Biomass is gaining increased attention as a sustainable and low-cost hard carbon (HC) precursor. However, biomass properties are often unexplored and unrelated to HC performance. Herein, we used pine, beechwood, miscanthus, and wheat straw precursors to synthesize HCs at 1000 °C, 1200 °C and 1400 °C by a two-steps pyrolysis treatment. The final physicochemical and electrochemical properties of the HC evidenced dissimilar trends, mainly influenced by the precursor’s inorganic content, and less by the thermal treatment. Pine and beechwood HCs delivered the highest reversible capacity and coulombic efficiency (CE) at 1400 °C of about 300 mAh·g−1 and 80%, respectively. This performance can be attributed to the structure derived from the high carbon purity precursors. Miscanthus and wheat straw HC performance was strongly affected by the silicon, potassium, and calcium content in the biomasses, which promoted simultaneous detrimental phenomena of intrinsic activation, formation of a silicon... [more]

Biomass has been demonstrated as a capable source of energy to fulfill the increasing demand for clean energy sources which could last a long time. Replacing fossil fuels with biomass-based ones can potentially lead to a reduction of carbon emissions, which is the main target of the EU climate strategy. Based on RED II (revised Renewable Energy Directive 2018/2001/EU) and the European Green Deal, biomass is a promising energy source for achieving carbon neutrality in the future. However, the sustainable potential of biomass resources in the forthcoming decades is still a matter of question. This review aims at estimating the availability of biomass for energy reasons in the EU, and to evaluate its potential to meet the coal power plant capacity of the main lignite-producer countries, including Germany, Poland and Greece. Plants in line with the sustainability criteria of RED II have been selected for the preliminary estimations concerning their full conversion to the biomass power conc... [more]

The objective of this study is to assess the techno-economic potential of the proposed novel energy system, which allows for negative emissions of carbon dioxide (CO2). The analyzed system comprises four main subsystems: a biomass-fired combined heat and power plant integrated with a CO2 capture and compression unit, a CO2 transport pipeline, a CO2-enhanced geothermal system, and a supercritical CO2 Brayton power cycle. For the purpose of the comprehensive techno-economic assessment, the results for the reference biomass-fired combined heat and power plant without CO2 capture are also presented. Based on the proposed framework for energy and economic assessment, the energy efficiencies, the specific primary energy consumption of CO2 avoidance, the cost of CO2 avoidance, and negative CO2 emissions are evaluated based on the results of process simulations. In addition, an overview of the relevant elements of the whole system is provided, taking into account technological progress and tec... [more]

Biomass-fueled combined heat and power systems (CHPs) can potentially offer environmental benefits compared to conventional separate production technologies. This study presents the first environmental life cycle assessment (LCA) of a novel high-efficiency bio-based power (HBP) technology, which combines biomass gasification with a 199 kW solid oxide fuel cell (SOFC) to produce heat and electricity. The aim is to identify the main sources of environmental impacts and to assess the potential environmental performance compared to benchmark technologies. The use of various biomass fuels and alternative allocation methods were scrutinized. The LCA results reveal that most of the environmental impacts of the energy supplied with the HBP technology are caused by the production of the biomass fuel. This contribution is higher for pelletized than for chipped biomass. Overall, HBP technology shows better environmental performance than heat from natural gas and electricity from the German/Europe... [more]

The coal-producing territories in the world are facing the production of renewable energy in their thermal systems. The production of biocoal has emerged as one of the most promising thermo-energetic conversion technologies, intended as an alternative fuel to coal. The aim of this research is to assess how the model of biomass to biocoal conversion in mining areas is applied for thermal systems engineering. The Central Asturian Coal Basin (CACB; Spain) is the study area. The methodology used allows for the analysis of the resource as well as the thermo-energetic conversion and the management of the bioenergy throughout the different phases in a process of analytical hierarchy. This is carried out using a multiphase mathematical algorithm based on the availability of resources, the thermo-energetic conversion, and the energy management in the area of study. Based on the working conditions, this research highlights the potential of forest biomass as a raw material for biocoal production... [more]

