The rising trend towards continuous production in the field of small-scale crystallization has generated many creative concepts for apparatuses for the production of active pharmaceutical ingredients. One of these promising apparatuses is the Slug Flow Crystallizer (SFC), which enables the adjustment of the particle size distribution and the achievement of high yields through its alternating slug flow. To realize and understand the crystallization inside the SFC, high experimental effort has been necessary until now. Therefore, a mechanistic model considering the hydrodynamics of slug flow, the energy and mass balances, and the crystallization phenomena of growth and agglomeration inside the apparatus was developed. Its purpose is to improve the understanding of the process, estimate the effects of operating parameters on target properties, and predict crystallization behavior for different substance systems with minimal experimental effort. Successful modeling was validated with exper... [more]

This work primarily investigates the performance and structural integrity of the Wells turbines for power production in coastal locations and their associated unmanned vehicles. An innovative design procedure is imposed on the design stage of the Wells turbine and thus so seven different models are generated. In the first comprehensive investigation, these seven models underwent computational hydrodynamic analysis using ANSYS Fluent 17.2 for various coastal working environments such as hydro-fluid speeds of 0.34 m/s, 1.54 m/s, 12 m/s, and 23 m/s. After this primary investigation, the best-performing Wells turbine model has been imposed as the second comprehensive computational investigation for three unique design profiles. The imposed unique design profile is capable of enhancing the hydro-power by 15.19%. Two detailed, comprehensive investigations suggest the best Wells turbine for coastal location-based applications. Since the working environments are complicated, additional advance... [more]

The multi-stage pulse competition of pressurized pulsed water jet becomes the initial pulse at the head tip, and hydraulic parameters are the key parameters that affect the characteristics of multiple pulses. Based on the ultra-high-speed imaging system, a pressurized pulsed water jet flow field capture system was constructed, and the effects of initial pressure and driving pressure of the pressurized chamber on the characteristics of multi-stage pulses were studied. The experimental results show that as the initial pressure of the booster chamber increases, the jet changes from a discontinuous state to a continuous state, and the multi-level pulse simultaneously changes from dominant multi-pulse to implicit multi-pulse; as the driving pressure increases, the initial spacing between the first pulse and the second pulse increases, and the peak velocity of the initial pulse gradually increases. At the same time, the location of the peak velocity also shifts away from the nozzle as the dr... [more]

Severe erosion phenomena often occur in industrial polycrystalline silicon units, leading to hydrogen leakage accidents and affecting long-term operation. It is favorable to use a computational fluid dynamics (CFD) simulation with the dense discrete phase model (DDPM) and the sub-grid energy-minimization multi-scale (EMMS) drag model to improve the prediction accuracy of complex multiphase erosion phenomena in a connecting pipe of an industrial polycrystalline silicon unit. Furthermore, the effect of droplet the specularity coefficient on boundary conditions is thoroughly considered. The predicted erosion behaviors are consistent with industrial data. The effects of operations parameters were discussed with three-dimensional CFD simulation, including droplet size and hydrogen volume fraction on erosion behaviors. The results indicated that the non-uniform multiphase erosion flow behavior near the wall can be simulated accurately with the EMMS drag model in a coarse mesh. A suitable dro... [more]

Vacuum freeze-dried products exhibit properties characteristic of porous media, rendering them superior in both drying and rehydration capabilities. However, the process of sublimation drying is constrained by its substantial time and energy costs. To comprehensively grasp its technological process and identify the optimal process parameters, the cellular automata method was employed for sublimation process simulation. Carrot slices, measuring 10 mm in thickness and 40 mm in radius, were selected for both simulation and experimentation. The sublimation process was characterized using a two-dimensional heat and mass transfer equation, inclusive of a dusty gas model. Additionally, a cellular automaton model was applied to simulate the mass transfer process, temperature, and moisture content changes in the sublimation drying stage. Then, the accuracy of the model was verified through experimentation. There was a remarkable alignment between simulation and experimental outcomes, with deter... [more]

The present work is a numerical analysis of electro-thermo convection, occurring in a square differentially heated cavity filled with a dielectric fluid. The cavity experiences the combined effects of viscous, electrical, and thermal forces. The equations modelling the physical problem are solved via the finite volume approach. The study focuses on the effect of cavity tilt on the fluid flow structure and thermal performance inside the enclosure under the action of an electric field. A parametric study was performed, where the tilt angle is getting varied between 0° and 90°, as well as the Rayleigh number (5000 ≤ Ra ≤ 250,000) and the electric field (0 ≤ T ≤ 800). Furthermore, the electric charge injection level C, the mobility M and the Prandtl Pr numbers were all adjusted to a value of 10. The obtained results demonstrate that the hydrodynamic and thermal fields are significantly impacted by the cavity inclination. In addition, regardless of the thermal Rayleigh’s number, high electr... [more]

