The catalytic activity of metal oxides in the processes of low- and high-temperature oxidation (LTO and HTO, respectively) of oil was studied on model systems consisting of oil-saturated quartz sand with additives of Al2O3, Cr2O3 and MgO using thermal analysis methods. The used additives were shown to shift the LTO and HTO processes to the low-temperature region. The catalytic activity of a natural reservoir carbonate rock without and with water was studied. This study established that at room temperature in dry carbonate rock, the oil components undergo dealkylation and polycondensation of aromatic fragments for a week. In the presence of water, the polycondensation processes are suppressed, and the cracking of resin and asphaltene occurs. The cracking reactions lead to a decrease in the content of heteroatoms in resins and asphaltenes.

This article analyzes the key controlling factors and hydrocarbon distribution rules of lithologic reservoirs in a continental downfaulted basin according to the structural features, sedimentary evolution, types of sedimentary facies, source rock features, diagenesis evolution, reservoir features, hydrocarbon formation mechanisms, exploration status, and hydrocarbon resource potential. The results show that three major controlling factors (sandbody types, effective source rocks, and effective reservoirs) and one coupled factor (fractures that act as a tie) influence hydrocarbon accumulation in the lithologic traps in the Nantun Formation in Tanan Sag. With the increase in depth, sufficient hydrocarbon is generated in the source rock with thermal evolution. When the depth threshold is reached and critical conditions of hydrocarbon supply are met, hydrocarbon generation and expulsion are more intensive. Traps that are surrounded or contacted by source rock or connected by faults are able... [more]

Wellbore instability mainly occurs in shale formations, and it is of great significance to deeply analyze the characteristics of shale-failure behavior to evaluate the stability of the shale surrounding the well wall during drilling. Through a uniaxial compression experiment and DIC technology, the whole strain field of shale specimens with prefabricated holes and cracks under uniaxial compression is measured. The experimental data of load, displacement and strain field are analyzed comprehensively. The results show that the fracture location and expansion path of shale are closely related to the evolution of the strain field. The evolution of the strain field directly affects the failure behavior of the rock. Under the action of load, local high strain will first appear around the initial shale defects (pores and fractures), and stress concentration will occur. With the increase of load, cracks and failures will first appear in the local high-strain zone, and the failure will spread a... [more]

Based on core observation, rock thin sections, logging data, and testing data, taking the shale of the upper submember of the 4th Member to the lower submember of the 3rd Member of Paleogene Shahejie Formation in Jiyang Depression of Bohai Bay Basin as an example, we determine the lithofacies division scheme, divide the main lithofacies types, analyze the sedimentary origin and development location of different shale lithofacies, establish the continental lake basin sedimentary model, determine the types and enrichment areas of favorable lithofacies, and provide guidance for the exploration and development of Shale oil. The results show that: (1) According to the mineral composition, sedimentary structure, and organic matter abundance, the division scheme of shale lithofacies in the study area is proposed, and the shale lithofacies of the study area was mainly divided into 17 types. (2) Based on the lithologic changes, the lacustrine sedimentary shale area was divided into muddy water... [more]

This study aims to predict and evaluate the transfer behavior of silicon employing SiO2-bearing fluxes during submerged arc welding. Unlike previous studies that only focused on chemical reactions in the weld pool zone, this research investigates the elemental behavior of silicon subjected to essential reaction zones in a submerged arc welding process. The proposed method is compared with the traditional thermodynamic equilibrium models, enhancing the understanding of silicon transfer behavior in the submerged arc welding process. It is demonstrated that relying solely on thermodynamics within the weld pool zone is inadequate for accurately predicting the extent of silicon transfer level since the loss of silicon during the droplet zone and the improvement in oxygen content in the molten droplet are not considered, resulting in an overestimation of the ΔSi level. Finally, the limitations of the traditional elemental transfer quantification method and corresponding corrective suggestion... [more]

As an important natural resource, coal plays a critical role in social and economic development [...]

