correlate the flow of gasifying agents with the performance of updraft gasification in an autothermic 200 kWth pilot plant. The feedstocks used included eucalyptus wood chips, torrefied eucalyptus and spruce chips, lignin rich residues from biorefined straw and reed, shells of almond and hazelnut, which were gasified in flows of air, air and steam, oxygen, oxygen and steam. Thermal profiles inside the gasifier and gas quality in terms of incondensable gas and tar content were recorded and used to calculate the energy efficiency of converting solid feedstock into gaseous and liquid carriers. Common behaviors and parametric functionalities were identified to better understand the process and the most efficient tools to achieve the desired products. In analyzing data, the ratio steam to biomass was reported in terms of the equivalence ratio, ER(H2O) i.e., the fraction of the st... [more]
De-Risking Wood-Based Bioenergy Development in Remote and Indigenous Communities in Canada
Jennifer Buss, Nicolas Mansuy, Sebnem Madrali
April 19, 2023 (v1)
Subject: Energy Policy
Keywords: Biomass, climate change, community-based management, off-grid community, traditional knowledge
Remote and Indigenous communities in Canada have a unique opportunity to mobilize the vast amount of wood-based biomass to meet their energy needs, while supporting a local economy, and reducing greenhouse gas (GHG) emissions. This study realized in collaboration with five remote and Indigenous communities across Canada investigates the main barriers and potential solutions to developing stable and sustainable wood-based bioenergy systems. Our results highlight that despite the differences in available biomass and geographical context, these communities face common policy, economic, operational, cultural, social, and environmental risks and barriers to developing bioenergy. The communities identified and ranked the biggest barriers as follows; the high initial investment of bioenergy projects, the logistical and operational challenges of developing a sustainable wood supply chain in remote locations, and the limited opportunities for community leadership of bioenergy projects. Environm... [more]
Design of a 1 MWth Pilot Plant for Chemical Looping Gasification of Biogenic Residues
Falko Marx, Paul Dieringer, Jochen Ströhle, Bernd Epple
April 19, 2023 (v1)
Keywords: autothermal, Biomass, chemical looping, fluidized bed, gasification, pilot plant
Chemical looping gasification (CLG) is a promising process for the thermochemical solid to liquid conversion route using lattice oxygen, provided by a solid oxygen carrier material, to produce a nitrogen free synthesis gas. Recent advances in lab-scale experiments show that CLG with biomass has the possibility to produce a carbon neutral synthesis gas. However, all experiments have been conducted in externally heated units, not enabling autothermal operation. In this study, the modification of an existing pilot plant for demonstrating autothermal operation of CLG is described. Energy and mass balances are calculated using a validated chemical looping combustion process model extended for biomass gasification. Based on six operational cases, adaptations of the pilot plant are designed and changes discussed. A reactor configuration using two circulating fluidized bed reactors with internal solid circulation in the air reactor is proposed and a suitable operating strategy devised. The res... [more]
Pyrolysis Characteristics of Undervalued Wood Varieties in the Portuguese Charcoal Sector
Felix Charvet, Felipe Silva, Luís Ruivo, Luís Tarelho, Arlindo Matos, José Figueiredo da Silva, Daniel Neves
April 19, 2023 (v1)
Keywords: Biomass, carbonization, charcoal, pyrolysis, woody residues
Charcoal production in Portugal is mostly based on the valorization of woody residues from cork oak and holm oak, the latter being considered a reference feedstock in the market. Nevertheless, since wildfire prevention became a priority in Portugal, after the recent dramatic wildfires, urgent actions are being conducted to reduce the fuel load in the forests, which is increasing the amount of biomass that is available for valorization. Additionally, biomass residues from agriculture, forest management, control of invasive species, partially burnt wood from post-fire recovery actions, and waste wood from storm devastated forests need also to be considered within the national biomass valorization policies. This has motivated the present work on whether the carbonization process can be used to valorize alternative woody biomasses not currently used on a large scale. For this purpose, slow pyrolysis experiments were carried out with ten types of wood, using a fixed bed reactor allowing the... [more]
