The combustion of fuels has been studied by many researchers as it is used in a wide range of engineering applications. The chemical equilibrium approach served as the foundation for the investigation of combustion reactions. This article presents a software application designed to facilitate the calculation of combustion processes by calculating the combustion of 16 fuels among the common alkanes (CnH2n+2) and alcohols (CnH2n+1OH). The Ozan Combustion Calculator (OCC) offers a user-friendly and efficient graphical user interface (GUI) that allows users to easily input data and obtain results. The program was developed using MATLAB 2021a and LaTeX software, ensuring its reliability and accuracy. To perform these calculations, the program utilizes calculations of the thermophysical properties of fuels and water obtained from tables. The program consists of five modules, each serving a specific purpose. These modules calculate various parameters, such as the Adiabatic Flame Temperature,... [more]

The escalating challenge of waste management demands innovative strategies to mitigate environmental impacts and harness valuable resources. This study investigates waste-to-energy (WtE) technologies for municipal waste management in Kočevje, Slovenia. An analysis of available waste streams reveals substantial energy potential from mixed municipal waste, biodegradable waste, and livestock manure. Various WtE technologies, including incineration, pyrolysis, gasification, and anaerobic digestion, are compared. The results show that processing mixed municipal waste using thermochemical processes could annually yield up to 0.98 GWh of electricity, and, separately, 3.22 GWh of useable waste heat for district heating or industrial applications. Furthermore, by treating 90% of the biodegradable waste, up to 1.31 GWh of electricity and 1.76 GWh of usable waste heat could be generated annually from biodegradable municipal waste and livestock manure using anaerobic digestion and biogas combustio... [more]

Increasing production of poultry litter, and its associated problems, stimulates the need for generating useful energy in an environmentally friendly and efficient energy system, such as the use of shell-and-tube heat exchangers (STHE) in a fluidized-bed combustion (FBC) system. A holistic approach which involves the integration of the First Law of Thermodynamics (FLT) and Second Law of Thermodynamics (SLT) is required for conducting effective assessment of an energy system. In this study, the STHE designed by the CAESECT research group, which was integrated into the lab-scale FBC, was investigated to determine the maximum available work performed by the system and account for the exergy loss due to irreversibility. The effects of varying operating parameters and configuration of the space heaters connected to the STHE for space heating purposes were investigated in order to improve the thermal efficiency of the poultry litter-to-energy conversion process. Exergy and energy analysis pe... [more]

A thermoelectric generator (TEG) is studied by considering different leg structures of hollow/filled legs, using new cooling nanofluids, and analyzing the segmentation effect. TEG performance is characterized by power output, conversion efficiency, and exergy efficiency. This study shows the impact of different cooling nanofluids (TiO2, graphene, and Al2O3) on the performance of the thermoelectric generator. Furthermore, in the comparative analysis of nanofluid cooling enhancement for TEG, different hollow/filled thermoelectric legs recently proposed in the literature are considered. Likewise, three segmentation types are used, 2n-2p, 1n-2p, and 2n-1p, thus will be compared with the results of the unsegmented legs. This study calculates the performance of thermoelectric leg structures through a validated numerical simulation on the ANSYS Workbench (modeling, design, and simulation). In addition, the optimal working conditions are evaluated. This study found that quenching of nanofluids... [more]

The Hellisheidi geothermal power plant, located in Iceland, is a combined heat and power double-flash geothermal plant with an installed capacity of 303.3 MW of electricity and 133 MW of hot water. This study aimed to elucidate the environmental impacts of the electricity and heat production from this double-flash geothermal power plant. In this vein, firstly, the most updated inventory of the plant was generated, and secondly, a life-cycle assessment approach based on the exergy allocation factor was carried out instead of applying the traditionally used allocations in terms of mass and energy. The functional unit was defined as the production of 1 kWh of electricity and 1 kWh of hot water for district heating. The life-cycle stages included the (i) construction, (ii) operation (including abatement operations and maintenance), and (iii) well closure of the geothermal plant. All of the life-cycle stages from construction to dismantling were considered. Finally, the results on the parti... [more]