Proper working conditions must be one of the employers’ main concerns in any type of company but particularly in work locations where the employees are chronically exposed to hazardous compounds, like factories and production lines. Regarding this challenge, the present research addresses the mapping of a car factory painting line to possibly toxic volatile organic compounds emitted by all the coatings and chemicals used during the work shifts for the future evaluation of employees’ exposure. For the first time, a Gas Chromatography−Ion Mobility Spectrometry device was employed for the in situ detection of volatile organic compounds in an automotive factory. A total of 26 analytes were detected at nine different locations, of which 15 VOCs were accurately identified. Pure chemical-grade substances were used for the development of the VOC database. Although quantitative analysis was not the goal of this study, a calibration model was presented to one analyte for exemplificative purposes... [more]

Large-energy microseismic events, coal bursts, and other abnormal mine stress are often observed in spatial isolated island areas in the roof water-rich gob-side working face during mining operations. In view of this problem, numerical simulation and on-site microseismic monitoring are employed to study the advance abutment stress and strata fracture structure in the spatial island area formed by ‘roof drainage + goaf’ during mining and the method of eliminating the spatial island area. The results show that the lateral stress is distributed in a step-like pattern, and the drainage area and goaf are superimposed to form a high-stress space island area before the mining of the working face along the goaf. The distribution pattern of the advance abutment stress in the spatial island area changes from ‘C’ type to ‘S’ type during the mining process. The strata structure of the roof water-rich gob-side working face is either a single-peak arch or double-peak arch, and the arch peak correspo... [more]

Turbidite fans, serving as good reservoirs for petroleum accumulation, are typically formed during deep faulting periods in continental basins, particularly in steep slope zones. However, gentle slope zones are also significant and unique for the formation of turbidite fans. These turbidite fans hold immense importance in exploring concealed lithological reservoirs. Taking the Chezhen Depression of Bohai Bay Basin as an example, we conducted a comprehensive study of the turbidite fan deposits in the gentle slope zone. Our results indicate that (1) small-scale distal-source turbidite fans are a common sedimentary type in the Chezhen Depression of the Bohai Bay Basin; (2) the study area is mainly characterized by seven lithofacies; (3) there are incomplete Bouma sequences in the study interval. This study is an important turbidite investigation into continental faulted basins, and it can also provide an important reference value for exploration and development in unconventional reservoir... [more]

Shale diagenesis differs from that of sandstone and carbonate rocks with regard to the type, evolution stage, and evolution mode. The quality of shale reservoirs is closely linked to the extent of diagenetic evolution. This study identifies the types and characteristics of shale diagenesis using thin sections and scanning electron microscopy (SEM) observations. The stages of shale diagenesis are determined by analyzing organic matter evolution and clay mineral transformation and establishing a diagenetic evolution sequence. This paper describes the comprehensive diagenetic evolution of organic matter, clay minerals, clastic particles, and carbonate minerals to determine the diagenesis types, diagenetic sequences, and pore evolution occurring during diagenetic evolution. The results show that the diagenesis types of shale in the second member of the Funing Formation include compaction, dissolution, cementation, metasomatism, dolomitization, syneresis, and transformation of clay minerals... [more]

The pore fluid pressure is important for the generation, migration, and accumulation of hydrocarbons. The Chezhen Sag region in the Bohai Bay Basin is typically characterized by pore fluid overpressure, which is the difference between the pore fluid pressure and the hydrostatic pore pressure. The formation mechanisms of pore overpressure and the accumulation regularity of the “upper source-lower reservoir” type in this region remain unknown. In order to investigate these problems, based on the existing seismic, logging data, and regional tectonic stress environment, we established a two-dimensional finite element model to simulate the fluid−solid coupling processes in the Chegu 25 block of the Chezhen depression. We calculated the abnormal overpressure generated at the source rock during hydrocarbon generation and the processes of hydrocarbon migration and accumulation along the faults and analyzed the dynamic conditions of the hydrocarbon downward accumulation. The results showed that... [more]

