The overarching goal of process design (Figure 1) is to find technologically feasible, operable, economically attractive, safe and sustainable processing pathways and process configurations with specifications for the connectivity and design of unit operations that perform a set of tasks using selected functional materials (e.g., catalysts, solvents, sorbents, etc.) to convert a set of feed-stocks or raw materials into a set of products with desired quality at a scale that satisfies the demand. Process synthesis and integration can further screen, optimize and improve these pathways for given techno-econo-environmental targets or objectives. These objectives may include, but are not limited to, minimizing the overall investment and processing costs, minimizing the energy consumption, minimizing the emissions or wastes, maxim-zing the profit, and enhancing the safety, operability, controllability, flexibility, circularity, and sustainability, among others... (ABSTRACT ABBREVIATED)

This work explores the economic and environmental opportunities for sustainable aviation fuel (SAF) in the Brazilian sugarcane industry. Brazil was one of the first countries to use biomass fuels for transportation and is currently the 2nd largest producer of the world’s bioethanol. Bioethanol produced from sugarcane can be upgraded to SAF via the American Society for Testing and Materials (ASTM)-certified pathway alcohol-to-jet (ATJ); however, at least two challenges exist for commercial implementation. First, technologies to produce bio-jet fuels cost more than their conventional fossil-based counterparts. Second, there is considerable uncertainty regarding returns on investment as the sugar and ethanol markets have been historically volatile. As such, we propose a new optimization model to inform risk-conscious investment decisions on SAF production capacity in sugarcane mills. Specifically, we propose a linear program (LP) to model an integrated sugarcane mill that can produce suga... [more]

The food-energy-water nexus (FEWN) has been receiving increasing interest in the open literature as a framework to address the widening gap between natural resource availability and demand, towards more sustainable and cost-competitive solutions. The FEWN aims at holistically integrating the three interconnected subsystems of food, energy and water, into a single representative network. However, such an integration poses formidable challenges due to the complexity and multi-scale nature of the three subsystems and their respective interconnections. Additionally, the significant input data uncertainty and variability, such as energy prices and demands, or the evaluation of emerging technologies, contribute to the system’s inherent complexity. In this work, we revisit the FEWN problem in an attempt to elucidate and address in a systematic way issues related to its multi-scale complexity, uncertainty and variability. In particular, we provide a classification of the sources of data and te... [more]

Achieving worldwide sustainable development is a practical challenge that demands an efficient management of resources across their entire value chains. This practical task requires the optimal selection of pathways for extracting, processing, and transporting resources to meet the demands in different geographic regions at minimal economic cost and environmental impact. This work addresses the challenge by proposing a systematic framework for designing resource-processing networks that can be applied to resource management problems. The framework considers the integration and resource exchange within and across multiple processing clusters. It allows for the life cycle assessment of the environmental and economic impacts of the defined value chains, and design accordingly the different processing and transport systems from extraction to final use. The proposed representation and optimization model are demonstrated in a case study to assess the impact of energy transition under decarbo... [more]

Utilizing sustainable energy sources is crucial for expanding the range of solutions available to meet the growing energy demand and reducing reliance on environmentally damaging and depleting conventional fuels. Biosolids, a type of biomass, are generated as secondary effluent during wastewater treatment process in municipal and industrial sites. These solids possess the potential to serve as a sustainable energy source due to their richness of carbon. For an extended period, biosolids have been landfilled, even though it can be considered a wasteful use of a precious resource and a possible mean for contamination to the food supply chain. This has served as an extra impetus to investigate the potential for harnessing the capabilities of these substances. While many research studies have looked at different ways to put biomass waste to use, very little has been written on biosolids, especially those derived from industrial sources. This research assesses the feasibility of transformin... [more]

Biogas is often considered as a source of renewable energy, for heat and power production. However, biogas has greater promise as a source of concentrated CO2 in addition to methane, making it a rich supply of carbon and hydrogen for the generation of fuel and chemicals. In this work, we use the concept of attainable region in the enthalpy-Gibbs free energy space to identify opportunities for effective biogas valorization that maximizes the conversion of CO2. The AR concept allows us to study a chemical process without knowing the exact reaction mechanism that the species in the process use. Deriving Material Balance equations that relate a reactive process's output species to its input species is sufficient to identify process limits and explore opportunities to optimize its performance in terms of material, energy, and work. The conversion of biogas to valuable products is currently done in two steps; the high temperature and endothermic reformer step, followed by the low temperatur... [more]

