Browse
Records Added in April 2023
Records added in April 2023
Change month: January | February | March | April | May | June | July | August | September | October | November | December
6301. LAPSE:2023.29188
Experimental Feasibility Study of a Direct Contact Latent Heat Storage Using an Ester as a Bio-Based Storage Material
April 13, 2023 (v1)
Subject: Materials
Keywords: direct contact, emulsion, esters, Latent Heat Storage, methyl palmitate, PCM, phase change materials, proof-of-concept, thermal energy storage
Latent heat storage (LHS) represents a valuable technology for the integration of intermittent renewable energy sources in existing and future energy systems. Improvements in LHS can be sought by enhancing heat transfer efficiency, compactness and diminishing the environmental impact of storage systems. In this paper, direct contact latent heat storage (DC-LHS) using esters as phase change material (PCM) is proposed as a promising compact storage technology to achieve high performance both in terms of heat transfer and sustainability. The technology allows for the heat transfer fluid (HTF) to flow directly through the PCM, forming a large amount of small droplets and thus providing a large heat exchange surface area between the two materials. At the same time, using biobased esters as PCM, gives the technology clear ecological advantages when compared to alternative types of compact energy storage. Furthermore, no complex heat transfer enhancing structures are necessary in a DC-LHS, fu... [more]
6302. LAPSE:2023.29187
Fractional-Order Control of Grid-Connected Photovoltaic System Based on Synergetic and Sliding Mode Controllers
April 13, 2023 (v1)
Subject: Process Control
Keywords: fractional-order control, grid, photovoltaic system, sliding mode control, synergetic control
Starting with the problem of connecting the photovoltaic (PV) system to the main grid, this article presents the control of a grid-connected PV system using fractional-order (FO) sliding mode control (SMC) and FO-synergetic controllers. The article presents the mathematical model of a PV system connected to the main grid together with the chain of intermediate elements and their control systems. To obtain a control system with superior performance, the robustness and superior performance of an SMC-type controller for the control of the udc voltage in the DC intermediate circuit are combined with the advantages provided by the flexibility of using synergetic control for the control of currents id and iq. In addition, these control techniques are suitable for the control of nonlinear systems, and it is not necessary to linearize the controlled system around a static operating point; thus, the control system achieved is robust to parametric variations and provides the required static and... [more]
6303. LAPSE:2023.29186
Renovation of Public Lighting Systems in Cultural Landscapes: Lighting and Energy Performance and Their Impact on Nightscapes
April 13, 2023 (v1)
Subject: Energy Systems
Keywords: cultural landscape, Energy Efficiency, lighting retrofit, lightscape, nocturnal image, public lighting, urban lighting
The technological innovation in the field of lighting and the need to reduce energy consumption connected to public lighting are leading many municipalities to undertake the renewal of public lighting systems, by replacing the existing luminaires with LED technologies. This renovation process is usually aimed at increasing energy efficiency and reducing maintenance costs, whist improving the lighting performance. To achieve these results, the new luminaires are often characterised by a luminous flux distribution much more downward oriented, which may remarkably influence and alter the perception of the night image of the sites. In this study the implications of the renovation of public lighting systems in terms of lighting and energy performance as well as the effects relating to the alteration of the night image, in historical contexts characterized by significant landscape value, are analysed. Results, along with demonstrating the positive effect that more sustainable and energy effi... [more]
6304. LAPSE:2023.29185
Analysis of Factors Influencing Energy Efficiency Based on Spatial Quantile Autoregression: Evidence from the Panel Data in China
April 13, 2023 (v1)
Subject: Energy Systems
Keywords: Energy Efficiency, instrumental variable, Moran’s I, spatial quantile autoregression (SQAR)