In high-temperature wells, annular pressure buildup (APB) caused by temperature increase is a widespread phenomenon in production, especially in offshore thermal recovery wells. It increases the load on the tubing and casing and consequently threatens the wellbore integrity. Hence, research on casing safety evaluation and APB management has great significance for field production. In this paper, the tubing and casing safety evaluation and APB limit determination methods are presented considering the effect of thermal stress and APB. Based on the case study of an offshore thermal recovery well, an APB-management chart and the recommended optimal range of APB are provided. Finally, an analysis of three commonly used mitigation methods is presented. The effect and the recommended parameters of these mitigation methods are further discussed. The research results show that the thermal stress and APB phenomena affect the stress distribution of the casing and may bring great danger to the wel... [more]

The proposed planer layer dynamo physical model has real-world applications, especially in the Earth’s liquid core. Thus, in this paper, an attempt is made to understand the finite amplitude convection when there exists a coupling between the Lorentz force and the Coriolis force. In particular, the effect of a horizontally applied magnetic field is studied on the Rayleigh−Bénard convection (RBC) that contains the electrically conducting fluid and rotates about its vertical axis. Free−free boundary conditions are assumed on the geometry. Attention is focused on the nonlinear convective flow behavior during the occurrence of cross rolls which are perpendicular to the applied magnetic field and parallel to the rotation axis. The visualization of cross rolls is achieved using the Fourier analysis of perturbations up to the O(ε8). The relationship of the Nusselt number (Nu) with respect to the Rayleigh number (R), the Ekman number (E), and the Elsasser number (Λ) is investigated. It is obse... [more]

Oxy−fuel (O2/CO2) combustion technology shows great potential for carbon reduction. However, difference in the combustion atmosphere would affect coal combustion characteristics and pollutant emissions. In order to explore oxy−fuel combustion characteristics, two typical Chinese coals, sub−bituminous and lean coal, were utilized. Based on thermogravimetry and pilot−scale test, the ignition and burnout characteristics under oxy−fuel and air combustion atmosphere were investigated. Besides, the NOx emission characteristics were also investigated on the pilot−scale test. Through experimental results, these two kinds of coal showed different combustion characteristics, mainly due to differences in coal quality. Compared with air combustion, oxy−fuel combustion affected the coal combustion process. Firstly, the ignition temperature of sub−bituminous and lean coal decreased from 418 and 477 °C to 405 and 415 °C, respectively; the burnout temperature also decreased from 855 and 985 °C to 808... [more]

The surface hydrology and diffuse pollution loading is hypothesized based on the unique characteristics under different rainfall types in watersheds with a subtropical monsoon climate. This study evaluated the effects of different rainfall event intensity on surface runoff and diffuse nitrogen loss in a subtropical watershed located in the latitude range between 22.5° north and 25° north in southern China by adapting the hydrological model SWAT (Soil and Water Assessment Tool). The rainfall events were classified into four categories including light rainfall (LR), moderate rainfall (MR), intense rainfall (IR), and extreme rainfall (ER). Our results showed that the ER events had the lowest occurrences of 7 days per year, but they contributed the most to total surface runoff (54.29%) and TN losses (57.63%) in the subtropical watershed researched. Although forests and pastures had a better effect on reducing diffuse pollution, their surface runoff and nitrogen loss were still proved to be... [more]

