Ghana suffers from frequent power outages, which can be compensated by off-grid energy solutions. Photovoltaic-hybrid systems become more and more important for rural electrification due to their potential to offer a clean and cost-effective energy supply. However, uncertainties related to the prediction of electrical loads and solar irradiance result in inefficient system control and can lead to an unstable electricity supply, which is vital for the high reliability required for applications within the health sector. Model predictive control (MPC) algorithms present a viable option to tackle those uncertainties compared to rule-based methods, but strongly rely on the quality of the forecasts. This study tests and evaluates (a) a seasonal autoregressive integrated moving average (SARIMA) algorithm, (b) an incremental linear regression (ILR) algorithm, (c) a long short-term memory (LSTM) model, and (d) a customized statistical approach for electrical load forecasting on real load data o... [more]

This is a review of the concepts of purpose, direction, and objective in the discipline of thermodynamics, which is a pillar of physics, natural sciences, life science, and engineering science. Reviewed is the relentless evolution of this discipline toward accounting for evolutionary design with direction, and for establishing the concept of purpose in methodologies of modeling, analysis, teaching, and design optimization. Evolution is change after change toward flow access, with direction in time, and purpose. Evolution does not have an ‘end’. In thermodynamics, purpose is already the defining feature of methods that have emerged to guide and facilitate the generation, distribution, and use of motive power, heating, and cooling: thermodynamic optimization, exergy-based methods (i.e., exergetic, exergoeconomic, and exergoenvironmental analysis), entropy generation minimization, extended exergy, environomics, thermoecology, finite time thermodynamics, pinch analysis, animal design, geop... [more]

Electron transfer dynamics in dye sensitized solar cells (DSSCs) employing triphenylamine Y123 dye were investigated by means of femtosecond broadband transient absorption spectroscopy in the visible and mid-IR range of detection. The electron injection process to the titania conduction band was found to appear biphasically with the time constant of the first component within 350 fs and that of the second component between 80 and 95 ps. Subsequently, the effects of continuous irradiation on the ultrafast and fast electron transfer processes were studied in the systems comprising Y123 dye or carbazole MK2 dye in combination with cobalt- or copper-based redox mediators: [Co(bpy)3](B(CN)4)2/3 (bpy = 2,2′-bipyridine) or [Cu(tmby)2](TFSI)1/2 (tmby = 4,4′,6,6′ tetramethyl-2,2′-bipyridine, TFSI = bis(trifluoromethane)sulfonamide). We have found that the steady-state illumination led to acceleration of the electron injection process due to the lowering of titania conduction band edge energy. M... [more]

Influence of wastes generated during juice production: apple, carrot and red beet, added to barley straw, on density of pellet mass, pellet hardness, ash content and calorific value was assessed. Dry mass content of additives in the substrate to pellet production was: 0, 10, 20 and 30% of the mixture weight. The relative humidity of the raw material was: 17.0, 19.5 and 22%. Higher percentages of additives and higher moisture content in the raw materials increased the hardness and density of the pellet. The contents of natural polymers such as lignin, hemicellulose and cellulose were determined in primary materials used to prepare substrate and in pellet. Changes in the determination of these substances was observed as a result of the granulation process.

Usually, slaughterhouse wastewater has been considered as a single substrate whose anaerobic digestion can lead to inhibition problems and low biodegradability. However, the bovine slaughter process generates different wastewater streams with particular physicochemical characteristics: slaughter wastewater (SWW), offal wastewater (OWW) and paunch wastewater (PWW). Therefore, this research aims to assess the anaerobic co-digestion (AcoD) of SWW, OWW, PWW and bovine manure (BM) through biochemical methane potential tests in order to reduce inhibition risk and increase biodegradability. A model-based methodology was developed to assess the synergistic effects considering CH4 yield and kinetics simultaneously. The AcoD of PWW and BM with OWW and SWW enhanced the extent of degradation (0.64−0.77) above both PWW (0.34) and BM (0.46) mono-digestion. SWW Mono-digestion showed inhibition risk by NH3, which was reduced by AcoD with PWW and OWW. The combination of low CH4 potential streams (PWW a... [more]

