Pollutants resulting from domestic combustion would have harmful effects on public health, causing disturbances in the atmosphere chemistry and the climate. In this work, the emissions from the combustion of pellets made of 80% poplar (organically fertilized) and 20% cereal straw (Triticum aestivum) have been analysed. Poplar wood from I-214 and AF-8 clones was obtained from fertilized and non-fertilized plots (CONTROL). Dairy wastewater treatment (MUD) and dehydrated sewage sludge (BIOSOLIDS) were the fertilizers employed. BIOSOLIDS-I214 pellets had lower quality standards, so its combustion was omitted. A flue gas sample was sampled together with the particles emitted. The I-214 MUD sample had the highest emitted CO value (1505 mg/MJ). Regarding HCl emission factors, there was a homogeneity in the results linked with the Cl content present in the raw material. A higher particle emission was associated with pellets with higher ash content. Particles were composed mainly for elemental... [more]

In recent years, there has been a dynamic development of alternative energy sources and the use of plant biomass for the production of bioenergy is one of the possibilities of improving the energy mix. Therefore, it is worth reaching for new, less popular and perspective solutions, which certainly include sorghum, a drought-resistant plant with a high yielding potential and various applications in the bioeconomy. The aim of the research was to determine the amount of bioethanol obtained from the biomass of three sorghum varieties (Rona 1, Santos, Sucrosorgo 506) grown in the main and second crop for three years in the temperate climate typical of Central and Eastern Europe. The yields of sorghum cultivars grown as main and second crops, chemical components of sorghum biomass (cellulose, hemicellulose, lignin) and the amount of ethanol per a ton of dry matter of straw and ethanol yield per hectare were evaluated. The experiments and research carried out show, especially in the second ye... [more]

A crucial factor that determines the development of production and consumption markets for biofuels is the choice of raw materials that can ensure the highest possible production efficiency, the lowest cost and the smallest emission of harmful substances to the atmosphere during all production stages. Considerations underlying the development of biofuel production have been discussed as well as the theoretical mechanisms linking the generation of biofuels to the level of production and the variability of prices of agricultural raw products. The aim of this study has been to identify the scale at which energy raw materials originating from agriculture are used for liquid biofuels production and to explore their impact on food security. The study used public statistical data (OECD-FAO and IndexMundi). The time span of the analysis was from 2005 to 2018. First-generation biofuels based on food raw materials (cereal grains, root crops, sugarcane and vegetable oils) are becoming increasingl... [more]

The numerical simulation of biomass combustion requires a model that must contain, on one hand, sub-models for biomass conversion to primary products, which involves calculations for heat transfer, biomass decomposition rate, product fractions, chemical composition, and material properties, and on the other hand, sub-models for volatile products transport inside and outside of the biomass particle, their combustion, and the char reduction/oxidation. Creating such a complete mathematical model is particularly challenging; therefore, the present study proposes a versatile alternative—an originally formulated generalized 3D biomass decomposition model designed to be efficiently integrated with existing CFD technology. The biomass decomposition model provides the chemical composition and mixture fractions of volatile products and char at the cell level, while the heat transfer, species transport, and chemical reaction calculations are to be handled by the CFD software. The combustion model... [more]

Microalgae are a renewable source of unconventional biomass with potential application in the production of various biofuels. The production of carbon-neutral fuels is necessary for protecting the environment. This work determined the possibility of producing biomass of microalgae belonging to Monoraphidium genus using saline wastewater resulting from proecological salmon farming in the recirculating aquaculture system. The tests were carried out in tubular photobioreactors using LED light. As a part of the analyses, the growth and productivity of microalgal biomass, cell density in culture, and lipid concentration and ash content in biomass were determined. In addition, the concentration of selected phosphorus and nitrogen forms present in wastewater corresponding to the degree of their use by microalgae as a nutrient substrate was determined. The biomass concentration estimated in the tests was 3.79 g·L−1, while the maximum biomass productivity was 0.46 g·L−1·d−1. The cells’ optical... [more]

