In this study, novel lanthanide-containing double-decker polyhedral oligomeric silsesquioxanes (POSS) were prepared by combining the partially condensed TetraSilanolPhenyl POSS with terbium (Tb3+) and europium (Eu3+) ions. This open-cage POSS possesses four diametrically opposite silanol groups that are able to coordinate, under mild conditions, different luminescent ions through a simple corner-capping method. The two metal-containing POSS functionalized with Tb3+ and with an equimolar combination of Tb3+ and Eu3+ show a completely condensed structure with different luminescent properties. Their emission features depend on the chemical nature of the metal ions incorporated in the framework. An improved stokes shift was detected in the bimetallic compound containing both the Tb3+ and Eu3+ ions, promoted by the occurrence of a Tb3+→Eu3+ energy transfer mechanism. These characteristics identify this metal-functionalized silica platform as a potential candidate for the development of nove... [more]

This article deals with the influence of the final drying degree of moist biomass used as fuel in a power or CHP plant on indirect dryer sizing. For a description of the drying process, experiments with wet bark containing approx. 50 wt% of water were carried out in a laboratory indirect dryer. A new parameter called drying effectivity was introduced, whose size varies according to the degree of biomass being dried. Its maximum value corresponds to the optimal biomass drying, when the relative size of the indirect dryer to evaporate the required mass of water from the biomass would be smallest. Based on the experimentally determined drying characteristics of wet bark, the optimal drying of 13 wt% of water content was evaluated. If the bark was dried to a lower water content, the required relative size and price of the dryer would increase. Similarly, drying a bark with water content above 31 wt% is not very advantageous because drying effectivity continues to increase rapidly at this s... [more]

Screen-printed electrodes-based sensors can be successfully used to determine all kinds of analytes with great precision and specificity. However, obtaining a high-quality sensor can be difficult due to factors such as lack of reproducibility, surface contamination or other manufacturing challenges. An important step in ensuring reproducible results is the cleaning step. The aim of the current work is to help researchers around the world who struggle with finding the most suitable method for cleaning screen-printed electrodes. We evaluated the cleaning efficiency of different chemical compounds and cleaning methods using cyclic voltammetry and electrochemical impedance spectroscopy. The percentage differences in polarization resistance (Rp) before and after cleaning were as follows: acetone—35.33% for gold and 49.94 for platinum; ethanol—44.50% for gold and 81.68% for platinum; H2O2—47.34% for gold and 92.78% for platinum; electrochemical method—3.70% for gold and 67.96% for platinum.... [more]

The removal of radionuclides from the primary coolant system of nuclear power plants occurs with the dissolution of corrosion metal oxide layers deposited with the radionuclides. Kinetic dissolution experiments were conducted with a synthetic magnetite specimen in the form of a thin plate using an aqueous solution of oxalic acid as a reducing agent. The effects of acid concentration and temperature were investigated on the kinetics of the reductive dissolution of a magnetite specimen. In particular, the kinetic experiments were performed in a wide temperature range from low (57 °C) to high (120 °C), above the normal boiling point of water. The dissolution of magnetite increased with increasing acid concentration and temperature. The acid concentration dependence of the dissolution reaction rate of Fe at a given temperature was correlated with the nth power of the oxalic acid concentration. Additionally, the temperature dependence of the dissolution reaction rate of Fe at a fixed oxalic... [more]

The biodegradation of phenol, sodium salicylate (SA), and 4-chlorophenol (4-CP) by Pseudomonas putida (P. putida) was evaluated by batch and chemostat experiments in single and binary substrate systems. The Haldane kinetics model for cell growth was chosen to describe the batch kinetic behavior to determine kinetic parameters in the single or binary substrates system. In the single phenol and SA system, the kinetic constants of μm,P = 0.423 h−1, μm,A = 0.247 h−1, KS,P = 48.1 mg/L, KS,A = 71.7 mg/L, KI,P = 272.5 mg/L, and KI,A = 3178.2 mg/L were evaluated. Experimental results indicate that SA was degraded more rapidly by P. putida cells compared to phenol because SA has a much larger KI value than phenol, which makes the cells less sensitive to substrate inhibition even though the μ value is larger compared to μm,A. The ratio of inhibition of phenol degradation due to the presence of SA (IA) to the inhibition of SA degradation due to the presence of phenol (IA) is 2.3, indicating that... [more]

