In order to improve the recovery efficiency of the Jimusaer tight reservoir in Xinjiang, the nanometer oil displacement agent system suitable for the Jimusaer reservoir was used. In view of the low permeability, high formation temperature, and high salinity characteristics of the prepared water in the Jimusaer tight conglomerate reservoir in Xinjiang, the performance of the nanometer oil displacement agent affecting oil recovery was studied; the study considered interfacial tension, temperature resistance, wetting performance, static oil washing efficiency, and long-term stability. Nanometer oil displacement agent No. 4 had the lowest interfacial tension and could reach the order of 10−1 mN∙m−1; it had excellent temperature resistance and the best static oil washing efficiency and stability. Nano-oil displacement agent No. 2 had the best emulsification performance and wettability and also had good stability. By studying the performance and final oil displacement effect of the nano-oil... [more]

Digestate is the material remaining after the anaerobic digestion of a biodegradable feedstock. The use of digestate as a bedding material is analyzed marginally. The aim of the paper is to monitor the change of the solid phase of digestate due to the action of radiant heat and, based on the results, determine the options of using the solid phase of the digestate for bedding material. Experimental determination of the digestate ignition temperature was carried out according to EN 50281-2-1 (1998) by a hotplate device. Different amounts of samples (3, 5, and 10 g) on the course of thermal degradation were monitored. The results showed higher temperatures of thermal degradation in samples of additionally dried digestate, where these processes were observed earlier in terms of time. Samples of 3 and 10 g of digestate are not suitable as bedding material due to the fire safety of the material.

Drilling-fluid loss has always been one of the challenging issues in the field of drilling engineering. This article addresses the limitations of a single fluid-loss pressure mechanism model and the challenges in predicting positive drilling-fluid-loss pressure. By categorizing fluid losses of various types encountered during drilling, different geological formations associated with distinct mechanisms are considered. The actual drilling-fluid density in the wellbore at the time of fluid-loss occurrence is taken as a reference value for calculating the positive drilling-fluid-loss pressure of the already drilled well. Building upon this foundation, a combined model utilizing the Sparrow Search Algorithm (SSA) and Long Short-Term Memory (LSTM) neural network is constructed. This model effectively explores the intricate nonlinear relationship between well logging, logging engineering data, and fluid-loss pressure. By utilizing both data from the already drilled wells and upper formation... [more]

The shale of the Wufeng−Longmaxi formation in the Sichuan Basin is the preferred layer for shale gas exploration in China, and its petrophysical characteristics are the key to geological and engineering sweet spot prediction. However, the characteristics and impact mechanisms of its acoustic wave velocity and elastic anisotropy are currently unclear. In this paper, the Wufeng−Longmaxi shale is taken as the research object, and the P-wave and S-wave velocities of the samples are tested under the loading and unloading processes of confining pressure. The stress sensitivity variations in parameters such as wave velocity, wave velocity ratio, and anisotropy are discussed. P-wave and S-wave anisotropy parameters are correlated under different pressure conditions. X-ray diffraction, casting thin sections, scanning electron microscopy, micron CT scanning, and other analytical techniques are used to explore the mechanisms of stress sensitivity of elastic parameters. The research results indica... [more]

Fractures play a crucial role as fluid conduits and reservoir spaces in reservoirs. The distribution and characteristics of fractures determine the presence of high-quality reservoirs. To accurately analyze and observe fracture parameters, three-dimensional (3-D) digital cores generated from computed tomography (CT) are utilized. However, the current process of extracting fracture properties from these digital cores is time-consuming and labor-intensive. This paper introduces a new, fast, and automatic workflow for extracting the apparent dip angle and direction of fractures from 3-D digital core images. The proposed workflow involves several steps. Firstly, two perpendicular cross-sections are obtained from the digital core and converted into binary images. Next, the coordinates of four fracture feature points within the core image are automatically extracted. The fracture plane is then fitted using the least squares method based on the extracted coordinates. Finally, the apparent dip... [more]