This work evaluates date palm waste as a cheap and available biomass feedstock in UAE for the production of biofuels. The thermochemical and biochemical routes including pyrolysis, gasification, and fermentation were investigated. Simulations were done to produce biofuels from biomass via Aspen Plus v.10. The simulation results showed that for a tonne of biomass feed, gasification produced 56 kg of hydrogen and fermentation yielded 233 kg of ethanol. Process energy requirements, however, proved to offset the bioethanol product value. For 1 tonne of biomass feed, the net duty for pyrolysis was 37 kJ, for gasification was 725 kJ, and for fermentation was 7481.5 kJ. Furthermore, for 1 tonne of date palm waste feed, pyrolysis generated a returned USD $768, gasification generated USD 166, but fermentation required an expenditure of USD 763, rendering it unfeasible. The fermentation economic analysis showed that reducing the system’s net duty to 6500 kJ/tonne biomass and converting 30% hemic... [more]

Metabolic products such as lipids and proteins produced in cyanobacteria represent an excellent source of biomass and do not compete with agricultural land use unlike soybean and corn. Given their potential use as novel materials for biodiesel production, we aimed to explore the effect of cultivation period and nitrogen concentration on the growth rate and lipid content of Fremyella diplosiphon, a model cyanobacterium. In this study, F. diplosiphon grown in BG11/HEPES medium supplemented with 1.5 g L−1 sodium nitrate (NaNO3) for 7, 10, 15, and 20 days were compared to the untreated control in media amended with 0.25, 0.5, and 1.0 g L−1 NaNO3. Cultures were inoculated in liquid media and grown under continuous fluorescent light in an orbital incubator shaker, and extracted lipids subjected to gravimetric analysis and gas chromatography-mass spectroscopy to determine the best culture conditions for lipid production. Our results demonstrated that a reduction in nitrogen concentration had... [more]

Renewable energy sources, such as solar, wind, biomass, and geothermal energy, are being more and more adopted in small and micro-scale distributed generation systems. In this context, different hybrid configurations and layouts that may adopt, lead to different energy and economic performance of energy generation systems. In micro-scale applications, biomass and solar energy sources are more frequently investigated in literature compared to other combinations as biomass and wind energy. The analysis of the performance of a novel small-scale trigeneration system is presented in this paper. The system includes biomass boiler, water steam turbine, absorption chiller, and wind turbine, and it is linked to the electric grid by means of a bidirectional connection, allowing to the store virtually the electrical energy produced in excess, and use when needed. For the proposed system, a zootechnical farm and a residential building are considered as case study, including different scenarios for... [more]

Ultrasonic irradiation is known to enhance various physicochemical processes. In this work, the effect of ultrasound on the dissolution of sugarcane bagasse was studied, with the specific aims of quantifying the effect at low solids loading and mild reaction conditions, and determining whether the enhancement of dissolution by ultrasound is independent of temperature. The effects of agitation speed, reaction time, and sonication were examined on the dissolution of the biomass substrate at varying reaction temperatures during the pretreatment process. Sugarcane bagasse was mixed with a 0.3 M solution of sulfuric acid in a reaction vessel to undergo pretreatment. A kinetic model was applied to the mass dissolution of the biomass, as sonicated runs showed higher mass losses at each reaction time, compared to the non-sonicated runs. The ultrasonic enhancement in mass dissolution was seen to increase for an increase in the reaction time. It was observed that the induction period for the dis... [more]

The biomass combustion process is inevitably accompanied by the emission of pollutant gasses. This paper gives a comprehensive analysis of the external variables and combustion products of the biomass plant. The analyzed data were collected from 18 MWt boiler in combined heat and power plant Sremska Mitrovica over a period of four months. The correlations between the recorded data were determined using a unique methodology, which is based on association rule mining. The results of the study can be further used for the reduction of the harmful combustion products, as well as for the optimization of the operation process.

