The climate crisis and dependence on fossil fuels make the transition to renewable energy sources imperative, with biomass standing out for promoting decarbonization and circular economy. In this context, fluidized bed gasification emerges as an efficient route for converting waste into syngas, applicable to power and hydrogen generation. Given the variability of real operating conditions, dynamic models are essential to represent coupled fluid dynamic, thermal, and kinetic phenomena over time. In this work, a dynamic phenomenological model was developed using a lumped 0D ap-proach, in which the reactor is divided into two interacting zones represented as continuous stirred-tank reactors (CSTRs): a dense bed, where drying, devolatilization, and heterogeneous re-actions occur, and a freeboard, dominated by homogeneous gas-phase reactions. The model was validated against experimental data from a bubbling fluidized bed gasifier, showing good agree-ment for major syngas species (CO and H₂,... [more]

In this work, we propose a process to reduce CO2 emissions through its capture and utilization (CCU) as a raw material for producing valuable products in the chemical industry. As a case study, we design and evaluate the economic and environmental performances of a direct dimethyl ether (DME) synthesis from syngas plant reusing CO2 as a raw material. The decision making is carried out including all the design variables into a flowsheet superstructure, which is simulated and optimized to maximize the process profit. The optimum production of DME is 219.95 kt/year at 99.95% purity, with a profit of $51.01 million/year and emitting 0.784 kg CO2-eq/kg DME produced. After heat integration implementation, the profit is raised to $58.68 million/year and emissions are reduced to 0.510 kg CO2-eq/kg DME, being the latter a 61.4% lower than the one associated to the classic DME production. The financial risk associated with the post heat integration process is at 15.4%, while considering a 5% ris... [more]

Simulation plays a crucial role in the design and optimization of gasifiers by providing a detailed understanding of the involved physical processes and complex chemical reactions without the need for extensive trial-and-error experiments. It can also serve as a valuable tool for identifying potential technical issues in experimental devices that operate below expected performance. This study presents a comprehensive simulation of biomass gasification using the open-source software DWSIM. The simulated results were compared with experimental data from a pilot-scale spouted bed reactor, featuring a square-based design with a 20 kWth capacity, using pruning of apple tress as feedstock. Experimental results revealed that the reactor operated effectively at temperatures exceeding 850°C, maintaining stable conditions across a wide range of equivalence ratios. However, the distribution of products—particularly hydrogen (H2)—did not match expected results based on both literature and simulati... [more]

This study evaluated the air/steam co-gasification of crude glycerol (CG) and linear low density polyethylene (LLDPE). It was demonstrated that operating the process using air or a mixture of air and steam has significant implications for carbon conversion efficiency (CCE), cold gas efficiency (CGE), lower heating value (LHV) gasifier output temperature and syngas concentration. The CCE reached a maximum value of 100% at equivalence ratio (ER) of 0.3 for 25% LLDPE and an ER of 0.35 for 75% LLDPE when air was used. When steam was introduced in the gasifier at a fixed rate (SFR =0.5), the CCE of 100% was maximised at ER of 0.25 for 25% LLDPE and 0.3 for 75% LLDPE content. An increase in the steam to feedstock ratio (SFR) did not alter the CCE for 25% LLDPE at a constant ER, but for that of 75% LLDPE, a CCE was maximized at an SFR of 0.25. In the case of CGE, a maximum value of 79.24% and 78.12% was reached at ER of 0.3 and 0.35 for 25% LLDPE and 75% LLDPE respectively when pure air was u... [more]

The overarching goal of limiting the increase in global temperature to = 2.0° C likely requires both decarbonization and defossilization efforts. Direct air capture (DAC) and CO2 electrolysis stand out as promising technologies for capturing and utilizing atmospheric CO2. In this effort, we explore the details of designing and operating an integrated DAC-electrolysis process by examining some key parameters for economic feasibility. We evaluate the gross profit and net income to find the most appropriate capacity factor, average electricity price, syngas sale price, and CO2 taxes. Additionally, we study an optimistic scenario of CO2 electrolysis and perform a sensitivity analysis of the CO2 capture price to elucidate the impact of design decisions on the economic feasibility. Our findings underscore the necessity of design improvements of the CO2 electrolysis and DAC processes to achieve reasonable capacity factor and average electricity price limits. Notably, CO2 taxes and tax credits... [more]