This research mainly studies the factors influencing the efficiency of energy utilization. Firstly, by calculating Moran’sI and local indicators of spatial association (LISA) of energy efficiency of regions in mainland China, we found that energy efficiency shows obvious spatial autocorrelation and spatial clustering phenomena. Secondly, we established the spatial quantile autoregression (SQAR) model, in which the energy efficiency is the response variable with seven influence factors. The seven factors include industrial structure, resource endowment, level of economic development etc. Based on the provincial panel data (1998−2016) of mainland China (data source: China Statistical Yearbook, Statistical Yearbook of provinces), the findings indicate that level of economic development and industrial structure have a significant role in promoting energy efficient. Resource endowment, government intervention and energy efficiency show a negative correlation. However, the negative effect of... [more]
6305. LAPSE:2023.29184
Quasi-Z-Source Inverter-Based Photovoltaic Power System Modeling for Grid Stability Studies
April 13, 2023 (v1)
Subject: Modelling and Simulations
Keywords: photovoltaics, quasi-Z-source inverter, small-signal model, state-space model
Quasi-Z-source inverters (qZSIs) are becoming a powerful power conversion technology in photovoltaic (PV) power systems because they allow energy power conversion in a single stage operation. However, they can cause system resonances and reduce system damping, which may lead to instabilities. These stability problems are well known in grid-connected voltage source converter systems but not in quasi-Z-source inverter (qZSI)-based PV power systems. This paper contributes with Matlab/Simulink and PSCAD/EMTDC models of qZSI-based PV power systems to analyze transient interactions and stability problems. These models consider all power circuits and control blocks of qZSI-based PV power systems and can be used in sensitivity studies on the influence of system parameters on stability. PV power system stability is assessed from the proposed models. The causes of instabilities are analyzed from numerical simulations and possible solutions are proposed.
6306. LAPSE:2023.29183
Modeling and Dynamic Simulation of a Hybrid Liquid Desiccant System with Non-Adiabatic Falling-Film Air-Solution Contactors for Air Conditioning Applications in Buildings
April 13, 2023 (v1)
Subject: Modelling and Simulations
Keywords: air conditioning, Dynamic Modelling, experimental validation, falling film air-solution contactor, hybrid liquid desiccant system, multi-objective optimization
This paper presents an experimentally validated, dynamic model of a hybrid liquid desiccant system. For this purpose, we developed new components for the air-solution contactors, which are of the non-adiabatic falling-film type with horizontal tubes (made of improved polypropylene) and the solution tanks. We also provide new experimental correlations for both the tube-solution heat transfer coefficient and the mass transfer coefficient on the airside as a function of the air velocity. To validate the model, the results obtained from the dynamic simulations were compared with those obtained by monitoring a demonstration unit installed in a sports center in Taipei (Taiwan). Once validated, the model was used to perform a sensitivity analysis at different operational conditions, such as the inlet water temperatures in the air-solution contactors and the LiCl mass fraction at which the system operates. The results of the sensitivity analysis were used to optimize the seasonal performance i... [more]
6307. LAPSE:2023.29182
Hybridizing Lead−Acid Batteries with Supercapacitors: A Methodology
April 13, 2023 (v1)
Subject: Process Design
Keywords: battery degradation, depth of discharge, energy management system, hybrid energy storage system, lead–acid battery, supercapacitor, Technoeconomic Analysis
Hybridizing a lead−acid battery energy storage system (ESS) with supercapacitors is a promising solution to cope with the increased battery degradation in standalone microgrids that suffer from irregular electricity profiles. There are many studies in the literature on such hybrid energy storage systems (HESS), usually examining the various hybridization aspects separately. This paper provides a holistic look at the design of an HESS. A new control scheme is proposed that applies power filtering to smooth out the battery profile, while strictly adhering to the supercapacitors’ voltage limits. A new lead−acid battery model is introduced, which accounts for the combined effects of a microcycle’s depth of discharge (DoD) and battery temperature, usually considered separately in the literature. Furthermore, a sensitivity analysis on the thermal parameters and an economic analysis were performed using a 90-day electricity profile from an actual DC microgrid in India to infer the hybridizati... [more]