This paper presents a comprehensive computational fluid dynamics (CFD) model for describing the oxidative coupling of methane (OCM) carried out in fixed-bed reactors for olefin production. Initially, a single pellet model was developed and implemented to describe the heat and mass transfer within the pellet and between the gaseous and solid phases. Subsequently, sensitivity analyses were performed to assess the impact of pellet arrangement and feed conditions on the heat and mass transfer rates, subsequently affecting concentration and temperature profiles. As indicated by the simulations, a high ethylene content could be obtained with the increase in the CH4/O2 ratio, aligning well with previous experimental studies. Furthermore, it was observed that pellet arrangement can significantly affect the reactor performance. Additionally, the behavior of temperature and concentration in the gaseous and solid phases can be very different, such that pseudo-homogeneous modeling approaches shoul... [more]

Carbon dioxide (CO2) is widely used in the prevention and control of spontaneous coal combustion. In this manuscript, three low-rank coals with different metamorphic degrees were selected as the research objects. The temperature-programmed experiments, in situ infrared cooling experiments, simulation of the competitive adsorption of CO2 and oxygen (O2) in coal pores, and simulation study of the CO2 inhibition of the coal oxygen composite reaction were used to obtain the role and effect of CO2 in preventing oxygen adsorption in coal at the low-temperature oxidation stage. It was concluded that CO2 can displace the O2 near the pore wall to physically prevent the adsorption of O2. Through the changing law of heating rate and a kinetics analysis, it was found that CO2 can increase its activation energy by 5.3−108.3% during the slow heating stage of coal and reduce its heat rate. At around 120 °C, coal loses the protective effect of CO2. From the changes in functional groups, it can be seen... [more]

Separating heavy components from natural gas not only enhances safety, improves pipeline transportation, ensures product quality, and addresses environmental considerations, but it also exerts an influence on global energy trends. Therefore, separating heavy components is necessary and can result in beneficial goods. This article presents a comprehensive study on the process simulation and optimization of the recovery of natural gas condensate via the combined refrigeration of a mixture of ethane and propane as a refrigerant. The optimization objectives include maximizing the recovery of ethane and propane, minimizing energy consumption, and achieving desired product quality targets. A sensitivity analysis was performed to assess the impact of key parameters on process performance. Using Aspen HYSYS software, the influence of the cooler outlet stream temperature and expander outlet stream pressure on the shaft power and profit of a dry gas compressor was analyzed based on the operating... [more]

In recent years, lithologic oil and gas reservoirs have become an important target in continental hydrocarbon-bearing basins. Geophysical prospecting technology using seismic data is an indispensable tool for oil and gas exploration. However, while previous work has paid much attention to the seismic responses of reservoirs (sandstones), the seismic responses of depositional sequences composed of sandstone−mudstone cycles are not well understood in reservoir prediction. This problem seriously restricts efficient oil−gas exploration and development. The Cretaceous Baxigai Formation in the Yingmaili area, west of the Tabei Uplift, is an important exploration target for lithologic oil and gas reservoirs in the Tarim Basin. The Baxigai Formation is deeply buried with thin thickness. The Baxigai Formation in the study area is divided into a lower sandstone section and an upper mudstone section. Braided river delta sand bodies are developed in the lower sandstone section, and braided river d... [more]

Currently, most explored oil fields in Russia are at a late stage of development, and in order to maintain high levels of oil production, it is rational to put into operation fields with hard-to-recover reserves. For complicated oil fields, in particular fields with high-viscosity oil, the known traditional methods of development are ineffective. Therefore, the search for new technologies for the development and operation of such fields to significantly increase oil recovery and intensify production is of fundamental importance. One such method of heat treatment of the bottomhole formation zone is the use of heat and gas generating systems on site. In this work, new results were obtained on physical modeling of thermochemical reaction initiation with delayed-action catalyst (2,2-bis(hydroxymethyl)butanoic acid) filtration tests on composite core models of sandstone and carbonate with foam heat generation and initiating additives of binary type. Using hydrodynamic modelling, the results... [more]

High-speed water jets are widely used in deep mining and the in-depth study of jet characteristics helps to improve drilling efficiency. Three-dimensional Large Eddy Simulation is used to simulate turbulent flows generated by an organ-pipe nozzle. The simulation is validated with existing experimental data and is focused on the evolution and interaction of cavitation bubbles and vortices. Dynamic mode decomposition is performed to extract structural information about the different motion modes and their stability. Results show that the dominant fluid frequency is positively correlated with inlet pressure while unrelated to the divergence angle. Meanwhile, jets’ oscillation is amplified by a large divergence angle, which facilitates the occurrence of cavitation. Results about the flow field outside of an organ-pipe nozzle advance the understanding of the basic mechanism of cavitation jets.