To address the issues of strong subjectivity, low efficiency, and difficulty in on-site model deployment encountered in existing CCTV defect detection of pipelines, this article proposes an object detection model based on an improved YOLOv5s algorithm. Firstly, involution modules and GSConv simplified models are introduced into the backbone network and feature fusion network, respectively, to enhance the detection accuracy. Secondly, a CBAM attention mechanism is integrated to improve the detection accuracy of overlapping targets in complex backgrounds. Finally, knowledge distillation is performed on the improved model to further enhance its accuracy. Experimental results demonstrate that the improved YOLOv5s achieved an mAP@0.5 of 80.5%, which is a 2.4% increase over the baseline, and reduces the parameter and computation volume by 30.1% and 29.4%, respectively, with a detection speed of 75 FPS. This method offers good detection accuracy and robustness while ensuring real-time detecti... [more]

The multi-stage pulse competition of pressurized pulsed water jet becomes the initial pulse at the head tip, and hydraulic parameters are the key parameters that affect the characteristics of multiple pulses. Based on the ultra-high-speed imaging system, a pressurized pulsed water jet flow field capture system was constructed, and the effects of initial pressure and driving pressure of the pressurized chamber on the characteristics of multi-stage pulses were studied. The experimental results show that as the initial pressure of the booster chamber increases, the jet changes from a discontinuous state to a continuous state, and the multi-level pulse simultaneously changes from dominant multi-pulse to implicit multi-pulse; as the driving pressure increases, the initial spacing between the first pulse and the second pulse increases, and the peak velocity of the initial pulse gradually increases. At the same time, the location of the peak velocity also shifts away from the nozzle as the dr... [more]

The olefin separation from their mixture with paraffins by facilitated transport membranes is a very important process for the further macromolecular compounds production. Membranes loaded with silver ions, which are responsible for the facilitated olefin transport, are instable with time due to their reduction, while those containing protons catalyze the polymerization of olefins. In this work, membranes based on polyethylene with grafted sulfonated polystyrene in various ionic forms (H+, Li+, Na+) were used for the first time for the separation of the ethylene/ethane mixture. The influence of sulfonation time, relative humidity, and various ionic forms on ethylene separation was studied. The SEM study shows a non-uniform sulfur distribution over the membrane thickness for membranes sulfonated for different reaction times. With increasing sulfonation time and relative humidity the ethylene permeability and the factor of its separation with ethane increase. Separation factors for membr... [more]

To explore the flotation feasibility and flotation law of iron minerals from amphibole-type iron oxide ore with full-size minerals, a systematic study on the flotation behaviors of single minerals hematite, quartz, and amphibole was carried out with the anionic reverse flotation system. The effects of collectors, depressants, activators, and pH on the floatabilities of three single minerals was investigated. The flotation separations of binary mixed minerals and ternary mixed ores were carried out, respectively. The study results show that CaCl2 is adsorbed on the surfaces of quartz and amphibole, which can activate them. The hydroxyl groups of the starch molecular chain were adsorbed on the surfaces of the hematite and amphibole in the form of hydrogen bonds, but were hardly adsorbed on surface of the quartz. Therefore, both hematite and amphibole were depressed, resulting in a poor separation effect of the three single minerals in the anionic flotation system.

Ambrox is a marine natural compound with a delicious ambergris-type scent widely used in fine perfumery. The increase in the long-term scent and shelf life of perfumes has become a paramount endeavor in the fragrance industry. To the best of our knowledge, the exchange of hydrogen by deuterium to decrease the volatility of the constituents of a perfume has not yet been investigated. In this article, we propose this new use of deuteration to synthesize deuterated ambrox in order to decrease its volatility and improve the long-term scent and extend the shelf-life of perfumes.

