Initial design stages are inherently complex and often lack comprehensive information, posing challenges in evaluating sustainability metrics. Machine Learning (ML) emerges as a valuable solution to address these challenges. ML algorithms, particularly effective in predicting environmental impacts of new chemicals with limited data, enable more informed decisions in sustainable design. This study focuses on employing ML for predicting the environmental impacts related to human health, ecosystem quality, climate change, and resource utilization to aid in early-stage environmental impact assessment of chemical processes. The effectiveness of the ML algorithm, eXtreme Gradient Boosting (XGBoost) tested using a dataset of 350 points, divided into training, testing, and validation sets. The study also includes a practical application of the model in a cradle-to-cradle LCA of N-Methylpyrrolidone (NMP), demonstrating its utility in sustainable chemical process design. This approach signifies... [more]

The transition to net-zero greenhouse gas emissions requires a rapid redesign of energy systems. However, the redesign may shift environmental impacts to other categories than climate change. To assess the sustainability of the resulting impacts, the planetary boundaries framework provides absolute limits for environmental sustainability. This study uses the planetary boundaries framework to assess net-zero sector-coupled energy system designs for absolute environmental sustainability. Considering Germany as a case study, we extend the common focus on climate change in sustainable energy system design to seven additional Earth-system processes crucial for maintaining conditions favorable to human well-being. Our assessment reveals that transitioning to net-zero greenhouse gas emissions reduces many environmental impacts but is not equivalent to sustainability, as all net-zero designs transgress at least one planetary boundary. However, the environmental impacts vary substantially betwe... [more]

Sustainability and circular economy enclose initiatives to achieve economic systems and industrial value chains by improving resource use, productivity, reuse, recycling, pollution prevention, and minimizing disposed material. However, shifting from the traditional linear economic production system to a circular economy is challenging. One of the most significant hurdles is the absence of sustainable end-of-life (EoL)/manufacturing loops for recycling and recovering material while minimizing negative impacts on human health and the environment. Overcoming these challenges is critical in returning materials to upstream life cycle stage facilities such as manufacturing. Chemical flow analysis (CFA), sustainability evaluation, and process systems engineering (PSE) can supply chemical products and processes performances from environmental, economic, material efficiency, energy footprint, and technology perspectives. These holistic evaluation techniques can improve productivity, source mate... [more]

Sustainability of the chemical and materials industry (CMI) requires it to achieve net-zero emis-sions of greenhouse gases and other resources while making decisions that have a net-positive impact on nature and society. Many corporations, nations, and universities have pledged to meet such goals but systematic models, methods, and tools to guide this transition are missing. We pre-sent a framework to meet this need. It involves developing a comprehensive, open access model of the global CMI. In addition to existing technologies, this model includes emerging alternatives for renewable energy, circularization, and carbon capture, utilization and storage. Systematic methods help identify innovation opportunities and develop roadmaps that account for long-term changes such as technology evolution and climate change. Meeting the goal of net-zero emis-sions requires inclusion of life cycle impacts. Nature-positive decisions need to encourage eco-logical protection and restoration. Thi... [more]

This work investigates the water impact of carbon capture technologies employed in coal and natural gas power generation, viz. integrated gasification combined cycle, oxy-fuel combustion, solid oxide fuel cells and post-combustion solvent-based. The Water Impact per CO2 Avoided (WICa) metric was developed to understand the tradeoff between water usage and global warming potential, and additionally as a decision-making tool. It relates the impact on available water resources to greenhouse gas reduction over the cradle-to-plant-exit lifecycle by leveraging existing metrics, including the Water Impact Index (WII), water withdrawal, water consumption, water quality, and Water Scarcity Index (WSI). The results show that some carbon capture technologies increase the overall water usage of power generation plants, thereby increasing the water impact per CO2 avoided. Solid oxide fuel cells and oxy-fuel technology, though not mature in comparison to post-combustion capture, have the least water... [more]

