Anode recirculation with periodic purge is commonly used in polymer electrolyte fuel cell systems to control the accumulation of nitrogen, water, and other impurities that are present in the fuel or diffuse through the membrane from the cathode compartment. In this work, we develop a simple, generalized analytical model that simulates the time dependence of the accumulation of inert impurities in the anode compartment of such a system. It is shown that, when there is transport out of the anode chamber, the inert species is expected to accumulate exponentially until equilibrium is reached when the rate of inert entering the anode in the fuel supply and/or via crossover from the cathode is balanced by the rate of leakage and/or crossover to the cathode. The model is validated using recently published experimental data for the accumulation of N2, CH4, and CO2 in a recirculated system. The results show that nitrogen accumulation needs to be taken into account to properly adjust system para... [more]

The use of hydrogen in small scale gas turbines is currently limited by several issues. Blending hydrogen with methane or other gaseous fuels can be considered a low medium-term viable solution, with the goal of reducing greenhouse gas emissions. In fact, only small amounts can be mixed with methane in premixed combustors, due to the risk of flashback. The aim of this article is to investigate the injection of small quantities of steam as a method of increasing the maximum permissible hydrogen content in a mixture with methane. The proposed approach involves introducing the steam directly into the combustion chamber into the main fuel feeding system of a Turbec T100. The study is carried out by means of CFD analysis of the combustion process. A thermodynamic analysis of the energy system is used to determine boundary conditions. The combustion chamber is discretized using a three-dimensional mesh consisting of 4.7 million nodes and the RANS RSM model is used to simulate the effects of... [more]

A potentially viable solution to the problem of greenhouse gas emissions by vehicles in the transportation sector is the deployment of hydrogen as alternative fuel. A limitation to the diffusion of the hydrogen-fuelled vehicles option is the intricate refuelling stations that vehicles will require. This study examines the practical use of hydrogen fuel within the internal combustion engine (ICE)-powered long-haul, heavy-duty trucking vehicles. Specifically, it appraises the techno-economic feasibility of constructing a network of long-haul truck refuelling stations using hydrogen fuel, across Canada. Hydrogen fuel is chosen as an option for this study due to its low carbon emissions rate compared to diesel. This study also explores various operational methods, including variable technology integration levels and truck traffic flows, truck and pipeline delivery of hydrogen to stations, and the possibility of producing hydrogen onsite. The proposed models created for this work suggest im... [more]

Shipping accounts for about 3% of global CO2 emissions. In order to achieve the target set by the Paris Agreement, IMO introduced their GHG strategy. This strategy envisages 50% emission reduction from international shipping by 2050, compared with 2008. This target cannot be fulfilled if conventional fuels are used. Amongst others, hydrogen is considered to be one of the strong candidates as a zero-emissions fuel. Yet, concerns around the safety of its storage and usage have been formulated and need to be addressed. “Safety”, in this article, is defined as the control of recognized hazards to achieve an acceptable level of risk. This article aims to propose a new way of comparing two systems with regard to their safety. Since safety cannot be directly measured, fuzzy set theory is used to compare linguistic terms such as “safer”. This method is proposed to be used during the alternative design approach. This approach is necessary for deviations from IMO rules, for example, when hydroge... [more]

In this paper, a hybrid reformed methanol fuel cell−battery system for telecom backup applications was modeled in MATLAB Simulink. The modeling was performed to optimize the operating strategy of the hybrid system using an energy management system with a focus on a longer lifetime and higher fuel efficiency for the fuel cell, while also keeping the state-of-charge (SOC) of the battery within a reasonable range. A 5 kW reformed methanol fuel cell stack and a 6.5 kWh Li-ion battery were considered for the hybrid model. Moreover, to account for the effects of degradation, the model evaluated the performance of the fuel cell both in the beginning of life (BOL) and after 1000 h and 250 start−stop cycling tests (EOT). The energy management system (EMS) was characterized by 12 operating conditions that used the battery SOC, load requirements and the presence or absence of grid power as the inputs to optimize the operating strategy for the system. Additionally, the integration of a 400 W photo... [more]