6308. LAPSE:2023.29181
Biogas Upgrading and Ammonia Recovery from Livestock Manure Digestates in a Combined Electromethanogenic Biocathode—Hydrophobic Membrane System
April 13, 2023 (v1)
Subject: Energy Systems
Keywords: ammonia recovery, biocathode, electromethanogenesis, hydrophobic membrane, microbial electrolysis cell
Anaerobic digestion process can be improved in combination with bioelectrochemical systems in order to recover energy and resources from digestates. An electromethanogenic microbial electrolysis cell (MEC) coupled to an ammonia recovery system based on hydrophobic membranes (ARS-HM) has been developed in order to recover ammonia, reduce organic matter content and upgrade biogas from digested pig slurry. A lab-scale dual-chamber MEC was equipped with a cation exchange membrane (CEM) and ARS with a hydrophobic membrane in the catholyte recirculation loop, to promote ammonia migration and absorption in an acidic solution. On the other hand, an electromethanogenic biofilm was developed in the biocathode to promote the transformation of CO2 into methane. The average nitrogen transference through the CEM was of 0.36 gN m−2 h−1 with a removal efficiency of 31%, with the ARS-HM in the catholyte recirculation loop. The removal of ammonia from the cathode compartment helped to maintain a lower p... [more]
6309. LAPSE:2023.29180
Designing of Dynamic Spectrum Shifting in Terms of Non-Local Space-Fractional Mechanics
April 13, 2023 (v1)
Subject: Process Design
Keywords: continuum non-local model, discrete model, fractional calculus, fractional mechanics
In this paper, the applicability of the space-fractional non-local formulation (sFCM) to design 1D material bodies with a specific dynamic eigenvalue spectrum is discussed. Such a formulated problem is based on the proper spatial distribution of material length scale, which maps the information about the underlying microstructure (it is important that the material length scale is one of two additional material parameters of sFCM compared to the classical local continuum mechanics—the second one, the order of fractional continua—is treated herein as a scaling parameter only). Technically, the design process for finding adequate length scale distribution is not trivial and requires the use of an inverse optimization procedure. In the analysis, the objective function considers a subset of eigenvalues reduced to a single value based on Kreisselmeier−Steinhauser formula. It is crucial that the total number of eigenvalues considered must be smaller than the limit which comes from the ratio o... [more]
6310. LAPSE:2023.29179
A Review of Recent Advances in Emerging Alternative Heating and Cooling Technologies
April 13, 2023 (v1)
Subject: Environment
Keywords: alternative refrigeration, barocaloric, elastocaloric, electrocaloric, emerging refrigeration technologies, magnetic, stirling, thermoacoustic, thermoelectric
The heating and cooling industry underpins everything we do, e.g., manufacturing, commercial and residential applications. Many of these applications invariably use mechanical refrigeration technologies, consequently contributing significantly to the environmental impacts of the refrigeration, air conditioning, and heat pump (RACHP) industry both through direct and indirect emissions of CO2. To reduce these emissions, research and development worldwide aim to improve the performance of conventional systems and the development of new refrigeration technologies of potentially much lower environmental impacts. As we transition to a low carbon economy, there are sizable environmental and economic benefits from developing and using efficient, innovative, low carbon heating and cooling technologies that reduce energy use and carbon emissions. This paper provides an up-to-date and comprehensive critical review and evaluation of recent advances in emerging alternative heating and cooling techn... [more]
6311. LAPSE:2023.29178
Polish Energy Transition 2040: Energy Mix Optimization Using Grey Wolf Optimizer
April 13, 2023 (v1)
Subject: Energy Policy
Keywords: cost optimization energy efficiency, energy sources, energy transition, Grey Wolf Optimizer, Poland