Biomass is a solid fuel that can be used instead of coal to address the issue of greenhouse gases. Currently, biomass is used directly in combustion or via co-combustion in coal-fired power plants. However, its use is limited due to calorific value and ash problems. In this study, wet torrefaction (WT) was carried out at various temperatures (160 °C, 180 °C, and 200 °C) and the properties of the product were evaluated. In comparison to dry torrefaction, the ash contained in biomass was extracted by an acidic solution (i.e., acetic acid) from the overreaction of the biomass. From examining the ash content of the treated WT, it was confirmed that K2O of basic ash was mainly extracted. In particular, in the case of K2O, since the main cause of combustion problems are issues such as fouling and slagging, the removed WT can be stably combusted in the boiler. Finally, the combustion and emission behaviors were evaluated by TGA-DTG and TGA-FTIR. As the fuel-N was decreased in the WT proess, t... [more]

The importance of efficient utilization of biomass as renewable energy in terms of global warming and resource shortages are well known and documented. Biomass gasification is a promising power technology especially for decentralized energy systems. Decisive progress has been made in the gasification technologies development during the last decade. This paper deals with the control and optimization problems for an isolated microgrid combining the renewable energy sources (solar energy and biomass gasification) with a diesel power plant. The control problem of an isolated microgrid is formulated as a Markov decision process and we studied how reinforcement learning can be employed to address this problem to minimize the total system cost. The most economic microgrid configuration was found, and it uses biomass gasification units with an internal combustion engine operating both in single-fuel mode (producer gas) and in dual-fuel mode (diesel fuel and producer gas).

One of the ways used to reduce the emission of carbon dioxide and other harmful substances is the implementation of biomass co-firing processes with coals. Such processes have been implemented for many years throughout many countries of the world, and have included using existing high-power coal boilers. Despite numerous experiments, there are still no analyses in the literature allowing for their generalization. The purpose of this paper is to determine the generalized energy and ecological characteristics of dust steam boilers co-firing hard coal with biomass. The energy characteristics determined in the paper are the dependence of the gross energy efficiency of boilers on such decision parameters as their efficiency and the share of biomass chemical energy in fuel. However, the ecological characteristics are the dependence of emission streams: CO, NO, SO2, and dust on the same decision parameters. From a mathematical point of view, the characteristics are approximation functions bet... [more]

Bioenergy plays a major role as a renewable energy source in the European Union. Solid biomass is derived mainly as wood from forests and wood processing plants. Willow plantations set up on marginal lands can be a supplementary source of wood for energy generation. This study aimed to determine the energy value of yield and the thermophysical properties and elemental composition of the biomass of 7-year rotation willow harvested on marginal soil. Three varieties and three clones were cultivated in the Eko-Salix system on three marginal soils in northern Poland: riparian, alluvial soil, classified as heavy complete humic alluvial soil (Obory); organic, peat−muck soil formed from peat (Kocibórz); very heavy mineral clay soil (Leginy). Favourable conditions for obtaining high energy value biomass were at Kocibórz and Obory with a high groundwater level. The energy value of biomass at Leginy was lower than at Kocibórz and Obory (by 33% and 26%, respectively). The Ekotur variety had the si... [more]

This paper reports the performance of a spark ignition engine using gasoline blended with an upgraded bio-oil rich in aromatics and ethanol. This upgraded bio-oil was obtained using a two-step catalytic process. The first step comprised an in-situ catalytic pyrolysis process with CaO in order to obtain a more stable deoxygenated organic fraction, while the second consisted of a catalytic cracking of the vapours released using ZSM-5 zeolites to obtain an aromatics-rich fraction. To facilitate the mixture between bio-oil and gasoline, ethanol was added. The behaviour of a stationary spark ignition engine G12TFH (9600 W) was described in terms of fuel consumption and electrical efficiency. In addition, gaseous emissions and polycyclic aromatic hydrocarbon (PAH) concentrations were determined. Trial tests suggested that it is possible to work with a blend of gasoline, ethanol and bio-oil (90/8/2 vol%, herein named G90E8B2) showing similar fuel consumption than pure gasoline (G100) at the s... [more]