In this article, a thermodynamic, exergy, and environmental impact assessment was carried out on a Brayton S-CO2 cycle coupled with an organic Rankine cycle (ORC) as a bottoming cycle to evaluate performance parameters and potential environmental impacts of the combined system. The performance variables studied were the net power, thermal and exergetic efficiency, and the brake-specific fuel consumption (BSFC) as a function of the variation in turbine inlet temperature (TIT) and high pressure (PHIGH), which are relevant operation parameters from the Brayton S-CO2 cycle. The results showed that the main turbine (T1) and secondary turbine (T2) of the Brayton S-CO2 cycle presented higher exergetic efficiencies (97%), and a better thermal and exergetic behavior compared to the other components of the System. Concerning exergy destruction, it was found that the heat exchangers of the system presented the highest exergy destruction as a consequence of the large mean temperature difference be... [more]

Energy and exergy (EnE) efficiencies are considered the most important parameters to compare the performance of various thermal systems. In this paper, an analysis was carried out for EnE efficiencies of a flat plate solar collector (FPSC) using four different kinds of nanofluids as flowing mediums, namely, Al2O3/water, MgO/water, TiO2/water, and CuO/water, and compared with water as a flowing medium (traditional base fluid). The analysis considered nanofluids made of nanomaterials’ volume fractions of 1−4% with water. The volume flow rates of nanofluids and water were 1 to 4 L/min. The solar collector′s highest EnE efficiency values were obtained for CuO/water nanofluid among the four types of nanofluids mentioned above. The EnE efficiencies of the CuO nanofluid-operated solar collector were 38.21% and 34.06%, respectively, which is significantly higher than that of water-operated solar collectors. For the same volume flow rate, the mass flow rate was found to be 15.95% higher than wa... [more]

Direct steam generation is a promising alternative to conventional heat transfer fluids for solar thermal power plants using linear concentrators because water and steam do not have thermal and chemical stability problems. The novelty of this study, an energy and exergy (2E) analysis, was that it was performed on several configurations of a conceptual direct steam generation solar power plant with optimized Fresnel reflectors in Agua Prieta, Mexico coupled with a regenerative steam Rankine power cycle to quantify their efficiency and establish a reference for future implementation of this technology in concentrated solar power plants in Mexico. The thermal model was assumed to be a 1D steady-state flow and validated against results in the literature. It was then applied directly to a case study to determine the size of the solar field. The design point was the lowest solar irradiance day, and evaluating the solar multiple with the highest solar irradiance, taking care not to oversize t... [more]

Combustion processes continue to be essential for the energy supply sector. A reliable energetic evaluation of these processes is crucial, particularly since the pollutants resulting from combustion have a significant impact on global warming. This work evaluates a combustion using the exergetic evaluation and the Physical Optimum (PhO) as it is described in VDI-Guideline 4663. Differences between PhO and exergy are investigated, allowing a distinct differentiation and examining the PhO’s added value in combustion analysis. Based on the evaluation of a simulated methane combustion, this paper shows that the PhO-Factor may be used to evaluate combustion processes. However, it shows that the PhO of a combustion process is a simplification of this fuels exergy and does not provide advantages to the exergy evaluation. Nevertheless, an adaption of the PhO is not carried out in the context of this work since the minimal deviation of the simulated energy indicators currently cannot justify an... [more]

This study investigates the technical and economic feasibility of replacing throttling valves with smale-scale, oil-free turbomachinery in industrial steam networks. This is done from the perspective of the turbomachine, which has to be integrated into a new or existing process. The considered machines have a power range of P=[0.5,…,250 kW] and have been designed using real industrial data from existing processes. Design guidelines are developed, which take into account the thermodynamic process as well as engineering aspects of such a turbomachine. The results suggest that steam conditioning prior to heat exchange could be completed by small expanders to produce mechanical work, reducing exergy destruction and improving site-wide energy efficiency compared to throttling valves. Cost estimates for such machines are presented, which serve as a basis for case-specific investment calculations. The resulting payback times of less than 18 months highlight the economic potential such solutio... [more]