Utilizing syngas components CO, CO2, and H2 to produce fatty acids and alcohols offers a sustainable approach for biofuels and chemicals, reducing the global carbon footprint. The development of robust strains, especially for higher alcohol titers in C4 and C6 compounds, and the creation of cost-effective media are crucial. This study compared syngas fermentation capabilities of three novel strains (Clostridium carboxidivorans P20, C. ljungdahlii P14, and C. muellerianum P21) with existing strains (C. ragsdalei P11 and C. carboxidivorans P7) in three medium formulations. Fermentations in 250-mL bottles were conducted at 37 °C using H2:CO2:CO (30:30:40) using P11, P7, and corn steep liquor (CSL) media. Results showed that P11 and CSL media facilitated higher cell mass, alcohol titer, and gas conversion compared to the P7 medium. Strains P7, P14, and P20 formed 1.4- to 4-fold more total alcohols in the CSL medium in comparison with the P7 medium. Further, strain P21 produced more butanol... [more]

Global population growth requires the use of various natural resources to satisfy the basic needs of humanity. Fossil fuels are mainly used to produce electricity, transportation and the artificial air conditioning of habitats. Nevertheless, countries around the world are looking for alternative energy sources due to the decrease in the availability of these fuels and their high environmental impact. The mixture of hydrogen and carbon monoxide (H2 + CO), commonly called syngas, is a high-value feedstock for various industrial applications. By varying the composition of syngas, especially the H2/CO molar ratio, it can be used to produce methanol, fuels or synthetic natural gas. However, when this ratio is very low, the separation of this gas usually represents a great problem when making the energy balance, which is why it is proposed to adapt a combustion process in chemical cycles, taking advantage of the energy of this gas, reducing the energy impact of the process. During the presen... [more]

The overarching goal of limiting the increase in global temperature to ≤ 2.0˚ C likely requires both decarbonization and defossilization efforts. Direct air capture (DAC) and CO2 electrolysis stand out as promising technologies for capturing and utilizing atmospheric CO2. In this effort, we explore the details of designing and operating an integrated DAC-electrolysis process by examining some key parameters for economic feasibility. We evaluate the gross profit and net income to find the most appropriate capacity factor, average electricity price, syngas sale price, and CO2 taxes. Additionally, we study an optimistic scenario of CO2 electrolysis and perform a sensitivity analysis of the CO2 capture price to elucidate the impact of design decisions on the economic feasibility. Our findings underscore the necessity of design improvements of the CO2 electrolysis and DAC processes to achieve reasonable capacity factor and average electricity price limits. Notably, CO2 taxes and tax credits... [more]

A new approach to preparing a series of Co/Sm2O3 catalysts for hydrogen production by the dry reforming of methane has been developed. The catalyst precursors were synthesized with a simple method, including the evaporation of aqueous solutions of cobalt and samarium nitrates, followed by a short-term calcination of the resulting material. The as-prepared and spent catalysts were characterized using X-ray diffraction, scanning electron microscopy, transmission electron microscopy, temperature-programmed reduction, and thermogravimetric analysis. The content of cobalt in the synthesized materials affects their phase composition and carbonization resistance in the dry reforming of the methane reaction. It has been shown that preheating in N2 atmosphere produces catalysts that provide a stable yield of hydrogen and CO of 94−98% for at least 50 h at 900 °C. These yields are among the highest currently available for the dry reforming of methane catalysts made from Co-Sm complex oxides. It h... [more]

Chemical looping gasification (CLG) is an effective coal utilization technology. In this work, the CLG of bituminite was investigated through fixed-bed batch experiments using NiFe2O4 oxygen carrier (OC) to achieve high-quality syngas. The changes in the phase of the oxygen carrier during the chemical looping reaction and the reaction mechanism were explored. The results show that elevated temperature and adding a fraction of steam facilitate the gasification reaction. Adding an appropriate amount of ZrO2 into the NiFe2O4 and modification with alkali metal can enhance the performance of the oxygen carrier. A carbon conversion of 95% and a syngas (CO and H2) selectivity of 86% were obtained under the optimized reaction conditions of 950 °C, an oxygen-carrier-to-bituminite (O/B) ratio of 7:3, a NiFe2O4/ZrO2 ratio of 7:3, and a steam rate of 0.08 mL/min. Modification of the NiFe2O4 by doping alkali metal can significantly facilitate the CLG process. Alkali lignin ash has a more pronounced... [more]