Peanuts, being crucial crops of global importance, have gained widespread recognition for their versatility and nutritional value. In addition to direct consumption, either with or without treatment, peanuts can be the subject of diverse applications focusing mainly on two distinct objectives: oil extraction and defatting processes. As a result of the first process, a solid matrix is generated as a by-product, necessitating the exploration of strategies for its valorization, while the second process is centered on obtaining protein-rich, low-fat peanuts, for which the oil recovered becomes the by-product. As consumers increasingly seek out plant-based foods for their potential health benefits, this trend is expected to persist, encompassing peanut-based foods as well. This review elucidates the methods used for extracting peanut oil, including mechanical and chemical processes that have been combined with biological or physical pre-treatment techniques. Their primary goals are to maxim... [more]

Research on the flow electrification characteristic is of paramount importance for ensuring the electrostatic safety of liquid hydrogen transportation systems. However, the discussion about electrostatic saturation in flow electrification has been lacking. To address this gap, a theoretical model governing the process of flow electrification is constructed which couples the charge conservation equation with the Navier-Stokes equations and applies the Neumann boundary conditions at the solid-liquid interface, and the application of this model is validated by existing experimental data with the simulation parameters of At and n being 9.08 × 1012 and 0.85 for liquid hydrogen. A comparison with benzene reveals that benzene almost reaches the electrostatic saturation state after flowing one meter, whereas the flow of liquid hydrogen remains in the linear growth stage. However, with an increase in pipe length, a gradual saturation trend emerges in the curves of streaming current versus flow... [more]

Severe erosion phenomena often occur in industrial polycrystalline silicon units, leading to hydrogen leakage accidents and affecting long-term operation. It is favorable to use a computational fluid dynamics (CFD) simulation with the dense discrete phase model (DDPM) and the sub-grid energy-minimization multi-scale (EMMS) drag model to improve the prediction accuracy of complex multiphase erosion phenomena in a connecting pipe of an industrial polycrystalline silicon unit. Furthermore, the effect of droplet the specularity coefficient on boundary conditions is thoroughly considered. The predicted erosion behaviors are consistent with industrial data. The effects of operations parameters were discussed with three-dimensional CFD simulation, including droplet size and hydrogen volume fraction on erosion behaviors. The results indicated that the non-uniform multiphase erosion flow behavior near the wall can be simulated accurately with the EMMS drag model in a coarse mesh. A suitable dro... [more]

The development of natural fractures (NFs) in shale gas reservoirs is conducive to improving the productivity of shale gas wells. However, NF development leads to high-frequency frac hits between the infill and parent wells, which critically restricts its efficiency. To elucidate the large contribution of hydraulic fractures (HFs) and NFs in frac hits during the production and the development of NF-developed shale gas reservoirs, such reservoirs in the WY area of western China are taken as an example. A total of 197 frac hits well events in this area are systematically classified via the frac-hit discrimination method, and the effects of different factors on HF- and NF- dominated frac hits are classified and studied. Combined with the correlation analysis method and the chart method, the main controlling factors affecting the two types of frac hits are determined, and the corresponding frac-hit prevention countermeasures are proposed. The research demonstrates that (1) the distribution... [more]

Vacuum freeze-dried products exhibit properties characteristic of porous media, rendering them superior in both drying and rehydration capabilities. However, the process of sublimation drying is constrained by its substantial time and energy costs. To comprehensively grasp its technological process and identify the optimal process parameters, the cellular automata method was employed for sublimation process simulation. Carrot slices, measuring 10 mm in thickness and 40 mm in radius, were selected for both simulation and experimentation. The sublimation process was characterized using a two-dimensional heat and mass transfer equation, inclusive of a dusty gas model. Additionally, a cellular automaton model was applied to simulate the mass transfer process, temperature, and moisture content changes in the sublimation drying stage. Then, the accuracy of the model was verified through experimentation. There was a remarkable alignment between simulation and experimental outcomes, with deter... [more]

