An essential prerequisite for safe transport and use of natural gas is their appropriate odorization. This enables the detection of uncontrolled gas leaks. Proper and systematic odorization inspection ensures both safe use of gas and continuity of the process itself. In practice, it is conducted through, among others, measuring odorant concentrations in gas. Control devices for rapid gas odorization measurements that are currently used on a large scale in the gas industry are equipped with electrochemical detectors selective for sulfur compounds like tetrahydrothiophene (THT). Because the selectivity of electrochemical detector response to one compound (e.g., THT), the available declarations of manufacturers show that detector sensitivity (indirectly also the quality of the measurement result) is influenced by the presence of increased e.g., sulfur or hydrogen compound content in the gas. Because of the lack of sufficient source literature data in this field, it was necessary to experi... [more]

The Republic of Djibouti has untapped potential in terms of renewable energy resources, such as geothermal, wind, and solar energy. This study examines the economic feasibility of green hydrogen production by water electrolysis using wind and geothermal energy resources in the Asal−Ghoubbet Rift (AG Rift), Republic of Djibouti. It is the first study in Africa that compares the cost per kg of green hydrogen produced by wind and geothermal energy from a single site. The unit cost of electricity produced by the wind turbine (0.042 $/kWh) is more competitive than that of a dry steam geothermal plant (0.086 $/kWh). The cost of producing hydrogen with a suitable electrolyzer powered by wind energy ranges from $0.672/kg H2 to $1.063/kg H2, while that produced by the high-temperature electrolyzer (HTE) powered by geothermal energy ranges from $3.31/kg H2 to $4.78/kg H2. Thus, the AG Rift area can produce electricity and green hydrogen at low-cost using wind energy compared to geothermal energy... [more]

This article presents a power to SNG (synthetic natural gas) system that converts hydrogen into SNG via a methanation process. In our analysis, detailed models for all the elements of the system are built. We assume a direct connection between a wind farm and a hydrogen generator. For the purposes of our calculations, we also assume that the hydrogen generator is powered by the renewable source over a nine-hour period per day (between 21:00 and 06:00), and this corresponds to the off-peak period in energy demand. In addition, a hydrogen tank was introduced to maximize the operating time of the methanation reactor. The cooperation between the main components of the system were simulated using Matlab software. The primary aim of this paper is to assess the influence of various parameters on the operation of the proposed system, and to optimize its yearly operation via a consideration of the most important constraints. The analyses also examine different nominal power values of renewables... [more]

This work reports a numerical investigation of microcombustion in an undulate microchannel, using premixed hydrogen and air to understand the effect of the burner design on the flame in order to obtain stability of the flame. The simulations were performed for a fixed equivalence ratio and a hyperbolic temperature profile imposed at the microchannel walls in order to mimic the heat external losses occurred in experimental setups. Due to the complexity of the flow dynamics combined with the combustion behavior, the present study focuses on understanding the effect of the fuel inlet rate on the flame characteristics, keeping other parameters constant. The results presented stable flame structure regardless of the inlet velocity for this type of design, meaning that a significant reduction in the heat flux losses through the walls occurred, allowing the design of new simpler systems. The increase in inlet velocity increased the flame extension, with the flame being stretched along the mic... [more]

Hydrogen (H2) can be a promising energy carrier for decarbonizing the economy and especially the transport sector, which is considered as one of the sectors with high carbon emissions due to the extensive use of fossil fuels. H2 is a nontoxic energy carrier that could replace fossil fuels. Fuel Cell Electric Vehicles (FCEVs) can decrease air pollution and reduce greenhouse gases when H2 is produced from Renewable Energy Sources (RES) and at the same time being accessible through a widespread network of Hydrogen Refueling Stations (HRSs). In this study, both the sizing of the equipment and financial analysis were performed for an HRS supplied with H2 from the excess electrical energy of a 10 MW wind park. The aim was to determine the optimum configuration of an HRS under the investigation of six different scenarios with various numbers of FCEVs and monthly demands, as well as ascertaining the economic viability of each examined scenario. The effect of the number of vehicles that the ins... [more]