An experimental study of the ignition and combustion processes of coal-water slurry (CWS) droplets based on coal enrichment waste in a high-temperature oxidizer at 650−850 °C with a syngas addition was carried out. The fuel slurry was a mixture of finely dispersed solid combustible particles (coal sludge, 10−100 µm in size) and water. The syngas was a product of biomass pyrolysis and two waste-derived fuels in a laboratory gasifier. Composition of the syngas was controlled by a precision analytical gas analyzer. The feasibility of co-firing CWS with syngas was experimentally established. Under such conditions, the CWS droplets ignition process was intensified by 15−40%, compared to fuel combustion without the addition of syngas to the combustion chamber. The greatest positive effect was achieved by adding the gas obtained during the biomass pyrolysis. The ignition delay times of CWS droplets are 5.2−12.5 s versus 6.1−20.4 s (lower by 15−39%) when ignited in a high-temperature medium wi... [more]

The underground coal gasification (UCG) represents an effective coal mining technology, where coal is transformed into syngas underground. Extracted syngas is cleaned and processed for energy production. Various gasification agents can be injected into an underground georeactor, e.g., air, technical oxygen, or water steam, to ensure necessary temperature and produce syngas with the highest possible calorific value. This paper presents an experimental study where dynamic optimization of operating variables maximizes syngas calorific value during gasification. Several experiments performed on an ex situ reactor show that the optimization algorithm increased syngas calorific value. Three operation variables, i.e., airflow, oxygen flow, and syngas exhaust, were continually optimized by an algorithm of gradient method. By optimizing the manipulation variables, the calorific value of the syngas was increased by 5 MJ/m3, both in gasification with air and additional oxygen. Furthermore, a high... [more]

The development of a one-dimensional (1D) phenomenological model for biomass gasification in downdraft reactors is presented in this study; the model was developed with the aim of highlighting the main advantages and limits related to feedstocks that are different from woodchip, such as hydro-char derived from the hydrothermal carbonization of green waste, or a mix of olive pomace and sawdust. An experimental validation of the model is performed. The numerically evaluated temperature evolution along the reactor gasifier is found to be in agreement with locally measured values for all the considered biomasses. The model captures the pressure drop along the reactor axis, despite an underestimation with respect to the performed measurements. The producer gas composition resulting from the numerical model at the exit section is in quite good agreement with gas-chromatograph analyses (12% maximum error for CO and CO2 species), although the model predicts lower methane and hydrogen content i... [more]

Due to increasing demand for clean and green energy, a need exists for fuels with low emissions, such as synthetic gas (syngas), which exhibits excellent combustion properties and has demonstrated promise in low-emission energy production, especially at microscales. However, due to complicated flame properties in microscale systems, it is of utmost importance to describe syngas combustion and comprehend its properties with respect to its boundary and inlet conditions, and its geometric characteristics. The present work studied premixed syngas combustion in a two-dimensional channel, with a length of 20 mm and a half-width of 1 mm, using computational approaches. Specifically, a fixed temperature gradient was imposed at the upper wall, from 300 K at the inlet to 1500 K at the outlet, to preheat the mixture, accounting for the conjugate heat transfer through the walls. The detailed chemistry of the ignition process was imitated using the San Diego mechanism involving 46 species and 235 r... [more]

Power generation units based on the bio-syngas system face two main challenges due to (i) the possible temporary shortage of primary sources and (ii) the engine power derating associated with the use of low-energy density fuels in combustion engines. In both cases, an external input fuel is provided. Hence, complementing syngas with traditional fuels, like natural gas, becomes a necessity. In this work, an experimental methodology is proposed, aiming at the quantification of the impact of the use of both natural gas and syngas in spark ignition (SI) engines on performance and emissions. The main research questions focus on investigating brake thermal efficiency (BTE), power derating, and pollutant emission (NOx, CO, THC, CO2) formation, offering quantitative findings that present the basis for engine optimization procedures. Experimental measurements were performed on a Toyota 4Y-E engine (a 4-cylinders, 4-stroke spark ignition engine) at partial load (10 kW) under different syngas ene... [more]