Paracetamol can induce hypothermia in humans and rodents. The study’s aim is to review the mechanisms of paracetamol-induced hypothermia in rodents or the results issued from in vitro studies on the same species’ tissues (in doses that do not produce hepatic impairment) using the latest developments published in scientific journals over the last 15 years. Available human studies are also analysed. An extensive search in PubMed databases exploring the hypothermic response to paracetamol was conducted. 4669 articles about paracetamol’s effects on body temperature in mice or rats were found. After applying additional filters, 20 articles were selected for review, with 9 of them presented in tabular forms. The analysis of these articles found that the hypothermic effect of paracetamol is due to the inhibition of a cyclooxygenase-1 variant, is potentiated by endothelin receptor antagonists, and can be mediated through GABAA receptors and possibly through transient receptor potential cation... [more]

Heavy metals mainly enter tea from the soil. In this study, stratified soil samples were collected, at a depth of 0−60 cm, using a soil drill in An-tea plantations. Speciation of As, Cd, Cr, Cu, Ni, Pb, and Zn was determined using the European Community Bureau of Reference sequential extraction method, and the heavy metal concentrations in the extracts were determined by inductively coupled plasma−mass spectrometry. Compared with other soil layers, the mean Cd, Cu, Pb, and Zn concentrations were highest in the 0−20 cm layer, the Ni concentrations were highest in the 20−40 cm layer, and the As and Cr concentrations were highest in the 40−60 cm layer. The mean contributions of the non-residual fractions, including the acid-soluble, reducible, and oxidizable fractions, to the total concentrations were higher than those of the residual fraction for Cr, Cu, and Ni at all depths in soil from a flat area, as well as for Cd and Zn at all depths in soil from a sloping area. The contributions of... [more]

Diffusion coefficients, D, for ethanol in supercritical carbon dioxide (scCO2) were measured in the temperature range 306.15−331.15 K and along the 10.5 MPa isobar, using the Taylor dispersion technique. The obtained diffusivities ranged from 1.49 × 10−8 to 2.98 × 10−8 m2 s−1, an order of magnitude higher than in usual liquids. The dependence of D on temperature and solvent density was examined. Various correlation models based in the hydrodynamic theory were assessed to estimate the diffusion coefficients, with reasonable results obtained for the Wilke−Chang and Lai−Tan models.

The distribution of gas contents in the No.5 coal seams of the Weibei Field of southeastern Ordos Basin, North China, is highly variable and its mechanism remains unclear. In this study, systematic evaluation of the gas content and its geological control factors are conducted based on the field investigation together with 16 coalbed methane (CBM) wells in the Weibei Field, southeastern Ordos Basin, North China. The gas content variability is determined from the perspectives of gas generation, migration, and preservation. The results indicate that the gas generation is largely relevant with the subsidence and fluctuation of the coal seam during the middle-late Yanshanian orogeny, which controls the gas content variability of the Weibei Field. Besides, gas migration and preservation determine the gas content on a regional scale, significantly related to fault types, roof lithology, burial depth, and hydrodynamic conditions, but scarcely affected by the roof thickness. In the Weibei Field... [more]

Plasma is the fourth state of matter, contrasted with the other states: solid, liquid, and gas [...]

Because surface roughness is similar to the size of the sealing gap in terms of scale, the effect of surface roughness on sealing performance must be considered. A calculation model determining the micro-gap flow and surface roughness is used to prove that the existence of surface roughness can effectively improve the sealing performance and that it can especially improve the opening force. The results indicated that the opening force of the lubrication film increases as the surface roughness increases and that the growth rate increases as the rotating speed increases. Due to different roughness sensitivities, the opening force increases differently in different parts of the seal. With regard to leakage, the roughness of the rotating ring’s grooved zone only increases the negative leakage when the rotating speed is higher than 8000 rpm. When the non-grooved zone of the rotating ring is rough, it can inhibit the negative leakage flow and cause the negative leakage to become positive whe... [more]

The soil at ancient roasting sites in the surroundings of the Idrija mine (Slovenia) is highly contaminated with mercury. To assess the impact of mercury on groundwater by infiltration and find an eco-friendly remediation method, the leaching of mercury from the soil containing 1347 mg Hg/kg, followed by sorption of the total leached mercury on cost-effective natural zeolite (NZ) clinoptilolite, was performed. The leaching of soil in ultrapure water of pHo = 3.00−11.46 after 24 h resulted in the total leached mercury concentration in the range 0.33−17.43 µg/L. Much higher concentrations (136.9−488.0 µg/L) were determined after the first few hours of leaching and were high above the maximum permissible level in water for human consumption. The NZ showed very good sorption of the total leached mercury, with a maximum removal efficiency of 94.2%. The leaching of mercury in presence of the NZ resulted in a significant decrease of the total leached mercury (1.9−20.3 µg/L compared to 12.8−42... [more]

