The hydrogen economy is one of the possible directions of development for the European Union economy, which in the perspective of 2050, can ensure climate neutrality for the member states. The use of hydrogen in the economy on a larger scale requires the creation of a storage system. Due to the necessary volumes, the best sites for storage are geological structures (salt caverns, oil and gas deposits or aquifers). This article presents an analysis of prospects for large-scale underground hydrogen storage in geological structures. The political conditions for the implementation of the hydrogen economy in the EU Member States were analysed. The European Commission in its documents (e.g., Green Deal) indicates hydrogen as one of the important elements enabling the implementation of a climate-neutral economy. From the perspective of 2050, the analysis of changes and the forecast of energy consumption in the EU indicate an increase in electricity consumption. The expected increase in the pr... [more]

Hydrogen has the potential to decarbonize a variety of energy-intensive sectors, including steel production. Using the life cycle assessment (LCA) methodology, the state of the art is given for current hydrogen production with a focus on the hydrogen carbon footprint. Beside the state of the art, the outlook on different European scenarios up to the year 2040 is presented. A case study of the transformation of steel production from coal-based towards hydrogen- and electricity-based metallurgy is presented. Direct reduction plants with integrated electric arc furnaces enable steel production, which is almost exclusively based on hydrogen and electricity or rather on electricity alone, if hydrogen stems from electrolysis. Thus, an integrated steel site has a demand of 4.9 kWh of electric energy per kilogram of steel. The carbon footprint of steel considering a European sustainable development scenario concerning the electricity mix is 0.75 kg CO2eq/kg steel in 2040. From a novel perspect... [more]

The production, storage, and use of hydrogen for energy purposes will become increasingly important during the energy transition. One way to use hydrogen is to apply it to power vehicles. This green technological solution affects low-emissions transport, which is beneficial and important, especially in cities. The authors of this article analyzed the use of hydrogen production infrastructure for bus propulsion in the city of Katowice (Poland). The methods, used in the study, included a greedy algorithm and cost methods, which were applied for the selection of vehicles and identification of the infrastructure for the production, storage and refueling of hydrogen, as well as to conduct the economic analysis during this term. The article presented the complexity of the techno-economic analysis of the infrastructure and its installation. The key element was the selection of the number of vehicles to the hydrogen production possibilities of an electrolyser and capabilities of the storage an... [more]

In this paper, the results of an experimental study on hydrogen production at a tungsten discharge electrode with negative polarity in the DC electrolysis of a typical 10 wt% Na2CO3 aqueous solution in three operational regimes (the Faradaic, transition, and plasma-driven solution electrolysis (PDSE)) are presented for the first time. To focus the study on hydrogen production, a flowing inert gas (argon) was used to transport the gas mixture produced at the discharge electrode and prevent any other potential chemical reactions. The results showed that the highest hydrogen production rate of 0.147 g(H2)/h was achieved in the cathodic PDSE regime at the applied DC voltage of 198 V. However, the energy yield of hydrogen production of 0.405 g(H2)/kWh obtained at the applied voltage range of 141−170 V in the PDSE regime was lower than that obtained in the Faradaic regime (0.867 g(H2)/kWh) at 28 V. The energy balance of hydrogen production in the cathodic PDSE regime for the typical aqueous... [more]

Hydrogen is a key enabler of a sustainable society. Refurbishment of the existing natural gas infrastructure for up to 100% H2 is considered one of the most energy- and resource-efficient energy transportation methods. The question remains whether the transportation of 100% H2 with reasonable adaptions of the infrastructure and comparable energy amounts to natural gas is possible. The well-known critical components for refurbishment, such as increased compressor power, reduced linepack as well as pipeline transport efficiencies, and their influencing factors were considered based on thermodynamic calculations with a step-by-step overview. A H2 content of 20−30% results in comparable operation parameters to pure natural gas. In addition to transport in pipelines, decentralized H2 production will also play an important role in addressing future demands.