Co-Combustion of Biomass with Coal in Grate Water Boilers at Low Load Boiler Operation
Krzysztof Nowak, Sławomir Rabczak
April 19, 2023 (v1)
Subject: Environment
Keywords: air pollutants, Biomass, cofiring, hard coal, Polish heat market
Environmental protection, and in particular air protection against pollution, is an extremely important element of the global policy of many countries. The problem of air pollution is particularly important in Poland, where the heating market is one of the largest in Europe and is based in 74% on the use of fossil fuels, in particular hard coal. One of the technological solutions for the implementation of cleaner fuels is the co-combustion of coal and biomass. This process enables the reduction of harmful pollutants such as CO2, SO2, and can be implemented in existing boilers. Heating boilers achieve the highest design efficiency during optimal load at the level of 85−95% of nominal power. Under such conditions, heat production is most efficient. During operation, boilers are often started, extinguished or run below rated output, resulting in increased emissions. This publication presents the results of measurements of efficiency and concentrations of pollutants in the WR water boiler... [more]
Weed Management Practices to Improve Establishment of Selected Lignocellulosic Crops
Ioannis Gazoulis, Panagiotis Kanatas, Panayiota Papastylianou, Alexandros Tataridas, Efthymia Alexopoulou, Ilias Travlos
April 19, 2023 (v1)
Keywords: Arundo donax L., bioethanol, Biomass, cultural practices, Cynara cardunculus L., Hibiscus cannabinus L., Miscanthus × Giganteus, Panicum virgatum L., Sorghum bicolor Monech L., weeds
Lignocellulosic biomass is one of the dominant renewable energy resources suited for the production of sustainable biofuels and other energy purposes. This study was focused on weed management strategies that can improve the establishment of six lignocellulosic crops. The studied crops included: giant miscanthus, switchgrass, giant reed, cardoon, sweet sorghum, and kenaf. Delayed planting, increased planting densities, and mulching techniques can suppress weeds in giant miscanthus. Weed competition is detrimental for switchgrass establishment. Seedbed preparation and cultivar selection can determine its ability to compete with weeds. Giant reed is unlikely to get outcompeted by weeds, and any weed control operation is required only for the first growing season. Competitive cultivars and increased seeding rates maximize the competitiveness of cardoon against weeds. Several cultural practices can be used for non-chemical weed management in sweet sorghum and kenaf. For all crops, pre-emer... [more]
Importance of Agriculture in Creating Energy Security—A Case Study of Poland
Stanisław Bielski, Renata Marks-Bielska, Anna Zielińska-Chmielewska, Kęstutis Romaneckas, Egidijus Šarauskis
April 19, 2023 (v1)
Subject: Energy Policy
Keywords: Biofuels, Biomass, energy agriculture, Poland, renewable energy sources (RES)
Analyses of statistical data were made and their results discussed in this article to identify the level of Poland’s energy security and to determine the role of agriculture in ensuring it. It has been demonstrated that coal continues to be the staple resource for the generation of energy in Poland. The current demands and requirements concerning the reduced consumption of non-renewable resources and Poland’s obligations towards the European Union regarding the production of energy from renewable resources—all these considerations contribute to the promotion of a skillful development of energy crop farming, which, in Poland, is likely to be very successful. Agriculture plays an important role in ensuring Poland’s energy security, and this branch of farming can grow dynamically provided adequate legal regulations and promotion are in place. The chief resource for renewable energy generation is biomass. Straw and biogas production in agricultural biogas plants are two solutions whose ful... [more]
Current Status, Scenario, and Prospective of Renewable Energy in Algeria: A Review
