The growth in the number of vehicles circulating has led to a proportional increase in polluting gas emissions. Bioenergy can be used to help meet these increasing energy demands and mitigate environmental impacts. This work verified the effect of the content of ethanol on the exergy and exergoenvironmental analyses of a spark-ignition engine. Different gasoline−ethanol mixtures were tested along with hydrous ethanol (4.6% water by volume). The thermodynamic data refer to wide-open throttle conditions and variable engine speeds. The life cycle assessment methodology quantified the environmental impacts associated with equipment and fuel using the Eco-indicator 99 method. Pollutants emitted during combustion were measured and included in the environmental assessment (nitrogen oxides, carbon monoxide, and dioxide). Hydrous ethanol at 1500 rpm presented the highest energy efficiency. The effects of the environmental impact rate of pollutant formation and exergy efficiency were significant... [more]

The growth in the number of vehicles circulating has led to a proportional increase in polluting gas emissions. Bioenergy can be used to help meet these increasing energy demands and mitigate environmental impacts. This work verified the effect of the content of ethanol on the exergy and exergoenvironmental analyses of a spark-ignition engine. Different gasoline−ethanol mixtures were tested along with hydrous ethanol (4.6% water by volume). The thermodynamic data refer to wide-open throttle conditions and variable engine speeds. The life cycle assessment methodology quantified the environmental impacts associated with equipment and fuel using the Eco-indicator 99 method. Pollutants emitted during combustion were measured and included in the environmental assessment (nitrogen oxides, carbon monoxide, and dioxide). Hydrous ethanol at 1500 rpm presented the highest energy efficiency. The effects of the environmental impact rate of pollutant formation and exergy efficiency were significant... [more]

This study focuses on the measurement of sub-23 nm particles emitted from a small DI/PFI spark ignition engine through conventional techniques and innovative systems. Measurements were performed with well-known systems, such as the EEPS coupled to a PMP-compliant sample conditioning device. Moreover, a novel instrument developed within the European project Sureal-23, the advanced HM-DMA, capable of operating with a simplified conditioning setup was used. The engine was fueled with ethanol, both pure and in blend at 30% v/v. The effects of fuel on the particle emissions were analyzed at different operating conditions. The results highlighted that a larger fraction of emissions consists of particles smaller than 23 nm, and their number changes according to the fuel, injection strategy and operating condition. A significant effect of the sampling system conditions was observed reveling the inception of nucleation mode particles or the condensation of the volatiles onto existing particles... [more]

To understand the effect of hydrogen addition on the laminar burning velocity (LBV) of ethanol−air mixtures, experiments were conducted in a constant volume combustion chamber with the high-speed schlieren photography technique. The experiments were carried out under the equivalence ratios (ERs) of 0.7−1.4, an initial temperature of 400 K, an initial pressure of 0.1 MPa, and hydrogen fractions of 30% and 90% by volume, respectively. The effects of ER, initial temperature, initial pressure, and hydrogen fractions on the LBV were investigated. Moreover, adiabatic flame temperature (AFT), heat release rate (HRR), flow rate sensitivity analysis, and ROP (rate of production) analysis were also performed. Results showed that LBV increased with increasing hydrogen addition and temperature but decreased with increasing pressure. The hydrogen addition significantly increased the HRR of ethanol−hydrogen−air flames. The sensitivity analysis showed that R5 (O2 + H = O + OH) significantly influence... [more]

The present work describes highly efficient hydrogen production from ethanol in a plasma-catalytic reactor depending on the discharge power and catalyst bed temperature. Hydrogen production increased as the power increased from 15 to 25 W. A further power increase to 35 W did not increase hydrogen production. The catalyst was already active at a temperature of 250 °C, and its activity increased with increasing temperature to 450 °C. The further temperature increase did not increase the activity of the cobalt catalyst. The most important advantage of using the catalyst was the increased ethanol conversion to CO2 instead of CO production. As a result, the hydrogen yield was very high and reached 4.1 mol(H2)/mol(C2H5OH). This result was obtained with a stoichiometric molar ratio of water to ethanol of 3.

