This paper aims at assessing the impact of retrofitting an existing, 730 MWe, coal-fired power plant into a biomass-fired combined heat and power (CHP) plant on its energetic and exergetic performances. A comprehensive thermodynamic model of the power plant was developed and validated against field data, resulting in less than 1% deviation between the model and the measurements for the main process parameters. The validated model was then used to predict the behaviour of the biomass CHP after retrofitting. The modelled CHP unit is coupled to a steam-explosion biomass upgrading plant, a biorefinery process, and a high-temperature heat network. 13 scenarios were studied. At constant boiler load, delivering heat to the considered heat clients can increase the total energy efficiency of the plant from 44% (electricity only) to 64%, while the total exergy efficiency decreases from 39% to 35%. A total energy efficiency of 67% could be reached by lowering the network temperature from 120∘C to... [more]

The cocombustion of coal and pinus sawdust waste is an economically viable and sustainable option for increasing the share of biomass in energy production. This technology also has the potential to reduce the emission of greenhouse gases from existing coal fired power plants. The thermal synergistic effects of cocombusting Hwange bituminous coal (HC) with Pinus sawdust (PS) were thus investigated using thermogravimetric analysis. Fuel blending mass ratios of 100HC, 90HC10PS, 80HC20PS, 70HC30PS, and 100PS under an oxidative atmosphere at three different heating rates of 5, 12.5, and 20 °C/min were used for the experimental setup. Zero to negative synergy was generally observed for the mass loss curves (TG) at different blending ratios. Generally positive synergy was observed with relation to rate of mass loss curves (DTG) for the 80HC20PS and 70HC30PS fuel blends only. The ignition index increased with blending ratio by an average of 42.86%, whilst the burnout index showed a maximum inc... [more]

The development of the world economy goes hand in hand with increased energy consumption and global warming caused by greenhouse gases. These issues can be tackled by implementing promising technologies of power generation. They differ from the known ones in that new energy resources are involved, e.g., mixtures of various types of biomass, provided that hazardous gas emissions during the production process are minimized. The development of high-potential energy-efficient and environmentally friendly technologies which use biofuel in the energy industry requires scientific evidence for the mechanisms, conditions, and characteristics of physical and chemical processes during pyrolysis and gasification of biomass, including its multicomponent types. This article analyzes the world technologies and research findings in the field of biomass pyrolysis and gasification. The effect of a group of factors on the intensity and completeness of gasification and pyrolysis of biofuel compositions ha... [more]

The potential of using the biomass of four wetland plant species (Iris pseudacorus, Juncus effusus, Phragmites australis and Typha latifolia) grown in treatment wetland systems and under natural conditions were tested to produce high-value materials using hydro-thermal liquefaction (HTL). The results show that the wetland plants biomass is suitable for biocrude and biochar production regardless of the origin. The hydrothermal liquefaction products’ (biocrude, biochar, aqueous and gaseous phase) yields vary according with the specific biomass composition of the species. Furthermore, the results show that the biomass composition can be affected by the growing condition (treatment wetland or natural unpolluted conditions) of the plants. None of the single components seems to have a determinant effect on the biocrude yields, which reached around 30% for all the analyzed plants. On the contrary, the biochar yields seem to be affected by the composition of the biomass, obtaining different yi... [more]

In the age of the impending climate crisis, and further forecast ecological catastrophes, humankind has begun to think with growing interest about replacing existing energy sources with renewable ones. An increasing number of people have begun to discuss the need to implement registries that collect information about the energy potential of specific parts of the environment we live in. Additionally, the simultaneous registration of installations used for obtaining energy from alternative sources is desirable. In addition to quantitative attributes, such databases should also contain comprehensive spatial information. Since, in the era of globalization, the creation of such databases ought to be standardized, the purpose of this study is to indicate the directions in which the cadastre of renewable energy sources should be developed by: (i) reviewing the solutions of renewable energy sources that have been described in the scientific literature; (ii) analyzing the content of selected ge... [more]