Younes Zahraoui, M. Reyasudin Basir Khan, Ibrahim AlHamrouni, Saad Mekhilef, Mahrous Ahmed
April 19, 2023 (v1)
Keywords: Algeria, Biomass, geothermal, hydro, Renewable and Sustainable Energy, solar, Wind
Energy demand has been overgrowing in developing countries. Moreover, the fluctuation of fuel prices is a primary concern faced by many countries that highly rely on conventional power generation to meet the load demand. Hence, the need to use alternative resources, such as renewable energy, is crucial in order to mitigate fossil fuel dependency, while ensuring reductions in carbon dioxide emissions. Algeria—being the largest county in Africa—has experienced a rapid growth in energy demand over the past decade due to the significant increase in residential, commercial, and industry sectors. Currently, the hydrocarbon-rich nation is highly dependent on fossil fuels for electricity generation, with renewable energy only having a small contribution to the country’s energy mix. However, the country has massive potential for renewable energy generation, such as solar, wind, biomass, geothermal, and hydropower. Therefore, the government aims to diversify away from fossil fuels and promote re... [more]
Thermogravimetric Analysis of Solid Biofuels with Additive under Air Atmosphere
Joanna Wnorowska, Szymon Ciukaj, Sylwester Kalisz
April 19, 2023 (v1)
Keywords: Biomass, Coal, combustion, fuel additives, non-isothermal model methods
The paper presents the combustion profile of selected fuels as a result of thermogravimetric analysis. The main purpose of this study was to investigate a mixture of different types of fuel and the influence of the use of a fuel additive on the combustion process profile. As a fuel additive, halloysite was used to investigate the thermogravimetric profiles. It was confirmed that the main combustion parameters such as ignition temperature, burnout temperature, and maximum peak temperature correlated accordingly with different combustibility indices such as the ignition index, the burnout index, and the combustion indices. Furthermore, the present study provided a comparison of selected methods for analyzing non-isothermal solid-state kinetic data and investigated the kinetics of thermal decomposition to describe the ongoing process. Two non-isothermal model methods (Kissinger and Ozawa) were used to calculate the Arrhenius parameters. The effect of heating rate and the addition of hallo... [more]
The Analysis of a Prototype Installation for Biogas Production from Chosen Agricultural Substrates
Kinga Borek, Wacław Romaniuk, Kamil Roman, Michał Roman, Maciej Kuboń
April 19, 2023 (v1)
Keywords: biogas yield, Biomass, manure, methane fermentation, methane production by fermentation, pocket
Methane production by fermentation is a complex biochemical process, in which micromolecular organic substances are broken down by anaerobic bacteria into simple stabilized chemicals—mainly methane CH4 and carbon dioxide CO2. The organic matter of the slurry consists mainly of fats, proteins and carbohydrates. As a result of biochemical changes in the process of anaerobic decomposition, some of this matter is mineralized to simple chemical compounds. Cattle and pig husbandry offers enormous potential for useable biogas plant substrates. As a result of the constantly increasing amounts of animal husbandry products, and increasingly stringent environmental protection requirements aimed at reusing natural fertilizers, it is necessary to look for alternative processing methods. The need for efficiency in obtaining biogas from substrates (e.g., manure) was met by the laboratory stand presented in this article, for which the Polish patent No. 232200 was obtained. The new technology also allo... [more]
Biomass Combustion Modeling Using OpenFOAM: Development of a Simple Computational Model and Study of the Combustion Performance of Lippia origanoides Bagasse
Gabriel Fernando García Sánchez, Jorge Luis Chacón Velasco, David Alfredo Fuentes Díaz, Yesid Javier Rueda-Ordóñez, David Patiño, Juan Jesús Rico, Jairo René Martínez Morales
April 18, 2023 (v1)
Keywords: agricultural waste, bioenergy, Biomass, Computational Fluid Dynamics, Modelling