The present work is a numerical analysis of electro-thermo convection, occurring in a square differentially heated cavity filled with a dielectric fluid. The cavity experiences the combined effects of viscous, electrical, and thermal forces. The equations modelling the physical problem are solved via the finite volume approach. The study focuses on the effect of cavity tilt on the fluid flow structure and thermal performance inside the enclosure under the action of an electric field. A parametric study was performed, where the tilt angle is getting varied between 0° and 90°, as well as the Rayleigh number (5000 ≤ Ra ≤ 250,000) and the electric field (0 ≤ T ≤ 800). Furthermore, the electric charge injection level C, the mobility M and the Prandtl Pr numbers were all adjusted to a value of 10. The obtained results demonstrate that the hydrodynamic and thermal fields are significantly impacted by the cavity inclination. In addition, regardless of the thermal Rayleigh’s number, high electr... [more]

This paper presents a comprehensive computational fluid dynamics (CFD) model for describing the oxidative coupling of methane (OCM) carried out in fixed-bed reactors for olefin production. Initially, a single pellet model was developed and implemented to describe the heat and mass transfer within the pellet and between the gaseous and solid phases. Subsequently, sensitivity analyses were performed to assess the impact of pellet arrangement and feed conditions on the heat and mass transfer rates, subsequently affecting concentration and temperature profiles. As indicated by the simulations, a high ethylene content could be obtained with the increase in the CH4/O2 ratio, aligning well with previous experimental studies. Furthermore, it was observed that pellet arrangement can significantly affect the reactor performance. Additionally, the behavior of temperature and concentration in the gaseous and solid phases can be very different, such that pseudo-homogeneous modeling approaches shoul... [more]

Carbon dioxide (CO2) is widely used in the prevention and control of spontaneous coal combustion. In this manuscript, three low-rank coals with different metamorphic degrees were selected as the research objects. The temperature-programmed experiments, in situ infrared cooling experiments, simulation of the competitive adsorption of CO2 and oxygen (O2) in coal pores, and simulation study of the CO2 inhibition of the coal oxygen composite reaction were used to obtain the role and effect of CO2 in preventing oxygen adsorption in coal at the low-temperature oxidation stage. It was concluded that CO2 can displace the O2 near the pore wall to physically prevent the adsorption of O2. Through the changing law of heating rate and a kinetics analysis, it was found that CO2 can increase its activation energy by 5.3−108.3% during the slow heating stage of coal and reduce its heat rate. At around 120 °C, coal loses the protective effect of CO2. From the changes in functional groups, it can be seen... [more]

Pecan (Carya illinoinensis) nuts are rich in functional compounds (unsaturated fatty acids, phytosterols, polyphenols, and tocopherols) associated with various health benefits. Commercially, pecan nuts are roasted to enhance their physical, chemical, and sensory properties. In the present study, response surface methodology (RSM) was used to optimise the quality and nutritional and antioxidant attributes of ‘Wichita’ pecan nuts roasted by using a microwave process with a range of microwave power (96.45−803.55 W) and roasting time (1.37−5.62 min). The microwave-roasted pecan nuts were analysed for hardness, total colour difference (TCD), and radical scavenging activity and modelled using the central composite design. The results showed that microwave power and roasting time significantly (p < 0.05) influenced the quality attributes of the pecan. The quadratic model adequately described the changes in TCD and hardness, respectively, while the 2FI model adequately described the changes... [more]

This work focuses on developing and applying Encrypted Lyapunov-based Model Predictive Control (LMPC) in a nonlinear chemical process network for Ethylbenzene production. The network, governed by a nonlinear dynamic model, comprises two continuously stirred tank reactors that are connected in series and is simulated using Aspen Plus Dynamics. For enhancing system cybersecurity, the Paillier cryptosystem is employed for encryption−decryption operations in the communication channels between the sensor−controller and controller−actuator, establishing a secure network infrastructure. Cryptosystems generally require integer inputs, necessitating a quantization parameter d, for quantization of real-valued signals. We utilize the quantization parameter to quantize process measurements and control inputs before encryption. Through closed-loop simulations under the encrypted LMPC scheme, where the LMPC uses a first-principles nonlinear dynamical model, we examine the effect of the quantization... [more]