The steel industry in China, the world’s largest, contributes to about 15% of the nation’s total carbon emissions. Instead of direct combustion, the technology of converting off-gas from the steel industry into liquid fuels not only enhances the added value of this byproduct but also helps alleviate carbon emissions. This study, for the first time, integrates the specific circumstances of China to evaluate the carbon emissions of Ethanol to Jet (ETJ) and Fischer−Tropsch to Jet (FTJ) fuel technologies utilizing Basic Oxygen Furnace Gas (BOFG) and Coke Oven Gas (COG) as feedstocks. Six cases were examined using Aspen Plus (V11) for mass and energy balance: Case 1: BOFG/ETJ, Case 2: BOFG/FTJ, Case 3: COG/ETJ, Case 4: COG/FTJ, Case 5: (COG + BOFG)/ETJ, and Case 6: (COG + BOFG)/FTJ. The analysis underscores that the FTJ pathway exhibits superior carbon reduction efficiency relative to ETJ. Compared to traditional petroleum-based aviation fuels (86.65 g CO2eq/MJ), the FTJ pathways utilizing... [more]

Life cycle assessment (LCA) is used to evaluate the environmental load of fibre composite manufacturing technologies in the shipyards industry in a frame of the Fibre4Yards (Horizon 2020) project. This paper is focused on the LCA of fibre-reinforced polymer (FRP) technologies used to produce all elements of the floating unit, i.e., the conventional vacuum infusion technology for the deck panel and adaptive mould process for superstructure panels, ultraviolet (UV) curved pultrusion process for the production of stiffeners, hot stamping technology for brackets, and three-dimensional (3D) printing and automatic tape placement (ATP) for pillars. Environmental impact was assessed based on standard indicators: Global Warming Potential, water consumption, and fossil resource scarcity. The results indicate that the total carbon footprint of analysed FRP technologies is mainly produced by the type of the materials applied rather than by the amount of energy consumed during the process.

Sustainable product development requires combining aspects, including quality and environmental. This is a difficult task to accomplish. Therefore, procedures are being sought to combine these aspects in the process of product improvement. Therefore, the objective of the investigation was to develop a procedure that supports the integration of quality-level indicators and life-cycle assessment (LCA) to determine the direction of product improvement. The procedure involves determining the quality indicators based on the expectations of the customer, which are subsequently processed using the formalised scoring method (PS). A life-cycle assessment index is determined for the main environmental impact criterion. According to the proposed mathematical model, these indicators are aggregated, and this process takes into account their importance in terms of product usefulness and environmental friendliness. Interpretations of the results and the direction of product improvement are from the r... [more]

The development of sustainable biofuels can help to reduce the reliance on fossil fuels and mitigate the impact of climate change. This study analyzes bioethanol production from agro-forestry residual biomass, namely eucalyptus residues and corn stover. The study includes process simulation using Aspen Plus software, followed by economic analysis and life cycle assessment (LCA) with the help of SimaPro software and by applying the environmental footprint (EF) 3.0 method. The economic analysis on the biorefinery’s economic viability, equipment, and production costs reveals a positive decision for bioethanol production from eucalyptus residues due to logistical and transportation costs. The minimum ethanol selling price (MESP) obtained was 2.19 €/L and 2.45 €/L for eucalyptus residues and corn stover, respectively. From the LCA with a functional unit of 1 MJ of ethanol, bioethanol production from eucalyptus residues results in a single score impact of 37.86 µPt, whereas for corn stover,... [more]

The early phases of product development effect fundamental changes in products throughout their life cycle. Therefore, the objective of the investigation was to develop a simplified model that supports the process of product design simultaneously in terms of qualitative and environmental factors. The model is dedicated to the design phase in the life cycle assessment of the product (LCA). The originality of the model consists in: (i) analysis of customers’ satisfaction from qualitative alternatives of products; (ii) assessments of the environmental impact of these alternatives; (iii) definition of the importance of qualitative and environmental attributes of products; and (iv) prediction of favourable changes in products according to qualitative−environmental levels. The model was tested for photovoltaic panels (PVs). The model is mainly dedicated to small and medium-sized enterprises (SMEs) for support in making decisions in the design phases of products in their life cycles.