Currently, high-performance power conversion requirements are of increasing interest in microgrid applications. In fact, isolated bidirectional dc-dc converters are widely used in modern dc distribution systems. The dual active bridge (DAB) dc-dc converter is identified as one of the most promising converter topology for the mentioned applications, due to its benefits of high power density, electrical isolation, bidirectional power flow, zero-voltage switching, and symmetrical structure. This study presents a power management control scheme in order to ensure the power balance of a dc microgrid in stand-alone operation, where the renewable energy source (RES) and the battery energy storage (BES) unit are interfaced by DAB converters. The power management algorithm, as introduced in this work, selects the proper operation of the RES system and BES system, based on load/generation power and state-of-charge of the battery conditions. Moreover, a nonlinear robust control strategy is propos... [more]

In this research, optimization of the integrated biodiesel production process composed of transesterification of edible sunflower oil, catalyzed by commercial lipase, with simultaneous extraction of glycerol from the reaction mixture was performed. Deep eutectic solvents (DESs) were used in this integrated process as the reaction and extraction media. For two systems, choline chloride:glycerol (ChCl:Gly) and choline chloride:ethylene glycol (ChCl:EG), respectively, the optimal water content, mass ratio of the phase containing the mixture of reactants (oil and methanol) with an enzyme and a DES phase (mass ratio of phases), and the molar ratio of deep eutectic solvent constituents were determined using response surface methodology (RSM). Experiments performed with ChCl:Gly resulted in a higher biodiesel yield and higher glycerol extraction efficiency, namely, a mass ratio of phases of 1:1, a mass fraction of water of 6.6%, and a molar ratio of the ChCl:Gly of 1:3.5 were determined to be... [more]

The article presents a method of forecasting the deformation of the land surface over large fields of underground gas storage facilities located in salt caverns. The solution allows for taking into account many parameters characterising the operation of underground gas storage facilities, such as cavern processes (leaching, enlargement, operational, etc.), their depth, distribution, diameter, shape, and many others. The advantage of the applied method over other available options is the possibility of using it for large fields of caverns while keeping the calculations simple. The effectiveness of the method has been proven for predicted surface subsidence for the EPE field with 114 underground caverns. The hypothesis was compared with the measurement outcomes.

Using aerodynamic resistance to provide braking force for trains is an economical braking method. It has few components to wear out and requires no energy. But the aerodynamic braking plate will significantly affect train’s aerodynamics behaviors. This paper studies the effect of the braking plates’ layout on the aerodynamic force of head car when a train is running under a crosswind. The results show that the braking plate will not only increase the drag force, but also significantly affect the lift and lateral force of the train’s head car. The installation position of the braking plates will also have a great effect on the aerodynamic force. In order to increase the drag force and weaken other aerodynamic force changes of the head car, we suggest that the first braking plate be arranged at the end of a streamlined shape, and the second braking plate be arranged at the middle of the car body. Compared with trains without braking plates, the head car’s drag force increases by 85.7%, l... [more]

Finding a way for mitigating climate change is one of the main challenges of our generation. Sorption-enhanced gasification (SEG) is a process by which syngas as an important intermediate for the synthesis of e.g., dimethyl ether (DME), bio-synthetic natural gas (SNG) and Fischer−Tropsch (FT) products or hydrogen can be produced by using biomass as feedstock. It can, therefore, contribute to a replacement for fossil fuels to reduce greenhouse gas (GHG) emissions. SEG is an indirect gasification process that is operated in a dual-fluidized bed (DFB) reactor. By the use of a CO2-active sorbent as bed material, CO2 that is produced during gasification is directly captured. The resulting enhancement of the water−gas shift reaction enables the production of a syngas with high hydrogen content and adjustable H2/CO/CO2-ratio. Tests were conducted in a 200 kW DFB pilot-scale facility under industrially relevant conditions to analyze the influence of gasification temperature, steam to carbon (S... [more]