With the world’s energy resources decreasing, ethanol/acetone/ethyl acetate mixed fuel has the potential as a fossil fuel alternative or oxygenated fuel additive. In this work, the burning characteristics of ethanol/acetone/ethyl acetate mixed fuels including 3 pure fuels, 9 binary fuels, and 7 ternary fuels were studied at a temperature of 358 K, the pressure of 1 bar, and the equivalence ratios of 0.7 to 1.4 in the constant volume combustion chamber (CVCC). The burning velocities of the ternary fuels were compared at ϕ = 0.8, 1.0, and 1.4. The results show that the laminar burning velocities of the mixed fuels are affected by the contents of ethanol, acetone, and ethyl acetate. The Markstein length, Markstein number, and burning flux were also analyzed in this paper. Furthermore, a detailed chemical mechanism comprising 506 species and 2809 reactions was reduced to a skeletal mechanism including 98 species and 642 reactions, using the directed relation graph with error propagation (D... [more]

Many countries have adopted the addition of biodiesel to diesel as a way of inserting renewable content into mineral fuel and making a contribution to the environment. The addition of ethanol to the diesel/biodiesel blend to increase the renewable content of the added fuel blend and reduce the percentage of biodiesel could be a strategysince the demand for biodiesel production is high, and this fuel has a high production cost when compared to ethanol. Thus, this study evaluated the performance and the content of NOx, CO and CO2 exhaust gases from a diesel engine fueled with blends of diesel/biodiesel/ethanol: pure B7, B7E3 (B7 with 3% ethanol) and B7E10 (B7 with 10% ethanol). Emissions of fuel blends were evaluated using the engine speed variation and tested at a speed of 1500 rpm under constant load (185 Nm). Assays were performed at engine speeds of 1000, 1100, 1250, 1500 and 1750 rpm and with loads of 10, 25, 50, 75 and 100% of the maximum torque. Through the performance curves, the... [more]

Wet ethanol is a biofuel that can be rapidly integrated into the existing transportation sector infrastructure and have an immediate impact on decarbonization. Compared to conventional hydrocarbon fuels, wet ethanol has unique fuel properties (e.g., short carbon chain, oxygenated, high heat of vaporization, no cool-flame reactivity), which can actually improve the efficiency and engine-out emissions of internal combustion engines while decarbonizing. In this work, wet ethanol 80 (80% ethanol, 20% water by mass) was experimentally studied at high loads under boosted conditions in compression ignition to study the tradeoffs in efficiency and emissions based on boosting and injection strategies. Specifically, this work explores the potential of adding a third, mixing-controlled injection at high loads. The results indicate that adding a third, mixing-controlled injection results in combustion stabilization at high loads, where the peak pressure limit of the engine is a constraint that req... [more]

The brown Tunisian seaweed Halopteris scoparia was used as a feedstock for producing renewable bioethanol, biogas, and biodiesel to demonstrate the proof of concept for the North African energy sector. A quantitative and qualitative quantification of H. scoparia composition using different colorimetric methods was completed to highlight its bioconversion potential. These substrate inputs were subjected to anaerobic fermentation by Saccharomyces cerevisiae to produce bioethanol. The materials were also used to generate bio-hydrogen and volatile fatty acids during dark fermentation by a bacterial consortium and using the oleaginous yeast Yarrowia lipolytica. The lipids were extracted and trans-esterified to Fatty Acid Methyl Esters (FAMEs), and their profiles were then analyzed with gas chromatography (GC). A significant ratio of the bioethanol, e.g., 0.35 g ethanol/g DW substrate, was produced without pretreatment, consistent with the theoretical Gay-Lussac yield. The production of the... [more]

This article presents a method for quantification of methanol and ethanol integrated in the same gas-chromatographic run with a quantification of gases dissolved in mineral oil, making it an integrated tool in transformer diagnostics. The results of aging experiments at 120 °C and 60 °C of Kraft paper, copper, barrier, and pressboard immersed in mineral oil, as well as the aging of thermal upgrade paper in mineral and natural ester oil at 140 °C are presented, in order to investigate correlations between different aging markers and to evaluate their partitioning between oil and cellulose at defined conditions. The results of partitioning experiments at 60 °C showed that re-absorption of methanol from oil to the cellulose materials is faster than the re-absorption of furans. This means that methanol is a paper-degradation marker that can be used in diagnostics over shorter equilibrium times and for the detection of developing faults at broader temperature ranges. Furthermore, a statisti... [more]