This is the supplementary material for the Foundations of Computer Aided Process Design (FOCAPD 2024) Conference Proceedings: Novel Cost-Efficient Tributyl Citrate Production Process presented in the Systems and Control Transactions series

The understanding of the impact of buoyancy-driven flow on the migration of respiratory droplets remains limited. To investigate this phenomenon, the Lagrangian−Eulerian approach (k-ε turbulent model and discrete phase model) was employed to analyze the interaction between buoyancy-driven flow and coughing activity. The simulation approach was validated by simulating a jet problem in water. Although this problem describes the jet penetration in water, the governing equations for this problem are the same as those for coughing activity in the air. The results demonstrated that an umbrella-shaped airflow was generated above a person and a temperature stratification existed in the room. The buoyancy-driven flow significantly altered the dispersion pattern of the droplets. Notably, for large droplets with an initial diameter of 100 μm, the flow in the boundary layer led to an increased deposition time by about five times. Conversely, for small droplets with an initial diameter of 20 μm, th... [more]

Direct atomization of a free-flowing glass melt was carried out using a high-speed flame with the aim of producing tiny, self-expanding glass melt droplets to form hollow glass microspheres. Atomization experiments were carried out using a specially adapted free-fall atomizer in combination with a high-power gas burner to achieve sufficient temperatures to atomize the melt droplets and to directly expand them into hollow glass spheres. In addition, numerical simulations were carried out to investigate non-measurable parameters such as hot gas velocities and temperatures in the flame region by the finite volume-based software Star CCM+® (v. 2022.1.1), using the Reynolds-Averaged Navier−Stokes (RANS) turbulence and the segregated flow model. To calculate the combustion process, the laminar flamelet method was used. The experiments and simulations indicated that a maximum gas velocity of about 170 m/s was achieved at the point of atomization in the flame. The particle size distribution of... [more]

High-speed planetary mixers can rapidly and efficiently combine rheological liquids, such as polymer resins and paste materials, because of the large centrifugal forces generated by the planetary motion of the mixing vessel. Only a few attempts have been made to computationally model and analyze the intricate mixing patterns of highly viscous substances. This paper presents meshless flow simulations of the planetary mixing of polymeric fluids. This research utilized the smoothed particle hydrodynamics (SPH) approach for numerical calculations. This method has advantages over the finite-volume method, which is a grid-based computational technique, when it comes to modeling interfacial and free surface flow problems. Newtonian rheology and interfacial surface force models were used to calculate the dissipative forces in the partial differential momentum equation of fluid motion. Simulations of the flow of an uncured polyurethane resin were carried out while it was mixed in a planetary mi... [more]

In order to solve the problem of the low qualification rate of the pilling and coating of small-grain forage seeds, a vibration force field is introduced to the traditional vertical disk coating machine to promote the mixing of materials and improve the qualification rate of the pilling. Using the typical small-grain forage seed red clover as an example, we used the vibration force field after adding seed powder particles to a coating pot for the theoretical analysis of the force situation, using the discrete element software EDEM to construct a red clover seed simulation model with the coefficient of discretization as the evaluation index. We studied the effects of the rotational speed of the coating pot, the vibration frequency of the pot, the amplitude of the vibration of the pot, and the other operating parameters of the pot on the uniformity of the seed powder mixing, with the pelletization of the pass rate as the physical evaluation standard, using a one-way test to study the eff... [more]

Tungsten, essential in the industrial, military, and civilian domains and deemed a strategic resource by various nations, necessitates careful consideration in room and pillar mines due to the potential instability and safety hazards posed by untouched mine pillars, making tungsten recovery crucial for worker safety and economic gain. This research aims to provide guidance for recovering tungsten from mine pillars and making mining operations safer for workers in the Xianglushan mine. Numerical simulations are conducted to study the mechanical response of a preformed roadway in a backfill body subjected to static and dynamic loads with various explosive distances and positions. Blasting vibration velocity and blasting-induced damage in the backfill body are extracted to evaluate the mechanical response of the backfill body. The numerical results indicate that the steel frame and preformed roadway remain stable under the influence of both gravity and the impact from blasting, using a ch... [more]

This study considers the practical issue of severe noise observed in a multi-stage sleeve control valve within an engineering project. Employing computational fluid dynamics (CFD) methodology, we initially performed numerical simulations to analyze the steady-state flow field within the control valve. Subsequently, we identified the underlying factors contributing to the noise issue within the valve. To assess the aerodynamic noise of the control valve, we applied the FW-H acoustic analogy theory and determined the intensity and distribution characteristics of the aerodynamic noise. Finally, we validated the numerical simulation results of the aerodynamic noise against theoretical calculations. Our findings indicate that the steam medium experiences high-speed flow due to disturbances caused by various components within the valve, resulting in significant turbulence intensity. This intense turbulence leads to pressure fluctuations in the steam, serving as the main catalyst for noise ge... [more]