To understand the effect of hydrogen addition on the laminar burning velocity (LBV) of ethanol−air mixtures, experiments were conducted in a constant volume combustion chamber with the high-speed schlieren photography technique. The experiments were carried out under the equivalence ratios (ERs) of 0.7−1.4, an initial temperature of 400 K, an initial pressure of 0.1 MPa, and hydrogen fractions of 30% and 90% by volume, respectively. The effects of ER, initial temperature, initial pressure, and hydrogen fractions on the LBV were investigated. Moreover, adiabatic flame temperature (AFT), heat release rate (HRR), flow rate sensitivity analysis, and ROP (rate of production) analysis were also performed. Results showed that LBV increased with increasing hydrogen addition and temperature but decreased with increasing pressure. The hydrogen addition significantly increased the HRR of ethanol−hydrogen−air flames. The sensitivity analysis showed that R5 (O2 + H = O + OH) significantly influence... [more]

The present work describes highly efficient hydrogen production from ethanol in a plasma-catalytic reactor depending on the discharge power and catalyst bed temperature. Hydrogen production increased as the power increased from 15 to 25 W. A further power increase to 35 W did not increase hydrogen production. The catalyst was already active at a temperature of 250 °C, and its activity increased with increasing temperature to 450 °C. The further temperature increase did not increase the activity of the cobalt catalyst. The most important advantage of using the catalyst was the increased ethanol conversion to CO2 instead of CO production. As a result, the hydrogen yield was very high and reached 4.1 mol(H2)/mol(C2H5OH). This result was obtained with a stoichiometric molar ratio of water to ethanol of 3.

The interest in and need for carbon-free fuels that do not rely on fossil fuels are constantly growing from both environmental and energetic perspectives. Green hydrogen production is at the core of the transition away from conventional fuels. Along with popularly investigated pathways for hydrogen production, thermochemical water splitting using redox materials is an interesting option for utilizing thermal energy, as this approach makes use of temperature looping over the material to produce hydrogen from water. Herein, two-step thermochemical water splitting processes are discussed and the key aspects are analyzed using the most relevant information present in the literature. Redox materials and their compositions, which have been proven to be efficient for this reaction, are reported. Attention is focused on non-volatile redox oxides, as the quenching step required for volatile redox materials is unnecessary. Reactors that could be used to conduct the reduction and oxidation reacti... [more]

The operating conditions can have uncontrolled effects on the voltage of a High-Temperature Proton Exchange Membrane Fuel Cell (HT-PEMFC). For instance, the HT-PEMFC can be used at ambient pressure, i.e., without having a back pressure regulator. In this case, the variation in the atmospheric pressure directly affects pressures inside the fuel cell, which induces voltage variation. Moreover, in transient phases, several coupled phenomena can have an uncontrolled effect on the voltage. For example, following a change in the current operating point, thermal conditions in the fuel cell can vary, and the temperature stabilization then leads to a voltage variation. This article introduces a readjustment method for the fuel cell voltage to compensate for the effects of the pressure and temperature variations that are undergone and to decouple their effects. This methodology is based on the realization of a design of experiments to characterize the voltage sensitivity to pressure ([1; 1.5 bar... [more]

The aim of the paper is to analyze how regulatory design and its framework’s topics, other than macroeconomic factors, might impact green innovation by taking into consideration a brand-new renewable source of energy that is becoming more and more important in recent years: hydrogen and fuel cell patenting activities. Such activities have been used as a proxy for green technological change in a panel data of 52 countries over a 6-year period. A series of sectorial, energy regulation, and macroeconomic variables were tested to assess their impact on that technological frontier of green energy transition policy. As might have been expected, the empirical analysis carried out with the model that was prefigured confirms significant evidence of lock-in effects on fossil fuel policies. The model confirms, however, another evidence: countries already investing in renewables might be willing to invest in hydrogen projects. A sort of reinforcement to the further development of green sustainable... [more]

