Using biodiesel in diesel engines is beneficial for reducing emissions of carbon monoxide (CO), hydrocarbons (HC) and particulate matters (PM). Biodiesel is usually produced from vegetable oils or animal fats. When produced from plant oil or woody plant sources, biodiesel can reduce a significant amount of carbon dioxide on a life cycle basis. The objective of this study is to produce biodiesel from a non-conventional woody plant source that is, crude tall oil, which is a dark brown viscous liquid extracted and processed in wood pulping plants. It contains a high percentage of fatty acids. From raw crude tall oil, tall oil fatty acids were separated and were successfully used for the production of biodiesel in this study. Although biodiesel produces lower CO, HC and PM than petroleum diesel fuel, it produces higher oxides of nitrogen (NOx) emissions in diesel engines. Water emulsifications of diesel-biodiesel blends are investigated in a direct injection (DI) diesel engine in this work... [more]

We propose a mathematical model for phenol and p-cresol mixture degradation in a continuously stirred bioreactor. The model is described by three nonlinear ordinary differential equations. The novel idea in the model design is the biomass specific growth rate, known as sum kinetics with interaction parameters (SKIP) and involving inhibition effects. We determine the equilibrium points of the model and study their local asymptotic stability and bifurcations with respect to a practically important parameter. Existence and uniqueness of positive solutions are proved. Global stabilizability of the model dynamics towards equilibrium points is established. The dynamic behavior of the solutions is demonstrated on some numerical examples.

Population Balance Modeling (PBM) is a powerful modeling framework that allows the prediction of the dynamics of distributed properties of a population of individuals at the mesoscale [...]

In industrial maintenance activity, very sophisticated technical and human factors are needed to achieve the great process or service that the company provides, with a large dose of knowledge based on the personal experience of maintenance technicians. However, the management and application of knowledge in this activity is often relegated to a third level (or simply forgotten). The aim of this study is to identify, classify and prioritize the different barriers and facilitators that can be found in maintenance organizations of the company in reference to knowledge management in strategic maintenance activities, and what competitive advantages could be used for their appropriate introduction in the company. For this, qualitative techniques have been used through a field study and observation, as well as semi-structured interviews between company directors and maintenance managers of first-level companies in various sectors (industrial or services), to draw conclusions on the applicatio... [more]

Thermal energy storage systems help to couple thermal energy generation and process demand in cogeneration facilities. One single deposit with two design temperatures and one main temperature step in sensible thermal energy storage define the thermocline systems. Performance of one high size real thermocline thermal energy storage system is analysed. Starting from temperature and mass flow rate data registered by the plant control system, one advanced thermodynamic analysis is performed. The quality of heat storage is analysed in terms of evaluation of the stratification in the thermocline zone. The temperature data registered at 21 positions is extended by displacement analysis generating detailed profiles. Fraction of recoverable heat, thermocline width, stratification indices based on energy and exergy analysis, and mean temperature gradients in the thermocline region are calculated. These parameters are monitored under real operation conditions of the plant. The calculated paramete... [more]

Developing economical and robust catalysts for the highly selective and stable destruction of chlorinated volatile organic compounds (CVOCs) is a great challenge. Here, hollow nanosphere-like VOx/CeO2 catalysts with different V/Ce molar ratios were fabricated and adopted for the destruction of1,2−dichloroethane (1,2−DCE). The V0.05Ce catalyst possessed superior catalytic activity, reaction selectivity, and chlorine resistance owing to a large number of oxygen vacancies, excellent low-temperature redox ability, and chemically adsorbed oxygen (O− and O2−) species mobility. Typical chlorinated byproducts (CHCl3, CCl4, C2HCl3, and C2H3Cl3) derived from the cleavage of C−Cl and C−C bonds of 1,2−DCE were detected, which could be effectively inhibited by the abundant acid sites and the strong interactions of VOx species with CeO2. The presence of water vapor benefited the activation and deep destruction of 1,2−DCE over V0.05Ce owing to the efficient removal of Cl species from the catalyst sur... [more]