This study uses high-speed imaging to investigate the dynamic collision behavior of a single hydrous ethanol droplet in different water/ethanol ratios on a heated horizontal glass surface. The initial droplet diameter varied from 3.3 to 4.1 mm, and the impact velocity was 0.57 m/s. The study covers a range of surface temperatures (373 K to 553 K) and ethanol mass fractions (0% to 100%) to reveal four regimes of droplet-impinging behaviors, including quiescent surface evaporation, puffing or partial boiling, explosive nuclear boiling, and the Leidenfrost effect. The addition of volatile ethanol to less volatile water shifts the droplet collision behavior toward explosive boiling and the Leidenfrost phenomenon. As the ethanol mass fraction increased from 0% to 100%, the superheat limit temperature decreased by approximately 80 K, while the Leidenfrost temperature decreased by at least 100 K. The dimensionless droplet diameter in the regime of droplet spreading with quiescent surface evap... [more]

Cavitation and cavitation erosion are complex hydrodynamic behaviors that significantly influence the stability and reliability of pumping units in aerospace and navigation power systems, hydraulic engineering, and other fields. Studies on cavitation have primarily and heavily focused on the collapse of multiple cavitation bubbles; understanding the movement of multiple cavitation bubbles is important for cavitation research. In this study, the collapse process of near-wall double-cavitation bubbles was numerically simulated and experimentally verified, and the evolution of the near-wall double-cavitation bubble collapse was investigated. Two different distances were altered in the study. The distance between the double-cavitation bubble and the distance between the cavitation bubbles and the wall, the effects of dimensionless parameters, such as the near-wall coefficient and the cavitation bubble spacing coefficient, the collapse time, jet angle, and impact load on the wall can be det... [more]

Deep reservoirs are in a high-pressure and high-temperature (HPHT) environment, while the experimental conditions for rock electrical properties that meet the deep reservoir conditions are harsh and costly. Although digital rock technology can simulate the electrical properties of rocks, it is limited to electrical simulation studies under normal temperature and pressure conditions (NPT), which limits their ability to capture the electrical characteristics of deep hydrocarbon reservoirs. This limitation affects the accuracy of saturation prediction based on resistivity logging. To simulate the rock electrical properties under HPHT conditions, we proposed a low-cost and high-efficiency HPHT digital rock electrical simulation workflow. Firstly, samples from deep formations were CT-scanned and used to construct multi-component digital rocks that reflect the real microstructure of the samples. Then, mathematical morphology was used to simulate the overburden correction under high-pressure... [more]

Hybrid electric vehicles (HEVs) have certain advantages over internal combustion engines in terms of energy consumption and emission performance. However, the transmission system parameters are uncertain. The low matching between the engine and the power transmission system makes it a big problem to improve the efficiency of hybrid vehicles. Therefore, the multi-objective optimization design of hybrid vehicles is studied. The transmission system parameters of hybrid vehicles are analyzed from the objective function, decision variables, and constraints. The NSGA-II algorithm with elite strategy is introduced to realize the optimal selection of parameters and formulation of energy consumption optimization strategy. The results showed that the multi-objective optimization algorithm could adjust the position of the working point of the engine and improve the efficiency by more than 10%. There was an average difference of 2.15% after the improvement in the fuel consumption of four-gear vehi... [more]

To address safety problems caused by goaf and water accumulation in open-pit mines, the shallow three-dimensional seismic method and transient electromagnetic method were integrated and applied to detect the mining goaf distribution scope and the water accumulation conditions. In view of the special topographic conditions of an ultrashallow layer and high drop in an open-pit mine, we proposed utilizing bin homogenization and multidomain joint denoising to improve the reliability of seismic data. By using seismic-sensitive attributes to predict the goaf, the transient electromagnetic method was employed to further predict the water accumulation in the goaf. The results show that the shallow seismic method could clearly reflect the reflected-wave variation features of the goaf. The features of a junction between a normal seam and goaf vary obviously, and the prediction effect of the goaf boundary with high resolution is in line with the actual situation. Furthermore, taking the goaf scop... [more]