Poland is facing demanding challenges to achieve a sustainable energy mix in the near future. Crucial and tough decisions must be made about the direction of the national energy economy, safety, and environmental impact. Considering the electricity and heating demand forecast, this paper proposes an optimization model based on the Grey Wolf Optimizer meta-heuristic to support the definition of ideal energy mix considering the investment and operational costs. The proposed methodology uses the present energy mix in Poland (the most recent values are from 2017) to calibrate the model implemented in the EnergyPLAN tool. Afterwards, EnergyPLAN relates to an optimization process allowing the identification of the most convenient energy mix in 2040 in Poland. The values obtained are compared with those proposed by Polish public entities showing advantage regarding the global costs of the project nevertheless respecting the same levels of CO2 and the energy import and export balance. The expe... [more]
6312. LAPSE:2023.29177
Continuous Production of Lipids with Microchloropsis salina in Open Thin-Layer Cascade Photobioreactors on a Pilot Scale
April 13, 2023 (v1)
Subject: Modelling and Simulations
Keywords: continuous production, microalgae, Microchloropsis salina, open photobioreactors, process simulation, thin-layer cascade
Studies on microalgal lipid production as a sustainable feedstock for biofuels and chemicals are scarce, particularly those on applying open thin-layer cascade (TLC) photobioreactors under dynamic diurnal conditions. Continuous lipid production with Microchloropsis salina was studied in scalable TLC photobioreactors at 50 m2 pilot scale, applying a physically simulated Mediterranean summer climate. A cascade of two serially connected TLC reactors was applied, promoting biomass growth under nutrient-replete conditions in the first reactor, while inducing the accumulation of lipids via nitrogen limitation in the second reactor. Up to 4.1 g L−1 of lipids were continuously produced at productivities of up to 0.27 g L−1 d−1 (1.8 g m2 d−1) at a mean hydraulic residence time of 2.5 d in the first reactor and 20 d in the second reactor. Coupling mass balances with the kinetics of microalgal growth and lipid formation enabled the simulation of phototrophic process performances of M. salina in T... [more]
6313. LAPSE:2023.29176
Monofacial and Bifacial Micro PV Installation as Element of Energy Transition—The Case of Poland
April 13, 2023 (v1)
Subject: Energy Policy
Keywords: bifacial PV, CO2 emission, Mój Prąd, monofacial PV, my electricity, photovoltaic, Poland, PV, renewable energy source
The several government subsidies available in Poland contributed to an increased interest in PV installations. Installed PV capacity increased from 100 MW in 2016 up to 2682.7 MW in July 2020. In 2019 alone, 104,000 microinstallations (up to 50 kWp) were installed in Poland. The paper determines the energy gain and the associated reduction of CO2 emissions for two types of solar installation located in Poland. The monofacial solar modules with a power of 5.04 kWp (located in Leki) and bifacial solar modules with a power of 6.1 kWp (located in Bydgoszcz). Both installations use mono-crystalline Si-based 1st generation PV cells. With comparable insolation, a bifacial installation produces approx. 10% (for high insolation) to 28% (for low insolation) more energy than a monofacial PV installation. Avoided annual CO2 emission in relation to the installation capacity ranges from 0.58 to 0.64 Mg/kWp for monofacial and from 0.68 to 0.74 Mg/kWp for bifacial and is on average approx. 16% higher... [more]
6314. LAPSE:2023.29175
Horizontally Assembled Trapezoidal Piezoelectric Cantilevers Driven by Magnetic Coupling for Rotational Energy Harvester Applications
April 13, 2023 (v1)
Subject: Energy Management
Keywords: energy harvesting, magnetic coupling, magneto-piezo-elastic, piezoelectric bimorph, trapezoidal cantilever
Horizontally assembled trapezoidal piezoelectric cantilevers driven by magnetic coupling were fabricated for rotational energy harvester applications. A dodecagonal rigid frame with an attached array of six trapezoidal cantilevers served as a stator for electrical power generation. A rotor disk with six permanent magnets (PMs) interacted magnetically with the counterpart cantilever’s tip-mass PMs of the stator by rotational motion. Each trapezoidal piezoelectric cantilever beam was designed to operate in a transverse mode that utilizes a planar Ag/Pd electrode printed onto lead zirconate titanate (PZT) piezoelectric thick film. The optimized distance between a pair of PMs of the rotor and the stator was evaluated as approximately 10 mm along the same vertical direction to make the piezoelectric cantilever beam most deflectable without the occurrence of cracks. The theoretically calculated resistance torque was maximized at 46 mN·m for the optimized trapezoidal piezoelectric cantilever.... [more]
6315. LAPSE:2023.29174
An Integrated Approach to Convert Lignocellulosic and Wool Residues into Balanced Fertilisers
April 13, 2023 (v1)
