Ion exchange resin is used to remove potentially corrosive impurities from coolant in the first circuit of a nuclear power plant. After one operational cycle, the used and unused resin in the mixed bed is discarded as solid waste. The aim of this work is to create a mathematical model to predict the operational cycle time of the mixed bed resin for reducing unused resin discharge. A partial differential equation (PDE) was set up with the conservation of matter. A finite difference method was used to solve the PDE. Matlab was the programming and calculating tool used in this work. The data from solution were obtained at different time and space nodes. The model was then verified experimentally using different ions on exchange columns. Concentrations of K+, Mn2+, and Cl- were calculated to verify the validation of the model by comparing it with experimental data. The calculated values showed good consistency with the experimental value.

High electricity demand, as well as emissions generated from this activity impact directly to global warming. Mexico is paying attention to this world difficulty and it is convinced that sustainable economic growth is possible. For this reason, it has made actions to face this problem like as launching constitutional reforms in the power sector. This paper presents an energy model to optimize the grid of power plants in the Mexican electricity sector (MES). The energy model considers indicators and parameters from Mexican Energy Reforms. Electricity demand is defined as a function of two population models and three electricity consumption per capita. Prospectives are presented as a function of total annual cost of electricity generation, an optimal number of power plants—fossil and clean—as well as CO2eq emissions. By mean of the energy model, optimized grid scenarios are identified to meet the governmental goals (energy and environment) to 2050. In addition, this model could be used a... [more]

This work develops a methodology based on real chemical plant data collected from a Nitrogen-Phosphorus-Potassium fertilizer (NPK) cooling rotary drum. By blending thermodynamic variables given by global energy and mass balances with computational fluid dynamics-discrete element method (CFD-DEM) modeling and simulation, the methodology provides an initial approximation to the understanding of heat transfer inside industry rotary coolers. The NPK cooling process was modeled in CFD software Simcenter STAR − CCM + 13.06.011 using a Eulerian−Lagrangian scheme through a coupled CFD-DEM method using one-way coupling. The average temperature of the NPK particles was obtained as well as the average mass flow of the particles dropping as the drum was rotating. The analysis was performed for two-particle diameters (8 and 20 mm) during 17.5 s. The average heat transfer coefficient between the fluid and the NPK particles during the simulated time was obtained. A thermodynamic analysis was carried... [more]

Tabular Q-learning (QL) can be easily implemented into a controller to realize self-learning energy management control of a plug-in hybrid electric bus (PHEB). However, the “curse of dimensionality” problem is difficult to avoid, as the design space is huge. This paper proposes a QL-PMP algorithm (QL and Pontryagin minimum principle (PMP)) to address the problem. The main novelty is that the difference between the feedback SOC (state of charge) and the reference SOC is exclusively designed as state, and then a limited state space with 50 rows and 25 columns is proposed. The off-line training process shows that the limited state space is reasonable and adequate for the self-learning; the Hardware-in-Loop (HIL) simulation results show that the QL-PMP strategy can be implemented into a controller to realize real-time control, and can on average improve the fuel economy by 20.42%, compared to the charge depleting−charge sustaining (CDCS) strategy.

The throttling characteristics of the diaphragm valve are numerically studied in this paper. Firstly, the diaphragm deformation performance is analyzed by a finite element method, while the upper boundary morphology of the internal flow field under different valve openings was obtained. Then the two-dimensional simulation of the weir diaphragm valve flow field is carried out in order to explore the optimal design of flow path profile. The study shows that the throttling characteristics can be improved by flatting the ridge side wall, widening the top of the ridge and gently flatting the internal protruding of the flow path. In addition, using the local grid encryption techniques based on velocity gradient adaptive and y+ adaptive can improve the accuracy of simulation results. Finally, a cavitation two-phase flow simulation is carried out. The results show that cavitation may occur below 50% opening of diaphragm valve in ultra-pure water system, which becomes more intense with the incr... [more]

This paper presents the process design and assessment of a sugarcane-based ethanol production system that combines the usage of both mass and heat integration (pinch analysis) strategies to enhance the process efficiency and renewability performance. Three configurations were analyzed: (i) Base case: traditional ethanol production (1G); (ii) mass-integrated (1G2G); and (iii) mass and heat-integrated system (1G2G-HI). The overall assessment of these systems was based on complementary approaches such as mass and mass−heat integration, energy and exergy analysis, exergy-based greenhouse gas (GHG) emissions, and renewability exergy criteria. The performances of the three cases were assessed through five key performance indicators (KIPs) divided into two groups: one is related to process performance, namely, energy efficiency, exergy efficiency, and average unitary exergy cost (AUEC), and the other one is associated to environmental performance i.e., exergy-based CO2-equation emissions and... [more]