In this work, an experimental study and kinetic characterization of the combustion process and a morphologic study of hydrogen/methane−air mixtures are presented. The experimental study was performed in an optical access cylindrical constant-volume combustion bomb. This bomb is equipped to register the instantaneous pressure during combustion and records the combustion images using the high-speed Schlieren optical technique. This provides straightforward information to compute the flame propagation speed and direct evidence of the apparition of cellularity on the flame front. Through the images of the combustion process, it is possible to conduct a morphological study of the process using a flame monitoring model. Simultaneously, by means of a two-zone thermodynamical model, with the temporal evolution of pressure as the main intake, significant parameters are determined during the combustion process of different fuels under premixed conditions: burning velocity, rate of combustion, bu... [more]

The paper analyses operating and developing technologies for hydrogen implementation, transition, and storage at operating thermal power plants (TPPs) to make recommendations for realization of perspective projects for evaluation of the use of hydrogen as a fuel. Over the medium-term horizon of the next decade, it is suggested that using the technology of burning a mixture of hydrogen and natural gas in gas turbines and gas-and-oil-fired boilers in volume fractions of 20% and 80%, respectively, be implemented at operating gas fired TPPs. We consider the construction of the liquefied hydrogen and natural gas storage warehouses for the required calculated quantities of the gas mixture as a reserve energy fuel for operating the TPPs. We consider the possibility of the reserve liquid fuel system being replaced by the technology involving storage of liquefied hydrogen in combination with natural gas. An economic assessment of the storing cost of reserve fuel on the TPP site is given. The pa... [more]

The greatest challenge of our times is to identify low cost and environmentally friendly alternative energy sources to fossil fuels. From this point of view, the decarbonization of industrial chemical processes is fundamental and the use of hydrogen as an energy vector, usable by fuel cells, is strategic. It is possible to tackle the decarbonization of industrial chemical processes with the electrification of systems. The purpose of this review is to provide an overview of the latest research on the electrification of endothermic industrial chemical processes aimed at the production of H2 from methane and its use for energy production through proton exchange membrane fuel cells (PEMFC). In particular, two main electrification methods are examined, microwave heating (MW) and resistive heating (Joule), aimed at transferring heat directly on the surface of the catalyst. For cases, the catalyst formulation and reactor configuration were analyzed and compared. The key aspects of the use of... [more]

To reduce greenhouse gases and air pollutants, new technologies are emerging to reduce fossil fuel usage and to adopt more renewable energy sources. As the major aspects of fuel consumption, power generation, transportation, and industrial applications have been given significant attention. The past few decades witnessed astonishing technological advancement in these energy sectors. In contrast, the residential sector has had relatively little attention despite its significant utilization of fuels for a much longer period. However, almost every energy transition in human history was initiated by the residential sector. For example, the transition from fuelwood to cheap coal in the 1700s first took place in residential houses due to urbanization and industrialization. The present review demonstrates the energy transitions in the residential sector during the past two centuries while portending an upcoming energy transition and future energy structure for the residential sector. The feas... [more]

In recent years, the development of energy prices in Germany has been frequently accompanied by criticism and warnings of socio-economic disruptions. Especially with respect to the electricity sector, the debate on increasing energy bills was strongly correlated with the energy system transition. However, whereas fossil fuels have rapidly increased in price recently, renewable substitutes such as green hydrogen and synthetic fuels also enter the markets at comparatively high prices. On the other hand, the present fossil fuel supply is still considered too low-priced by experts because societal greenhouse gas-induced environmental impact costs are not yet compensated. In this study, we investigate the development of the price gap between conventional energy carriers and their renewable substitutes until 2050 as well as a suitable benchmark price, incorporating the societal costs of specific energy carriers. The calculated benchmark prices for natural gas (6.3 ct kWh−1), petrol (9.9 ct k... [more]