In designing low-carbon processes, the unintended emission of CO2 remains a significant concern due to its global environmental impact. This paper explores carbon management within chemical processes, specifically examining the correlation between the process material balance (PMB) and CO2 emissions to understand and identify the potential for reducing these emissions. We interrogate the foundational issue of carbon discharge by analyzing the interplay among mass, energy, and entropy balances, which collectively influence the PMB. We introduce the concept of the Target Material Balance (TMB), which represents the material balance of a process corresponding to minimum CO2 emissions within the given constraints. We could ask what decisions in the design and operation of processes result in higher CO2 emissions than the TMB. We will focus on the interaction between reactions and recycles and how the arrangement of recycles in processes can inadvertently change the PMB, thereby increasing... [more]

This paper discusses the symbiotic relationship between technology research and development (R&D) and energy transition modeling. On the one hand, energy system modeling has a noteworthy history of providing macroscopic views and critical insights concerning the role that myriad technologies may play in the future energy system. On the other hand, R&D can lead to both incremental and disruptive technological advances that can shape energy transition planning. In this work, we focus on the bidirectional flow of information between the two with a particular focus on highlighting the potential role of carbon capture, storage, and sequestration technology.

Given the urgency to combat climate change and ensure environmental sustainability, this review examines the transition to net-zero emissions in chemical and process industries. It addresses the core areas of carbon emissions reduction, efficient energy use, and sustainable practices. What is new, however, is that it focuses on cutting-edge technologies such as biomass utilization, biotechnology applications, and waste management strategies that are key drivers of this transition. In particular, the study addresses the unique challenges faced by industries such as cement manufacturing and highlights the need for innovative solutions to effectively reduce their carbon footprint. In particular, the role of hydrogen as a clean fuel is at the heart of revolutionizing the chemical and process sectors, pointing the way to cleaner and greener operations. In addition, the manuscript explores the immense importance of the European Green Deal and the Sustainable Development Goals (SDGs) for the... [more]

Energy generation using microbial fuel cells (MFC) and removing toxic metal ions is a potentially exciting new field of study as it has recently attracted a lot of interest in the scientific community. However, MFC technology is facing several challenges, including electron production and transportation. Therefore, the present work focuses on enhancing electron generation by extracting sugarcane waste. MFC was successfully operated in a batch mode for 79 days in the presence of 250 mg/L Pb2+ and Hg2+ ions. Sugarcane extract was regularly fed to it without interruption. On day 38, the maximum current density and power density were recorded, which were 86.84 mA/m2 and 3.89 mW/m2, respectively. The electrochemical data show that a sufficient voltage generation and biofilm formation produce gradually. The specific capacitance was found to be 11 × 10−4 F/g on day 79, indicating the steady growth of biofilm. On the other hand, Pb2+ and Hg2+ removal efficiencies were found to be 82% and 74.85... [more]

Industrial manufacturing processes have evolved and improved since the disruption of the Industry 4.0 paradigm, while energy has progressively become a strategic resource required to maintain industrial competitiveness while maximizing quality and minimizing environmental impacts. In this context of global changes leading to social and economic impact in the short term and an unprecedented climate crisis, Digital Twins for Energy Efficiency in manufacturing processes provide companies with a tool to address this complex situation. Nevertheless, already existing Digital Twins applied for energy efficiency in a manufacturing process lack a flexible structure that easily replicates the real behavior of consuming machines while integrating it in complex upper-level environments. This paper presents a combined multi-paradigm approach to industrial process modeling developed and applied during the GENERTWIN project. The tool allows users to predict energy consumption and costs and, at the sa... [more]

It is quite essential to obtain an excellent CO2 adsorption capacity, CO2 adsorption selectivity and water vapor stability at the same time for practical CO2 capture after combustion. Through the combination of ultramicropore and the high density of CO2-philic sites without OMSs, an ultra-microporous Cu-based metal−organic framework has been designed and synthesized, featuring a high CO2 capacity (99 cm3 g−1 and 56.6 cm3 g−1 at 273 K and 298 K, respectively), high selectivity over N2 (118 at a scale of CO2/N2 15/85, 298 K) and excellent water vapor stability, simultaneously. Theoretical calculations indicate that neighboring ketonic O atoms with suitable distance play vital roles in boosting CO2 selective capture.