The paper concerns the analysis of harmful emissions during the combustion process in households. The subject of the analysis is a low emission heating device with an output of 50 kW for burning biomass of forest origin (low-quality hardwoods or softwoods). The proposed boiler is automatically fed from the connected container by means of a screw conveyor. In this way, the optimum amount of fuel is supplied for maximum heat output (adjustment of the ratio of primary air to fuel). The proposed biomass heating system is equipped with a primary and secondary air supply system and exhaust gas sensors. This ensures optimal regulation of the air mixture and efficient and clean combustion. Proper control of the combustion process, control of the air supply by means of a lambda sensor and power control of the system ensure a low-emission combustion process. The system precisely adjusts to the heat demand. This results in highly efficient heating technology with low operating costs. In the prese... [more]

The shortage of resources and increasing climate changes have brought the need for sustainable and renewable resources to people’s attention. Biomass is an earth-abundant material and has great potential as a feedstock for alternative fuels and chemicals. For the effective utilization of biomass, this biopolymer has to be depolymerized and transformed into key building blocks and/or the targeted products, and biological or chemical catalysts are commonly used for the rapid and energy-efficient reactions. This Special Issue introduces recent advances in the catalytic conversion of biomass into biofuels and value-added products.

The impact of N2 and CO2 atmospheres on the interaction between Eucalyptus pilularis biomass and a ternary molten carbonate eutectic (Li2CO3: Na2CO3: K2CO3) has been investigated at 600 °C and 900 °C. For lower temperature conversion under CO2, prevention of volatile release in the eutectic treated biomass is slightly higher than under N2 injection; however, similar bubble-shaped morphology of the remnant char is observed under both carrier gases. By increasing the temperature to 900 °C under CO2, the reverse Boudouard reaction begins to consume carbon fuel, while molten carbonate gasification also accelerates the reaction to a lower temperature set point (shifted from ~735 °C to ~640 °C). The mass loss of carbonate under CO2 and N2 at 900 °C is 0 (negligible) and 18 wt.%, respectively. In the absence of carbon particles, the decomposition of carbonate to M2O (l) and CO2 (g), as well as molten salt vaporization, are the sole potential routes of weight loss in an inert gas. Previous obs... [more]

This paper presents a 1.5D model of a fluidized bed chemical looping combustion (CLC) built with the use of a comprehensive simulator of fluidized and moving bed equipment (CeSFaMB) simulator. The model is capable of calculating the effect of gas velocity in the fuel reactor on the hydrodynamics of the fluidized bed and the kinetics of the CLC process. Mass of solids in re actors, solid circulating rates, particle residence time, and the number of particle cycles in the air and fuel reactor are considered within the study. Moreover, the presented model calculates essential emissions such as CO2, SOX, NOX, and O2. The model was successfully validated on experimental tests that were carried out on the Fluidized-Bed Chemical-Looping-Combustion of Solid-Fuels unit located at the Institute of Advanced Energy Technologies, Czestochowa University of Technology, Poland. The model’s validation showed that the maximum relative errors between simulations and experiment results do not exceed 10%.... [more]

High dependency on fossil fuels, low energy efficiency, poor diversification of energy sources, and a low rate of access to electricity are challenges that need to be solved in many developing countries to make their energy systems more sustainable. Cogeneration has been identified as a key strategy for increasing energy generation capacity, reducing greenhouse gas (GHG) emissions, and improving energy efficiency in industry, one of the most energy-demanding sectors worldwide. However, more studies are necessary to define approaches for implementing cogeneration, particularly in countries with tropical climates (such as Ecuador). In Ecuador, the National Plan of Energy Efficiency includes cogeneration as one of the four routes for making energy use more sustainable in the industrial sector. The objective of this paper is two-fold: (1) to identify the potential of cogeneration in the Ecuadorian industry, and (2) to show the positive impacts of cogeneration on power generation capacity,... [more]