The existing possibilities for modeling the kinetics of supercritical processes at the molecular level are considered from the point of view that the Second Law of thermodynamics must be fulfilled. The only approach that ensures the fulfillment of the Second Law of thermodynamics is the molecular theory based on the discrete−continuous lattice gas model. Expressions for the rates of the elementary stage on its basis give a self-consistent description of the equilibrium states of the mixtures under consideration. The common usage today of ideal kinetic models in SC processes in modeling industrial chemistry contradicts the non-ideal equation of states. The used molecular theory is the theory of absolute reaction rates for non-ideal reaction systems, which takes into account intermolecular interactions that change the effective activation energies of elementary stages. This allows the theory to describe the rates of elementary stages of chemical transformations and molecular transport at... [more]

A new method incorporating geophysical analysis and geological analysis is proposed to define the sedimentary characteristics and distributions in basins with few drilling wells to promote the exploration of reservoirs. This method is applied to a study, through which its principles, closed-loop workflow and technologies are introduced in detail and the sedimentary characteristics and distributions of the study area are accurately defined. During the application process of the method, a compatible geological model is established, based on which the seismic data are interpreted and the results derived from the interpretation are further verified via seismic forward modeling. The study results exhibit a successive sand-rich deposition from the retrogradational gully-filling gravity flow deposition including near-shore fans, slope fans and basin-floor fans delimited by different slope break belts in transgressive sequences to the progradational delta deposition in a retrogressive sequence... [more]

The utilization of metallurgical waste heat for urban sludge drying and dewatering not only affects the subsequent cost of sludge treatment but also provides a pathway for the rational utilization of metallurgical waste heat. The influence of different experimental conditions on sludge drying characteristics, such as drying temperature and thickness, was analyzed based on metallurgical waste heat. Based on the analysis and evaluation of the drying kinetics parameters of commonly used drying mathematical models, a modified Midilli drying kinetic model is proposed. The kinetic parameters and effective diffusivity of sludge drying were analyzed in three stages of sludge drying: rising rate, constant rate, and falling rate. By utilizing the Arrhenius equation, the relationship between the effective diffusion coefficient and thermodynamic temperature is established, revealing the apparent activation energies for the three stages of urban sludge drying as 29.772 kJ·mol−1, 37.129 kJ·mol−1, an... [more]

Directed at the problems of low positioning accuracy and irregular section forming of cutting heads of road header in coal mine production sites, a new cutting head positioning system based on ultra-wideband positioning technology is proposed based on the cutting head motion model and the working principle of ultra-wideband positioning technology, which verifies the anti-interference and the accuracy of its positioning. Combined with the simulation experiment under on-site working conditions, the influence degree of three typical influencing factors on positioning accuracy was obtained, and the accuracy optimization of the ultra-wideband positioning system was guided. Through the dynamic solution experiment, the positioning accuracy of the system is measured, and the results are verified based on the positioning system solution accuracy evaluation standard.

The homogeneous field measurement of internal flow and spray of internal combustion engine injector nozzles under high pressure has always been one of the difficulties in experimental research. In this paper, an actual-size aluminum alloy nozzle is designed, and the simultaneous measurement of internal flow and near-field spray is successfully realized with the help of synchrotron radiation X-ray phase contrast imaging technology under an injection pressure of 30~90 MPa. For a 0.25 mm aperture nozzle, different radii of the inlet corner can induce different cavitation layer thicknesses, and the measured flow section shrinkage ratio is 0.70. The flow characteristics in the nozzle are entirely connected to the jet characteristics, indicating a tight correlation between internal flow and jet morphology. Finally, the internal cavitation of the nozzle was studied by the CFD simulation, and the simulation results are in good agreement with the experiment.

In deep oil reservoirs, the existence of associated gas generally has a crucial impact on crude oil properties and flow performance. In this work, adopting molecular dynamic simulation, we studied the occurrence characteristics of oil with associate gas methane (the molar ratio of methane to oil rm/o were 1/4, 2/3, 3/2, and 4/1) in nano-pore throat and the displacement behavior of oil and methane in the water flooding process. Simulation results indicated: (1) an increasing replacement of the adsorption-status oil by methane as the methane content increased; (2) the oil and methane displacement efficiency was enhanced as the methane content increased in the water displacement oil and gas process; (3) the threshold displacement pressure gradually decreases as the methane content increases. The microscopic characteristics of the occurrence features and displacement performance of crude oil with associated methane in nano-pore throat were discussed in detail, and the underlying mechanism... [more]