The early phases of product development effect fundamental changes in products throughout their life cycle. Therefore, the objective of the investigation was to develop a simplified model that supports the process of product design simultaneously in terms of qualitative and environmental factors. The model is dedicated to the design phase in the life cycle assessment of the product (LCA). The originality of the model consists in: (i) analysis of customers’ satisfaction from qualitative alternatives of products; (ii) assessments of the environmental impact of these alternatives; (iii) definition of the importance of qualitative and environmental attributes of products; and (iv) prediction of favourable changes in products according to qualitative−environmental levels. The model was tested for photovoltaic panels (PVs). The model is mainly dedicated to small and medium-sized enterprises (SMEs) for support in making decisions in the design phases of products in their life cycles.

The design of distillation columns significantly impacts the economy, energy consumption, and environment of chemical processes. However, optimizing the design of distillation columns is a very challenging problem. In order to develop an intelligent technique to obtain the best design solution, improve design efficiency, and minimize reliance on experience in the design process, a design methodology based on the GA-BP model is proposed in this paper. Firstly, a distillation column surrogate model is established using the back propagation neural network technique based on the training data from the rigorous simulation, which covers all possible changes in feed conditions, operating conditions, and design parameters. The essence of this step is to turn the distillation design process from model-driven to data-driven. Secondly, the model takes the minimum TAC as the objective function and performs the optimization search using a Genetic Algorithm to obtain the design solution with the min... [more]

In this paper, a life cycle assessment was used to evaluate fuel ethanol production from food waste with a capacity of 20 tons/day. The energy and pollution emissions during the whole process were recorded and compared by the method of electricity conversion to standard coal. Different indicators, such as GWP (global warming potential), ODP (ozone depletion potential), AP (acid potential), EP (possibility of eutrophication), POCP (photochemical oxidation potential), and DUST (dust), were used to perform an environmental impact analysis with and without by-product utilization. The result shows that the indicator sequence under the weighted factor sequence was AP > DUST > GWP > ODP > EP > POCP. The consideration of by-products decreased the values of GWP, AP, and DUST significantly; EP declined slightly; ODP and POCP increased; and the overall energy output was negative. The consideration of by-product utilization was determined to be environmentally friendly.

The increasing consumption of electrical and electronic equipment (EEE), correlated with the fast innovation pace in this field, generates a large amount of annual waste. The current established management practices cannot keep up with it, and the results are of increased significance given the negative effects on the environment and human health. Thus, the current study aimed to analyze the environmental impact of three different scenarios of waste electrical and electronic equipment (WEEE) management, following population awareness campaigns regarding its collection in the Municipality of Iasi, Romania. Data processing was carried out considering Life Cycle Assessment (LCA) methodology with the established functional unit for each scenario according to the collected amount. The results were quantified using the CML2001 and ReCiPe methods and showed that the highest environmental impact was obtained for scenario II (S2) (1.59 × 10−7 pers. equiv. using the CML2001 method and 32.7 pers.... [more]

Alternative sour2ces of energy are on the rise primarily because of environmental concerns, in addition to the depletion of fossil fuel reserves. Currently, there are many alternatives, approaches, and attempts to introduce alternative energy sources in the field of transport. This article centers around the need to explore additional energy sources beyond the current ones in use. It delves into individual energy sources that can be utilized for transportation, including their properties, production methods, and the advantages and disadvantages associated with their use across different types of drives. The article not only examines the situation in the Czech Republic but also in other nations. In addition to addressing future mobility, the thesis also considers how the utilization of new energy sources may impact the environment.