Solid recovered fuel (SRF) residue, which is leftovers from the SRF manufacturing process, usually is discarded in landfill because of its low heating value and high ash and moisture content. However, it could be used as a fuel after mechanical and biological treatment. Gasification experiments were conducted on treated SRF residue (TSRFR) to assess the viability of syngas production. Efforts were also made to improve the gasification performance by adding low-cost natural minerals such as dolomite and lime as bed material, and by blending with biomass waste. In the case of additive mineral tests, dolomite showed better performance compared to lime, and in the case of biomass blends, a 25 wt% pine sawdust blend with TSRFR showed the best performance. Finally, as an appropriate condition, a combined experiment was conducted at an equivalence ratio (ER) of 0.2 using a 25 wt% pine sawdust blend with TSRFR as a feedstock and dolomite as the bed material. The highest dry gas yield (1.81 Nm3... [more]

Short rotation woody crops (SRWC) like shrub willow are highly productive biomass resources of interest for energy and fuel applications. Hot water extraction (HWE) as an upgrading tool to enable the use of willow biomass in pellet applications has been proposed, and is of increasing interest. This study treats willow and mixes of willow and conventional mixed hardwood feedstock with HWE in a tumbling laboratory reactor to elucidate the effects of time, temperature, feedstock mixes, and other process considerations (water:biomass ratio, presteaming, counter-current processing) on mass removals and other extraction outcomes (e.g., sugar, acetate, and furan yields). Results demonstrated alignment of extraction outcomes with P-factor from 155 °C to 175 °C, with a good compromise of removed mass and co-product potential in the range from 575−800 P-factor. The preferred condition was chosen as 575 P-factor. HWE of mixes of willow and hardwood feedstocks showed a linear response of extractio... [more]

Two bimetallic Fe-Cu and Fe-Ca oxygen carriers were studied for chemical looping gasification (CLG) of biomass. The SEM results indicated that there was no obvious agglomeration on the bimetallic Fe-Cu oxygen carrier supported on Al2O3 and Fe-Ca oxygen carrier after five redox cycles while agglomeration occurred on CuO supported on Al2O3 due to the low melting point of CuO. The XRD results indicated the presence of copper-ferrite and calcium-ferrite phases in the bimetallic materials. The two bimetallic oxygen carriers can be re-oxidized with air to form a crystalline that is similar to the fresh materials. The Fe-Ca oxide became active at 360 °C which was lower than 380 °C for the Fe-Cu oxygen carrier. The high thermal stability and redox reactivity of bimetallic Fe-Cu and Fe-Ca oxygen carriers make the bimetallic oxygen carriers more suitable for recycling during CLG. The method for preparing Fe-Cu oxygen carriers had no significant impact on biomass conversion efficiency but had sig... [more]

Microalgae can be a future source of biomass with a wide range of applications, including its use to solve current environmental issues. One of the main variables for microalgal cultivation is the light supply: (i) its intensity that often does not present a uniform spatial distribution inside the culture; (ii) photoperiod; and (iii) spectrum. Therefore, this study aims to evaluate the growth of the microalgae Chlorella vulgaris in a tubular photobioreactor with compound parabolic collectors (CPCs) under outdoor conditions. The effect of ultraviolet and visible radiation on biomass productivity and nutrients (nitrogen and phosphorus) uptake was assessed. The maximum biomass productivity was (5 ± 1) × 10−3 g·L−1·h−1, and the specific growth rates ranged from (1.1 ± 0.3) × 10−2 to (2.0 ± 0.6) × 10−2 h−1. Regarding nutrient uptake, initial removal rates of (0.9 ± 0.4) mg N·L−1·h−1 for nitrogen and (0.17 ± 0.04) mg P·L−1·h−1 for phosphorus were reached. These values increased with visible... [more]

Organic Rankine Cycle (ORC) turbogenerators are a well-established technology to recover from medium to ultra-low grade heat and generate electricity, or heat and work as cogenerative units. High firmness, good reliability and acceptable efficiency guarantee to ORCs a large range of applications: from waste heat recovery of industrial processes to the enhancement of heat generated by renewable resources like biomass, solar or geothermal. ORC unit coupled with biomass boiler is one of the most adopted arrangements. However, despite biomass renewability, it is mandatory to evaluate the environmental impact of systems composed by boilers and ORCs taking into account the entire life cycle. To this purpose, the authors perform a life cycle assessment of a commercially available 150 kW cogenerative ORC unit coupled with a biomass boiler to assess the global environmental performance. The system is modelled in SimaPro using different approaches. Results show that the most impacting processes... [more]