Combustion is the most commonly used technology to produce energy from biomass; nevertheless, there are still thermal efficiency problems in current biomass combustion furnaces and a lack of knowledge about the properties of residual biomasses that could be used as fuels. Aiming to contribute to knowledge of the potential of residual biomass for energy generation, this work reports on the implementation of a 2D computational model to study the combustion performance of several solid biomass fuels, and its application in the analysis of Lippia origanoides bagasse combustion. The model uses an Eulerian−Lagrangian approach; in the continuous phase, governing equations are solved, and in the dispersed phase, particles are tracked and the mass, momentum, species and energy transfer between the phases are calculated. The model was validated against experimental data from a combustor fueled by three biomasses: wood pellets, olive stone and almond shell. The results show deviations of less tha... [more]
Extensive Experimental Characterization with Kinetic Data for the Gasification Simulation of Solid Biofuels
Maximilian Robert Heinrich, André Herrmann, Andy Gradel, Marco Klemm, Tobias Plessing
April 18, 2023 (v1)
Keywords: Biomass, boudouard reaction, char combustion, downdraft gasifier, gasification, kinetics, pyrolysis, Simulation, spruce, steam gasification
In this study, biomass−specific gasification data is experimentally collected for numerical simulations of fixed−bed reactors. Since biomass properties vary, it is crucial to have characteristic biomass data. Extensive data is collected to determine an appropriate description of specific biomass behavior, including basic data (e.g., heating value, size, densities, ultimate and total analysis etc.), biomass pyrolysis and heterogeneous gasification reaction data. Heterogeneous reactions were comparatively investigated in the forms of powder, particles, and a fixed−bed. The powder was investigated in depth with CO2, O2, and H2O (gas fraction 5−20 vol.%; temperature CO2, O2 and H2O, respectively, at 730−790 °C, 360−405 °C, 720−780 °C), while particle reactions and fixed−bed reaction were only studied with CO2. A model description for a fixed−bed batch reactor was applied, modified, and compared to experimental fixed−bed batch reactor results. This study concludes that determining the appro... [more]
Process Optimization and CO2 Emission Analysis of Coal/Biomass Gasification Integrated with a Chemical Looping Process
Ratikorn Sornumpol, Dang Saebea, Amornchai Arpornwichanop, Yaneeporn Patcharavorachot
April 18, 2023 (v1)
Keywords: Biomass, calcium looping, co-gasification, CO2 emission, Coal
Biomass gasification is an attractive technology and one of the pathways for producing hydrogen. Due to the variable seasons and low calorific value of biomass, the addition of coal in the gasifier is suggested because coal has a high calorific value and carbon-to-hydrogen ratio. In general, the gaseous product obtained in gasification always contains a high amount of carbon dioxide, therefore, the co-gasification of biomass and coal should integrate with the calcium looping carbon dioxide capture process to provide purified hydrogen. In this work, the model of the co-gasification of biomass and coal integrated with the calcium looping carbon dioxide capture process was developed through an Aspen Plus simulator. The developed model was used to analyze the performance of this process. The sensitivity analysis demonstrated that increasing the gasification temperature, steam-to-feed (S/F) ratio, calcium oxide-to-feed (CaO/F) ratio, and regenerator temperature could improve hydrogen produc... [more]
Comparative Production of Bio-Oil from In Situ Catalytic Upgrading of Fast Pyrolysis of Lignocellulosic Biomass
Ali Abdulkhani, Zahra Echresh Zadeh, Solomon Gajere Bawa, Fubao Sun, Meysam Madadi, Xueming Zhang, Basudeb Saha
April 18, 2023 (v1)
Keywords: bio-oil, Biomass, catalytic pyrolysis, fractionation, lignin, upgrading
Catalytic upgrading of fast pyrolysis bio-oil from two different types of lignocellulosic biomass was conducted using an H-ZSM-5 catalyst at different temperatures. A fixed-bed pyrolysis reactor has been used to perform in situ catalytic pyrolysis experiments at temperatures of 673, 773, and 873 K, where the catalyst (H-ZSM-5) has been mixed with wood chips or lignin, and the pyrolysis and upgrading processes have been performed simultaneously. The fractionation method has been employed to determine the chemical composition of bio-oil samples after catalytic pyrolysis experiments by gas chromatography with mass spectroscopy (GCMS). Other characterization techniques, e.g., water content, viscosity, elemental analysis, pH, and bomb calorimetry have been used, and the obtained results have been compared with the non-catalytic pyrolysis method. The highest bio-oil yield has been reported for bio-oil obtained from softwood at 873 K for both non-catalytic and catalytic bio-oil samples. The r... [more]