A novel procedure to determine the environmental quality of boilers based on the combustion entropy degradation, the pollutants emission and the device efficiency is proposed. The entropy generation due to the chemical reaction was determined and then the irreversibilities on the external environment were first quantified. Successively, the entropy generation numbers of the combustion reactions were combined with the heat transfer process entropy generation of the boilers to consider the actual functioning conditions, in order to quantify the environmental damages by introducing an Environment Quality Index (EQI). A parametric study varying the heat exchanger efficiency, fluid flow rates and temperatures, for different fuel typologies, was performed to assess the environmental impact. Solar hydrogen was considered for its importance as future renewable energy carrier. The results showed that the highest EQI was produced by the natural gas, but if heat exchanger parameters are defined o... [more]

Due to insufficient mass transfer and mixing issues, cells in the industrial-scale bioreactor are often forced to experience glucose feast/famine cycles, mostly resulting in reduced commercial metrics (titer, yield and productivity). Trehalose cycling has been confirmed as a double-edged sword in the Penicillium chrysogenum strain, which facilitates the maintenance of a metabolically balanced state, but it consumes extra amounts of the ATP responsible for the repeated breakdown and formation of trehalose molecules in response to extracellular glucose perturbations. This loss of ATP would be in competition with the high ATP-demanding penicillin biosynthesis. In this work, the role of trehalose metabolism was further explored under industrially relevant conditions by cultivating a high-yielding Penicillium chrysogenum strain, and the derived trehalose-null strains in the glucose-limited chemostat system where the glucose feast/famine condition was imposed. This dynamic feast/famine regim... [more]

Coprecipitation-adsorption plays a significant role during coagulation-flocculation-sedimentation (C/F/S) of antimony (Sb) in water. This work uses a Box−Behnken statistical experiment design (BBD) and response surface methodology (RSM) to investigate the effects of major operating variables such as initial Sb(III, V) concentration (100−1000 µg/L), ferric chloride (FC) dose (5−50 mg/L), and pH (4−10) on redox Sb species. Experimental data of Sb(III, V) removal were used to determine response function coefficients. The model response value (Sb removal) showed good agreement with the experimental results. FC showed promising coagulation behavior of both Sb species under optimum pH (6.5−7.5) due to its high affinity towards Sb species and low residual Fe concentration. However, a high dose of 50 mg/L of FC is required for the maximum (88−93%) removal of Sb(V), but also for the highest (92−98%) removal of low initial concentrations of Sb(III). Furthermore, BBD and RSM were found to be reli... [more]

For reliability and safety issues of injection wells, corrosion resistance of materials used needs to be determined. Herein, representative low-cost materials, including carbon steel X70/1.8977 and low alloyed steel 1.7225, were embedded in mortar to mimic the realistic casing-mortar interface. Two types of cement were investigated: (1) Dyckerhoff Variodur commercial Portland cement, representing a highly acidic resistant cement and (2) Wollastonite, which can react with CO2 and become stable under a CO2 stream due to the carbonation process. Exposure tests were performed under 10 MPa and at 333 K in artificial aquifer fluid for up to 20 weeks, revealing crevice corrosion and uniform corrosion instead of expected pitting corrosion. To clarify the role of cement, simulated pore water was made by dispersing cement powder in aquifer fluid and used as a solution to expose steels. Surface analysis, accompanied by element mapping on exposed specimens and their cross-sections, was carried out... [more]

The prevalence of the antibiotic resistant bacteria remains a global issue. Cheap, sustainable and multifunctional antibacterial membranes are at the forefront of filtrating materials capable of treating multiple flow streams, such as water cleansing treatments. Carbon nanomaterials are particularly interesting objects shown to enhance antibacterial properties of composite materials. In this article, amino-functionalized, photoluminescent carbon nanodots (CNDs) were synthesized from chitosan by bottom-up approach via simple and green hydrothermal carbonization. A chemical model for the CNDs formation during hydrothermal treatment of chitosan is proposed. The use of urea as an additional nitrogen source leads to the consumption of hydroxyl groups of chitosan and higher nitrogen doping level as pyridinic and pyrrolic N-bonding configurations in the final carbonaceous composition. These functionalized carbon nanodots that consist of carbon core and various surface functional groups were u... [more]