In the context of the need to significantly reduce greenhouse gas emissions from personal transportation, a new process for the production of e-methanol is presented. It is a CO2 hydrogenation process, powered mainly by renewable energy sources such as photovoltaic electricity, with direct capture of carbon dioxide from the ambient air. With the main objective of estimating the feasibility and the impact of such a large-scale plant, the various components are evaluated in terms of masses and quantities necessary for an annual fuel production of 500,000 tons. The main reactor is analyzed to assess the required quantities of hydrogen and CO2. The production of hydrogen from the electrolysis of water is estimated, as well as the electrical power required and supplied by a large photovoltaic plant. The size of a realistic plant and its footprint are estimated. In addition, the mass of seawater to be desalinized and split in the electrolyser is calculated. The CO2 capture system is evaluate... [more]

Land available for energy production is limited in cities owing to high population density. To reach the net zero goal, cities contributing 70% of overall greenhouse gas emissions need to dramatically reduce emissions and increase self-sufficiency in energy production. Environmental infrastructures such as sewage treatment and incineration plants can be used as energy production facilities in cities. This study attempted to examine the effect of using environmental infrastructure such as energy production facilities to contribute toward the carbon neutrality goal through urban energy systems. In particular, since the facilities are suitable for hydrogen supply in cities, the analysis was conducted focusing on the possibility of hydrogen production. First, the current status of energy supply and demand, and additional energy production potential in sewage treatment and incineration plants in Seoul, were analyzed. Then, the role of these environmental infrastructures toward energy self-s... [more]

The Italian National Recovery and Resilience Plan (NRRP) includes, among other measures, investments in hydrogen vehicle refuelling stations, intending to promote the use of fuel cell electric vehicles (FCEVs) for long-haul freight transport. This paper evaluates the impact that this action could have on CO2 emissions and fuel consumption, focusing on a case study of the Campania region. The proposed approach, which can also be transferred to other geographical contexts, requires the implementation of a freight road transport simulation model; this model is based on the construction of a supply model, the estimation of road freight demand, and an assignment procedure for computing traffic flows. This study covers the period from 2025 to 2040, according to the forecasts of the NRRP and some assumptions on the action effects; moreover, it is assumed that hydrogen is entirely produced from renewable sources (green hydrogen). The key findings from three different scenarios show that saving... [more]

This paper reports the critical reviews on the gassing tendency of different insulating fluids along with the precautionary measures to be considered during their fault diagnosis in transformer insulation. The experimental techniques and procedures for identifying the gassing due to electrical and thermal stress along with the stray gassing phenomenon has been elucidated. The different interpretation schemes used for determining the faults in transformers results in unexpected errors when the historical data relating to mineral oil is used for the other alternative fluids. Mineral oil and natural ester show a positive gassing tendency compared to synthetic ester which exhibit a negative gassing tendency. The stray gases are mostly due to breakage of C-C bonds under normal operating temperature of transformer. Among the different hydrocarbons, hydrogen and ethylene are more predominantly formed under lower temperatures. The silicone oil and ester fluids are more stable even under locali... [more]

The emissions from direct injection (DI) diesel engines remain a serious setback from the viewpoint of environmental pollution, especially for those who have been persuaded to use biofuel as an alternative fuel. The main drawbacks of using biofuels and their mixtures in DI diesel engines are increased emissions and decreased brake thermal efficiency (BTE) compared to using neat diesel fuel. The current study analyses the biodiesel made from cashew nut shell liquid (CNSL) using a single-cylinder, direct-injection diesel engine to validate the engine’s performance and discharge characteristics. In addition to the improved CNSL and a twin-fuel engine that runs on hydrogen, ethanol was added to the fuel at rates of 5%, 10%, and 15%. The investigation was conducted using a single-cylinder direct injection diesel engine at steady-state settings, above the sustained engine speed (1500 RPM). Several performance parameters and pollutant emissions, such as hydrocarbons (HC), carbon monoxide (CO)... [more]