The development of noble-metal-free electrocatalysts is regarded as a key factor for realizing industrial-scale hydrogen production powered by renewable energy sources. Inspired by nature, which uses Fe- and Ni-containing enzymes for efficient hydrogen generation, Fe/Ni-containing chalcogenides, such as oxides and sulfides, received increasing attention as promising electrocatalysts to produce hydrogen. We herein present a novel synthetic procedure for mixed Fe/Ni (oxy)sulfide materials by the controlled (partial) sulfidation of NiFe2O4 (NFO) nanoparticles in H2S-containing atmospheres. The variation in H2S concentration and the temperature allows for a precise control of stoichiometry and phase composition. The obtained sulfidized materials (NFS) catalyze the hydrogen evolution reaction (HER) with increased activity in comparison to NFO, up to −10 and −100 mA cm−2 at an overpotential of approx. 250 and 450 mV, respectively.

In this study, the authors present a techno-economic assessment of on-site hydrogen refuelling stations (450 kg/day of H2) based on different hydrogen sources and production technologies. Green ammonia, biogas, and water have been considered as hydrogen sources while cracking, autothermal reforming, and electrolysis have been selected as the hydrogen production technologies. The electric energy requirements of the hydrogen refuelling stations (HRSs) are internally satisfied using the fuel cell technology as power units for ammonia and biogas-based configurations and the PV grid-connected power plant for the water-based one. The hydrogen purification, where necessary, is performed by means of a Palladium-based membrane unit. Finally, the same hydrogen compression, storage, and distribution section are considered for all configurations. The sizing and the energy analysis of the proposed configurations have been carried out by simulation models adequately developed. Moreover, the economic... [more]

In which way, and in which sectors, will renewable energy be integrated in the German Energy System by 2030, 2040, and 2050? How can the resulting energy system be characterised following a −95% greenhouse gas emission reduction scenario? Which role will hydrogen play? To address these research questions, techno-economic energy system modelling was performed. Evaluation of the resulting operation of energy technologies was carried out from a system and a business point of view. Special consideration of gas technologies, such as hydrogen production, transport, and storage, was taken as a large-scale and long-term energy storage option and key enabler for the decarbonisation of the non-electric sectors. The broad set of results gives insight into the entangled interactions of the future energy technology portfolio and its operation within a coupled energy system. Amongst other energy demands, CO2 emissions, hydrogen production, and future power plant capacities are presented. One main co... [more]

In which way, and in which sectors, will renewable energy be integrated in the German Energy System by 2030, 2040, and 2050? How can the resulting energy system be characterised following a −95% greenhouse gas emission reduction scenario? Which role will hydrogen play? To address these research questions, techno-economic energy system modelling was performed. Evaluation of the resulting operation of energy technologies was carried out from a system and a business point of view. Special consideration of gas technologies, such as hydrogen production, transport, and storage, was taken as a large-scale and long-term energy storage option and key enabler for the decarbonisation of the non-electric sectors. The broad set of results gives insight into the entangled interactions of the future energy technology portfolio and its operation within a coupled energy system. Amongst other energy demands, CO2 emissions, hydrogen production, and future power plant capacities are presented. One main co... [more]

Nuclear power plants in the United States are increasingly challenged to compete in wholesale electricity markets due to the low electricity costs and increasingly dynamic grid conditions from competing generation sources. An alternative market for nuclear power is industrial facilities that can use the thermal and/or electrical power generated by a nuclear power plant to offset the economic losses incurred by electricity market challenges. A generic pressurized water reactor (PWR) simulator was used to show the results of a basic design for a generic thermal power extraction system and tests were run using a set of procedures to show what happens when a nuclear power plant transitions from full electrical power dispatch to 15% and 50% thermal power dispatch. This type of operation leads to losses in turbine performance efficiency due to the deviation from the design operating point, but because the thermal power is also used by the industry load without conversion losses, the combined... [more]

