It has been demonstrated that energy systems driven by conventional energy sources like fossil fuels are one of the main causes of climate change. Organic Rankine cycles can help to reduce that impact, as they can be operated by using the industrial waste heat of renewable energies. The present study presents a comprehensive bibliographic review of organic Rankine cycles. The study not only actualizes previous reviews that mainly focused on basic cycles operating on subcritical or supercritical conditions, but also includes the analysis of novel cycles such as two-stage and hybrid cycles and the used fluids. Recuperative and regenerative cycles are more efficient than reheated and basic single-stage cycles. The use of two-stage cycles makes it possible to achieve higher thermal efficiencies and net power outputs of up to 20% and 44%, respectively, compared with those obtained with single-stage cycles. Theoretical studies show that hybrid systems, including Brayton and organic Rankine c... [more]

This article presents a simulation study which focuses on the thermodynamic analysis of a solar-driven trigeneration system for heating, cooling, and electricity production. The system uses parabolic trough collectors operating with Therminol VP-1 for feeding an organic Rankine cycle operating with toluene and an absorption heat pump operating with a LiBr−H2O working pair. The collecting area is selected at 100 m2 and the storage tank at 4 m3. The system is studied parametrically in order to examine the impact of various parameters on the system energy efficiency, system exergy efficiency, electricity production, heating production, and cooling production in the simple payback period of the investment. The examined parameters are the following: solar beam irradiation level, solar beam irradiation angle, superheating degree in the turbine inlet, pressure level in the turbine inlet, heat source temperature level, generator temperature level, and the heat input in the generator. For the n... [more]

Efficient and flexible operation is essential for competitiveness in the energy market. However, the CO2 emissions of conventional power plants have become an increasingly significant environmental dilemma. In this study, the optimization of a steam power process of an IGCC was carried out, which improved the overall performance of the plant. CCPP with a subcritical HRSG was modelled using EBSILON Professional. The numerical results of the model were validated by measurements for three different load cases (100, 80, and 60%). The results are in agreement with the measured data, with deviations of less than 5% for each case. Based on the model validation, the model was modified for the use of syngas as feed and the integration of heat into an IGCC process. The integration was optimized with respect to the performance of the CCPP by varying the extraction points, adjusting the steam parameters of the extractions and modifying the steam cycle. For the 100% load case, a steam turbine power... [more]

This article aims to present an evaluation of the environmental performance of a combustion polygeneration plant fed with lignocellulosic material from cardoon (Cynara cardunculus L.) through the technique of Life Cycle Assessment (LCA). The system boundaries encompassed macro-phases of crop production, transportation, and polygeneration processes that were able to produce 100 kW of electricity, a residual thermal energy recovery system and district heating and cooling with 270 kW of heating, and a 140 kW of cooling. The LCA was performed using Cumulative Energy Demand and ReCiPe Life Cycle Impact Assessment methods through midpoint and endpoint indicators. From 2000 h/year, 165.92 GJ of electricity and 667.23 GJ of primary energy were consumed, and 32.82 tCO2eq were emitted. The rates of Greenhouse Gas (GHG) and energy demand per MJ produced were 0.08 MJSE/MJPD, 0.30 MJPE/MJPD, and 0.01 kgCO2eq/MJPD. According to the ReCiPe method, the impact categories with the highest impact loads w... [more]

Bio-hydrogen from residual biomass may involve energy-intensive pre-treatments for drying and size management, as in the case of wet agro-industrial residues. This work assesses the performance of an alternative process layout for bio-hydrogen production from citrus peel gasification, with the aim of cogenerating heat and power along with hydrogen, using minimal external energy sources. The process consists of an air-steam fluidized bed reactor, a hydrogen separation unit, a hydrogen compression unit, and a combined heat and power unit fed by the off-gas of the separation unit. Process simulations were carried out to perform sensitivity analyses to understand the variation in bio-hydrogen production’s thermodynamic and environmental performance when the steam to biomass ratios (S/B) vary from 0 to 1.25 at 850 °C. In addition, energy and exergy efficiencies and the integrated renewability (IR) of bio-hydrogen production are evaluated. As main results, the analysis showed that the highes... [more]