The thermal energy conversion of natural gas (NG) using appropriate configuration cycles represents one of the best nonrenewable energy resources because of its high heating value and low environmental effects. The natural gas can be converted to liquefied natural gas (LNG), via the liquefaction process, which is used as a heat source and sink in various multigeneration cycles. In this paper, a new configuration cycle is proposed using LNG as a heat source and heat sink. This new proposed cycle includes the CO2 cycle, the organic Rankine cycle (ORC), a heater, a cooler, an NaClO plant, and reverse osmosis. This cycle generates electrical power, heating and cooling energy, potable water (PW), hydrogen, and salt all at the same time. For this purpose, one computer program is provided in an engineering equation solver for energy, exergy, and thermo-economic analyses. The results for each subsystem are validated by previous researches in this field. This system produces 10.53 GWh electrica... [more]

Ocean thermal energy conversion (OTEC) uses a very simple process to convert the thermal energy stored mainly in tropical oceans into electricity. In designs, operations, and evaluations, we need to consider the unique characteristics of OTEC to achieve the best performance or lower the electricity cost of projects. The concept and design constraints of OTEC power generation differ from those of conventional thermal power plants due to the utilization of a low temperature difference. This research theoretically recognizes the unique characteristics of the energy conversion system and summarizes the appropriate performance evaluation methods for OTEC based on finite-time thermodynamics and the equilibrium condition of the heat source. In addition, it presents the concept of normalization of thermal efficiency for OTEC and exergy efficiency based on the available thermal energy in the ocean defined as the transferable thermal energy from the ocean and the equilibrium condition as the dea... [more]

We conducted energy and exergy analyses of an adsorption chiller to investigate the effect of recooling-water temperatures on the cooling capacity and Coefficient of Performance (COP) with variable cycle modes. We investigated both the effect of the recooling-water temperature and the dead state temperature on the exergy destruction in the chiller components. Our results show that there is an optimum reheat cycle mode for each recooling-water temperature range. For the basic single stage cycle, the exergy destruction is mainly accrued in the desorber (49%), followed by the adsorber (27%), evaporator (13%), condenser (9%), and expansion valve (2%). The exergy destruction for the preheating process is approximately 35% of the total exergy destruction in the desorber. By contrast, the precooling process is almost 58% of the total exergy destruction in the adsorber. The exergy destruction decreases when increasing the recooling-water and the dead state temperatures, while the exergy effici... [more]

The aim of this scientific research is to experimentally determine the exergy losses of a ground heat pump and further optimization for more efficient use of operating modes and improvement of individual structural elements. In addition, it is proposed to use photovoltaic panels as a backup power source for the experimental installation under study. The exergetic losses are calculated, not only for the ground heat pump itself, with R407C refrigerant. The research methodology consists in a comprehensive assessment of exergetic flows, their optimization using new methods of approximation of piecewise linear functions, and the development of prerequisites for the use of anergy as one of the components of a new type of analysis of the efficiency of low-potential energy sources. As a result of processing the experimental data, the values of Coefficient of performance (COP) 4.136, exergetic temperature for the lower heat source 0.0253 and for the upper heat source 0.155, exergetic efficiency... [more]

The application of thermal storage materials in solar systems involves materials that utilize sensible heat energy, thermo-chemical reactions or phase change materials, such as hydrated salts, fatty acids paraffin and non-paraffin like glycerol. This article reviews the various exergy approaches that were applied for several solar systems including hybrid solar water heating, solar still, solar space heating, solar dryers/heaters and solar cooking systems. In fact, exergy balance was applied for the different components of the studied system with a particular attention given to the determination of the exergy efficiency and the calculation of the exergy during charging and discharging periods. The influence of the system configuration and heat transfer fluid was also emphasized. This review shows that not always the second law of thermodynamics was applied appropriately during modeling, such as how to consider heat charging and discharging periods of the tested phase change material. A... [more]