The global COVID-19 pandemic has had strong impacts on national and international freight, construction and tourism industry, supply chains, and has resulted in a rapid decline in the demand for traditional energy sources. In fact, research has outlined that urban areas depend on global supply chains for their day-to-day basic functions, including energy supplies, food and safe access to potable water. The disruption of global supply chains can leave many urban areas in a very vulnerable position, in which their citizens may struggle to obtain their basic supplies, as the COVID-19 crisis has recently shown. Therefore, solutions aiming to enhance local food, water and energy production systems, even in urban environments, have to be pursued. The COVID-19 crisis has also highlighted in the scientific community the problem of people’s exposure to outdoor and indoor pollution, confirmed as a key element for the increase both in the transmission and severity of the contagion, on top of invo... [more]

Solar thermochemical gasification is a promising solution for the clean production of low-emission synthetic fuels. It offers the possibility to upgrade various biomasses and waste feedstocks and further provides an efficient way to sustainably store solar energy into high-value and energy-intensive chemical fuels. In this work, a novel continuously-fed solar steam gasifier was studied using beechwood and solid recovered fuels (SRF) particles. Solar-only and hybrid solar/autothermal gasification experiments were performed at high temperatures to assess the performance of the reactor and its flexibility in converting various types of feedstocks. The hybrid operation was considered to increase the solar reactor temperature when the solar power input is not sufficient thanks to partial feedstock oxy-combustion. The hybrid solar process is thus a sustainable alternative option outperforming the conventional gasification processes for syngas production. Wood and waste particles solar conver... [more]

It has been reported that improving electrical conductivity and maintaining stable structure during discharge/charge process are challenge for Si to be used as an anode for lithium ion batteries (LIB). To address this problem, milkweed (MW) was carbonized to prepare hollow carbon microtubes (HCMT) derived from biomass as an anode template for LIB. In order to improve electrical conductivity, various materials such as chitosan (CTS), agarose, and polyvinylidene fluoride (PVDF) are used as carbon source (C1, C2, and C3) by carbonization. Carbon coated HCMT@Si composits, HCMT@Si@C1, HCMT@Si@C1@C2, and HCMT@Si@C1@C3, have been successfully synthesized. Changes in structure and crystallinity of HCMT@Si composites were characterized by using X-ray diffraction (XRD). Specific surface area for samples was calculated by using BET (Brunauer−Emmett−Teller). Also, pore size and particle size were obtained by particle and pore size analysis system. The surface morphology was evaluated using high re... [more]

Concern for climate change is one of the drivers of new, transitional energy policies oriented towards economic growth and energy security, along with reduced greenhouse gas (GHG) emissions and preservation of biodiversity. Since 2010, the Climate Policy Initiative (CPI) has been publishing annual Global Landscape of Climate Finance reports. According to these reports, US$3660 billion has been spent on global climate change projects over the period 2011−2018. Fifty-five percent of this expenditure has gone to wind and solar energy. According to world energy reports, the contribution of wind and solar to world energy consumption has increased from 0.5% to 3% over this period. Meanwhile, coal, oil, and gas continue to supply 85% of the world’s energy consumption, with hydroelectricity and nuclear providing most of the remainder. With this in mind, we consider the potential engineering challenges and environmental and socioeconomic impacts of the main energy sources (old and new). We find... [more]

This paper performs technical, economic and environmental feasibility analyses of two different solar cogeneration plants, consisting of a solar system (a parabolic trough collector field coupled with thermal energy storage), an Organic Rankine Cycle (ORC), and mechanical chillers, that should cover the electrical and cooling demands of a commercial center located in Zaragoza (Spain). System A is hybridized with an auxiliary biomass boiler that complements the solar system’s thermal production, providing a constant heat supply to the ORC, which operates at full load during the operating hours of the solar system. In contrast, system B is not hybridized with biomass, so the ORC is fully driven by the solar system, operating at partial load according to the solar resource availability. Both systems are connected to the electrical grid, allowing electricity purchases and sales when needed. The design procedure involves the sizing of the equipment as well as the modelling of the hourly beh... [more]