Co/TiO2−MgAl2O4 was investigated in a fixed bed reactor for the dry reforming of methane (DRM) process. Co/TiO2−MgAl2O4 was prepared by modified co-precipitation, followed by the hydrothermal method. The active metal Co was loaded via the wetness impregnation method. The prepared catalyst was characterized by XRD, SEM, TGA, and FTIR. The performance of Co/TiO2−MgAl2O4 for the DRM process was investigated in a reactor with a temperature of 750 °C, a feed ratio (CO2/CH4) of 1, a catalyst loading of 0.5 g, and a feed flow rate of 20 mL min−1. The effect of support interaction with metal and the composite were studied for catalytic activity, the composite showing significantly improved results. Moreover, among the tested Co loadings, 5 wt% Co over the TiO2−MgAl2O4 composite shows the best catalytic performance. The 5%Co/TiO2−MgAl2O4 improved the CH4 and CO2 conversion by up to 70% and 80%, respectively, while the selectivity of H2 and CO improved to 43% and 46.5%, respectively. The achieve... [more]

The development of a selective and efficient catalyst for CO2 electroreduction is a great challenge in CO2 storage and conversion research. Silver metal is an attractive alternative due to its enhanced catalytic performance of CO2 electroreduction to CO. Here, we prepared Ag nanowires anchored on carbon support as an excellent electrocatalyst with remarkably high selectivity for the CO2 reduction to CO. The CO Faradic efficiency was approximately 100%. The enhanced catalytic performances may be ascribed to dense active sites exposed on the Ag nanowires’ high specific surface area, by the uniform dispersion of Ag nanowires on the carbon support. Our research demonstrates that Ag nanowires supported on carbon have potential as promising catalysts in CO2 electroreduction.

This study optimizes pyrolysis conditions that will maximize energy recovery from the Beauty Leaf Tree (BLT; Calophyllum inophyllum L.) oil seed press cake. Response surface methodology (RSM) was used to determine the behavior of pyrolysis coproducts (solid, liquid and gas) at various temperatures and residence times. One significant discovery was that 61.7% of the energy (of the whole BLT oil seed) was still retained in the BLT oil seed cake after oil extraction. Controlled pyrolysis produced various proportions of biochar, bio-oil and syngas coproducts. Predictive models were developed to estimate both the mass and energy yields of the coproducts. In all experimental runs, the biochar component had the highest mass yield and energy content. Biochar mass yields were high at the lowest operating temperature used, but the energy yields based on a high heating value (HHV) of products were optimal at higher operating temperatures. From the RSM models, energy from the biochar is optimized... [more]

The underground coal gasification (UCG) process represents a modern and effective coal mining technology that enables coal energy extraction through thermic decomposition. The coal is transformed into syngas by oxidizers (e.g., air, technical oxygen, or water steam) and is injected into a georeactor. The produced syngas is exhausted on the surface, where it is transformed into the desired form of energy. This paper presents an experimental study of two experiments performed in ex-situ reactors. The paper describes the equipment for the UCG process, the physical models of the coal seam, and the analysis of coal. The obtained results from the experiments are presented as the behavior of the temperatures in the coal during the experiment, the syngas composition, and its calorific value. The material balance and effective gasification time of the UCG process were also identified for the individual experiments. The aim was to evaluate the impact of the coal seam model on the gasification pr... [more]

The article presents an experimental laboratory setup used for the empirical determination of the gasification of coal samples in the form of solid rock, cut out in the form of a cylinder. An experimental laboratory set enabled a series of experiments carried out at 700 °C with steam as the gasification agent. The samples were prepared from the coal seam, the use of which can be planned in future underground and ground gasification experiments. The result of the conducted coal gasification process, using steam as the gasification agent, was the syngas, including hydrogen (H2) with a concentration between 46% and 58%, carbon dioxide (CO2) with a concentration between 13% and 17%, carbon monoxide (CO) with a concentration between 7% and 11.5%, and methane(CH4) with a concentration between 9.6% and 20.1%.The results from the ex-situ experiments were compared with the results of numerical simulations using computational fluid dynamics (CFD) methods. A three-dimensional numerical model for... [more]