The availability of freshwater and energy is a serious issue in remote and islanded areas, especially at a small scale, where there may not be the possibility to access the grid and/or water distribution systems. In this context, polygeneration systems operating on the basis of local, renewable energy sources can be an answer to the users’ demand for electricity, heating, cooling, and domestic hot water. The scope of the proposed paper was to investigate, numerically, the energy and economic feasibility of a novel hybrid polygeneration system powered by biomass, solar, and wind energy for a micro-district of households. The proposed system consists of a biomass-fueled steam cycle, wind turbine, photovoltaic field coupled with thermal and electrical energy storage, adsorption chiller, and a reverse osmosis water desalination unit. The system is also assisted by an LPG generator set running as backup. The system provides space heating and cooling, electrical energy, and fresh and domesti... [more]

Besides satisfying the energy demands of buildings, distributed generation can contribute toward environmental conservation. However, determining the best configuration and operational strategy for these systems is a complex task due to the available technology options and the dynamic operating conditions of buildings and their surroundings. This work addressed the synthesis and optimization of an energy system for a commercial building (hotel). Electricity, hot water, and cooling demands were established for a hotel located in Northeast Brazil. The optimization problem was based on mixed-integer linear programming and included conventional equipment, solar energy resource (photovoltaic and thermal technologies), and biomass. The objective function of the optimization was to minimize annual economic costs, which involved considering the capital and operation costs. A reference system was established for comparison purposes, where energy demands were met conventionally (without cogenera... [more]

The energy sector is nowadays facing new challenges, mainly in the form of a massive shifting towards renewable energy sources as an alternative to fossil fuels and a diffusion of the distributed generation paradigm, which involves the application of small-scale energy generation systems. In this scenario, systems adopting one or more renewable energy sources and capable of producing several forms of energy along with some useful substances, such as fresh water and hydrogen, are a particularly interesting solution. A hybrid polygeneration system based on renewable energy sources can overcome operation problems regarding energy systems where only one energy source is used (solar, wind, biomass) and allows one to use an all-in-one integrated systems in order to match the different loads of a utility. From the point of view of scientific literature, medium- and large-scale systems are the most investigated; nevertheless, more and more attention has also started to be given to small-scale... [more]

Solid oxide fuel cells are an emerging energy conversion technology suitable for high-temperature power generation with proper auxiliary heat. Combining SOFCs and polygeneration has produced practical applications for modern energy system designs. Even though many researchers have reviewed these systems’ technologies, opportunities and challenges, reviews regarding the optimal strategy for designing and operating the systems are limited. Polygeneration is more complicated than any other energy generation type due to its ability to generate many types of energy from various prime movers. Moreover, integration with other applications, such as vehicle charging and fueling stations, increases the complication in making the system optimally serve the loads. This study elaborates on the energy planning and guidelines for designing a polygeneration system, especially for residential applications. The review of polygeneration technologies also aligns with the current research trend of developi... [more]

Small-scale decentralized polygeneration systems have several energetic, economic and environmental benefits. However, using multiple energy sources and providing multiple energy services can lead to complicated studies which require advanced optimization techniques for determining optimal solutions. Furthermore, several parameters can influence the design and performance of a polygeneration system. In this study, the effects of heat load, renewable generation and storage units on the optimal design and performance of a polygeneration system for a hypothetical hospital located in northern Italy are investigated. The polygeneration system shows higher performance compared to the reference system, which is based on the separate generation of heat and power. It reduces fuel consumption by 14⁻32%, CO₂ emissions by 10⁻29% and annualized total cost by 7⁻19%, for various studied scenarios. The avoided fuel and electricity purchase of the polygeneration system has a positive impact on the econ... [more]