The effects of hydrolysis methods (hydrothermal, acid, alkali, hydrothermal-enzyme, acid-enzyme, and alkali-enzyme) on hydrolysate characteristics and photo fermentative hydrogen production (PFHP) of corn straw (CS) and sorghum straw (SS) were investigated. The optimum production of reducing the sugar of straw in different solvent environments was studied by one-step hydrolysis and co-enzymatic hydrolysis pretreatment through a 3,5-dinitrosalicylic acid method. The hydrogen production process by photolytic fermentation of hydrolysates of Rhodobacter sphaeroides HY01 was further analyzed through a gas chromatograph, including the differences in accumulated PFHP yield, chemical oxygen consumption (COD), and volatile fatty acid (VFA) composition. The results showed that the highest reducing sugar yield was obtained by the acid method among one-step hydrolysis. In contrast, acid-enzyme hydrolysis can further increase the reducing sugar yield, which reached 0.42 g·g−1-straw of both straws.... [more]

In the current study, plain and lignin loaded with Zeolite Y, hydrogen was decomposed in a pyrolysis chamber. The reaction parameters were optimized and 390 °C, 3% catalyst with a reaction time of 40 min were observed as the most suitable conditions for better oil yield. The bio-oil collected from the catalyzed and non-catalyzed pyrolytic reactions was analyzed by gas chromatography mass spectrometry (GCMS). Catalytic pyrolysis resulted in the production of bio-oil consisting of 15 components ranging from C3 to C18 with a high percentage of fuel range benzene derivatives. Non-catalytic pyrolysis produced bio-oil that consists of 58 components ranging from C3 to C24; however, the number and quantity of fuel range hydrocarbons were lower than in the catalyzed products. The pyrolysis reaction was studied kinetically for both samples using thermogravimetry at heating rates of 5, 10, 15 and 20 °C/min in the temperature range 20−600 °C. The activation energies and pre-exponential factors wer... [more]

An experimental study of a hydrogen-containing jet’s impact on a palladium-based catalyst in an air atmosphere was carried out. High-intensity temperature fluctuations on the catalyst surface are obtained in the case when large-scale vortex structures are contained in the jet. These superstructures have a longitudinal size of 20−30 initial jet diameters and a transverse size of about 3−4 diameters. To form such structures, it is necessary to use long, round tubes in the Reynolds number range of 2000−3000 as a source of the impinging jet when a laminar-turbulent transition occurs in the channel according to the intermittency scenario. This effect was obtained at a low hydrogen content in the mixture (XH2 = 3…15%) and a low initial temperature of the catalyst (180 °C). It is shown that the smallest temperature fluctuations are obtained for the laminar flow in the tube (<1.5%), and they are more significant (<4%) for the turbulent regime at low Reynolds numbers (Re < 6000). The g... [more]

Given the increase in population and energy demand worldwide, alternative methods have been adopted for the production of hydrogen as a clean energy source. This energy offers an alternative energy source due to its high energy content, and without emissions to the environment. In this bibliometric analysis of energy production using electrolysis and taking into account the different forms of energy production. In this analysis, it was possible to evaluate the research trends based on the literature in the Scopus database during the years 2011−2021. The results showed a growing interest in hydrogen production from electrolysis and other mechanisms, with China being the country with the highest number of publications and the United States TOP in citations. The trend shows that during the first four years of this study (2011−2014), the average number of publications was 74 articles per year, from 2015 to 2021 where the growth is an average of 209 articles, the journal that published the... [more]

In this paper, the effect of rotating magnetic fields on hydrogen generation from water electrolysis is analyzed, aiming to provide a research reference for hydrogen production and improving hydrogen production efficiency. The electrolytic environment is formed by alkaline solutions and special electrolytic cells. The two electrolytic cells are connected to each other in the form of several pipes. The ring magnets are used to surround the pipes and rotate the magnets so that the pipes move relative to the magnets within the ring magnetic field area. Experimentally, the electrolysis reaction of an alkaline solution was studied by using a rotating magnetic field, and the effect of magnetic field rotation speed on the electrolysis reaction was analyzed using detected voltage data. The experimental phenomenon showed that the faster the rotation speed of the rotating magnetic field, the faster the production speed of hydrogen gas.