This is a review of the concepts of purpose, direction, and objective in the discipline of thermodynamics, which is a pillar of physics, natural sciences, life science, and engineering science. Reviewed is the relentless evolution of this discipline toward accounting for evolutionary design with direction, and for establishing the concept of purpose in methodologies of modeling, analysis, teaching, and design optimization. Evolution is change after change toward flow access, with direction in time, and purpose. Evolution does not have an ‘end’. In thermodynamics, purpose is already the defining feature of methods that have emerged to guide and facilitate the generation, distribution, and use of motive power, heating, and cooling: thermodynamic optimization, exergy-based methods (i.e., exergetic, exergoeconomic, and exergoenvironmental analysis), entropy generation minimization, extended exergy, environomics, thermoecology, finite time thermodynamics, pinch analysis, animal design, geop... [more]

Although shrimp processing wastes have been studied as source of high-value products at lab-scale, no contributions are found in the literature regarding the energetic and safety performance of shrimp-based biorefineries at pilot or large-scale. This works is focused on the inherent safety assessment and exergy analysis of a pilot-scale biorefinery designed to produce shrimp meat and four by-products: chitin, chitosan, nitrogenous extract, and astaxanthin. Total irreversibilities, exergy losses, exergy of wastes and utilities were calculated for stages and the overall process using mass and energy balances of the biorefinery. The hazards associated with chemicals and process conditions were analyzed through substance properties and process data. A Numerical Descriptive Inherent Safety Technique (NuDIST) score of 557.23 suggested a moderate level of risk for the biorefinery compared to other processes, reaching chemical and process safety scores of 185.88 and 371.35, respectively. Secti... [more]

The water supply system is one of the most important elements in a city. Currently, many cities struggle with a water deficit problem. Water is a commonly available resource and constitutes the majority of land cover; however, its quality, in many cases, makes it impossible to use as drinking water. To treat and distribute water, it is necessary to supply a certain amount of energy to the system. An important goal of water utility operators is to assess the energy efficiency of the processes and components. Energy assessments are usually limited to the calculation of energy dissipation (sometimes called “energy loss”). From a physical point of view, the formulation of “energy loss” is incorrect; energy in water transport systems is not consumed but only transformed (dissipated) into other, less usable forms. In the water supply process, the quality of energy—exergy (ability to convert into another form)—is consumed; hence, a new evaluation approach is needed. The motivation for this st... [more]

As the world grapples with the COVID-19 pandemic, there has been a sudden and abrupt change in global energy landscape. Traditional fossil fuels that serve as the linchpin of modern civilization have found their consumption has rapidly fallen across most categories due to strict lockdown and stringent measures that have been adopted to suppress the disease. These changes consequently steered various environmental benefits across the world in recent time. The present article is an attempt to investigate these environmental benefits and reversals that have been materialized in this unfolding situation due to reduced consumption of fossil fuels. The life cycle assessment tool was used hereby to evaluate nine environmental impacts and one energy based impact. These impacts include ozone formation (terrestrial ecosystems), terrestrial acidification, freshwater eutrophication, marine eutrophication, terrestrial ecotoxicity, freshwater ecotoxicity, marine ecotoxicity, land use, mineral resour... [more]

There is a burden of adequate energy supply for meeting demand and reducing emission to avoid the average global temperature of above 2 °C of the pre-industrial era. Therefore, this study presents the exergoeconomic and environmental analysis of a proposed integrated multi-generation plant (IMP), with supplemental biomass-based syngas firing. An in-service gas turbine plant, fired by natural gas, was retrofitted with a gas turbine (GT), steam turbine (ST), organic Rankine cycle (ORC) for cooling and power production, a modified Kalina cycle (KC) for power production and cooling, and a vapour absorption system (VAB) for cooling. The overall network, energy efficiency, and exergy efficiency of the IMP were estimated at 183 MW, 61.50% and 44.22%, respectively. The specific emissions were estimated at 122.2, 0.222, and 3.0 × 10−7 kg/MWh for CO2, NOx, and CO, respectively. Similarly, the harmful fuel emission factor, and newly introduced sustainability indicators—exergo-thermal index (ETI)... [more]