Co-combustion of biomass and solid fuels from wastes in existing highly efficient power plants is a low-cost solution that can be applied quickly and with low effort to mitigate climate change. Circulating fluidized bed combustion has several advantages when it comes to co-combustion, such as high fuel flexibility. The operational flexibility of circulating fluidized bed (CFB) co-combustion is investigated in a 1 MWth pilot plant. Straw pellets and refuse-derived fuel (RDF) are co-combusted with lignite at full load and part loads. This study focusses on the impact on the hydrodynamic conditions in the fluidized bed, on the heat transfer to the water/steam side of the boiler, and on the flue gas composition. The study demonstrates the flexibility of CFB combustion for three low-rank fuels that differ greatly in their properties. The co-combustion of RDF and straw does not have a negative effect on hydrodynamic stability. How the hydrodynamic conditions determine the temperature and pre... [more]

Current work presents an optical setup, its calibration and reference process and the first results from single particle emissivity measurements of pulverized biomass and coal fuel particles. In contrast to earlier attempts, the setup offers the possibility of emissivity measurements during the whole particle burn-off. A laser ignites a single particle, placed in the center of the setup. Two photomultipliers observe the emitted particle radiation in the visible range (550 nm and 700 nm) for temperature calculation, using two-color pyrometry. An InSb-detector records the emitted particle radiation between 2.4 µm and 5.5 µm, which is later used to calculate particle emissivity in this range. The conclusion of multiple particle measurements lead to decreasing particle emissivity with increasing temperature. For coal particles the emissivity decreases from 0.45 at 2300 K to 0.03 at 3400 K. Biomass char shows a similar trend with a decrease from 0.18 (2100 K) to 0.03 (2900 K).

There has been intense debate over the depletion of fossil fuel reserves in recent decades as well as the greenhouse gas emissions that are causing climate change. At the same time, new legislation in Greece, national policies, European policies, and realistic needs, need effective waste management and the protection of national resources. As a result, it seems a necessity to exploit waste treatments, while expanding the use of renewable energy sources. In this study, an attempt is made to focus our interest and research on a specific biomass waste stream, namely the waste biomass from the agricultural-livestock sector. The possibility of processing these wastes through the technology of biomass biorefinery with anaerobic digestion as its central process will be studied. The technology of anaerobic digestion is a process widely used for the treatment of agricultural residues and livestock waste as well as for the exploitation of energy crops (energy development, soil enhancement) mainl... [more]

Investigations were performed in relation to the thermal gasification of wood granulate using steam in an allothermal reactor with electric heaters. They studied the impact of the temperature inside the reactor and the steam flow rate on the percentage shares of H2, CH4, CO, and CO2 in synthesis gas and on the calorific value of syngas. The tests were conducted at temperatures inside the reactor equal to 750, 800, and 850 °C and with a steam flow rate equal to 10.0, 15.0, and 20.0 kg∙h−1. The intensity of gasified biomass was 20 kg∙h−1. A significant impact of the temperature on the percentages of all the components of synthesis gas and a significant impact of the steam flow rate on the content of hydrogen and carbon dioxide in syngas were found. The highest percentage of hydrogen obtained was 43.3%. The calorific value of the gas depended significantly on the temperature inside the reactor and the correlation between the temperature and the steam flow rate. Its maximum value was 13.3... [more]

An advanced thermal conversion system involving high-temperature gasification of biomass and municipal waste into biofuel, syngas or hydrogen-rich gas is presented in this paper. The decomposition of solid biomass and wastes by gasification is carried out experimentally with a modern and innovative regenerator and updraft continuous gasifier, among others. A ceramic high-cycle regenerator provides extra energy for the thermal conversion of biomass or any other solids waste. Highly preheated air and steam gas (heated up to 1600 °C) was used as an oxidizing or gasification agent (feed gas). Preheated feed gas also enhances the thermal decomposition of the gasification solids for fuel gas. However, the main objective of this work is to promote new and advanced technology for the thermochemical conversion of biomass for alternative energy production. Selected results from experimental and numerical studies are also presented.