Aiming at the stability of the output speed and the poor adaptability of the transmission system during the operation of a cotton picker, a control strategy of hydro-mechanical continuously variable transmission (HMCVT) for cotton pickers based on gray prediction and fuzzy PID is proposed. Firstly, the hardware and software of the existing hydraulic mechanical coupling transmission test-bed of cotton pickers are designed, and the HMCVT human-computer interaction measurement and control system is built by using LABVIEW 2020 software. Then, combined with the transmission theory, the control strategy and gray prediction model are designed. Finally, the continuity test, transmission efficiency test, and adaptive control verification test are carried out. The results show that as the input speed increases, the peak time of the pump motor output speed is prolonged, while the overall speed regulation process is smoother, and the output speed process of the HMCVT system is continuous. As the d... [more]

The process of energy transition in Colombia has sparked an exploration into appropriate geographical areas for the utilization of solar energy. The country’s rugged terrain and significant climate variability pose challenges for implementing standardized technologies uniformly across all regions. Consequently, this study aims to develop and apply a mathematical model to characterize the performance of a solar adsorption cooling system under the environmental conditions found in six distinct Colombian cities, taking into account different thermal profiles and extreme weather periods such as the El Niño and La Niña phenomena. The selected mathematical model was simulated in these cities, considering ambient temperature and solar radiation variables over a twelve-month period during these extreme weather phenomena and an additional twelve-month period representative of a typical year with minimal influence from these phenomena. The results indicated that despite a lower coefficient of pe... [more]

Improving the resolution and accuracy of the mechanical properties of organic-rich shale is very important. The results can reveal the mechanical properties of shale from micro scale and serve as a guide for the design of hydraulic fracture optimization parameters. This study introduced an advanced technique to obtain the mechanical properties of shale with high resolution (58.6 nm/pixel) by combining SEM, EDS, and Atomic Force Microscopy (AFM). To locate the target area in SEM and AFM accurately, a positioning technique that uses special distributions of pyrite was established. AFM PeakForce QNM mode was selected due to its advantages at capturing topography and mechanical properties in material. Results illustrated the ability of AFM to obtain the mechanical properties (modulus) of individual mineral components in shale, the detailed topography of crack, and mechanical properties of minerals in a specific area. In particular, the mechanical properties of minerals around crack explain... [more]

Rockfall disasters have long restricted the further improvement of the safety level of steeply dipping coal seams (SDCSs). When a rockfall disaster occurs, it causes damage to the hydraulic support and other equipment at the working face. An effective way to carry out protection design is using the law of rockfall migration and energy evolution. Therefore, this study used the polyhedral rockfall migration and its impact process on the hydraulic support equipment of the working face as the research object and analyzed the influence of relevant parameters on the maximum contact deformation, maximum impact force, and energy absorption of the column during the collision and contact between the rockfall and the hydraulic support column. Firstly, with hexahedral rockfall as an example, the migration process of rockfall was simulated using PFC3D software. Secondly, according to the Hertz contact theory, the contact model of the shock process between the rockfall and the hydraulic support colu... [more]

Adsorbents presenting high adsorption capacity, fast adsorption rate, easy regeneration, and a good possibility for reusability are ideal for removing 4-chloro-2-methyl-phenoxyacetic acid (MCPA) or other pesticides from wastewater. Here, the effects of regeneration treatments on adsorption−desorption cycles are examined using two commercial activated carbons (ACs) (Merck and Norit 1240 X). MCPA adsorption was fast on Merck and Norit ACs in powder form (6 h) but on Norit AC, in granular form, adsorption was too slow, and the equilibrium time was reached only after 288 h. MCPA adsorption kinetic data were analyzed by applying pseudo-first-order, pseudo-second-order, and Weber−Morris models. The pseudo-second-order model fit better to all data, and the Weber−Morris representation allows confirming that on Norit 1240 X, in granular form, the pore diffusion was the limiting factor concerning the MCPA adsorption. Merck and Norit 1240 X (in powder and granular form) ACs loaded with MCPA were... [more]