Subject: Environment
Keywords: biochar, biomass pyrolysis, circular economy, hydrolysis, integrated approach, wool residue
Valorising biomass waste and producing renewable energy or materials is the aim of several conversion technologies. In this work, we consider two residues from different production chains: lignocellulosic residues from agriculture and wool residues from sheep husbandry. These materials are produced in large quantities, and their disposal is often costly and challenging for farmers. For their valorisation, we focus on slow pyrolysis for the former and water hydrolysis for the latter, concisely presenting the main literature related to these two processes. Pyrolysis produces the C-rich biochar, suitable for soil amending. Hydrolysis produces a N-rich fertiliser. We demonstrate how these two processes could be fruitfully integrated, as their products can be flexibly mixed to produce fertilisers. This solution would allow the achievement of balanced and tuneable ratios between C and N and the enhancement of the mechanical properties. We propose scenarios for this combined valorisation and... [more]
6316. LAPSE:2023.29173
Energy and Economic Investigation of a Biodiesel-Fired Engine for Micro-Scale Cogeneration
April 13, 2023 (v1)
Subject: Energy Systems
Keywords: biodiesel, CHP, economic assessment, emissions, energy performance, internal combustion engine, multi-objective optimisation, numerical model
The work aims at investigating the techno-economic performance of a biodiesel micro combined heat and power (CHP) system for residential applications. The CHP unit is based on a direct-injection compression ignition engine providing 6.7 kWel and 11.3 kWth. A 0D model is developed and validated to characterise the behaviour of the biodiesel-fired engine at full and partial load in terms of efficiency, fuel consumption, and emissions. Furthermore, non-dimensional polynomial correlations are proposed to foresee the performance of biodiesel-fuelled engines for micro-CHP applications at partial loads. Afterwards, the CHP system is adopted to satisfy the electric and thermal demand of domestic users in Southern Italy. To this purpose, a parametric analysis is performed considering a different number of apartments and operating strategies (electric-driven and thermal-driven). A bi-variable optimisation based on the primary energy saving (PES) index and payback period (PBT) permits selecting t... [more]
6317. LAPSE:2023.29172
Experimental Validation of a Reduced-Scale Rail Power Conditioner Based on Modular Multilevel Converter for AC Railway Power Grids
April 13, 2023 (v1)
Subject: Energy Management
Keywords: electrified railway systems, modular multilevel converter, power quality, rail power conditioner
Rail power conditioner (RPC) has the ability to improve the power quality in AC railway power grids. This power conditioner can increase the loading capacity of traction substations, balance the active power between the feeder load sections, and compensate for reactive power and current harmonics. At present, there is increasing use of multilevel converter topologies, which provide scalability and robust performance under different conditions. In this framework, modular multilevel converter (MMC) is emerging as a prominent solution for medium-voltage applications. Serving that purpose, this paper focuses on the implementation, testing, and validation of a reduced-scale laboratory prototype of a proposed RPC based on an MMC. The developed laboratory prototype, designed to be compact, reliable, and adaptable to multipurpose applications, is presented, highlighting the main control and power circuit boards of the MMC. In addition, MMC parameter design of the filter inductor and submodule... [more]
6318. LAPSE:2023.29171
Effect of the Foresight Horizon on Computation Time and Results Using a Regional Energy Systems Optimization Model
April 13, 2023 (v1)
Subject: Optimization
Keywords: energy system model, myopic, Optimization, perfect foresight
Due to the high complexity of detailed sector-coupling models, a perfect foresight optimization approach reaches complexity levels that either requires a reduction of covered time-steps or very long run-times. To mitigate these issues, a myopic approach with limited foresight can be used. This paper examines the influence of the foresight horizon on local energy systems using the model DISTRICT. DISTRICT is characterized by its intersectoral approach to a regionally bound energy system with a connection to the superior electricity grid level. It is shown that with the advantage of a significantly reduced run-time, a limited foresight yields fairly similar results when the input parameters show a stable development. With unexpected, shock-like events, limited foresight shows more realistic results since it cannot foresee the sudden parameter changes. In general, the limited foresight approach tends to invest into generation technologies with low variable cost and avoids investing into d... [more]
