LAPSE:2024.0468
Published Article

LAPSE:2024.0468
Integration of Chemical Looping Combustion to a Gasified Stream with Low Hydrogen Content
June 5, 2024
Abstract
Global population growth requires the use of various natural resources to satisfy the basic needs of humanity. Fossil fuels are mainly used to produce electricity, transportation and the artificial air conditioning of habitats. Nevertheless, countries around the world are looking for alternative energy sources due to the decrease in the availability of these fuels and their high environmental impact. The mixture of hydrogen and carbon monoxide (H2 + CO), commonly called syngas, is a high-value feedstock for various industrial applications. By varying the composition of syngas, especially the H2/CO molar ratio, it can be used to produce methanol, fuels or synthetic natural gas. However, when this ratio is very low, the separation of this gas usually represents a great problem when making the energy balance, which is why it is proposed to adapt a combustion process in chemical cycles, taking advantage of the energy of this gas, reducing the energy impact of the process. During the present project, mass and energy balances were developed for combustion in chemical cycles, using ilmenite as a carrier, integrating heat exchangers to take advantage of the residual energy at the output of the process, to preheat the inlet current in the regenerator. Here, a comparative was made at different temperatures of the air stream and evaluating the mechanism of the ilmenite when a syngas stream is used as fuel.
Global population growth requires the use of various natural resources to satisfy the basic needs of humanity. Fossil fuels are mainly used to produce electricity, transportation and the artificial air conditioning of habitats. Nevertheless, countries around the world are looking for alternative energy sources due to the decrease in the availability of these fuels and their high environmental impact. The mixture of hydrogen and carbon monoxide (H2 + CO), commonly called syngas, is a high-value feedstock for various industrial applications. By varying the composition of syngas, especially the H2/CO molar ratio, it can be used to produce methanol, fuels or synthetic natural gas. However, when this ratio is very low, the separation of this gas usually represents a great problem when making the energy balance, which is why it is proposed to adapt a combustion process in chemical cycles, taking advantage of the energy of this gas, reducing the energy impact of the process. During the present project, mass and energy balances were developed for combustion in chemical cycles, using ilmenite as a carrier, integrating heat exchangers to take advantage of the residual energy at the output of the process, to preheat the inlet current in the regenerator. Here, a comparative was made at different temperatures of the air stream and evaluating the mechanism of the ilmenite when a syngas stream is used as fuel.
Record ID
Keywords
Carbon Dioxide, chemical looping combustion, mass and energy balances, reduction of emissions, Syngas
Subject
Suggested Citation
Fraga-Cruz GS, Pérez-Méndez MA, Jiménez-García G, Huirache-Acuña R, Nápoles-Rivera F, Espino-Valencia J, Maya-Yescas R. Integration of Chemical Looping Combustion to a Gasified Stream with Low Hydrogen Content. (2024). LAPSE:2024.0468
Author Affiliations
Fraga-Cruz GS: Facultad de Ingeniería Química, Universidad Michoacana de San Nicolás de Hidalgo, Ciudad Universitaria, Morelia 58060, Michoacán de Ocampo, Mexico
Pérez-Méndez MA: Facultad de Ingeniería Química, Universidad Michoacana de San Nicolás de Hidalgo, Ciudad Universitaria, Morelia 58060, Michoacán de Ocampo, Mexico [ORCID]
Jiménez-García G: Academia de Ingeniería Biomédica, Instituto Tecnológico Superior de Pátzcuaro, Av. Tecnológico #1, Tzurumutaro, Pátzcuaro 58660, Michoacán de Ocampo, Mexico
Huirache-Acuña R: Facultad de Ingeniería Química, Universidad Michoacana de San Nicolás de Hidalgo, Ciudad Universitaria, Morelia 58060, Michoacán de Ocampo, Mexico [ORCID]
Nápoles-Rivera F: Facultad de Ingeniería Química, Universidad Michoacana de San Nicolás de Hidalgo, Ciudad Universitaria, Morelia 58060, Michoacán de Ocampo, Mexico
Espino-Valencia J: Facultad de Ingeniería Química, Universidad Michoacana de San Nicolás de Hidalgo, Ciudad Universitaria, Morelia 58060, Michoacán de Ocampo, Mexico
Maya-Yescas R: Facultad de Ingeniería Química, Universidad Michoacana de San Nicolás de Hidalgo, Ciudad Universitaria, Morelia 58060, Michoacán de Ocampo, Mexico [ORCID]
Pérez-Méndez MA: Facultad de Ingeniería Química, Universidad Michoacana de San Nicolás de Hidalgo, Ciudad Universitaria, Morelia 58060, Michoacán de Ocampo, Mexico [ORCID]
Jiménez-García G: Academia de Ingeniería Biomédica, Instituto Tecnológico Superior de Pátzcuaro, Av. Tecnológico #1, Tzurumutaro, Pátzcuaro 58660, Michoacán de Ocampo, Mexico
Huirache-Acuña R: Facultad de Ingeniería Química, Universidad Michoacana de San Nicolás de Hidalgo, Ciudad Universitaria, Morelia 58060, Michoacán de Ocampo, Mexico [ORCID]
Nápoles-Rivera F: Facultad de Ingeniería Química, Universidad Michoacana de San Nicolás de Hidalgo, Ciudad Universitaria, Morelia 58060, Michoacán de Ocampo, Mexico
Espino-Valencia J: Facultad de Ingeniería Química, Universidad Michoacana de San Nicolás de Hidalgo, Ciudad Universitaria, Morelia 58060, Michoacán de Ocampo, Mexico
Maya-Yescas R: Facultad de Ingeniería Química, Universidad Michoacana de San Nicolás de Hidalgo, Ciudad Universitaria, Morelia 58060, Michoacán de Ocampo, Mexico [ORCID]
Journal Name
Processes
Volume
12
Issue
5
First Page
1033
Year
2024
Publication Date
2024-05-19
ISSN
2227-9717
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PII: pr12051033, Publication Type: Journal Article
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LAPSE:2024.0468
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https://doi.org/10.3390/pr12051033
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