In order to improve the accuracy of numerical simulation, a new heat transfer model is developed by using a modular approach in the Anstalt für Verbrennungskraftmaschinen (AVL)-Boost software. The improved heat transfer model mainly considers the effects of the swirl and boiling heat transfer inside the engine. In addition, a chemical kinetics mechanism including 475 reactions and 134 species is employed to predict the combustion of diesel engines fueled with biodiesel. The result shows that the boiling heat transfer will occur, especially in the high-temperature area. Analysis shows that the improved model is reliable and its precision is increased. Finally, the perturbation method is employed to investigate the relatively important inputs as the complex nonlinear function with a lot of output data and input data produced by the improved model. The relative effects of different parameters such as EGR, injection mass, injection timing, compression ratio, inlet air pressure, fuel inject... [more]

The agriculture and livestock industry generate waste used in anaerobic digestion to produce biogas containing methane (CH4), useful in the generation of electricity and heat. However, although biogas is mainly composed of CH4 (~65%) and CO2 (~34%), among the 1% of other compounds present is hydrogen sulphide (H2S) which deteriorates engines and power generation fuel cells that use biogas, generating a foul smell and contaminating the environment. As a solution to this, anoxic biofiltration, specifically with biotrickling filters (BTFs), stands out in terms of the elimination of H2S as it is cost-effective, efficient, and more environmentally friendly than chemical solutions. Research on the topic is uneven in terms of presenting performance markers, underestimating many microbiological indicators. Research from the last decade was analyzed (2010−2020), demonstrating that only 56% of the reviewed publications did not report microbiological analysis related to sulphur oxidising bacteria... [more]

Understanding the influence of gas flow maldistribution in honeycombs can be beneficial for the process design in various technical applications. Although recent studies have investigated the effect of maldistribution by comparing the results of numerical simulations with experimental measurements, an exhaustive 3D full-field comparison is still lacking. Such full-field comparisons are required to identify and eliminate possible limitations of numerical and experimental tools. For that purpose, spatially resolved flow patterns were simulated by computational fluid dynamics (CFD) and measured experimentally by non-invasive NMR velocimetry (MRV). While the latter might suffer from a misinterpretation of artefacts, the reliability of CFD is linked to correctly chosen boundary conditions. Here, a full-field numerical and experimental analysis of the gas flow within catalytic honeycombs is presented. The velocity field of thermally polarized methane gas was measured in a regular 3D-printed... [more]

Hydrogen-fueled fuel cells are considered one of the key strategies to tackle the achievement of fully-sustainable mobility. The transportation sector is paying significant attention to the development and industrialization of proton exchange membrane fuel cells (PEMFC) to be introduced alongside batteries, reaching the goal of complete de-carbonization. In this paper a multi-phase, multi-component, and non-isothermal 3D-CFD model is presented to simulate the fluid, heat, and charge transport processes developing inside a hydrogen/air PEMFC with a serpentine-type gas distributor. Model results are compared against experimental data in terms of polarization and power density curves, including an improved formulation of exchange current density at the cathode catalyst layer, improving the simulation results’ accuracy in the activation-dominated region. Then, 3D-CFD fields of reactants’ delivery to the active electrochemical surface, reaction rates, temperature distributions, and liquid w... [more]