To become sustainable, the production of electricity has been oriented towards the adoption of local and renewable sources. Distributed electric and thermal energy generation is more suitable to avoid any possible waste, and the Micro Gas Turbine (MGT) can play a key role in this scenario. Due to the intrinsic properties and the high flexibility of operation of this energy conversion system, the exploitation of alternative fuels and the integration of the MGT itself with other energy conversion systems (solar field, ORC, fuel cells) represent one of the most effective strategies to achieve higher conversion efficiencies and to reduce emissions from power systems. The present work aims to review the results obtained by the researchers in the last years. The different technologies are analyzed in detail, both separately and under a more complete view, considering two or more solutions embedded in micro-grid configurations.

Solid oxide cells represent one of the most efficient and promising electrochemical technologies for hydrogen energy conversion. Understanding and monitoring degradation is essential for their full development and wide diffusion. Techniques based on electrochemical impedance spectroscopy and distribution of relaxation times of physicochemical processes occurring in solid oxide cells have attracted interest for the operando diagnosis of degradation. This research paper aims to validate the methodology developed by the authors in a previous paper, showing how such a diagnostic tool may be practically implemented. The validation methodology is based on applying an a priori known stress agent to a solid oxide cell operated in laboratory conditions and on the discrete measurement and deconvolution of electrochemical impedance spectra. Finally, experimental evidence obtained from a fully operando approach was counterchecked through ex-post material characterization.

Biomass gasification for energy purposes has several advantages, such as the mitigation of global warming and national energy independency. In the present work, the data from an innovative and intensified steam/oxygen biomass gasification process, integrating a gas filtration step directly inside the reactor, are presented. The produced gas at the outlet of the 1 MWth gasification pilot plant was analysed in terms of its main gaseous products (hydrogen, carbon monoxide, carbon dioxide, and methane) and contaminants. Experimental test sets were carried out at 0.25−0.28 Equivalence Ratio (ER), 0.4−0.5 Steam/Biomass (S/B), and 780−850 °C gasification temperature. Almond shells were selected as biomass feedstock and supplied to the reactor at approximately 120 and 150 kgdry/h. Based on the collected data, the in-vessel filtration system showed a dust removal efficiency higher than 99%-wt. A gas yield of 1.2 Nm3dry/kgdaf and a producer gas with a dry composition of 27−33%v H2, 23−29%v CO, 3... [more]

The use of lignocellulosic biomass to obtain biofuels and chemicals produces a large amount of lignin as a byproduct. Lignin valorization into chemicals needs efficient conversion processes to be developed. In this work, hydrocracking of organosolv lignin was performed by using nickel Raney catalyst. Organosolv lignin was obtained from the pretreatment of eucalyptus wood at 170 °C for 1 h by using 1/100/100 (w/v/v) ratio of biomass/oxalic acid solution (0.4% w/w)/1-butanol. The resulting organic phase of lignin in 1-butanol was used in hydrogenation tests. The conversion of lignin was carried out with a batch reactor equipped with a 0.3 L vessel with adjustable internal stirrer and heat control. The reactor was pressurized at 5 bar with hydrogen at room temperature, and then the temperature was raised to 250 °C and kept for 30 min. Operative conditions were optimized to achieve high conversion in monomers and to minimize the loss of solvent. At the best performance conditions, about 10... [more]

Hydrogen is mainly produced by steam reforming of natural gas, a nonrenewable resource. Alternative and renewable routes for hydrogen production play an important role in reducing dependence on oil and minimizing the emission of greenhouse gases. In this work, butanol, a model compound of bio-oil, was employed for hydrogen production by steam reforming. The reaction was evaluated for 30 h in a tubular quartz reactor at 500 °C, atmospheric pressure, GHSV of 500,000 h−1, and an aqueous solution feed of 10% v/v butanol. For this reaction, catalysts with 20 wt.% NiO were prepared by wet impregnation using three supports: γ-alumina and alumina modified with 10 wt.% of cerium and lanthanum oxides. Both promoters increased the reduction degree of the catalysts and decreased catalyst acidity, which is closely related to coke formation and deactivation. Ni/La2O3−Al2O3 presented a higher nickel dispersion (14.6%) which, combined with other properties, led to a higher stability, higher mean hydro... [more]