Hybrid photovoltaic−regenerative hydrogen fuel cell (PV-RHFC) microgrid systems are considered to have a high future potential in the effort to increase the renewable energy share in the form of solar PV technology with hydrogen generation, storage, and reutilization. The current study provides a comprehensive review of the recent research progress of hybrid PV-RHFC microgrid systems to extract conclusions on their characteristics and future prospects. The different components that can be integrated (PV modules, electrolyzer and fuel cell stacks, energy storage units, power electronics, and controllers) are analyzed in terms of available technology options. The main modeling and optimization methods, and control strategies are discussed. Additionally, various application options are provided, which differentiate in terms of scale, purpose, and further integration with other power generating and energy storage technologies. Finally, critical analysis and discussion of hybrid PV-RHFC mic... [more]

The target of net-zero emissions set by the 2015 Paris Agreement has strongly commissioned the energy production sector to promote decarbonization, renewable sources exploitation, and systems efficiency. In this framework, the utilization of hydrogen as a long-term energy carrier has great potential. This paper is concerned with the combustion characterization in a non-premixed gas turbine burner, originally designed for natural gas, when it is fed with NG-H2 blends featuring hydrogen content from 0 to 50% in volume. The final aim is to retrofit a 40 MW gas turbine. Starting from the operational data of the engine, a CFD model of the steady-state combustion process has been developed, with reference to the base load NG conditions, by reducing the fuel mass-flow rate by up to 17% to target the baseline turbine inlet temperature. When the fuel is blended with hydrogen, for a given temperature at turbine inlet, an increase in the peak temperature up to 800 K is obtained, if no countermeas... [more]

A study of energy supply alternatives was carried out based on a cogeneration fuel cell system fed from the natural gas network of compact Mediterranean cities. As a case study it was applied to the residential energy demands of the L’Illa Perduda neighbourhood, located in the east of the city of Valencia and consisting of 4194 residential cells. In total, eight different alternatives were studied according to the load curve, the power of the system, the mode of operation and the distribution of the fuel cells. In this way, the advantages and disadvantages of each configuration were found. This information, together with the previous study of the energy characteristics of the neighbourhood, enabled selection of the most promising configuration and to decide whether or not to recommend investment. The chosen configuration was a centralised system of phosphoric acid fuel cells in cogeneration, with approximately 4 MW of thermal power and an operating mode that varied according to the out... [more]

With little time left for humanity to reduce climate change to a tolerable level, a highly scalable and rapidly deployable solution is needed that can be implemented by any country. Offshore wind energy in international waters is an underused resource and could even be harnessed by landlocked countries. In this paper, the use of sailing wind turbines operating autonomously in high seas to harvest energy is proposed. The electrical energy that is generated by the wind turbine is converted to a renewable fuel and stored onboard. Later, the fuel will be transferred to shore or to other destinations of use. The presented idea is explored at the system level, where the basic subsystems necessary are identified and defined, such as energy conversion and storage as well as propulsion subsystems. Moreover, various operating possibilities are investigated, including a comparison of different sailing strategies and fuels for storage. Existing ideas are also briefly addressed and an example conce... [more]

Hydrogen is a carbon-free fuel that can be produced in many ways starting from different sources. Its use as a fuel in internal combustion engines could be a method of significantly reducing their environmental impact. In spark-ignition (SI) engines, lean hydrogen−air mixtures can be burnt. When a gaseous fuel like hydrogen is port-injected in an SI engine, working with lean mixtures, supercharging becomes very useful in order not to excessively penalize the engine performance. In this work, the performance of a turbocharged PFI spark-ignition engine fueled by hydrogen has been investigated by means of 1-D numerical simulations. The analysis focused on the engine behavior both at full and partial load considering low and medium engine speeds (1500 and 3000 rpm). Equivalence ratios higher than 0.35 have been considered in order to ensure acceptable cycle-to-cycle variations. The constraints that ensure the safety of engine components have also been respected. The results of the analysis... [more]