The achievement of climate neutrality in the European Union by 2050 will not be possible solely through a reduction in fossil fuels and the development of energy generation from renewable sources. Large-scale implementation of various technologies is necessary, including bioenergy with carbon capture and storage (BECCS), carbon capture and storage (CCS), and carbon capture and utilisation (CCU), as well as industrial electrification, the use of hydrogen, the expansion of electromobility, low-emission agricultural practices, and afforestation. This research is devoted to an analysis of BECCS as a negative emissions technology (NET) and the assessment of its implementation impact upon the possibility of achieving climate neutrality in the EU. The modelling approach utilises tools developed within the LIFE Climate CAKE PL project and includes the MEESA energy model and the d-PLACE CGE economic model. This article identifies the scope of the required investment in generation capacity and t... [more]

Methods to assess wood-based bioenergy projects have tended to focus on technological and physical constraints. Less is known about how longer-term environmental, economic, and social systems—the three pillars of sustainable development—have influenced technological development in the context of woody biomass energy. This research offers new methods for assessing the sustainability of wood-based energy projects by combining spatial analysis, semi-structured interviews, and archival data analysis. By integrating quantitative and qualitative methods, this project offers ways to understand how social and environmental dynamics from the past shape technological development in the future. A propensity analysis of biomass energy plants in Michigan, USA was performed using US Census data grouped by social, economic, and environmental categories. This quantitative analysis helped to characterize community and landscape types in which woody biomass plants were developed in Michigan in the late-... [more]

This Editorial provides an overview of the 13 papers published in the Special Issue Environmental and Energetic Valorization of RenewableResources belonging to Section B: Sustainable Energy of the Energies journal, five being review papers and the remaining being scientific articles.

According to United Nations data, half of the world’s population lives in cities and forecasts indicate that by the middle of the 21st century, this percentage will have increased to 65%. The increase in the urban population favors the creation of a network of interactions that entails a series of material and energy flows. These cause environmental impacts that affect the quality of life of citizens and the environment as a whole. According to data from the International Energy Agency, cities occupy 3% of the planet’s surface and are responsible for 67% of global energy consumption. The effects caused by this consumption, as well as its impact on the depletion of resources, make it necessary to carry out an exhaustive study of renewable energies and new energy saving systems. This Special Issue aims to present new advances and developments in renewable energy and energy saving systems that allow cities to evolve in a sustainable way.

The worldwide transformation from fossil fuels to sustainable energy sources will increase the demand for biomass. However, the ash content of many available biomass sources exceeds the limits of national standards. In this study, short-rotation coppice willow biomass was hydrothermally treated at 150, 170 and 185 °C. The higher heating value increased by 2.6% from x¯ = 19,279 J × g−1 to x¯ = 19,793 J × g−1 at 185 °C treatment temperature. The mean ash content was reduced by 53% from x¯ = 1.97% to x¯ = 0.93% at 170 °C treatment temperature, which was below the limit for category TW1b of the European pellet standard for thermally treated biomass. The nitrogen, sulfur and cadmium concentrations were reduced below the limits for category TW1b of the European biomass pellet standard (N: from 0.52% to 0.34%, limit at 0.5%; S: from 0.051% to 0.024%, limit at 0.04%; Cd: from 0.83 mg × kg−1 to 0.37 mg × kg−1, limit at 0.5 mg × kg−1). The highest reduction rates were sampled for phosphor (80−84... [more]

Elevated emissions of hydrogen chloride (HCl) from the combustion of biomass in utility boilers are a major issue because they can cause corrosion problems and deposit molten alkali chloride salts on boilers’ water tubes, resulting in further corrosion. Pyrolysis is a good pre-treatment for solving this problem. This work conducted pyrolysis and co-pyrolysis of pulverized corn straw and lignite coal in a horizontal muffle furnace, with compositions typical of power plant combustion effluents (5% O2, 15% CO2, 80% N2) at different temperatures. Cl compounds were monitored in fuel, flue gas, and solid production of pyrolysis. The co-pyrolysis significantly affected Cl release from fuel. Cl release from corn straw into fuel gas was reduced during biomass co-pyrolysis with lignite. Co-pyrolysis had little influence on the release of organic Cl and KCl. Furthermore, at moderate-temperature pyrolysis, O2 promoted HCl release, when compared with pyrolysis under a N2 atmosphere.