The increasing consumption of electrical and electronic equipment (EEE), correlated with the fast innovation pace in this field, generates a large amount of annual waste. The current established management practices cannot keep up with it, and the results are of increased significance given the negative effects on the environment and human health. Thus, the current study aimed to analyze the environmental impact of three different scenarios of waste electrical and electronic equipment (WEEE) management, following population awareness campaigns regarding its collection in the Municipality of Iasi, Romania. Data processing was carried out considering Life Cycle Assessment (LCA) methodology with the established functional unit for each scenario according to the collected amount. The results were quantified using the CML2001 and ReCiPe methods and showed that the highest environmental impact was obtained for scenario II (S2) (1.59 × 10−7 pers. equiv. using the CML2001 method and 32.7 pers.... [more]

Nowadays, the main challenge for industrial and municipal enterprises is related to the tightening regulations and recommendations regarding environmental protection, which have been included in the circular economy (CE) package. Enterprises from all sectors, including water and sewage management, are obliged to actively participate in the CE transition. Modern wastewater treatment plants (WWTPs) should include actions aimed at a more sustainable use of available resources (water, energy, raw materials) to contribute to the protection of natural resources. In this way, they can be treated as resource facilities. This paper proposes a conceptual framework for a ‘Wastewater Treatment Plant of the Future’ that includes several technological solutions that take into account circular management of waste streams generated in WWTPs, such as wastewater (WW), sewage sludge (SS) and sewage sludge ash (SSA). Many actions have been already taken to modernize and build WWTPs that can respond to cur... [more]

Energy has the most significant input to agricultural production. The EU’s effort to produce a carbon-neutral economic entity necessitates changes in the energy mix used for agricultural production. Therefore, we employ different variables, in particular, the emissions generated by energy sources, namely coal, natural gas, and diesel gas and their interlinkages with the GDP share generated from agriculture. The data are annual and refer to the period 1970−2020. The ARDL methodology is the econometric tool employed. The year 1990 is identified as a statistically significant break point for all variables, while for the cointegrating equation, the year 2009 appears to play a significant role. Emissions generated by coal appear to play a vital role in the GDP share generated by agriculture and, therefore, should be the main focus of the policy measures taken. Coal should be replaced by other renewable sources or the use of technologies by farmers that improve energy efficiency in order to... [more]

This paper addresses the conditions behind energy-related carbon dioxide (CO2) emissions in Poland following its accession to the European Union. The study analyzed some energy, fossil fuel, economic, and environmental indicators, such as energy use, CO2 emissions, driving factors, decoupling elasticity status, and decoupling effort status. It relied on the Kaya identity and Logarithmic Mean Divisia Index (LMDI) in determining the drivers of CO2 emissions. As shown by the results, between 2004 and 2020, energy consumption in Poland grew at an average annual rate of 0.8%, while fossil fuel carbon emissions declined at 0.7% per year. Energy intensity was found to be the key force behind the reduction in CO2 emissions, whereas rapid economic growth was the main driver of CO2 emissions. While other factors, i.e., carbon intensity, energy mix, and population, also contributed to reducing the emissions, they had a much smaller—if not marginal—effect. In turn, the decoupling elasticity analys... [more]

A new way is proposed to thermodynamically gauge the evolving complexity of nation-states and their growing cities. Energy rate density is a useful metric to track the evolution of energy budgets, which help facilitate how well or badly human society trends toward winning or losing. The fates of nations and their cities are unknown, their success is not assured. Those nations and cities with rising per-capita energy usage while developing and those that are nearly flat while already developed seem destined to endure; those with falling energy usage seem likely to fail. Globally, more energy, not less, and more energy rate density, too, will be needed in the 21st century. Conserving energy and efficiently using it are welcome since energy costs less when used less, but neither will likely help much to mitigate increasing energy demands. To survive, humanity nationally and internationally needs to culturally adapt to using more, clean, safe energy by embracing the Sun in an evolving Univ... [more]

A case study of solar collector outdoor test of the experimental technique conducted at Avadi, Chennai. To lower the temperature of solar PV panels, water, and water-based nanofluids were utilized concurrently. Higher cell temperatures restrict the effectiveness of solar PV systems since only a minor amount of power from the sun is gathered as electricity from the energy conversion, and the remaining energy is squandered as heat. The study aimed to develop and build a hybrid collector while also analyzing its electrical and thermal energy performance. The effort was invested in improving the system’s performance; the PVT collector was tested at volume concentrations of two, such as 0.5 and 1.0 L per minute (LPM). The PV/T collector determined thermal efficiency as highest was 48.38 percent and 54.03 percent, respectively, at 0.5 LPM and 1.0 LPM of volume flow rates. The PV/T collector’s highest electrical efficiency was 18.32 percent and 19.35 percent, respectively, for 0.5 LPM and 1.0... [more]

Perception towards nuclear energy is a vital factor determining the success or failure of nuclear projects. An online survey obtained attitudes toward nuclear energy, opinions on whether benefits of nuclear energy outweigh the risks, and views of using nuclear energy as an energy source. A total of 4318 participants from across the U.S. completed the survey. Logistic regression was used to predict perceptions of nuclear energy by participant demographics and geographical location. Participants living closest to Idaho National Laboratory (INL) were more likely to have positive attitudes towards nuclear energy (aOR: 7.18, p < 0.001), believe the benefits were greater than the risks (aOR: 4.90, p < 0.001), and have positive attitudes toward using nuclear energy as an electricity source (aOR: 5.70, p < 0.001), compared to people living farther from INL. Males and non-Hispanic white participants were more likely to have positive perceptions of nuclear energy. Developing and impleme... [more]