This presentation concerns the promising new area of flexible polygeneration, a chemical process design concept in which a chemical plant is able to change its product outputs throughout its lifetime in response to changing market conditions, business objectives, or other external factors. In this talk we present a new flexible polygeneration process system that can switch between dimethyl ether (DME) or methanol production, depending on need. Classic flexible polygeneration systems typically utilize separate process trains for each product, in which whole process trains are turned on or off (or up or down) depending on the current product. However, our proposed process combines the two process trains into one, in which most of the process equipment is always used during either mode of production, but with different operating conditions. In this work, we show how this significantly reduces capital expenditure, reduces the plant footprint, and ultimately is more economical than a tradit... [more]

Nowadays conventional district heating and cooling (DHC) systems face the challenge of reducing fossil fuel dependency while maintaining profitability. To address these issues, this study examines the possibility of retrofitting DHC systems with refuse-derived fuel (RDF) gasifiers and gas upgrading equipment. A novel system is proposed based on the modification of an existing DHC system. Thermodynamic and economic models were established to allow for a parametric analysis of key parameters. The study revealed that such an upgrade is both feasible and economically viable. In the basic scenario, the retrofitted DHC system can simultaneously produce 60.3 GWh/year of heat, 65.1 GWh/year of cold, 33.2 GWh/year of electricity and 789.5 tons/year of synthetic natural gas. A significant part of the heat load can be generated from the waste heat of the upgrading equipment. The investment in retrofitting the polygeneration DHC system presents a payback period of 3 years.

This Special Issue aims at collecting the recent studies dealing with polygeneration systems, with a special focus on the possible integration of different technologies into a single system, able to convert one or multiple energy sources into energy services (electricity, heat and cooling) and other useful products (e.g., desalinized water, hydrogen, glycerin, ammonia, etc.). Renewable sources (solar, wind, hydro, biomass and geothermal), as well as fossil fuels, feeding advanced energy systems such as fuel cells and cogeneration systems, are considered. Special attention is paid to control strategies and to the management of the systems in general. Studies including thermoeconomic analyses and system optimizations are presented.

In this study, a new Biomass-Gas-Nuclear heat-To-Liquid fuel (BGNTL) process is presented which uses high-temperature nuclear heat as the heat source for steam methane reforming (SMR). This process co-produces liquid fuels (Fischer-Tropsch liquids, methanol and DME) and power. The BGNTL process was simulated using a combination of different software packages including gPROMS, MATLAB, ProMax, and Aspen Plus. This included the use of a rigorous multi-scale model for the nuclear-heat-powered SMR reactor which was developed in a prior work in gPROMS. Energy efficiency and cradle-to-grave life cycle inventory and life-cycle impact analyses of greenhouse gas (GHG) emissions were accomplished to analyze the environmental impacts of the BGNTL system. Plant performance was compared with a base case Biomass-Gas-To-Liquid (BGTL) process at the same size. In both processes, a carbon capture and storage (CCS) option is considered. It has been found that both processes result in negative total life... [more]

New polygeneration processes for the co-production of liquid fuels (Fischer-Tropsch liquids, methanol, and dimethyl ether) and electricity are presented. The processes use a combination of biomass, natural gas, and nuclear energy as primary energy feeds. Chemical process models were created and used to simulate candidate versions of the process, using combinations of models ranging from complex multi- scale models to standard process flowsheet models. The simulation results are presented for an Ontario, Canada case study to obtain key metrics such as efficiency and product conversions. Sample Aspen Plus files are provided in the supplementary material to be used by others.

Two process designs for the separation section of a flexible dimethyl ether and methanol polygeneration plant are presented, as well as an optimization method which can determine the optimal design under market uncertainty quickly and to global optimality without loss of model fidelity. The polygeneration plant produces a product mixture that is either mostly dimethyl ether or mostly methanol depending on market conditions by using a classic two-stage dimethyl ether production catalytic reaction route in which the second stage is bypassed when the market demand is such that methanol production is more favorable than dimethyl ether. The downstream distillation sequence is designed to purify the products to desired specifications despite the wide variability in feed condition that corresponds to the upstream reaction system operating either in DME-rich or methanol-rich mode. Because the optimal design depends on uncertain market conditions (realized as the percentage of the time in which... [more]