Straw is treated as agricultural waste, and it is available in almost every region of Poland. A total of 30 million tons of straw is produced per year, of which there is a surplus of approximately 13.5 million tons of undeveloped straw. For energy purposes, straw from cereals or rapeseed is most often used. When analyzing scientific publications, it was noticed that, in Poland, large amounts of oat straw are produced, and there is no alternative use for it. Hence, we conducted research to determine the energy value of oat straw. Raw material was obtained from an individual farm from 2018 to 2020. Selected energy parameters for straw burned alone (100%) or co-fired with coal were analyzed in the following weight proportions: 70/30, 80/20, and 90/10 coal/oat straw. It was shown that changing weather conditions, in particular years, had a modifying effect on some of the energy parameters of straw. The calorific value of straw was lower than that of coal, but its impact on environmental po... [more]

Energy demand is steadily growing as society becomes more industrialised. Renewable energy sources (RES) have long been used for various applications by thermal energy systems in the European Union (EU). Biomass and solar energy represent important RES in the development of energy transition in some regions such as coal-mining areas of Europe. Bioenergy is a key renewable energy storage mechanism for solar energy which, when combined, can tackle many of the barriers to the use of solar energy. Against this background, this study evaluates the potential implementation of both biomass and solar energy for energy production in coal-mining areas in Spain as a direct alternative to coal. The shown methodology relies on a comprehensive analysis of existing resources and their conversion to thermal energy from a multi-parametric point of view. The obtained results show that the solar−biomass combination can be used for thermal energy systems as a challenging option. The theoretical total hybr... [more]

Currently, fossil fuels are still the primary fuel source and reducing agent in the steel industries. The utilization of fossil fuels is strongly associated with CO2 emissions. Therefore, an alternative solution for green steel production is highly recommended, with the use of biomass as a source of fuel and a reducing agent. Biomass’s growth consumes carbon dioxide from the atmosphere, which may be stored for variable amounts of time (carbon dioxide removal, or CDR). The pellets used in this study were prepared from a mixture of low-grade iron ore and palm kernel shells (PKS). The reducing reactivity of the pellets was investigated by combining thermogravimetric analysis (TGA) and laboratory experiments. In the TGA, the heating changes stably from room temperature to 950 °C with 5−15 °C/min heating rate. The laboratory experiments’ temperature and heating rate variations were 600−900 °C and 10−20 °C/min, respectively. Additionally, the reduction mechanism was observed based on the X-r... [more]

This study aimed to assess biomass production costs from perennial energy crops, such as Miscanthus giganteus, Sida hermaphrodita, and coppiced willow, in selected agricultural holdings. This assessment was based on applied technologies for harvesting the biomass of the energy crops mentioned above. The scope of the study included research on ten farms located in Małopolska and establishing the possibility of biomass production from selected energy crops in these entities. Biomass production costs have been estimated using the computer application “Bioalkylation”. The result of the research was the answer to the question: what can be the cost range of biomass production from perennial energy crops for the crops Miscanthus giganteus, Sida hermaphrodita, and coppiced willow as the most popular plants? The study shows that production costs depend primarily on the harvesting technology used and the machinery used in the farm. The harvest with rotary mowers, small presses, and windrows was... [more]