This study attempted to assess the influence of mechanical forces on potato, tapioca, wheat, rice, and maize starch granules. For this purpose, we used digital analysis of microscopic images of starch granules before and after starch grinding using ImageJ software. Additionally, we studied the influence of temperature on the size and shape of starch granules by drying the starches for 30 min at 60 °C. Our results indicate that mechanical forces very rarely cause damage to starch granules, such as breaking or cracking. In most cases, the action of mechanical forces results only in smoother shape of starch granules and their shrinking, linked with rising temperature. Results of this study show that ImageJ software can be successfully used to assess starch granule size and shape.

In the present work, the reaction pathways and the origin of catalytic activity for the production of lactic acid from glycerol catalyzed by an iridium−heterocyclic carbene (Iridium-NHC) complex at 383.15 K were investigated by DFT study at the M06-D3/6-311++G (d, p)//SDD level. Compared to the noncatalytic reaction pathway, the energy barrier sharply decreased from 75.2 kcal mol−1 to 16.8 kcal mol−1 with the introduction of the iridium−NHC complex. The catalytic reaction pathway catalyzed by the iridium−NHC complex with a coordinated hydroxide included two stages: the dehydrogenation of glycerol to 2,3-dihydroxypropanal, and the subsequent isomerization to lactic acid. Two reaction pathways, including dehydrogenation in terminal and that in C2-H, were studied. It was found that the formation of dihydroxyacetone from the H-removal in C2-H was more favorable, which might have been due to the lower energy of LUMO, whereas dihydroxyacetone could be easily transferred to 2,3-dihydroxypropa... [more]

The study addresses the topic of disasters associated with the electricity sector in relation to strengthening its resilience as one of the basic elements of critical infrastructure. One of the important tools for the management of risks associated with the electricity sector is the activity and functioning of emergency boards, which are used during large-scale disasters. At the emergency board meeting, the current situation and the expected development of the event are assessed, possible solutions are proposed, and decisions are taken to coordinate activities at the strategic management level and to plan the disaster management process. Decision-making processes in the emergency board are often characterized by a high level of uncertainty in the incoming information. The case study and the research conducted are focused on the specific conditions of the Czech Republic. The purpose of the study is to assess the level of development of crisis-management plans with an emphasis on the ele... [more]

The increased use of plastics has seen the emergence of microplastics, which have become progressively more problematic. Although many degradation studies have been conducted to address the problem of microplastics, their impact has not been significant, and much time has been consumed. In this study, low-density polyethylene (LDPE) was degraded using a dielectric barrier discharge (DBD) plasma under various electrical conditions. The experimental results showed that after 120 min of treatment, the removal efficiency reached 5.44%, the carbonyl index (CI) was 1.7308, and the O/C ratio was 0.028. The degree of degradation shown in previous studies was achieved rapidly, and experimental results showed that the degree of LDPE degradation and energy yield was proportional to the voltage and frequency—more specifically, the degree of LDPE surface and internal degradation differed, which should be considered in terms of reducing the extent of mass loss. The results of this study should be he... [more]

As a topic of widespread concern in the international community, the issue of energy prices has “increased in popularity” in recent years due to its prominent strategic position and the impact of the development of alternative renewable resources [...]

The current challenges in the energy crisis, triggered primarily by the Russo-Ukrainian conflict, have had an unprecedented impact on investment in the energy market [...]

The issue of detecting and locating defects generating partial discharges (PDs) is very important for the proper functioning of power grids. Despite the existence of many localization methods, both very large and relatively small objects are still a challenge due to the problem of obtaining the required measurement accuracy. This article presents the idea of the method of PD localization in small objects of simple structure with the use of a system of four capacitive probes. Based on the relative difference in the amplitudes of the signals recorded by the pair of capacitive sensors and considering their distance characteristics, it is possible to determine the place where the PD pulses are generated. In the example of measurements made on a support insulator, it was shown that the location of a defect using the proposed method allows for an indication accuracy of up to 0.5 cm.