Identifying decarbonization strategies at the district level is increasingly necessary to align the development of urban projects with European climate neutrality objectives. It is well known that district heating and cooling networks are an attractive energy system solution because they permit the integration of renewable energies and local excess of hot or cold sources. The detailed design and optimization of network infrastructures are essential to achieve the full potential of this energy system. The authors conducted an attributional life cycle assessment to compare the environmental profile of five distribution network infrastructures (i.e., pipes, heat carrier fluid, trenches, heat exchangers, valves, and water pumps) based on a study case in Marseille, France. The work aims to put into perspective the environmental profile of subsystems comprising a district heating infrastructure, and compare pipe typologies that can be used to guide decision-making in eco-design processing. R... [more]

Lightweight design is a common approach to reduce energy demand in the use stage of vehicles. The production of lightweight materials is usually associated with an increase in energy demand, so the environmental impacts of lightweight structures need to be assessed holistically using a life cycle assessment. To estimate the life cycle environmental impacts of a product in its developmental stage, for example, by life cycle engineering, future changes in relevant influencing factors must be considered. Prospective life cycle assessment provides methods for integrating future scenarios into life cycle assessment studies. However, approaches for integrating prospective life cycle assessment into product development are limited. The objective of this work is to provide the methodological foundation for integrating future scenarios of relevant influencing factors in the development of lightweight structures. The applicability of the novel methodology is demonstrated by a case study of a str... [more]

Glazing is considered as a preferred solution for the buildability, aesthetic, and comfort of commercial buildings since glass cover can protect occupants from external environmental conditions, ensure the light transmission, and provide view and ventilation. At the same time, in the context of climate change and global warming, the use of renewable solar energy, such as solar and wind power, are encouraged to be utilized. Specifically, solar energy has become a renewable energy source that is clean and endless, at reasonable cost, to contribute to energy security as well as ensure sustainable development. Therefore, the study proposes a method for supporting the decision making in installing solar panels on vertical glazing façades of the building in the worst case that the remaining radiant energy from the sun was only transferred to the inside of the building. The Life Cycle Assessment and the Life Cycle Costing methodologies are applied to consider both environmental and economic a... [more]

In this article, a thermodynamic, exergy, and environmental impact assessment was carried out on a Brayton S-CO2 cycle coupled with an organic Rankine cycle (ORC) as a bottoming cycle to evaluate performance parameters and potential environmental impacts of the combined system. The performance variables studied were the net power, thermal and exergetic efficiency, and the brake-specific fuel consumption (BSFC) as a function of the variation in turbine inlet temperature (TIT) and high pressure (PHIGH), which are relevant operation parameters from the Brayton S-CO2 cycle. The results showed that the main turbine (T1) and secondary turbine (T2) of the Brayton S-CO2 cycle presented higher exergetic efficiencies (97%), and a better thermal and exergetic behavior compared to the other components of the System. Concerning exergy destruction, it was found that the heat exchangers of the system presented the highest exergy destruction as a consequence of the large mean temperature difference be... [more]

The Czech Republic is introducing new technological concepts for mitigation of greenhouse gases (GHG) in coal-based energy industries. One such technology, in power plants, is post combustion CO2 capture from flue gases by activated carbon adsorption. A life cycle assessment (LCA) was used as the assessment tool to determine the environmental impacts of the chosen technology. This article focuses on a comparative LCA case study on the technology of temperature-swing adsorption of CO2 from power plant flue gases, designed for the conditions of the Czech Republic. The LCA study compares the following two alternatives: (1) a reference power unit and (2) a reference power unit with CO2 adsorption. The most significant changes are observed in the categories of climate change potential, terrestrial acidification, and particulate matter formation. The adsorption process shows rather low environmental impacts, however, the extended LCA approach shows an increase in energy demands for the proce... [more]