The integration of reaction and extractive distillation system is beneficial for reducing the process cost. A systematic method is proposed to identify the optimal solvent, solvent-to-feed ratio, extractive distillation sequence and reactor operating conditions based on the integration of reactor and extractive distillation. The non-key component matrix method is used to generate the extractive distillation sequences. The proposed method can be used to evaluate different solvents, solvent-to-feed ratios, as well as the extractive distillation sequences; the optimal extractive distillation parameters corresponding to the minimum total annualized cost (TAC) can be identified considering different operating conditions. For the selective hydrogenation of benzene to cyclohexene process, the minimum total annualized cost of unit desired product, 4.01 $·kmol−1, is achieved when the reactor’s inlet temperature is 333 K, solvent N-Formylmorpholine and sequence S2 are employed, and the solvent-t... [more]

Removal of nitrogen oxides during coal combustion is a subject of great concerns. The present study reviews the state-of-art catalysts for NO reduction by CO, CH4, and H2. In terms of NO reduction by CO and CH4, it focuses on the preparation methodologies and catalytic properties of noble metal catalysts and non-noble metal catalysts. In the technology of NO removal by H2, the NO removal performance of the noble metal catalyst is mainly discussed from the traditional carrier and the new carrier, such as Al2O3, ZSM-5, OMS-2, MOFs, perovskite oxide, etc. By adopting new preparation methodologies and introducing the secondary metal component, the catalysts supported by a traditional carrier could achieve a much higher activity. New carrier for catalyst design seems a promising aspect for improving the catalyst performance, i.e., catalytic activity and stability, in future. Moreover, mechanisms of catalytic NO reduction by these three agents are discussed in-depth. Through the critical rev... [more]

Novel technologies such as partial nitritation (PN) and partial denitritation (PDN) could be combined with the anammox-based process in order to alleviate energy input. The former combination, also noted as deammonification, has been intensively studied in a frame of lab and full-scale wastewater treatment in order to optimize operational costs and process efficiency. For the deammonification process, key functional microbes include ammonia-oxidizing bacteria (AOB) and anaerobic ammonia oxidation bacteria (AnAOB), which coexisting and interact with heterotrophs and nitrite oxidizing bacteria (NOB). The aim of the presented review was to summarize current knowledge about deammonification process principles, related to microbial interactions responsible for the process maintenance under varying operational conditions. Particular attention was paid to the factors influencing the targeted selection of AOB/AnAOB over the NOB and application of the mathematical modeling as a powerful tool en... [more]

The issue of sustainability is a growing concern and has led to many environmentally friendly chemical productions through a great intensification of the use of biomass conversion processes. Thermal conversion of biomass is one of the most attractive tools currently used, and pyrolytic treatments represent the most flexible approach to biomass conversion. In this scenario, microwave-assisted pyrolysis could be a solid choice for the production of multi-chemical mixtures known as bio-oils. Bio-oils could represent a promising new source of high-value species ranging from bioactive chemicals to green solvents. In this review, we have summarized the most recent developments regarding bio-oil production through microwave-induced pyrolytic degradation of biomasses.

Due to the poor protein availability of algae in their unprocessed form, development of extraction methods for phycobiliproteins is of great significance. This study aimed to extract phycoerythrin (PE) and phycocyanin (PC) from Porphyra via bacterial enzymatic hydrolysis and to evaluate their bioactivity. To induce enzyme production, Porphyra powder was added into the culture medium of two marine bacterial strains. The pH and enzyme activity of the cultured supernatant, namely crude enzyme solution, were significantly raised. For PE and PC extraction, Porphyra were incubated within crude enzyme solution with homogenization and ultrasonication followed by ultrafiltration process. After distinguishing by fast performance liquid chromatography (FPLC), three major fractions were observed and identified as R-PE, R-PC and small molecular PE by high-performance liquid chromatography (HPLC) and polyacrylamide gel electrophoresis (PAGE) analysis. With respect to bioactivity, these three fractio... [more]