Future low-carbon systems with very high shares of variable renewable generation require complex models to optimise investments and operations, which must capture high degrees of sector coupling, contain high levels of operational and temporal detail, and when considering seasonal storage, be able to optimise both investments and operations over long durations. Standard energy system models often do not adequately address all these issues, which are of great importance when considering investments in emerging energy carriers such as Hydrogen. An advanced energy system model of the Irish power system is built in SpineOpt, which considers a number of future scenarios and explores different pathways to the wide-scale adoption of Hydrogen as a low-carbon energy carrier. The model contains a high degree of both temporal and operational detail, sector coupling, via Hydrogen, is captured and the optimisation of both investments in and operation of large-scale underground Hydrogen storage is d... [more]

In this paper, a gas-to-power (GtoP) system for power outages is digitally modeled and experimentally developed. The design includes a solid-state hydrogen storage system composed of TiFeMn as a hydride forming alloy (6.7 kg of alloy in five tanks) and an air-cooled fuel cell (maximum power: 1.6 kW). The hydrogen storage system is charged under room temperature and 40 bar of hydrogen pressure, reaching about 110 g of hydrogen capacity. In an emergency use case of the system, hydrogen is supplied to the fuel cell, and the waste heat coming from the exhaust air of the fuel cell is used for the endothermic dehydrogenation reaction of the metal hydride. This GtoP system demonstrates fast, stable, and reliable responses, providing from 149 W to 596 W under different constant as well as dynamic conditions. A comprehensive and novel simulation approach based on a network model is also applied. The developed model is validated under static and dynamic power load scenarios, demonstrating excell... [more]

Hydrogen as a carbon-free fuel is commonly expected to play a major role in future energy supply, e.g., as an admixture gas in natural gas grids. Which impacts on residential and commercial gas appliances can be expected due to the significantly different physical and chemical properties of hydrogen-enriched natural gas? This paper analyses and discusses blends of hydrogen and natural gas from the perspective of combustion science. The admixture of hydrogen into natural gas changes the properties of the fuel gas. Depending on the combustion system, burner design and other boundary conditions, these changes may cause higher combustion temperatures and laminar combustion velocities, while changing flame positions and shapes are also to be expected. For appliances that are designed for natural gas, these effects may cause risk of flashback, reduced operational safety, material deterioration, higher nitrogen oxides emissions (NOx), and efficiency losses. Theoretical considerations and firs... [more]

The grand challenges in renewable energy lie in our ability to comprehend efficient energy conversion systems, together with dealing with the problem of intermittency via scalable energy storage systems. Relatively little progress has been made on this at grid scale and two overriding challenges still need to be addressed: (i) limiting damage to the environment and (ii) the question of environmentally friendly energy conversion. The present review focuses on a novel route for producing hydrogen, the ultimate clean fuel, from the Sun, and renewable energy source. Hydrogen can be produced by light-driven photoelectrochemical (PEC) water splitting, but it is very inefficient; rather, we focus here on how electric fields can be applied to metal oxide/water systems in tailoring the interplay with their intrinsic electric fields, and in how this can alter and boost PEC activity, drawing both on experiment and non-equilibrium molecular simulation.

This article presents the concept of renewable methanol production in the gas turbine cycle. As part of the work, an analysis was performed, including the impact of changing the parameters in the methanol reactor on the obtained values of power, yield and efficiency of the reactor, and chemical conversion. The aim of this research was to investigate the possibility of integrating the system for the production of renewable methanol and additional production of electricity in the system. The efficiency of the chemical conversion process and the efficiency of the methanol reactor increases with increasing pressure and decreasing temperature. The highest efficiency values, respectively η = 0.4388 and ηR = 0.3649, are obtained for parameters in the reactor equal to 160 °C and 14 MPa. The amount of heat exchanged in all exchangers reached the highest value for 14 MPa and 160 °C and amounted to Q˙ = 2.28 kW. Additionally, it has been calculated that if an additional exchanger is used bef... [more]