Heat pumps (HPs) are being developed with a new emphasis on cold climates. To lower the environmental impact of greenhouse gas (GHG) emissions, alternate low global warming potential (GWP) refrigerants must also replace the exclusive use of the refrigerant R410A, preferably without re-engineering the mechanical hardware. In this paper, we analyze the performance of four low-GWP alternative refrigerants (R32, R452B, R454B, and R466A) relative to the conventional R410A and draw conclusions on the relative performances for providing heating in cold climates based on the Air-Conditioning, Heating, and Refrigeration Institute (AHRI) 210/240 standard for two-speed heat pumps. The simulations are carried using the Department of Energy, Oak Ridge National Laboratory (DOE/ORNL) Heat Pump Design Model (HPDM), a well-known heating, ventilation, and air conditioning (HVAC) modeling and design tool in the public domain and the HVAC research and development community. The results of the simulation a... [more]

Lighting provides an indispensable energy service, illumination. The field of societal exergy analysis considers light (and many other energy products) to be enablers of economic growth, and lighting contributes a non-negligible proportion of total useful exergy supplied to modern economies. In societal exergy analysis, the exergetic efficiency of electric lamps is central to determining the exergy contribution of lighting to an economy. Conventionally, societal exergy practitioners estimate the exergetic efficiency of lamps by an energy efficiency, causing confusion and, sometimes, overestimation of exergetic efficiency by a factor as large as 3. In response, we use recent results from the fields of radiation thermodynamics and photometry to develop an exact method for calculating the exergy of light and the exergetic efficiency of lamps. The exact method (a) is free of any assumptions for the value of the maximum luminous efficacy, (b) uses a non-unity spectral exergy-to-energy ratio... [more]

A photovoltaic-thermal (PVT) collector is a solar-based micro-cogeneration system which generates simultaneously heat and power for buildings. The novelty of this paper is to conduct energy and exergy analysis on PVT collector performance under two different European climate conditions. The performance of the PVT collector is compared to a photovoltaic (PV) panel. Finally, the PVT design is optimized in terms of thermal and electrical exergy efficiencies. The optimized PVT designs are compared to the PV panel performance as well. The main focus is to find out if the PVT is still competitive with the PV panel electrical output, after maximizing its thermal exergy efficiency. The PVT collector is modelled into Matlab/Simulink to evaluate its performance under varying weather conditions. The PV panel is modelled with the CARNOT toolbox library. The optimization is conducted using Matlab gamultiobj-function based on the non-dominated sorting genetic algorithm-II (NSGA-II). The results indi... [more]

This research presents the energy, exergy, economic, and environmental assessment, and multi-objective optimization of a flash-binary geothermal CCHP cycle. A sensitivity analysis of production well inlet temperature and cooling to power flow ratio on exergetic, economic, and environmental parameters was conducted. Furthermore, the effects of the inflation rate and plant working hours on economic parameters were investigated. Results showed that increasing the production well inlet temperature harms exergy efficiency and exergetic performance criteria and results in a gain in exergo-environmental impact index and heating capacity. In addition, the total plant cost increased by raising the production well temperature. Furthermore, increasing the cooling to power flow ratio caused a reduction in exergy efficiency, exergetic performance criteria, and produced net power and an enhancement in exergy destruction, cooling capacity, and total plant cost. The exergy efficiency and total cost ra... [more]

This paper contains the basic definition and application of the physical optimum as a method for process evaluation and optimization. By means of the exemplary balance of a wood pellet-fired boiler, the conventional efficiency is compared to the PhO. Furthermore, this study demonstrates the possibility of applying the thermodynamic state variable exergy as a physical reference property of a system within the PhO method. To explain the approach, the heat generation in the wood pellet-fired boiler is compared to the supply from a heat pump, which itself is connected to a power plant. Furthermore, the process-independent PhO is explained in order to illustrate the limitations of feasible optimization. Additionally, possible research topics such as the integration of dynamic behavior in the method are approached. As a conclusion, the differences between the methods outline the advantage of the PhO in the optimization process.