For biomass compaction, it is important to determine all aspects of the process that will affect the quality of pellets and briquettes. The low bulk density of biomass leads to many problems in transportation and storage, necessitating the use of a compaction process to ensure a solid density of at least 1000 kg·m−3 and bulk density of at least 600 kg·m−3. These parameters should be achieved at a relatively low compaction pressure that can be achieved through the proper preparation of the raw material. As the compaction process includes a drying stage, the aim of this work is to determine the influence of the drying temperature of pine biomass in the range of 60−140 °C on the compaction process. To determine whether this effect is compensated by the moisture, compaction was carried out on the material in a dry state and on the materials with moisture contents of 5% and 10% and for compacting pressures in the 130.8−457.8 MPa range. It was shown that drying temperature affects the specif... [more]

The agricultural sector can play an important role in the transformation of the energy economy in Poland. Special attention in this paper has been paid to the development of the agricultural biogas market in Poland. The considerations mainly concern organizational and economic aspects. Agricultural biogas plant represents the circular cycle of matter and energy. It enables the establishment of low-carbon, resource-efficient links between the agriculture and energy sectors. This is an important element of the circular economy, where waste from agricultural production and the agri-food industry, coming from renewable resources, is transformed into goods with a higher added value. The social and economic needs of the present generation and future generations are considered. The paper presented the characteristics of the Polish market, i.e., the number of entities, the number and location of plants, as well as the production volumes. Analyses were performed in the area of raw materials use... [more]

In this research, the idea of multicomponent, one-vessel cleaning of syngas through simultaneous dedusting and adsorption is described. Data presented were obtained with the use of a pilot-scale 60 kWth fixed-bed GazEla reactor, coupled with a dry gas cleaning unit where mineral sorbents are injected into raw syngas at 500−650 °C, before dedusting at ceramic filters. The research primarily presents results of the application of four calcined sorbents, i.e., chalk (CaO), dolomite (MgO−CaO), halloysite (AlO−MgO−FeO), and kaolinite (AlO−MgO) for high-temperature (HT) adsorption of impurities contained in syngas from gasification of biomass. An emphasis on data regarding the stability of the filtration process is provided since the addition of coating and co-filtering materials is often necessary for keeping the filtration of syngas stable, in industrial applications.

Agriculture can provide biomass for bioproducts, biofuels and as energy feedstock with a low environmental impact, derived from carbohydrate, protein and oil annual crops, as well from lignocellulosic crops. This paper presents the thermophysical and chemical features of camelina and crambe straw depending on nitrogen fertilisation rate with a view to their further use in a circular bioeconomy. A two-factorial field experiment was set up in 2016, with camelina and crambe as the first factor and the N fertilizer rate (0, 60 and 120 kg·ha−1·N) as the second factor. Ash content in crambe straw (6.97% d.m.) was significantly higher than in camelina straw (4.79% d.m.). The higher heating value was higher for the camelina (18.50 MJ·kg−1·d.m.) than for the crambe straw (17.94 MJ·kg−1·d.m.). Sulphur content was also significantly higher in camelina than in crambe straw. An increase in nitrogen content with increasing fertilisation rate was visible in the straw of both species (from 1.19 to 1.3... [more]

Sugarcane harvesting requires a significant amount of energy and time to manage dry leaves after the harvesting process. Therefore, the objective of this study was to minimize the energy requirement to process the cane and dry leaves’ harvesting (CDLH) for sugarcane while, at the same time, maximizing sugar production from cane and energy from dry leaves in Sri Lanka. The CDLH was conceptualized using a novel approach to optimize sugarcane harvesting to maximize biomass supply for energy production while reducing supply chain sugar-loss. The CDLH was investigated for manual harvesting capacity, energy consumption, sugar loss, and biomass energy potential. It was observed that CDLH consumed higher energy compared to the present practices of harvesting. However, the energy used for fieldwork was reduced because of the shifting of cane chopping and cleaning from the field to the factory. Low bulk density of the harvested cane of the CDLH system had a higher energy requirement in transport... [more]