Renewable fuel standards for biofuels have been written into policy in the U.S. to reduce the greenhouse gas (GHG) intensity of transportation energy supply. Biofuel feedstocks sourced from within a regional market have the potential to also address sustainability goals. The U.S. Mid-Atlantic region could meet the advanced fuel designation specified in the Renewable Fuel Standard (RFS2), which requires a 50% reduction in GHG emissions relative to a gasoline baseline fuel, through ethanol produced from winter barley (Hordeum vulgare L.). We estimate technology configurations and winter barley grown on available winter fallow agricultural land in six Mid-Atlantic states. Using spatially weighted stochastic GHG emission estimates for winter barley supply from 374 counties and biorefinery data from a commercial dry-grind facility design with multiple co-products, we conclude that winter barley would meet RFS2 goals even with the U.S. EPA’s indirect land use change estimates. Using a conser... [more]

California has set two ambitious targets aimed at achieving a high level of decarbonization in the coming decades, namely (i) to generate 60% and 100% of its electricity using renewable energy (RE) technologies, respectively, by 2030 and by 2045, and (ii) introducing at least 5 million zero emission vehicles (ZEVs) by 2030, as a first step towards all new vehicles being ZEVs by 2035. In addition, in California, photovoltaics (PVs) coupled with lithium-ion battery (LIB) storage and battery electric vehicles (BEVs) are, respectively, the most promising candidates for new RE installations and new ZEVs, respectively. However, concerns have been voiced about how meeting both targets at the same time could potentially negatively affect the electricity grid’s stability, and hence also its overall energy and carbon performance. This paper addresses those concerns by presenting a thorough life-cycle carbon emission and energy analysis based on an original grid balancing model that uses a combin... [more]

In the last twenty years, research activity around the environmental applications of metal−organic frameworks has bloomed due to their CO2 capture ability, tunable properties, porosity, and well-defined crystalline structure. Thus, hundreds of MOFs have been developed. However, the impact of their production on the environment has not been investigated as thoroughly as their potential applications. In this work, the environmental performance of various synthetic routes of MOF nanoparticles, in particular ZIF-8, is assessed through a life cycle assessment. For this purpose, five representative synthesis routes were considered, and synthesis data were obtained based on available literature. The synthesis included different solvents (de-ionized water, methanol, dimethylformamide) as well as different synthetic steps (i.e., hours of drying, stirring, precursor). The findings revealed that the main environmental weak points identified during production were: (a) the use of dimethylformamide... [more]

Fossil fuel vehicles, emitting air toxics into the atmosphere, impose a heavy burden on the economy through additional health care expenses and ecological degradation. Air pollution is responsible for millions of deaths and chronic and acute health problems every year, such as asthma and chronic obstructive pulmonary disease. The fossil-fuel-based transportation system releases tons of toxic gases into the atmosphere putting human health at risk, especially in urban areas. This analysis aims to determine the economic burden of environmental and health impacts caused by Highway 401 traffic. Due to the high volume of vehicles driving on the Toronto Highway 401 corridor, there is an annual release of 3771 tonnes of carbon dioxide equivalent (CO2e). These emissions are mainly emitted onsite through the combustion of gasoline and diesel fuel. The integration of electric and hydrogen vehicles shows maximum reductions of 405−476 g CO2e per vehicle-kilometer. Besides these carbon dioxide emiss... [more]

In recent years Asian Nations showed concern over the Life Cycle Assessment (LCA) of their civil infrastructure. This study presents a contextual investigation of a residential apartment complex in the territory of the southern part of India. The LCA is performed through Building Information Modelling (BIM) software embedded with Environmental Product Declarations (EPDs) of materials utilized in construction, transportation of materials and operational energy use throughout the building lifecycle. The results of the study illustrate that cement is the material that most contributes to carbon emissions among the other materials looked at in this study. The operational stage contributed the highest amount of carbon emissions. This study emphasizes variation in the LCA results based on the selection of a combination of definite software-database combinations and manual-database computations used. For this, three LCA databases were adopted (GaBi database and ecoinvent databases through One... [more]