Reducing the energy consumption of the heating, ventilation, and air conditioning (HVAC) systems while ensuring users’ comfort is of both academic and practical significance. However, the-state-of-the-art of the optimization model of the HVAC system is that either the thermal dynamic model is simplified as a linear model, or the optimization model of the HVAC system is single-timescale, which leads to heavy computation burden. To balance the practicality and the overhead of computation, in this paper, a multi-timescale bilinear model of HVAC systems is proposed. To guarantee the consistency of models in different timescales, the fast timescale model is built first with a bilinear form, and then the slow timescale model is induced from the fast one, specifically, with a bilinear-like form. After a simplified replacement made for the bilinear-like part, this problem can be solved by a convexification method. Extensive numerical experiments have been conducted to validate the effectivenes... [more]

Due to the toxicity of cadmium (Cd) and the scarcity of telluride (Te), CdTe-based photovoltaic modules have been under discussion during the last few years. In particular, the stability of CdTe in aqueous solutions is under debate. Here we show that the stability of CdTe depends not only on the pH of water-based solutions but also on size and surface treatment of CdTe particles. We compare milled module pieces with CdTe powders of different particle size. The leaching of CdTe is conditioned by the outdiffusion of Cd and Te at the interface between CdTe particles and the aqueous solution. The smaller the particle size, the faster the leaching. Therefore, milled module pieces decompose faster than CdTe powders with relatively large grains. We observe a dependence on time t according to t0.4. The room temperature diffusion coefficients are calculated as DCd ≈ 3 × 10−17 cm2/s for Cd, and DTe ≈ 1.5 × 10−17 cm2/s for Te in pH4. The chemical instability in aqueous solutions follows thermodyn... [more]

Shunt active power filters (APFs) are used to address power quality issues such as harmonic distortion and power system imbalance. Many control systems for shunt APFs demand measurements of voltages and currents for the determination of instantaneous real and reactive power signals. From these signals, the reference currents of the shunt APF are calculated. A method of control for the APF shunt that only measures currents is proposed in this paper. The control method includes a modified technique to extract the positive and negative sequence components in the time domain. The reference currents in the shunt APF are calculated by the negative sequence components of the measured currents. Simulation and experimental results confirm the efficiency of this control scheme under ideal and non-ideal conditions.

This paper offers new insights into a partial fuel stratification (PFS) combustion strategy that has proven to be effective at stabilizing overall lean combustion in direct injection spark ignition engines. To this aim, high spatial and temporal resolution optical diagnostics were applied in an optically accessible engine working in PFS mode for two fuels and two different durations of pilot injection at the time of spark: 210 µs and 330 µs for E30 (gasoline blended with ethanol by 30% volume fraction) and gasoline, respectively. In both conditions, early injections during the intake stroke were used to generate a well-mixed lean background. The results were compared to rich, stoichiometric and lean well-mixed combustion with different spark timings. In the PFS combustion process, it was possible to detect a non-spherical and highly wrinkled blue flame, coupled with yellow diffusive flames due to the combustion of rich zones near the spark plug. The initial flame spread for both PFS ca... [more]

In a high-power factor quasi-resonant Flyback, an ideal zero current detection (ZCD) circuit and control circuitry enable the power switch turn-on in the exact instant a zero ringing current is reached after demagnetization. A nonzero current at the turn-on instant affects the input current shape and; consequently, affects its Total Harmonic Distortion (THD). This paper firstly deeply analyzes the effect on the distortion due to a nonideal ZCD circuit. After, some typical implementations of the ZCD circuit and their effect on the THD are analyzed, identifying their pros and cons. Finally, some experimental results are obtained to validate the analytical investigation.