One of the most advanced systems of microbial fuel cells is the benthic microbial fuel cell (BMFC). Despite several developments, this strategy still has a number of significant flaws, such as instable organic substrate. Waste material (sugarcane) is used as a substrate in this work to address the organic substrate instability. The process was operated continuously for 70 days. A level of 300 mV was achieved after 33 days of operation, while the degradation efficiencies of Pb (II), Cd (II), and Cr (III) were more than 90%. More than 90% of the removed chemical oxygen demand (COD) was also recorded. The measured power density was 3.571 mW/m2 at 1000 external resistance with 458 internal resistance. This demonstrates that electrons are effectively transported throughout the operation. The Bacillus strains are the most dominant bacterial community on the surface of the anode. This research’s mechanism, which involves metal ion degradation, is also explained. Finally, parameter optimizatio... [more]

Auditing activity, in the last decade, is one of the most dynamically changing types of economic activity, on the one hand, due to an increase in the number of state projects implemented by many countries, and on the other hand, due to technological innovations and digitalization. Russian auditing practices are also being actively reformed. For example, the Ministry of Energy is updating their audit methodology. The subject of this study is to ensure the efficiency of spending public funds for the implementation of strategic projects. The object of this study is the methodology of a state audit. An analysis of the currently used Russian and international standards for public audits shows that there are many opportunities to improve the methodology for conducting financial, strategic and performance audits. First of all, there is a need to solve methodological problems in monitoring the efficiency of investment developments, since partnerships between private investors and government bo... [more]

The aim of this review was to analyze to what extent the relationship between corporate social responsibility (CSR), environment and energy has been addressed in the specialized literature and which are the deficient segments in this regard. VOSviewer was used for data extraction, mapping and grouping the articles from journals that have been indexed in Web of Science (WOS). A total of 102 papers were found approaching the topic of corporate social responsibility, environment and energy policy, 5192 research papers for CSR and the environment and 320 on CSR and energy policy. Following the bibliometric analysis, we can conclude that we are facing a shortage of works that analyze the relationship between the three fields together. The number of published articles was reduced to establish the direction of influence between the three variables, as well as the impact between them. However, the advantage that emerges from this lack of works is that there are many opportunities to find news... [more]

Energy security, as one of the most important components of state security, is a permanent element of academic debates and political discussions. Owing to the multidimensional and multifaceted nature of energy security, defining it is a complex process, requiring the consideration of a wide range of factors straddling economics, geology, ecology and geopolitics which decide whether we are dealing with the state of energy security or the lack of it. Energy security is usually equated with the security of supply. Another group of definitions of energy security focuses on the concept of security of services. A different approach to energy security issues is presented by energy exporting countries, whose objective is to ensure sufficiently high and stable income from sales of energy resource exports (security of demand). The subject of this paper is an analysis of the energy security of hydropower-producing countries—Tajikistan and Kyrgyzstan. Energy security has been analyzed in the conte... [more]

The development of emerging technologies not only has recently affected current industrial production but also has generated promising manufacturing opportunities that impact significantly on social and economic factors. Exploring upcoming renovation tendencies of technologies prematurely is essential for governments, research and development institutes, and industrial companies in managing strategies to achieve dominant advantages in business competitiveness. Additionally, the prospective changes, the scientific research directions, and the focus of technologies are crucial factors in predicting promising technologies. On the other hand, Industry 4.0 revolutionizes standards and models by accompanying significant technology developments in numerous sectors, including the sector of Smart energy. Moreover, asset performance management is always a prominent topic that has attained prevalence over the last decade because numerous challenges force all industrial companies to optimize their... [more]

This paper examines 16 years (2004−2019) of research on energy in eleven Central and Eastern European countries. The findings are based on an analysis of 3534 academic articles indexed in the Web of Knowledge database. The paper presents a systematic overview of the authorship, journal of publication, countries covered, and article content. The main conclusion is that the discussion is fragmented, because most of the journals (800 were identified) published only one paper on energy in the region. About one-fourth of the research was published in a handful of major journals. Male researchers dominated our dataset and there has been a visible increase in the average number of authors per article. The country most often covered by the research was Poland and energy efficiency was the most-discussed issue and renewables the most-frequently researched energy source. Surprisingly, nuclear energy and energy security, considered to be the dominant features of the CEE region energy picture, wer... [more]