The efficiency of Azadirachta indica (neem leaves) on the removal of Pb(II) ions by adsorption from aqueous solution was investigated in this study. The efficiency of these leaves (without chemical or thermal treatment) for the adsorption of Pb(II) ions has not previously been reported. Batch experiments were performed to study the effect of the particle size, pH, adsorbent dose, contact time, initial Pb(II) ion concentration, and temperature. The maximum removal of 93.5% was achieved from an original Pb(II) ion solution concentration of 50 mg/L after 40 min, at pH 7, with 0.60 g of an adsorbent dose. The maximum adsorption capacity recorded was 39.7 mg/g. The adsorption process was also studied by examining Langmuir, Freundlich, Temkin isotherm, and Dubinin−Radushkevich (D-R) isotherm models. The results revealed that the adsorption system follows the pseudo-second-order model and fitted the Freundlich model. Several thermodynamic factors, namely, the standard free energy (∆G°), entha... [more]

In this study, hydrodynamic interactions between passing and moored ships were studied by applying a time-domain numerical simulation method. The boundary value problem for a fluid domain was formulated based on a potential flow theory. A numerical method was developed based on a finite element method with an efficient re-mesh algorithm. Regarding the free-surface boundary conditions, both double-body and free-surface models were considered for examining the free-surface effect on the hydrodynamic forces due to the passing ship. First, numerical results were validated by comparison with the model test results of Kriebel et al. (2005), where generic Series 60 hulls were considered as the target model for the passing and moored ships. In addition, hydrodynamic pressure fields and force time-series were investigated to understand the passing ship problem. Second, a series of numerical simulations were performed to study the effects of the passing ship speed, separation distance, water dep... [more]

This study sought to investigate the cardioprotective potency and interaction of muskmelon (Cucumis melo) with enalapril (ENA) against myocardial damage caused by acute and chronic isoprenaline (ISO) treatments in rats. In the acute model, 150 mg/kg (s.c) of ISO was administered for two consecutive days at the end of pretreatment with either ENA, muskmelon, or both in their respective groups. ISO was introduced into the chronic therapy of ENA/muskmelon/ENA + muskmelon groups during the last 10 days at 3 mg/kg. Muskmelon was tested at three doses (100, 200, and 500 mg/kg, p.o., 30 days), and one normal dose of ENA (10 mg/kg) was used. Blood samples were taken at the end of treatment, and the animals were sacrificed. Biochemical markers such as LDH and CK-MB, as well as antioxidant (superoxide dismutase (SOD) and catalases) and thiobarbituric acid reactive species (TBARS) were measured in both serum and heart tissue homogenate (HTH). To confirm the biochemical findings, histological slid... [more]

Tip clearance has a great effect on the flow and pressure fluctuation characteristics in a multiphase pump, especially at multiple operating points. The phase distribution and pressure fluctuation in tip clearance in a multiphase pump are revealed using the CFD (computational fluid dynamics) technology and high-speed photography methods. In this paper, the phase distribution, the gas-liquid two-phase velocity slip, and the pressure fluctuation intensity are comprehensively analyzed. Results show with the increase of the tip clearance, the multiphase pump pressurization performance is obviously deteriorated. In the meantime, the gas accumulation mainly occurs at the hub, the blade suction side (SS), and the tip clearance, and the maximum gas-liquid two-phase velocity difference is near the impeller streamwise of 0.4. In addition, the tip clearance improves the gas-liquid two-phase distribution in the pump, that is, the larger the tip clearance is, the more uniform the gas-liquid distrib... [more]

Wettability patterning of a surface is a passive method to manipulate the flow and heat transport mechanism in many physical processes and industrial applications. This paper proposes a rational wettability pattern comprised of multiple superhydrophilic wedges on a superhydrophobic background, which can continuously remove the impacted spray droplets from the horizontal surface. We observed that the spray droplets falling on the superhydrophilic wedge region spread and form a thin liquid film, which is passively transported away from the surface. However, most of the droplets falling on the superhydrophobic region move towards the wedge without any flooding. The physics of the passive transport of the liquid film on a wedge is also delved into using numerical modelling. In particular, we elucidate the different modes of droplet transport in the superhydrophobic region and the interaction of multiple droplets. The observed droplet dynamics could have profound implications in spray cooli... [more]