There is an increasing necessity in reducing CO2 emissions and implementing clean energy technologies, and over the years the marine environment has shown a huge potential in terms of renewable energy. From this perspective, extracting marine renewable energy represents one of the most important technological challenges of the 21st century. In this context, the objective of the present work is to provide a new and comprehensive understanding concerning the global wave energy resources based on the most recent results coming from two different databases, ERA5 and the European Space Agency Climate Change Initiative for Sea State. In this study, an analysis was first made based only on the ERA5 data and concerns the 30-year period of 1989−2018. The mean wave power, defined as the energy flux per unit of wave-crest length, was evaluated at this step. Besides the spatial distribution of this parameter, its seasonal, inter, and mean annual variability was also assessed on a global scale. As... [more]

The energy crisis has forced researchers to look for various non-conventional energy sources. Wind energy is one of the potential sources, and researchers have invested resources in developing different kinds of wind turbines. Vertical axis wind turbines (VAWT) have received less attention than their horizontal-axis counterparts. A helical-bladed VAWT is preferred because it makes perfect sense as an improvement in design, as they have higher azimuth angles of power generation capabilities. This paper studies the effects of the helix angle of blades in the aerodynamic performance of VAWT using 3D numerical simulations. Three different helix angles of 60°, 90°, and 120° of a three-bladed VAWT operating across different tip speed ratios were studied. Turbulence is modelled using a four-equation transition SST k-ω model (shear stress transport). The 60° helical-bladed VAWT was found to be better performing in comparison with all other helical-bladed and straight-bladed VAWT. The ripple ef... [more]

During the last few years, the accuracy of static electricity meters (SEM) has been questioned. Significant metering deviations with respect to a reference meter have been observed at customer premises, and laboratory experimental tests results support such findings. The root cause of such errors remains unknown, as there are multiple elements that could affect the accuracy of electricity meters. Furthermore, standard compliant meters exposed to distorted signals may produce negligible, positive or negative relative error depending on the instrument design. Distorted current signals with fast amplitude transitions have produced the highest error in SEMs reported in the literature. In this paper, the accuracy of an energy metering Integrated Circuit (IC) is evaluated beyond the limits of the standards requirements employing a selection of distorted signals from the standards, real-world captured signals and a set of waveforms designed to test the IC under fast changing currents conditio... [more]

Modular multilevel converters can achieve high power quality and voltage ratings, becoming a good alternative for high-voltage direct-current applications. However, the circulating current and capacitor voltage ripple remain significant drawbacks, mainly due to the impact on efficiency and power density. In this work, a stationary operation of a modular multilevel converter is optimized by calculating the Pareto frontier of the arm energy ripple and the conduction losses for different operating conditions. From the set of optimal solutions, the best trade-off between energy ripple and power losses can be chosen depending on the application requirements. Therefore, an optimal operating point regarding capacitor voltage ripple and circulating current was found, optimizing efficiency and allowing a reduction of capacitance, hence size and cost. The theoretical analysis and results are validated experimentally on a prototype test-bench.

In this paper a novel hybrid piezoelectric and electromagnetic energy harvester for civil engineering low-frequency sloshing environment is reported. The architecture, fabrication and characterization of the harvester are discussed. The hybrid energy harvester is composed of a permanent magnet, copper coil, and PVDF(polyvinylidene difluoride) piezoelectric film, and the upper U-tube device containing a cylindrical fluid barrier is connected to the foundation support plate by a hinge and spring. The two primary means of energy collection were through the vortex street, which alternately impacted the PVDF piezoelectric film through fluid shedding, and the electromotive force (EMF) induced by changes in the magnetic field position in the conducting coil. Experimentally, the maximum output power of the piezoelectric transformer of the hybrid energy harvester was 2.47 μW (circuit load 270 kΩ; liquid level height 80 mm); and the maximum output power of the electromagnetic generator was 2.72... [more]