Biomass-based pellet is an important source of renewable energy. In this study, to obtain the high-quality fuel pellet via the densification of pruned branches of fruit trees, we investigated the optimization of blending ratios for different raw materials using branches from jujube (Ziziphus jujuba Mill.), which is a widely distributed waste biomass resource in China. Through the characterization of raw materials and pellets, the effects of different raw materials on the storage, transportation, and combustion performances of the pellets can be understood. The cost evaluation analysis showed that the two optimized, co-densified pellets had great cost advantages compared with the pure jujube branch pellets. This indicates the potential industrial value of optimized pellets. The results of this study can help to improve the application value of orchard residues and generate an additional profit for fruit plantations, simultaneously avoiding the environmental damage caused by its open com... [more]

In this paper, the authors present an overview of biomass gasification modeling approaches with the aim of evaluating their effectiveness as a modeling tool for the design and optimization of polygeneration plants based on biomass gasification. In fact, the necessity to build plant operating maps for efficiency optimization requires a significant number of simulations, and non-stoichiometry equilibrium models may allow fast computations thanks to their relative simplicity. The main objective consists of the assessment of thermodynamic equilibrium models performance as a function of biomass type and composition to better understand in which conditions of practical interest such models can be applied with acceptable reliability. To this aim, the authors developed two equilibrium models using both a commercial software (referred as Aspen model) and a simulation tool implemented in a non-commercial script (referred as analytical model). To assess their advantages and disadvantages, the two... [more]

Catalytic hydropyrolysis via the introduction of external hydrogen into catalytic pyrolysis process using hydrodeoxygenation catalysts is one of the major approaches of bio-oil upgrading. In this study, hydrodeoxygenation of acetone over Mo/HZSM-5 and HZSM-5 were investigated with focus on the influence of hydrogen pressure and catalyst deactivation. It is found that doped MoO3 could prolong the catalyst activity due to the suppression of coke formation. The influence of hydrogen pressure on catalytic HDO of acetone was further studied. Hydrogen pressure of 30 bar effectively prolonged catalyst activity while decreased the coke deposition over catalyst. The coke formation over the HZSM-5 and Mo/HZSM-5 under 30 bar hydrogen pressure decreased 66% and 83%, respectively, compared to that under atmospheric hydrogen pressure. Compared to the test with the HZSM-5, 35% higher yield of aliphatics and 60% lower coke were obtained from the Mo/HZSM-5 under 30 bar hydrogen pressure. Characterizati... [more]

Willows are one of the plants which can be used to produce biomass for energy purposes. Biomass production is classified as a renewable energy source. Increasing the share of renewable sources is one of the priority actions for European Union countries due to the need to reduce greenhouse gas emissions. To achieve the best possible growth of the willow and increase its biomass for fuel, it is crucial to provide optimal water conditions for its growth. The aim of the study was to determine the water requirements of willows under the conditions of the western Polish climate and to verify whether this area is potentially favourable for willow cultivation. The novelty of this paper lies in its multi-year climatic analysis in the context of willow water needs for the area of three voivodships: Lubusz, Lower Silesian, and West Pomeranian. This is one of the few willow water-needs analyses for this region which considers the potential for widespread willow cultivation and biomass production i... [more]

This study examines the kinetics of pyrolysis and oxidation of hydrochars through thermal analysis. Thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) techniques were used to investigate the decomposition profiles and develop two distributed activation energy models (DAEM) of hydrochars derived from the hydrothermal carbonization of grape seeds produced at different temperatures (180, 220, and 250 °C). Data were collected at 1, 3, and 10 °C/min between 30 and 700 °C. TGA data highlighted a decomposition profile similar to that of the raw biomass for hydrochars obtained at 180 and 220 °C (with a clear distinction between oil, cellulosic, hemicellulosic, and lignin-like compounds), while presenting a more stable profile for the 250 °C hydrochar. DSC showed a certain exothermic behavior during pyrolysis of hydrochars, an aspect also investigated through thermodynamic simulations in Aspen Plus. Regarding the DAEM, according to a Gaussian model, the severity of the... [more]