This article presents the results of the development of membrane-catalytic methods for obtaining purified hydrogen of various degrees of purity required for feeding high-, medium-, and low-temperature fuel cells. In order to conduct this, porous ceramic catalytic converters were obtained using self-propagating high-temperature synthesis. These converters are suitable for high-speed processes for producing synthesis gas with different carbon monoxide content (0.08−0.1 vol. %), which can be used to feed fuel cells of various types. Using a hybrid catalytic membrane reactor, in which the stage of catalytic conversion of organic substrates was combined with the stage of selective extraction of ultrapure hydrogen (content of H2 was not less than 99.9999 vol. %) from the reaction zone, combined carbon dioxide and steam reforming of organic substrates of various origins were carried out. The result of the work was the creation of a prototype of a small-sized electric generator plant in which... [more]

The graphitic carbon nitride (g-C3N4) is a class of two-dimensional layered material. The ever-growing research on this fascinating material is due to its unique visible light absorption, surface, electrocatalytic, and other physicochemical properties that can be useful to different energy conversion and storage applications. Photoelectrochemical (PEC) water splitting reaction is one of the promising applications of g-C3N4, wherein it acts as a durable catalyst support material. Very recently, the construction of g-C3N4-based binary and ternary heterostructures exhibited superior PEC water splitting performance owing to its reduced reunion of e-/h+ pairs and the fast transfer of charge carriers at the heterostructure interface. This review compiles the recent advances and challenges on g-C3N4-based heterostructured photocatalysts for the PEC water splitting reaction. After an overview of the available literature, we presume that g-C3N4-based photocatalysts showed enhanced PEC water spl... [more]

The paper investigates the stability and bifurcation phenomena that can occur in membrane reactors for the production of hydrogen by ammonia decomposition. A simplified mixed model of the membrane reactor is studied and two expressions of hydrogen permeation are investigated. The effect of the model design and operating parameters on the existence of steady state multiplicity is discussed. In this regard, it is shown that the adsorption-inhibition effect caused by the competitive adsorption of ammonia can lead to the occurrence of multiple steady states in the model. The steady state multiplicity exists for a wide range of feed ammonia concentration and reactor residence time. The effect of the adsorption constant, the membrane surface area and its permeability on the steady state multiplicity is delineated. The analysis also shows that no Hopf bifurcation can occur in the studied model.

An ultrasonic spray pyrolysis (USP) device consists of an evaporation and two reaction zones of equal length, into which an aerosol with a precursor compound enters, and where nanoparticles are formed in the final stage. As part of this research, we simulated the geometry of a side inlet, where the reaction gas (H2) enters into the reaction tube of the device by using numerical methods. Mixing with the carrier gas (N2) occurs at the entry of the H2. In the initial part, we performed a theoretical calculation with a numerical simulation using ANSYS CFX, while the geometries of the basic and studied models were prepared with Solidworks. The inlet geometry of the H2 included a study of the position and radius of the inlet with respect to the reaction tube of the USP device, as well as a study of the angle and diameter of the inlet. In the simulation, we chose the typical flows of both gases (N2, H2) in the range of 5 L/min to 15 L/min. The results show that the best geometry is with the H... [more]

To improve the reactor efficiency, this study investigated the influence of temperature on the biological hydrogen methanation (BHM) in trickle-bed reactors (TBR). Rising temperatures increase the metabolic activity of methanogenic microorganisms, thus leading to higher reactor specific methane formation rates (MFR). In order to quantify the potential for improved performance, experiments with four different operating temperatures ranging from 40 to 55 °C were carried out. Methane content increased from 88.29 ± 2.12 vol % at 40 °C to 94.99 ± 0.81 vol % at 55 °C with a stable biological process. Furthermore, a reactor specific methane formation rate (MFR) of up to 8.85 ± 0.45 m³ m−3 d−1 was achieved. It could be shown that the microorganisms were able to adapt to higher temperatures within hours. The tests showed that TBR performance with regard to BHM can be significantly increased by increasing the operating temperature.