Bioenergy accounts for 61.7% of all renewable energy sources, with solid fuels accounting for 43% of this amount. Poplar plantations can deliver woody biomass for energy purposes. A field experiment with poplar was located in the north-east of Poland on good quality soil formed from medium loam. The study aimed to determine the yield, the energy value of the yield and the thermophysical properties and elemental composition of the biomass of four poplar clones harvested in two consecutive 4-year harvest rotations. The highest biomass energy value was determined in the UWM 2 clone in the second harvest rotation (231 GJ ha−1·year−1). This value was 27−47% lower for the other clones. The biomass quality showed that poplar wood contained high levels of moisture and low levels of ash, sulphur, nitrogen and chlorine. This indicates that poplar can be grown in the north-east of Poland and that it gives a yield with a high energy value and beneficial biomass properties from the energy generatio... [more]

In this review, we focus on the literature that described the various unit operations in a process design flowsheet of biorefineries. We begin by establishing the accepted definitions of a biorefinery, go on to describe how to categorize biorefineries, and finally review the literature on biorefinery process designs by listing the unit operation in each process design. Distinguishing biorefineries based on feedstock, the types of processing units, and the products emanating from the biorefinery are discussed.

Rural areas of developing countries often have poor energy infrastructure and so rely on a very local supply. A local energy supply in rural Uganda frequently has problems such as limited accessibility, unreliability, a high expense, harmful to health and deforestation. By carbonizing waste biomass streams, available to those in rural areas of developing countries through a solar resource, it would be possible to create stable, reliable fuels with more consistent calorific values. An energy demand calculator is reported to assess the different energy demands of various thermochemical processes that can be used to create biofuel. The energy demand calculator then relates the energy required to the area of solar collector required for an integrated system. Pyrolysis was shown to require the least amount of energy to process 1 kg of biomass when compared to steam treatment and hydrothermal carbonization (HTC). This was due to the large amount of water required for steam treatment and HTC.... [more]

The paper presents the results of a study on chemical composition of ashes from three types of waste biomass in terms of fertilizer usefulness. Waste from the process of corn grain drying, including corn cobs, corn grains and corn husk and their mixtures in the ratio 4:1 (v/v) were examined. The study proved that corn grain was the material with the highest concentration of macroelements among those studied (P—21,452 ppm, K—25,970 ppm, S—5911 ppm) and the mixture of corn cobs with corn grains (Ca—81,521 ppm). When microelements were considered, the highest concentration was recorded for corn cobs (Cu—207 ppm, Mn—844 ppm, Zn—857 ppm) and corn husk (Fe—15,100 ppm). The analysis of toxic elements in the ashes of the biomass studied showed their highest concentration in corn husk ash (Ni—494 ppm, Cr—301 ppm, Pb—42.7 ppm, As—4.62 ppm). The analysis showed that regardless of the type of biomass studied, all ashes were strongly enriched (in relation to the average soil content) with phosphoru... [more]

In this study, lignin with fine structures and facile enzymatic saccharifying residue were successively dissociated based on the lignin-first biomass deconstruction strategy. In the lignin-first process, aldehyde-protected lignin fractions were firstly isolated by acid-catalyzed dioxane extraction in the presence of formaldehyde (FA) and acetaldehyde (AA) and then analyzed by advanced nuclear magnetic resonance (NMR) spectroscopy and gel permeation chromatography (GPC). The optimized hydrogenolysis of the extracted lignin (LFA and LAA) resulted in a high yield (42.57% and 33.00%) of lignin monomers with high product selectivity (mainly 2,6-dimethoxy-4-propylphenol) (39.93% and 46.61%). Moreover, the cellulose-rich residues were saccharified into fermentable glucose for bioethanol production. The glucose yield of the substrate (RAA) reached to 75.12%, which was significantly higher than that (15.4%) of the substrate (RFA). In short, the lignin-first biomass deconstruction by adding AA i... [more]