In the biomass densification process, a lot of energy is needed to prevent its spring-back and to overcome the friction between the material and the channel surface of the die so as to build up pressure. However, moisture, particle size, temperature, and type of material all influence the densification pressure, pellet quality, and the density. The research was aimed to find out how the densification pressure and density were affected by the die temperature based on an open-end densification method using a self-developed pellet extruder. When the piston fixed in the front of the extruder moved in a reciprocating way, the raw material was pressed into the opening die, which had a heater wrapped up. Crushed corn straw with a particle size under 4 mm and with a given moisture content of 10% was used to be compacted by the extruder. The results showed that with the increase of the die temperature, the value of densification pressure decreased; however, the quality of pellets was not good a... [more]

As a major technical route to utilize biomass energy, biomass combustion power generation (BCPG) has been shown to be of environmental and economic significance. According to the operating experience, the installed capacity has a decisive impact on the operation and economic return of BCPG projects. In China, an installed capacity of either 30 MW or 12 MW is often chosen for constructing a BCPG project. To explore which one is more suitable for China, this paper uses actual operating data to compare the operation performance and techno-economics of two representative BCPG projects with an installed capacity of 30 MW and 12 MW. The results show that the operation situation and electricity production of the 30 MW project are better than those of the 12 MW project. The 30 MW project has a lower biomass consumption than the 12 MW project to produce per unit of electricity. The Internal Rate of Return (IRR) of the 30 MW project is greater than the industry benchmark in China and is almost t... [more]

The integration of solid oxide fuel cells (SOFCs) with biomass gasification reactors raises the possibility of solid particle contamination of the gaseous fuel entering the cell. Technical specifications from SOFC manufacturers, among other sources, claim that SOFCs do not tolerate the presence of solid particles in fuel. However, there is very limited literature on the experimental investigation of feeding SOFCs with particulate matter aerosols. In this study, a standard 5 × 5 cm anode-supported SOFC was fueled by two types of aerosols, namely, (1) inert powder of grain sizes and concentration equivalent to gasifier fly ash and (2) a real downdraft gasifier fly ash, both suspended in a gaseous fuel mixture. For reference, cells were also investigated with a dust-free fuel gas of the same composition. A straightforward negative influence of the inert powder aerosol could not be confirmed in experiments with a duration of 6 days. That said, the introduction of carbonaceous fly ash aeros... [more]

A new, innovative approach in the search for an effective and cheap carbon dioxide sorbent, in line with the circular economy and sustainable development principles, directs the attention of researchers to various types of waste ashes generated as a result of biomass combustion. In addition to the use of environmentally safe materials that have been experimentally identified, and that, in some way, have adjustable sorption capacity, it is also possible to rationally develop a widely applicable, simple, and inexpensive technology based on large amounts of this type of post-industrial waste, which is also an equally important issue for the natural environment (reducing the need for ash storage and accumulation). Even the lower sorption capacity can be successfully compensated for by their common availability and very low cost. Thus, the CO2 adsorption capability of the ashes from the combustion of straw biomass was experimentally investigated with the use of a high-pressure adsorption st... [more]

In the presented paper, two types of animal-origin biomass, cow dung and chicken litter, are characterized in terms of combustion-related problems and ash properties. It was found that these parameters strongly depend on the farming style. Whether it is cow dung or chicken litter, free-range raw materials are characterized by higher ash contents than industrial farming ones. Free-range samples contain chlorine at lower levels, while industrial farming samples are chlorine rich. Free-range samples are characterized by the predominant content of silica in the ash: 75.60% in cow dung and 57.11% in chicken litter, while industrial farming samples contain more calcium. Samples were classified by 11 “slagging indices” based on the ash and fuel composition to evaluate their tendencies for slagging, fouling, ash deposition and bed agglomeration. Furthermore, an assessment was made against the current EU law regulations, whether the ashes can be component materials for fertilizers. The phosphor... [more]