6319. LAPSE:2023.29170
Lifetime Assessment of PILC Cables with Regard to Thermal Aging Based on a Medium Voltage Distribution Network Benchmark and Representative Load Scenarios in the Course of the Expansion of Distributed Energy Resources
April 13, 2023 (v1)
Subject: Energy Management
Keywords: Arrhenius law, distribution network benchmark, line and network load, load scenarios, Montsinger rule, thermal aging, thermal network method, thermal time constant
The decentralized feed-ins from distributed energy resources (DER) represent a significant change in the manner in which the power grid is used. If this leads to high loads on electrical equipment, its aging can be accelerated. This applies in particular with regard to the thermal aging of older generations of power cables, namely paper insulated lead covered (PILC) cables. This type of power cable can still be found frequently in medium voltage (MV) networks. If aging of these cables is significantly accelerated in the presence of DER, distribution system operators (DSO) could face unplanned premature cable failures and a high replacement demand and costs. Therefore, this paper investigates the thermal aging of PILC cables in a MV distribution network benchmark for different load scenarios, using standardized load profiles and representative expansion scenarios for wind power and photovoltaics plants in particularly affected network areas in Germany. A main objective of this paper is... [more]
6320. LAPSE:2023.29169
A DC Microgrid System for Powering Remote Areas
April 13, 2023 (v1)
Subject: Energy Systems
Keywords: DC microgrid, power conditioner system, Renewable and Sustainable Energy, scalable microgrid
DC microgrid has been gaining popularity as solution as a more efficient and simpler power system especially for remote areas, where the main grid has yet to be built. This paper proposes a DC microgrid system based on renewable energy sources that employs decentralized control and without communication between one grid point and another. It can be deployed as an individual isolated unit or to form an expandable DC microgrid through DC bus for better reliability and efficiency. The key element of the proposed system is the power conditioner system (PCS) that works as an interface between energy sources, storage system, and load. PCS consists of modular power electronics devices and a power management unit, which controls power delivery to the AC load and the grid as well as the storage system charging and discharging sequence. Prototypes with 3 kWp solar PV and 13.8 kWh energy storage were developed and adopt a pole-mounted structure for ease of transportation and installation that are... [more]
6321. LAPSE:2023.29168
Oxidation Stability of Natural Ester Modified by Means of Fullerene Nanoparticles
April 13, 2023 (v1)
Subject: Materials
Keywords: acid number, aging process, antioxidants, fullerene, natural ester, oxidation stability
Increasing environmental demands influence the requirements for devices and materials used in the power industry. One example is a power transformer and an electro-insulating liquid used in it. In order to meet these requirements, electro-insulating liquids should be characterized by, inter alia, high biodegradability and good fire properties. One of such liquids is natural ester. However, its oxidation stability is low in comparison to mineral oil and demands improvement, which can be achieved by the addition of an antioxidant. The authors of this work used fullerene nanoparticles for that purpose. Pure natural ester samples were prepared, and samples with two concentrations of fullerene, 250 mg/L and 500 mg/L in natural ester. All these samples were aged in a thermal oxidation process. Thereafter, the aging properties of all the samples were compared to assess the oxidation stability of modified liquids. Moreover, the electrical properties of prepared insulating liquids were investig... [more]
6322. LAPSE:2023.29167
Thermoelectric Generation with Impinging Nano-Jets
April 13, 2023 (v1)
Subject: Materials
Keywords: finite element method, jet impingement, nanofluid, TEG