The constantly growing number of vehicles sold and operated has resulted in greater contribution of automobiles to global pollution. One way to reduce emissions of carbon dioxide (CO2) and toxic compounds, including the particulates and nitrogen oxides (NOx) contained in exhaust gases, is to use alternative fuels. Within this group of fuels, those of plant origin, mainly alcohols, are attracting more and more attention because of their high oxygen content (around 35%), low viscosity, and good atomisation. However, alternative fuels have different physicochemical properties than diesel fuel, and these may affect the formation of the fuel spray, which, in turn, impacts the operation of the internal combustion engine, operating parameters, and the purity of the exhaust gases emitted into the environment. To make sure this type of fuel can be used in compression ignition engines, it is necessary to gain a thorough understanding of the phenomena and relationships occurring during fuel injec... [more]

The objective of this review is to provide a deep overview of liquid biofuels produced from sugarcane bagasse and to address the economic challenges of an ethanol and acetone-butanol-ethanol blend in commercial processes. The chemistry of sugarcane bagasse is presented. Pretreatment technologies such as physical, chemical pretreatment, biological, and combination pretreatments used in the fermentation process are also provided and summarised. Different types of anaerobic bacteria Clostridia (yeast) are discussed to identify the ingredient best suited for sugarcane bagasse, which can assist the industry in commercializing ethanol and acetone-butanol-ethanol biofuel from biomass sugarcane. The use of an acetone-butanol-ethanol mixture and ethanol blend in internal combustion engines is also discussed. The literature then supports the proposal of the best operating conditions for fermentation to enhance ethanol and acetone-butanol-ethanol plant efficiency in the sugar waste industry and i... [more]

The growing level of modern environmental problems and the need to ensure energy security creates new challenges for the development of the energy sector. Nowadays, countries must balance their international competitiveness and progress in achievement the Sustainable Development Goals. This provides a necessity for the development of alternative energy technologies. Modern trends in the development of alternative energy indicate a gradual increase in the relevance of biofuel production. At the same time, the development of clean energy technologies needs significant investments, and their commercial implementation is a long process. Moreover, energy industry transformations require significant changes in the functioning of complementary spheres. That makes necessary the use of additional incentives for the development of the bioenergy sector. Thus, an assessment of the impact of environmental taxes on biofuel production and consumption becomes crucial. This research is aimed at the ide... [more]

Adsorption heat storage is the most feasible technology for heating decarbonization, which can store large quantities of waste and renewable heat for an exceptionally long time. However, utilizing adsorption heat storage in geographical locations with sub-zero ambient conditions is challenging. Therefore, this paper experimentally investigates the use of ethanol as a working fluid paired with silica gel for adsorption heat storage and utilizes sub-zero ambient as the heat source. The heat storage characteristics, heat charging/discharging cyclic performance, and energy conversion performance via exergy analysis were determined under realistic operating conditions and benchmarked against the widely investigated silica gel/water. Ethanol adsorbate was successfully utilized as a working fluid to employ the evaporators operating under sub-zero ambient conditions. Silica gel/ethanol showed the most significant net cyclic uptake, twice that of silica gel/water. However, the physical characte... [more]

This study aims to provide a review of the state-of-the-art literature regarding the impacts and contributions of corn ethanol on retail gasoline prices in the US. For this, a systematic literature review following PRISMA statement was carried out, seeking to answer four research questions: (1) What are the main characteristics of the literature regarding the impact and contributions of ethanol on US retail gasoline prices? (2) What are the main article clusters identified in the evaluated literature? (3) What was the numerical impact of the Volumetric Ethanol Excise Tax Credit/Renewable Fuel Standard (VEETC/RFS) mandate on the price of gasoline and what are the main methods used for calculation in the literature? (4) What are the main trends and possibly new research directions for this literature? As a result of the characterization of the sample, driving themes, such as energy policy, costs, price dynamics, trade and energy market, were identified. Furthermore, three main clusters w... [more]