Biomass gasification is a versatile thermochemical process that can be used for direct energy applications and the production of advanced liquid and gaseous energy carriers. In the present work, the results are presented concerning the H2 production at a high purity grade from biomass feedstocks via steam/oxygen gasification. The data demonstrating such a process chain were collected at an innovative gasification prototype plant coupled to a portable purification system (PPS). The overall integration was designed for gas conditioning and purification to hydrogen. By using almond shells as the biomass feedstock, from a product gas with an average and stable composition of 40%-v H2, 21%-v CO, 35%-v CO2, 2.5%-v CH4, the PPS unit provided a hydrogen stream, with a final concentration of 99.99%-v and a gas yield of 66.4%.

Rapidly declining costs of renewable energy technologies have made solar and wind the cheapest sources of energy in many parts of the world. This has been seen primarily as enabling the rapid decarbonization of the electricity sector, but low-cost, low-carbon energy can have a great secondary impact by reducing the costs of energy-intensive decarbonization efforts in other areas. In this study, we consider, by way of an exemplary carbon capture and utilization cycle based on mature technologies, the energy requirements of the “industrial carbon cycle”, an emerging paradigm in which industrial CO2 emissions are captured and reprocessed into chemicals and fuels, and we assess the impact of declining renewable energy costs on overall economics of these processes. In our exemplary process, CO2 is captured from a cement production facility via an amine scrubbing process and combined with hydrogen produced by a solar-powered polymer electrolyte membrane, using electrolysis to produce methano... [more]

Hydrogen fuel cell technology is securing a place in the future of advanced mobility and the energy revolution, as engineers explore multiple paths in the quest for decarbonization. The feasibility of hydrogen-based fuel cell vehicles particularly relies on the development of safe, lightweight and cost-competitive solutions for hydrogen storage. After the demonstration of hundreds of prototype vehicles, today, commercial hydrogen tanks are in the first stages of market introduction, adopting configurations that use composite materials. However, production rates remain low and costs high. This paper intends to provide an insight into the evolving scenario of solutions for hydrogen storage in the transportation sector. Current applications in different sectors of transport are covered, focusing on their individual requirements. Furthermore, this work addresses the efforts to produce economically attractive composite tanks, discussing the challenges surrounding material choices and manufa... [more]

Hydrogen-based technologies are among the most promising solutions to fulfill the zero-emission scenario and ensure the energy independence of many countries. Hydrogen is considered a green energy carrier, which can be utilized in the energy, transport, and chemical sectors. However, efficient and safe large-scale hydrogen storage is still challenging. The most frequently used hydrogen storage solutions in industry, i.e., compression and liquefaction, are highly energy-consuming. Underground hydrogen storage is considered the most economical and safe option for large-scale utilization at various time scales. Among underground geological formations, salt caverns are the most promising for hydrogen storage, due to their suitable physicochemical and mechanical properties that ensure safe and efficient storage even at high pressures. In this paper, recent advances in underground storage with a particular emphasis on salt cavern utilization in Europe are presented. The initial experience in... [more]

By employing a specific particle interaction theory and a high-precision equation of states for the liquid and vapor phases of H2, respectively, a new H2 solubility model in pure water and aqueous NaCl solutions is proposed in this study. The model established by fitting the experimental data of H2 solubility can be used to estimate H2 solubility in pure water at temperatures and pressures of 273.15−423.15 K and 0−1100 bar, respectively, and in salt solutions (NaCl concentration = 0−5 mol/kg) at temperatures and pressures of 273.15−373.15 K and 0−230 bar, respectively. By adopting the theory of liquid electrolyte solutions, the model can also be used to predict H2 solubility in seawater without fitting the experimental data of a seawater system. Within or close to experimental data uncertainty, the mean absolute percentage error between the model-predicted and experimentally obtained H2 solubilities was less than 1.14%.