To solve the challenge of decarbonizing the transport sector, a broad variety of alternative fuels based on different concepts, including Power-to-Gas and Power-to-Liquid, and propulsion systems, have been developed. The current research landscape is investigating either a selection of fuel options or a selection of criteria, a comprehensive overview is missing so far. This study aims to close this gap by providing a holistic analysis of existing fuel and drivetrain options, spanning production to utilization. For this purpose, a case study for Germany is performed considering different vehicle classes in road, rail, inland waterway, and air transport. The evaluated criteria on the production side include technical maturity, costs, as well as environmental impacts, whereas, on the utilization side, possible blending with existing fossil fuels and the satisfaction of the required mission ranges are evaluated. Overall, the fuels and propulsion systems, Methanol-to-Gasoline, Fischer−Trops... [more]

A series of experiments were performed to investigate the effect of ignition energy (Eig) and hydrogen addition on the laminar burning velocity (Su), ignition delay time (tdelay), and flame rising time (trising) of lean methane−air mixtures. The mixtures at three different equivalence ratios (ϕ) of 0.6, 0.7, and 0.8 with varying hydrogen volume fractions from 0 to 50% were centrally ignited in a constant volume combustion chamber by a pair of pin-to-pin electrodes at a spark gap of 2.0 mm. In situ ignition energy (Eig ∼2.4 mJ ÷ 58 mJ) was calculated by integration of the product of current and voltage between positive and negative electrodes. The result revealed that the Su value increases non-linearly with increasing hydrogen fraction at three equivalence ratios of 0.6, 0.7, and 0.8, by which the increasing slope of Su changes from gradual to drastic when the hydrogen fraction is greater than 20%. tdelay and trising decrease quickly with increasing hydrogen fraction; however, trising... [more]

Proton Exchange Membrane (PEM) water electrolysis (WE) produces H2 with a high degree of purity, requiring only water and energy. If the energy is provided from renewable energy sources, it releases “Green H2”, a CO2-free H2. PEMWE uses expensive and rare noble metal catalysts, which hinder their use at a large industrial scale. In this work, the electrocatalytic properties of Transition Metal Phosphides (TMP) catalysts supported on Carbon Black (CB) for Hydrogen Evolution Reaction (HER) were investigated as an alternative to Platinum Group Metals. The physico-chemical properties and catalytic performance of the synthesized catalysts were characterized. In the ex situ experiments, the 25% FeP/CB, 50% FeP/CB and 50% CoP/CB with overpotentials of −156.0, −165.9 and −158.5 mV for a current density of 100 mA cm−2 showed the best catalytic properties, thereby progressing to the PEMWE tests. In those tests, the 50% FeP/CB required an overpotential of 252 mV for a current density of 10 mA cm−... [more]

(1) The German energy system transformation towards an entirely renewable supply is expected to incorporate the extensive use of green hydrogen. This carbon-free fuel allows the decarbonization of end-use sectors such as industrial high-temperature processes or heavy-duty transport that remain challenging to be covered by green electricity only. However, it remains unclear whether the current legislative framework supports green hydrogen production or is an obstacle to its rollout. (2) This work analyzes the relevant laws and ordinances regarding their implications on potential hydrogen production plant operators. (3) Due to unbundling-related constraints, potential operators from the group of electricity transport system and distribution system operators face lacking permission to operate production plants. Moreover, ownership remains forbidden for them. The same applies to natural gas transport system operators. The case is less clear for natural gas distribution system operators, wh... [more]

Several North American utilities are planning to blend hydrogen into gas grids, as a short-term way of addressing the scalable demand for hydrogen and as a long-term decarbonization strategy for ‘difficult-to-electrify’ end uses. This study documents the impact of 0−30% hydrogen blends by volume on the performance, emissions, and safety of unadjusted equipment in a simulated use environment, focusing on prevalent partially premixed combustion designs. Following a thorough literature review, the authors describe three sets of results: operating standard and “ultra-low NOx” burners from common heating equipment in “simulators” with hydrogen/methane blends up to 30% by volume, in situ testing of the same heating equipment, and field sampling of a wider range of equipment with 0−10% hydrogen/natural gas blends at a utility-owned training facility. The equipment was successfully operated with up to 30% hydrogen-blended fuels, with limited visual changes to flames, and key trends emerged: (a... [more]