The emissions from direct injection (DI) diesel engines remain a serious setback from the viewpoint of environmental pollution, especially for those who have been persuaded to use biofuel as an alternative fuel. The main drawbacks of using biofuels and their mixtures in DI diesel engines are increased emissions and decreased brake thermal efficiency (BTE) compared to using neat diesel fuel. The current study analyses the biodiesel made from cashew nut shell liquid (CNSL) using a single-cylinder, direct-injection diesel engine to validate the engine’s performance and discharge characteristics. In addition to the improved CNSL and a twin-fuel engine that runs on hydrogen, ethanol was added to the fuel at rates of 5%, 10%, and 15%. The investigation was conducted using a single-cylinder direct injection diesel engine at steady-state settings, above the sustained engine speed (1500 RPM). Several performance parameters and pollutant emissions, such as hydrocarbons (HC), carbon monoxide (CO)... [more]

Laser technology is being widely studied for controlled energy deposition for a range of applications, including flow control, ignition, combustion, and diagnostics. The absorption and scattering of laser radiation by liquid droplets in aerosols affects propagation of the laser beam in the atmosphere, while the ignition and combustion characteristics in combustion chambers are influenced by the evaporation rate of the sprayed fuel. In this work, we present a mathematical model built on OpenFOAM for laser heating and evaporation of a single droplet in the diffusion-dominated regime taking into account absorption of the laser radiation, evaporation process, and vapor flow dynamics. The developed solver is validated against available experimental and numerical data for heating and evaporation of ethanol and water droplets. The two main regimes—continuous and pulsed laser heating—are explored. For continuous laser heating, the peak temperature is higher for larger droplets. For pulsed lase... [more]

Algae are regarded among the most favorable feedstocks for producing sustainable biodiesel and utilizing it in diesel engines. Additionally, ethanol addition further enhanced the performance and reduce greenhouse emission. Algae biodiesel was produced, and an experimental study was performed to understand the diesel engine performance and emissions characteristics using different fuel blends by varying the ratio of diesel, biodiesel, and ethanol, such as D100, B10, B20, B5E5, and B10E10 (where number shows the percentage of the respective fuel). It was found that brake thermal efficiency was reduced by 0.49% and 1.29% for B10 and B20 blends, while the addition of ethanol enhanced the BTE by 0.37% and 1.60% respectively. However, SFC increases by 1.45%, 2.14%, 3.18%, and 3.78% respectively for B10, B20, B5E5, and B10E10 with respect to diesel fuel. Combustion characteristics were increased with increasing concentration of biodiesel and ethanol addition. Particulate matter, smoke emissio... [more]

Lipid vesicles, especially giant lipid vesicles (GLVs), are usually adopted as cell membrane models and their preparation has been widely studied. However, the effects of some nonelectrolytes on GLV formation have not been specifically studied so far. In this paper, the effects of the nonelectrolytes, including sucrose, glucose, sorbitol and ethanol, and their coexistence with sodium chloride, on the lipid hydration and GLV formation were investigated. With the hydration method, it was found that the sucrose, glucose and sorbitol showed almost the same effect. Their presence in the medium enhanced the hydrodynamic force on the lipid membranes, promoting the GLV formation. GLV formation was also promoted by the presence of ethanol with ethanol volume fraction in the range of 0 to 20 percent, but higher ethanol content resulted in failure of GLV formation. However, the participation of sodium chloride in sugar solution and ethanol solution stabilized the lipid membranes, suppressing the... [more]

Air pollution, especially in large cities around the world, is associated with serious problems both with people’s health and the environment. Over the past few years, there has been a particularly intensive demand for alternatives to fossil fuels, because when they are burned, substances that pollute the environment are released. In addition to the smoke from fuels burned for heating and harmful emissions that industrial installations release, the exhaust emissions of vehicles create a large share of the fossil fuel pollution. Alternative fuels, known as non-conventional and advanced fuels, are derived from resources other than fossil fuels. Because alcoholic fuels have several physical and propellant properties similar to those of gasoline, they can be considered as one of the alternative fuels. Alcoholic fuels or alcohol-blended fuels may be used in gasoline engines to reduce exhaust emissions. This study aimed to develop a gasoline engine model to predict the influence of different... [more]