This paper addresses the solar thermochemical conversion of biomass or waste feedstocks based on pyro-gasification for the clean production of high-value and energy-intensive fuels. The utilization of solar energy for supplying the required process heat is attractive to lower the dependence of gasification processes on conventional energy resources and to reduce emissions of CO2 and other pollutants for the production of high-value chemical synthetic fuels (syngas). Using concentrated solar energy to drive the endothermal reactions further allows producing more syngas with a higher gas quality, since it has not been contaminated by combustion products, while saving biomass resources. The solar-driven process is thus a sustainable and promising alternative route, enabling syngas yield enhancement and CO2 mitigation, thereby potentially outperforming the performance of conventional processes for syngas production. This review presents relevant research studies in the field and provides t... [more]

The main purpose of the present work was to evaluate the efficiency of the gasification process of three different types of agro-forest biomass residue (rapeseed, softwood, and sunflower husks) along with the characterization of size-segregated particulates’ emissions. The experiments were carried out in a drop tube furnace (DTF), using two different gasifying agents (O2/N2 and O2/N2/CO2) at atmospheric pressure and a constant temperature of 1000 °C. In focus was the effect of biomass and the gasifying agent on syngas composition (CO, H2, CH4, and CO2), cold gas and carbon conversion efficiency, and on the emissions of by-products, such as particulate matter (PM), known for having negative environmental and health impacts. The collected particulates were characterized by SEM/EDS and XPS analysis. The results reveal that: (i) the introduction of CO2 increased the production of CO and CH4 and syngas’ lower heating value (LHV), thus leading to higher cold gas and carbon conversion efficie... [more]

Solar thermochemical gasification is a promising solution for the clean production of low-emission synthetic fuels. It offers the possibility to upgrade various biomasses and waste feedstocks and further provides an efficient way to sustainably store solar energy into high-value and energy-intensive chemical fuels. In this work, a novel continuously-fed solar steam gasifier was studied using beechwood and solid recovered fuels (SRF) particles. Solar-only and hybrid solar/autothermal gasification experiments were performed at high temperatures to assess the performance of the reactor and its flexibility in converting various types of feedstocks. The hybrid operation was considered to increase the solar reactor temperature when the solar power input is not sufficient thanks to partial feedstock oxy-combustion. The hybrid solar process is thus a sustainable alternative option outperforming the conventional gasification processes for syngas production. Wood and waste particles solar conver... [more]

Biomass from cup plant (Silphium perfoliatum L.) is considered a renewable energy source that can be converted into alternative fuel. Calorific syngas, a promising type of advanced fuel, can be produced through thermochemical biomass gasification. In this study, the suitability of cup plant biomass for gasification was assessed, including the process energy balance and environmental impacts of waste from syngas purification. Silphium perfoliatum L. was cultivated as a gasification feedstock in different conditions (irrigation, fertilization). The experiments were performed in a membrane gasifier. All obtained energy parameters were compared to the biomass yield per hectare. The toxic effects of liquid waste were assessed using tests analyzing germination/seed root elongation of Sinapsis alba. Leachates collected from condensation tanks of a gas generator were introduced to soil at the following doses: 100, 1000 and 10,000 mg kg−1 DM of soil. The usefulness of Silphium perfoliatum L. fo... [more]

In recent years, the use of alternative fuels in thermal engine power plants has gained more and more attention, becoming of paramount importance to overcome the use of fuels from fossil sources and to reduce polluting emissions. The present work deals with the analysis of the response to two different gas fuels—i.e., hydrogen and a syngas from agriculture product—of a 30 kW micro gas turbine integrated with a solar field. The solar field included a thermal storage system to partially cover loading requests during night hours, reducing fuel demand. Additionally, a Heat Recovery Unit was included in the plant considered and the whole plant was simulated by Thermoflex® code. Thermodynamics analysis was performed on hour-to-hour basis, for a given day as well as for 12 months; subsequently, an evaluation of cogeneration efficiency as well as energy saving was made. The results are compared against plant performance achieved with conventional natural gas fueling. After analyzing the perfor... [more]