An analysis of the literature data indicates a wide front of research and development in the field of the use of methane−hydrogen mixtures as a promising environmentally friendly low-carbon fuel. The conclusion of most works shows that the use of methane−hydrogen mixtures in internal combustion engines improves their performance and emission characteristics. The most important aspect is the concentration of hydrogen in the fuel mixture, which affects the combustion process of the fuel and determines the optimal operating conditions of the engine. When using methane−hydrogen mixtures with low hydrogen content, the safety measures and risks are similar to those that exist when working with natural gas. Serious logistical problems are associated with the difficulties of using the existing gas distribution infrastructure for transporting methane−hydrogen mixtures. It is possible that, despite the need for huge investments, it will be necessary to create a new infrastructure for the product... [more]

Hydrogen is increasingly being viewed as a significant fuel for future industrial processes as it offers pathways to zero emission. The UK sees hydrogen as one of a handful of low-carbon solutions for transition to net zero. Currently, most hydrogen production is from steam reforming of natural gas or coal gasification, both of which involve the release of carbon dioxide. Hydrogen production from mini decentralised grids via a thermochemical process, coupled with electricity production, could offer favourable economics for small modular reactors (SMRs), whereby demand or grid management as a solution would include redirecting the power for hydrogen production when electricity demand is low. It also offers a clean-energy alternative to the aforementioned means. SMRs could offer favourable economics due to their flexible power system as part of the dual-output function. This study objective is to investigate the critical performance parameters associated with the nuclear power plant (NPP... [more]

Anaerobic digestion (AD) and sewage sludge digestion (SD) plants generate significant quantities of ammoniacal nitrogen in their digestate liquor. This article assesses the economic viability and CO2 abatement opportunity from the utilisation of this ammonia under three scenarios and proposes their potential for uptake in the United Kingdom. Each state-of-the-art process route recovers ammonia and uses it alongside AD-produced biomethane for three different end goals: (1) the production of H2 as a bus transport fuel, (2) production of H2 for injection to the gas grid and (3) generation of heat and power via solid oxide fuel cell technology. A rigorous assessment of UK anaerobic and sewage digestion facilities revealed the production of H2 as a bus fleet transport fuel scenario as the most attractive option, with 19 SD and 42 AD existing plants of suitable scale for process implementation. This is compared to 3 SD/1 AD and 13 SD/23 AD existing plants applicable with the aim of grid inje... [more]

With increasing attention to climate change, the penetration level of renewable energy sources (RES) in the electricity network is increasing. Due to the intermittency of RES, gas-fired power plants could play a significant role in backing up the RES in order to maintain the supply−demand balance. As a result, the interaction between gas and power networks are significantly increasing. On the other hand, due to the increase in peak demand (e.g., electrification of heat), network operators are willing to execute demand response programs (DRPs) to improve congestion management and reduce costs. In this context, modeling and optimal implementation of DRPs in proportion to the demand is one of the main issues for gas and power network operators. In this paper, an emergency demand response program (EDRP) is implemented locally to reduce the congestion of transmission lines and gas pipelines more efficiently. Additionally, the effects of optimal implementation of local emergency demand respo... [more]

This study presents an approach for estimating fuel boil-off behaviour in cryogenic energy carrier ships, such as future liquid hydrogen (LH2) carriers. By relying on thermodynamic modelling and empirical formulas for ship motion and propulsion, the approach can be used to investigate boil-off as a function of tank properties, weather conditions, and operating velocities during a laden voyage. The model is first calibrated against data from a liquefied natural gas (LNG) carrier and is consequently used to investigate various design configurations of an LH2 ship. Results indicate that an LH2 ship with the same tank volume and glass wool insulation thickness as a conventional LNG carrier stores 40% of the fuel energy and is characterised by a boil-off rate nine times higher and twice as sensitive to sloshing. Adding a reliquefaction unit can reduce the LH2 fuel depletion rate by at least 38.7% but can increase its variability regarding velocity and weather conditions. In calm weather, LH... [more]