The problem of hydraulic parameters estimation lies in the depth: the deeper the rock formation, the more expensive and difficult the field tests and samples acquisition, and the more challenging the technical issues. The article assesses the Triassic sandstone’s drainage potential at the stage of shaft sinking. It focuses on parameter analysis in varied scales, from drill-core sample laboratory testing, through a single well drawing test, to long-term pumping and recovery tests in the well with observation piezometers. The obtained results are compared to the values estimated in the past using different methods. Finally, the paper states whether it is reliable to forecast pore-fissure sandstone drainage potential based only on core samples’ laboratory tests. This research proved that lab tests underestimate pore-fissure rocks’ hydraulic parameters (mean hydraulic conductivity k = 9.79 × 10−8 m/s) tenfold more than long-term pumping tests (mean k = 4.45 × 10−7 m/s). However, it can be... [more]

The depletion of fossil fuels has led to a search for new methods of fuel and chemical production from biomass. One of the methods of converting biomass into valuable products is the process of pyrolysis. This process has been extensively researched in recent years due to the rising prices of energy and chemicals. This work contains basic information on the pyrolysis process concerning the individual components present in the biomass and the types of biomass used in the pyrolysis process. Particular attention was paid to sewage sludge, the management of which is a big challenge. The influence of the most important process parameters (temperature, heating rate, residence time of the solid and vapor, reaction atmosphere) on the pyrolysis products (char, oil, and gas) was presented. The paper presents an overview of the reactors used in the pyrolysis process, from slow to fast pyrolysis, together with their efficiency, advantages, and disadvantages. The analysis of the application of othe... [more]

Previous studies have shown that shale oil mobility depends on the relative content of free oil and adsorbed oil. However, the research on how to establish a shale oil mobility evaluation is relatively insufficient. This study aims to use pyrolysis data before and after extraction to accurately identify the content of free oil and adsorbed oil, analyze the influencing factors of shale oil mobility, characterize the hydrocarbon generation and expulsion process, and evaluate shale oil mobility. We utilized an integrated mineralogical and geochemical dataset from the PS18-1 well in the Liutun Sag, Dongpu Depression, Bohai Bay Basin. The results show that the adsorption capacity of type I organic matter (OM) on shale oil is greater than that of type II OM, the OM abundance is of great significance to shale oil mobility, and that quartz and feldspar can promote shale oil mobility. The Tmax corresponding to the threshold of hydrocarbon expulsion is 438~440 °C, and the oil saturation index (O... [more]

Load flow solutions refer to the steady-state stability of power systems and have a crucial role in the design and planning of slow-changing elements; e.g., in online tab changing actions, automatic generation control, over-excitation limiters and the power recovery characteristics of a load. Therefore, the purpose of this work was to show the connectivity between load flow analysis and long-term voltage stability using a generator model by introducing a novel voltage stability assessment based on the multi-machine dynamic model along with the load flow study for a power grid. The Euclidean distance (ED) was used to introduce a new voltage stability index based on the voltage phasor profile for real-time monitoring purposes. The effects of reactive power compensation, in addition to load-generation patterns and network topology changes in the system behavior, could be seen clearly on the voltage profiles of the buses. Thus, the increased values for the EDs of the buses’ voltage amplitu... [more]

Aiming at the delay caused by the phase-locked loop (PLL) and harmonic detection in the traditional control of a series active power filter (SAPF), a deadbeat direct control (DBDC)-based finite control set model predictive control (FCS-MPC) strategy for the SAPF is proposed in this work. Firstly, a reference voltage generation mechanism based on direct control is established, which avoids the delay in harmonic detection, thus improving the dynamic response performance of the system. Secondly, the reference current generation mechanism suitable for the SAPF is derived and established using the deadbeat control (DBC) in the αβ coordinate system, based on which the FCS-MPC system is constructed. It eliminates the complex coordinate transformation and PLL and effectively compensates for the full-frequency harmonic voltage. Finally, the proposed control strategy is verified by a simulation and an experiment. The results suggest that the proposed control strategy can effectively compensate f... [more]

The areas on the roofs of animal production facilities present great potential for generating solar energy. However, the impact that the addition of new material on the roof can generate on the installation’s thermal environment is still poorly studied. Thus, this study aims to investigate the effect of the application of photovoltaic panels in the roofs of prototypes, in reduced-scale aviaries, on the thermal environment, and on the animal comfort condition inside the prototypes. For this, six prototypes of aviaries on a reduced 1:5 scale are used. They are equipped with three types of tiles (ceramic, fiber-cement, and metal), with and without a photovoltaic panel. The effect of applying the photovoltaic panel is verified by evaluating the air temperature, the surface temperature of the roofs, the temperature and humidity index (THI), the black globe humidity index (BGHI), and the radiation heat load (RHL). The results show that applying the photovoltaic panel on the roof, regardless... [more]