In response to the global imperative to address climate change, this research focuses on enhancing the transparency and efficiency of the Carbon Capture Utilization and Storage (CCUS) supply chain under carbon tax. We propose a decision-making framework that integrates the CCUS supply chain's optimization model, emphasizing carbon tax policies, with a blockchain network. Smart contracts play a pivotal role in automating the exchange and utilization of carbon emissions, enhancing the digitalization of the CCUS supply chain from source to sink. This automation facilitates seamless matching of carbon sources with sinks, efficient transfer of emissions and funds besides record-keeping of transactions. Consequently, it improves the monitoring, reporting, and verification processes within the CCUS framework, thereby simplifying compliance with regulatory mandates for net emission reductions and carbon taxation policies. By eliminating reliance on third-party verifiers, our blockchain-based... [more]

Inspired by Nature, we propose that synergies between biorefinery and mineral refinery can be exploited so that at least a part of the carbon is captured before being released to the atmosphere. In doing so, carbon is captured not only from CO2 but also from biomass and developing more such processes may be the cornerstone for controlling CO2 emissions. A comparison of circular economy in traditional biorefineries and bio-mineral refineries is done by using general chemical formulas and it is shown that the bio-mineral refinery captures carbon. In this work, we have shown that Serpentine may be used to partially neutralise biomass pyrolysis oil. The extracted oil may be used as feedstock to produce downstream chemicals and further studies are required to produce the same.

There is a need to drastically reduce greenhouse gas emissions. While significant progress has been made in electrifying transport, heavy duty transportation and aviation are not likely to be capable of electrification in the near term, spurring significant research into biofuels. When coupled with carbon capture and storage, biofuels can achieve net-negative greenhouse gas emissions via many different conversion technologies such as fermentation, pyrolysis, or gasification to produce ethanol, gasoline, diesel, or jet fuel. However, each pathway has a different efficiency, capital and operating costs, and potential for carbon capture, making the optimal pathway dependent on policy and spatial factors. We use the Integrated Markal-EFOM System model applied to the USA, adding a rich suite of biofuel and carbon capture technologies, region-specific CO2 transportation and injection costs, and government incentives from the Inflation Reduction Act. We find that under current government ince... [more]

This paper discusses the symbiotic relationship between technology research and development (R&D) and energy transition modeling. On the one hand, energy system modeling has a noteworthy history of providing macroscopic views and critical insights concerning the role that myriad technologies may play in the future energy system. On the other hand, R&D can lead to both incremental and disruptive technological advances that can shape energy transition planning. In this work, we focus on the bidirectional flow of information between the two with a particular focus on highlighting the potential role of carbon capture, storage, and sequestration technology.

Biomass, a basic product of agriculture, is one of the main sinks of carbon in global cycle. Additionally, it can be used as a renewable source of energy, leading to depletion in CO2 emissions. The paper presents the results of estimations on the current and potential share of catch crop cultivation in climate change mitigation, in Poland, where the agricultural sector plays a significant economic role. The estimation of CO2 assimilation in biomass was performed on the basis of our own data on yields of commonly used catch crops, obtained in randomly selected 80 farms in Poland, and the content of carbon in the biomass. Calculation of energy potential of the biomass was conducted, assuming its conversion into biogas, on the basis of our own data on catch crop yields and the literature data on their biomethane potentials. The results have shown that catch crops in Poland, which are cultivated to an area of 1.177 mln ha sequestrate 6.85 mln t CO2 yr−1. However, considering the total area... [more]

The effect of supercritical CO2 on the shaly caprocks is one of the critical issues to be considered in CO2 sequestration programs. Shale-scCO2 interactions can alter the seal integrity, leading to environmental problems and bringing into question the effectiveness of the program altogether. Several analytical studies were conducted on samples from Jurassic Eneabba Basal Shale and claystone rich facies of the Triassic Yalgorup Member (725−1417 m) in the Harvey CO2 sequestration site, Western Australia, to address the shale-scCO2 interactions and their effect on the petrophysical properties of the caprock. Shale samples saturated with NaCl brine were exposed to scCO2 under the reservoir condition (T = 60 °C, P = 2000 psi) for nine months and then tested to determine their altered mineralogical, petrophysical and geochemical properties. The experimental study examined changes to the mineralogical composition, capillary threshold pressure, and pore size distribution (PSD) of samples. The... [more]

Shale oil and gas resources contribute significantly to the energy production in the U.S. Greenhouse gas emissions come from combustion of fossil fuels from potential sources of power plants, oil refineries, and flaring or venting of produced gas (primarily methane) in oilfields. Economic utilization of greenhouse gases in shale reservoirs not only increases oil or gas recovery, but also contributes to CO2 sequestration. In this paper, the feasibility and efficiency of gas injection approaches, including huff-n-puff injection and gas flooding in shale oil/gas/condensate reservoirs are discussed based on the results of in-situ pilots, and experimental and simulation studies. In each section, one type of shale reservoir is discussed, with the following aspects covered: (1) Experimental and simulation results for different gas injection approaches; (2) mechanisms of different gas injection approaches; and (3) field pilots for gas injection enhanced oil recovery (EOR) and enhanced gas reco... [more]

Example Aspen Plus chemical process simulations used in the book Exergy Tables: A Comprehensive Set of Exergy Values to Streamline Energy Efficiency Analysis, by Lingyan Deng, Thomas A. Adams II, and Truls Gundersen (McGraw-Hill Education, 2023). The examples are:

1. Medium-pressure steam generation using a natural-gas powered boiler
2. Medium-pressure steam generation using a natural-gas powered boiler with an economizer
3. Medium-pressure steam generation using an off-gas powered boiler
4. Postcombustion CO2 capture using diglycolamine (DGA) with CCS

Note, stream conditions may vary slightly from those in the book when simulated with different versions of the software.

Files are Aspen Plus v12.1, but should be openable on any version 12.1 or later.

We conducted a meta-study of CO2 capture processes, examining nearly 100 techno-economic analyses published in the recent open literature. Normally, it is difficult to compare one study to another because each study uses its own set of assumptions, such as plant scale, geography, market parameters, and inconsistent definitions of key metrics such as the cost of CO2 avoided (CCA). In this work, we present normalized versions of these studies using a consistent basis of comparison, such as net power delivered, base year of operation, pipeline CO2 pressure, currency, country of construction, and so on. In so doing, we are able to draw meaningful conclusions and direct comparisons between different classes of CO2 capture technology. The technologies considered include coal and gas-based processes using capture strategies including solvent-based post-combustion carbon capture, gasification-based strategies, membrane-based approaches, oxyfuel combustion, chemical looping combustion, calcium... [more]

This work is a meta-study of CO2 capture processes for coal and natural gas power generation, including technologies such as post-combustion solvent-based carbon capture, the integrated gasification combined cycle process, oxyfuel combustion, membrane-based carbon capture processes, and solid oxide fuel cells. A literature survey of recent techno-economic studies was conducted, compiling relevant data on costs, efficiencies, and other performance metrics. The data were then converted in a consistent fashion to a common standard (such as a consistent net power output, country of construction, currency, base year of operation, and captured CO2 pressure) such that a meaningful and direct comparison of technologies can be made. The processes were compared against a standard status quo power plant without carbon capture to compute metrics such as cost of CO2 emissions avoided to identify the most promising designs and technologies to use for CO2 emissions abatement.