In this study, thermoelectric generation with impinging hot and cold nanofluid jets is considered with computational fluid dynamics by using the finite element method. Highly conductive CNT particles are used in the water jets. Impacts of the Reynolds number of nanojet stream combinations (between (Re1, Re2) = (250, 250) to (1000, 1000)), horizontal distance of the jet inlet from the thermoelectric device (between (r1, r2) = (−0.25, −0.25) to (1.5, 1.5)), impinging jet inlet to target surfaces (between w2 and 4w2) and solid nanoparticle volume fraction (between 0 and 2%) on the interface temperature variations, thermoelectric output power generation and conversion efficiencies are numerically assessed. Higher powers and efficiencies are achieved when the jet stream Reynolds numbers and nanoparticle volume fractions are increased. Generated power and efficiency enhancements 81.5% and 23.8% when lowest and highest Reynolds number combinations are compared. However, the power enhancement... [more]
6323. LAPSE:2023.29166
Investigating the Asymmetric Effect of Economic Growth on Environmental Quality in the Next 11 Countries
April 13, 2023 (v1)
Subject: Environment
Keywords: asymmetric relationship, carbon emission, economic growth, energy consumption, next 11 countries
This study investigates the asymmetric cointegration and causal relationships between economic growth, carbon emissions, and energy consumption in the next eleven (11) countries over the period 1972−2013. The nonlinear autoregressive distributed lag (NARDL) bounds testing approach and nonpragmatic Granger causality tests are employed. This research’s empirical results have entrenched vital relationships that have significant policy implications. We affirm nonlinear cointegration among the variables in Bangladesh, Iran, Turkey, and Vietnam. The long-run asymmetric effect outcomes indicate a definite boom in economic growth, significantly increases carbon emission in Turkey, and a decline in Vietnam. Additionally, a positive shock to energy consumption significantly increases the carbon emission in Bangladesh, Iran, and Turkey, but a decrease in emissions in Vietnam. Findings from the Wald test reveal a long-run asymmetric effect between carbon emission and economic growth in Bangladesh,... [more]
6324. LAPSE:2023.29165
Al-ZSM-5 Nanocrystal Catalysts Grown from Silicalite-1 Seeds for Methane Conversion
April 13, 2023 (v1)
Subject: Materials
Keywords: Al-ZSM-5 zeolites, diffusion, methane dehydroaromatization, nanocrystal, silicalite-1
This study evaluated Al-ZSM-5 nanocrystals grown from silicalite-1 seed crystals as catalysts for the methane dehydroaromatization (MDA) reaction. Silicalite-1 seed crystals sized between 30 and 40 nm were used to grow Al-ZSM-5 under various synthesis conditions. The size of Al-ZSM-5 was significantly affected by the Si/Al ratio (SAR), synthesis time, and silica nutrients/seed crystal ratio (NSR). Larger crystals were obtained with an increased SAR in the synthesis sols. Gradual growth of Al-ZSM-5 occurred with synthesis time, although the growth in crystal size ceased at 5 h of synthesis at 120 °C, indicating the rapid growth of Al-ZSM-5 aided by the silicalite-1 seeds. Precise tuning of Al-ZSM-5 size was possible by changing the nutrient/silicalite-1 seed ratio; a higher NSR led to larger crystals. Two representative Al-ZSM-5 crystals with SARs of 35 and 140 were prepared for catalyst testing, and the crystal sizes were tailored to <100 nm by controlling NSR. The MDA reaction was... [more]
6325. LAPSE:2023.29164
Design and Prototyping of Efficient LED Counter Beam Light with Free-Formed Surface for Meeting International Tunnel Lighting Standards
April 13, 2023 (v1)
Subject: Process Design
Keywords: CIE 88:2004 regulation, freeform-surfaced secondary lens design, LED Counter Beam Light (CBL), tunnel lighting
An LED Counter Beam Light (CBL) with a free surface secondary lens is proposed to enhance the safety and efficiency of tunnels. The secondary lens was designed and produced to be mounted on a 50 W white-light LED array to generate the targeted counter beam pattern, in order to meet the standards for enhanced tunnel road lighting of the CIE (Commission Internationale de l’Eclairage)—CIE 88:2004—in a trial tunnel lighting scheme. Through the simulation of a road tunnel in Northern Taiwan using the LiteStar four-dimensional software, it was shown that the proposed LED light can serve as a qualifying CBL to generate an average road tunnel surface luminance (Lav) of 182.76 cd/m2, which is better than the 138 cd/m2 that commercial High-Pressure Sodium (HPS) tunnel lights can provide and the 181 cd/m2 minimum stipulated in the CIE 88:2004 regulations. The results also show that the proposed LED light accomplishes a contrast revealing coefficient qc of 1.03, which is above the minimum regulato... [more]
[0.06 s]