An Analysis of the Influence of Low Density Polyethylene, Novolac, and Coal Tar Pitch Additives on the Decrease in Content of Impurities Emitted from Densified Pea Husks during the Process of Their Pyrolysis
Marcin Bielecki, Valentina Zubkova, Andrzej Strojwas
April 18, 2023 (v1)
Keywords: Biomass, pyrolysis, volatile–char interactions
The course of pyrolysis of pea husks was studied. It was stated that the compaction of a sample during its pyrolysis causes an almost two-fold increase in the content of hydrocarbons in the composition of volatile products in the temperature range of 350−470 °C. Low density polyethylene (LDPE), novolac, and coal tar pitch (CTP) wastes were added to feedstocks in the amount of 2 wt% in order to decrease the contribution of saturated and unsaturated hydrocarbons along with oxygen-containing compounds in volatile products. The analysis of the obtained products of pyrolysis was conducted using the techniques of thermogravimetry/Fourier transform infrared spectroscopy (TG/FT-IR), attenuated total reflectance (ATR) and ultraviolet (UV)-spectroscopies, gas chromatography-mass spectrometry (GCMS), X-ray diffractions (XRD), scanning electron microscopy (SEM), and energy dispersive X-ray analysis (EDX). It was determined that pitch took the first place in a series of effectiveness in decreasing... [more]
A System Analysis of a Bio-Hydrogen Production System Using Granulated Mine Residue as a H2S Adsorbent
Kento Torii, Mayu Hamazaki, Shoichi Kumon, Kimitaka Sato, Shogo Kato, Kiyoshi Dowaki
April 18, 2023 (v1)
Subject: Environment
Keywords: Biomass, desulfurization, granulation, Hydrogen, life cycle assessment, neutralized sediment
An energy production system that combines biomass and fuel cells produces much energy with minimal environmental impact. However, the hydrogen sulfide (H2S) contained in gasified biomass degrades fuel cell performance, thus negating the advantages of this combination. In this study, the removal of H2S by adsorption after biomass gasification was investigated. Metal oxides with high adsorption performance are common H2S adsorbents. However, they have a significant environmental impact in terms of metal depletion, which is an environmental impact indicator. Therefore, neutralized sediment materials from mine drainage treatments can be used as H2S adsorbents. A previous study found that the adsorption performance of H2S adsorbents is equivalent to that of metal oxides, especially in the high-temperature zone (300 °C), and the environmental impact is considerably lower than that of metal oxides. However, because the neutralized sediment is a powder (Φ 4.5 μm on average), there is a possibi... [more]
The Apeli: An Affordable, Low-Emission and Fuel-Flexible Tier 4 Advanced Biomass Cookstove
Dennis Krüger, Özge Mutlu
April 17, 2023 (v1)
Keywords: 19867-1 standard, Biomass, clean cooking, cookstove, efficiency, emissions
Based on the decision of representatives from the West African region and feedback from locals in Togo, an advanced continuous-feed, forced-draft, biomass cookstove named “Apeli” was developed. The stove was tested in modified ISO measurements based on the ISO 19867-1:2018 standard. This included a long shutdown operation using wood pellets and short shutdown operations using wood pellets, bamboo pellets, wheat straw pellets and palm kernel shells. Due to the fast shutdown capability, the short shutdown was chosen for more realistic results using this stove type. For cold start and long shutdown operation using wood pellets, the thermal efficiency is determined as 44.1% at a 1116 W power output by emitting 0.272 g CO and 17.2 mg PM 2.5 per MJd at high load. At low load, the efficiency is 38.0% at a 526 W power output by emitting 1.1 g CO and 45.1 mg PM 2.5 per MJd. Due to a misinterpretation of the standard, the burnout duration of the tests with long shutdown is approx. 1.5 min shorte... [more]
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