As one of the core components of gas turbines, the combustion system operates in a high-temperature and high-pressure adverse environment, which makes it extremely prone to faults and catastrophic accidents. Therefore, it is necessary to monitor the combustion system to detect in a timely way whether its performance has deteriorated, to improve the safety and economy of gas turbine operation. However, the combustor outlet temperature is so high that conventional sensors cannot work in such a harsh environment for a long time. In practical application, temperature thermocouples distributed at the turbine outlet are used to monitor the exhaust gas temperature (EGT) to indirectly monitor the performance of the combustion system, but, the EGT is not only affected by faults but also influenced by many interference factors, such as ambient conditions, operating conditions, rotation and mixing of uneven hot gas, performance degradation of compressor, etc., which will reduce the sensitivity an... [more]

Natural gas is considered a helpful transition fuel in order to reduce the greenhouse gas emissions of other conventional power plants burning coal or liquid fossil fuels. Natural Gas Hydrates (NGHs) constitute the largest reservoir of natural gas in the world. Methane contained within the crystalline structure can be replaced by carbon dioxide to enhance gas recovery from hydrates. This technical review presents a techno-economic analysis of the full pathway, which begins with the capture of CO2 from power and process industries and ends with its transportation to a geological sequestration site consisting of clathrate hydrates. Since extracted methane is still rich in CO2, on-site separation is required. Focus is thus placed on membrane-based gas separation technologies widely used for gas purification and CO2 removal from raw natural gas and exhaust gas. Nevertheless, the other carbon capture processes (i.e., oxy-fuel combustion, pre-combustion and post-combustion) are briefly discu... [more]

The energy produced by a wind farm in a given location and its associated income depends both on the wind characteristics in that location—i.e., speed and direction—and the dynamics of the electricity spot price. Because of the evidence of cross-correlations between wind speed, direction and price series and their lagged series, we aim to assess the income of a hypothetical wind farm located in central Italy when all interactions are considered. To model these cross and auto-correlations efficiently, we apply a high-order multivariate Markov model which includes dependencies from each time series and from a certain level of past values. Besides this, we used the Raftery Mixture Transition Distribution model (MTD) to reduce the number of parameters to get a more parsimonious model. Using data from the MERRA-2 project and from the electricity market in Italy, we estimate the model parameters and validate them through a Monte Carlo simulation. The results show that the simulated income fa... [more]

Perovskite solar cells (PSCs) have already achieved comparable performance to industrially established silicon technologies. However, high performance and stability must be also be achieved at large area and low cost to be truly commercially viable. The fully printable triple-mesoscopic carbon perovskite solar cell (mCPSC) has demonstrated unprecedented stability and can be produced at low capital cost with inexpensive materials. These devices are inherently scalable, and large-area modules have already been fabricated using low-cost screen printing. As a uniquely stable, scalable and low-cost architecture, mCPSC research has advanced significantly in recent years. This review provides a detailed overview of advancements in the materials and processing of each individual stack layer as well as in-depth coverage of work on perovskite formulations, with the view of highlighting potential areas for future research. Long term stability studies will also be discussed, to emphasise the impre... [more]

The main purpose of the present work was to evaluate the efficiency of the gasification process of three different types of agro-forest biomass residue (rapeseed, softwood, and sunflower husks) along with the characterization of size-segregated particulates’ emissions. The experiments were carried out in a drop tube furnace (DTF), using two different gasifying agents (O2/N2 and O2/N2/CO2) at atmospheric pressure and a constant temperature of 1000 °C. In focus was the effect of biomass and the gasifying agent on syngas composition (CO, H2, CH4, and CO2), cold gas and carbon conversion efficiency, and on the emissions of by-products, such as particulate matter (PM), known for having negative environmental and health impacts. The collected particulates were characterized by SEM/EDS and XPS analysis. The results reveal that: (i) the introduction of CO2 increased the production of CO and CH4 and syngas’ lower heating value (LHV), thus leading to higher cold gas and carbon conversion efficie... [more]