The Jiuzhou fault in the Langgu Sag of the Bohai Bay Basin is a significant oil-source fault that connects source rocks and reservoirs, and thus it can transport oil and gas during the hydrocarbon accumulation period. The hydrocarbon distribution characteristics along the strike of the Jiuzhou fault differ distinctly, indicating that the transport capacity in different fault segments is also different. In this study, we focused on analyzing the fault development characteristics to accurately predict the location of favorable hydrocarbon transport pathways on the Jiuzhou fault. We found that the zones superimposed by paleo relay ramps developed before hydrocarbon accumulation, active faulting areas during hydrocarbon accumulation, and transport ridges of the fault are favourable along-fault locations for transporting hydrocarbons. Based on this idea and 3D seismic data, we investigated the distribution of the paleo relay ramps of the Jiuzhou fault and the fault activity rate during hydr... [more]

The use of multilateral wells is an important method to effectively develop complex oil reservoirs, and wellbore stability research of multilateral wells is of great importance. In the present study, the effects of formation fluids and rock damage were not taken into account by the wellbore stability model. Therefore, finite element analysis (FEA) software was used to establish a three-dimensional (3D) seepage-stress FEA model for the multilateral junctions. The model was used to analyze the wellbore stability of multilateral wells and study influences of wellbore parameters and drilling fluid density on wellbore stability at multilateral junctions. Simulation results show that the wellbore diameter insignificantly affects wellbore stability. When the angle between the main wellbore and branches enlarges to 45°, the equivalent plastic strain decreases by 0.0726, and the wellbores become more stable; when the angle is larger than or equal to 45°, the region prone to wellbore instability... [more]

The empirical formula is one of the traditional methods used for predicting ground deformation settlement caused by tunnel excavation. Due to its rationality and simplicity, the Peck formula is widely used for predicting surface subsidence. However, due to its limitations, it is necessary to modify it when predicting surface settlement caused by tunnel excavation in different strata. In this paper, a correction formula for the width coefficient of a tunnel surface settlement slot is derived from the Peck formula by taking into account the theory of strata slip cracks. Values are calculated using the correction formula and compared with measured data to verify the effectiveness of the correction formula. The main conclusions are: (1) The position corresponding to the width of the settlement in the Peck curve is the point where the formation is most prone to slip cracking. (2) In the general shallow buried case, the settlement groove width coefficient K and the internal friction angle φ... [more]

With the targets of petroleum exploration transferred to the deep and ancient strata, abundant oil and gas resources have been found in Lower Paleozoic and older strata in central and western China. Due to complex evolutionary processes including multiple episodes of hydrocarbon accumulation and ubiquitously accompanied by secondary alterations, significant uncertainties remain concerning the generation time and accumulation processes of these revealed petroleum sources. In this paper, relative pure Re and Os elements existing in the asphaltene fractions of Lower Cambrian solid bitumen collected from the Guangyuan area, western Sichuan Basin, SW China and Middle−Lower Ordovician heavy oils in the Aiding area of the Tahe oilfield in the Tarim Basin, NW China were successfully obtained by sample pretreatments, and Re−Os isotopic analysis was subsequently carried out for the dating of these. The Re−Os isotopic composition indicates a generation time of Guangyuan bitumen to between 572 Ma... [more]

To investigate gas flow characteristics in coal seams with strong anisotropy, a coupled anisotropic dual-porosity model was established. Effects of permeability anisotropy on variations in gas pressure, gas extraction volume and effective extraction areas were analyzed. Furthermore, mechanisms of crustal stress, initial gas pressure, ultimate adsorption strain and Langmuir volume constant on permeability anisotropy and extraction amount were studied. Results show that permeability anisotropy could result in an elliptical pressure drop zone around production boreholes. Changes in effective gas extraction areas are divided into three stages: slow growth in an elliptical shape, rapid growth with a superposition effect and steady growth in a funnel shape. Permeability isotropy enables faster reaching of stage III than the anisotropy case. As the vertical stress increases, gas pressure distribution around boreholes gradually changes from an ellipse with horizontal direction as long axis to... [more]