Corn ethanol bio-refineries are seeking economic processing strategies for recovering oil from their coproducts. The addition of ethanol can be an efficient method to recover the oil from the coproducts as the industry has available ethanol. This study considered the effects of ethanol on oil recovery from distillers’ dried grains with solubles (DDGS) and oil partitioning from whole stillage (WS) on a laboratory scale. Ethanol was added with original and heavier fraction DDGS in different temperatures (room temperature ~20 °C, 30 °C, 40 °C, and 50 °C) and solids loadings (20%, 30%, and 40%), and their effects on oil recovery were evaluated. The whole stillage was incubated with ethanol at room temperature (~20 °C) and 50 °C separately to analyze WS’s oil distribution in the liquid and solid phases. The amount of recovered oil from the original and heavier fractions of DDGS varies from 25−45% and 45−70%, respectively, with an increment of temperature. Increasing solids loadings up to 30... [more]

Waste heat recovery (WHR) in exhaust gas flow of automotive engines has proved to be a useful path to increase the overall efficiency of internal combustion engines (ICE). Recovery potentials of up to 7% are shown in several works in the literature. However, most of them are theoretical estimations. Some present results from prototypes fed by steady flows generated in an auxiliary gas tank and not with actual engine exhaust gases. This paper deals with the modeling and experimental validation of an organic Rankine cycle (ORC) with a swash-plate expander integrated in a 2 L turbocharged petrol engine using ethanol as working fluid. A global simulation model of the ORC was developed with a maximum difference of 5%, validated with experimental results. Considering the swash-plate as the main limiting factor, an additional specific submodel was implemented to model the physical phenomena in this element. This model allows simulating the fluid dynamic behavior of the swash-plate expander us... [more]

Over the years, due to the surge in energy demand, the use of alternative fuels has emerged as an interesting area of research. In the current work, a comparative study was conducted by employing gasoline, 6% ethanol−gasoline (E6), and 12% ethanol−gasoline (E12) in a spark-ignition engine. Performance, emissions, and lube oil damage tests were conducted at a constant load by varying engine speed. E12 showed improved performance, i.e., 7.82% higher torque and 14.69% improved brake thermal efficiency (BTE) in comparison with neat gasoline. In addition, CO, CO2, HC, and NOx emissions were found to be minimal for E12. Furthermore, lubricating oil properties (kinematic viscosity, flash point, and total base number (TBN)) and wear debris (iron, aluminum, and copper) showed a visibly improved performance with gasoline compared to E6 and E12. The highest decline in kinematic viscosity of 27.87%, compared to fresh oil, was recorded for E12. Thus, the lube oil properties have to be modified acco... [more]

is an important microbial organization involved in ethanol synthesis. Mutant strains that can withstand multiple pressures during this process are critical to the industrial development of biofuels. In this study, a dual high-throughput screening method of Triphenyl-2H-tetrazoliumchloride (TTC)-based macroscopic observation and the reaction of ferric nitrate with pyruvate (or pyruvate radical ion) in fermentation broth was used. Using this, an S. cerevisiae mutant library that could tolerate 381 g/L sucrose was established by ARTP random mutation and adaptive evolution to select the best strain; its ethanol yield was increased by an additional 20.48%; and the sucrose utilization rate was 81.64%. This method is specific to the selection of strains with increased ethanol production.

In this work, an algorithm was developed to determine different possibilities of distillation cuts to support productivity and improve the final quality of cachaça, a Brazilian spirit beverage. The distillation process was simulated using the Aspen Plus® software, considering a wide range of fermented musts compositions available in the literature obtained by fermentation with different yeast strains. Twenty-four simulations were carried out considering eight compounds as follows: water and ethanol (major compounds); acetic acid, acetaldehyde, ethyl acetate, 1-propanol, isobutanol, and isoamyl alcohol (minor compounds). The calculations considered a long-time process, i.e., until almost all the ethanol in the fermented must was distilled. The algorithm enabled the identification of countless distilling cuts, resulting in products with different alcoholic grades and process yields. One fermented must became viable to produce cachaça after the suggested non-traditional method of cuts pro... [more]