With the high degree of wind power penetration integrated into multi-area AC/DC interconnected power grids, the frequency regulation capacity of automatic generation control (AGC) units is not sufficient in the wind power-penetrated area, making it difficult to effectively suppress the frequency stability caused by the fluctuation of wind power. Therefore, a coordinated control strategy for AGC units across areas based on bi-level model predictive control is proposed in this paper to achieve resource sharing. The control scheme uses economic model predictive control to realize steady power optimal allocation of the AGC units across areas in the upper layer and distributed model predictive control to realize dynamic frequency optimization control of the multi-area AGC units in the lower layer. Taking a three-area AC/DC interconnected power grid with a wind farm as an example, the simulation results show that, compared with model predictive control using tie-line frequency bias control (... [more]

There is presently an urgent demand for efficient and/or renewable energy technologies to correct global warming. However, these energy technologies are limited mainly by political and economic constraints of high costs and the lack of subsidy. Carbon-pricing strategies, such as carbon-emission taxes and carbon-emission trading schemes, may reduce this gap between sustainable and unsustainable energy technologies. Therefore, this paper seeks to analyze both of these carbon-pricing instruments in the Mexican energy sector to promote upgrading biogas investment and to substitute liquified petroleum gas consumption using an optimization approach. Furthermore, we propose a multi-objective optimization approach to encourage investment in the biogas supply chain supported by an effective use of carbon-pricing schemes. A case study of the central western region of Mexico was made to analyze the performance of the proposed methodologies. The results show that carbon-emission taxes and carbon-e... [more]

Renewable liquid biofuels for transportation have recently attracted enormous global attention due to their potential to provide a sustainable alternative to fossil fuels. In recent years, the attention has shifted from first-generation bioethanol to the production of higher molecular weight alcohols, such as biobutanol, from cellulosic feedstocks. The economic feasibility of such processes depends on several parameters such as the cost of raw materials, the fermentation performance and the energy demand for the pretreatment of biomass and downstream processing. In this work, two conceptual process scenarios for isobutanol production, one with and one without integrated product removal from the fermentor by vacuum stripping, were developed and evaluated using SuperPro Designer®. In agreement with previous publications, it was concluded that the fermentation titer is a crucial parameter for the economic competitiveness of the process as it is closely related to the energy requirements f... [more]

Since 1991, from the beginning of the carbon nanotube era, this has been a focus point for investigation due to its synthetic and simple nature. Unique properties like good stiffness, high surface area, and resilience of carbon nanotubes (CNTs) have been investigated in many engineering applications such as hydrogen storage, composite material, energy storage, electrochemical super-capacitors, transistors, sensors, and field-emitting devices. Keeping in view these applications, we investigate single and multi-walled CNTs nanofluid flow having water as the base fluid between parallel and horizontal rotating plates with microstructure and inertial properties. The thermal radiation effect is considered for variable phenomenon of heat generation/consumption. The principal equations are first symmetrically transformed to a system of nonlinear coupled ordinary differential equations (ODEs), and then, Homotopy Analysis Technique (HAM) and numerical method are employed for solving these couple... [more]

We considered the steady flow of Buongiorno’s model over a permeable exponentially stretching channel. The mathematical model was constructed with the assumptions on curved channels. After applying the boundary layer approximation on the Navier−Stocks equation, we produced nonlinear partial differential equations. These equations were converted into a system of non-dimensional ordinary differential equations through an appropriate similarity transformation. The dimensionless forms of the coupled ordinary differential equations were elucidated numerically through boundary value problem fourth order method. This method gains fast convergence as compared to other method such as the shooting method and the Numerical Solution of Differential Equations Mathematica method. The influence of the governing parameters which are involved in ordinary differential equations are highlighted through graphs while R e s 1 / 2 C f , R e s 1 / 2 N u s , and R e s − 1 /... [more]

Hydraulic fracturing is a necessary method to develop shale gas reservoirs effectively and economically. However, the flow behavior in multi-porosity fractured reservoirs is difficult to characterize by conventional methods. In this paper, combined with apparent porosity/permeability model of organic matter, inorganic matter and induced fractures, considering the water film in unstimulated reservoir volume (USRV) region water and bulk water in effectively stimulated reservoir volume (ESRV) region, a multi-media water-gas two-phase flow model was established. The finite difference is used to solve the model and the water-gas two-phase flow behavior of multi-fractured horizontal wells is obtained. Mass transfer between different-scale media, the effects of pore pressure on reservoirs and fluid properties at different production stages were considered in this model. The influence of the dynamic reservoir physical parameters on flow behavior and gas production in multi-fractured horizontal... [more]

Remanufacturing could effectively solve resource shortage and environment crisis and achieve sustainable development of the economy. The original equipment manufacturer (OEM) could not only focus on its core business (i.e., producing new products), but also get profit from remanufacturing through the intellectual property rights. Based on the authorized remanufacturing, the game model between a manufacturer and a remanufacturer was constructed. Based on the game model, the impact of authorized remanufacturing on sustainable remanufacturing is analysed, and the coordination mechanism between manufacturer and remanufacturer is given. The main results are as follows: the OEM could increase its profit and change its unfavourable market competition status by authorizing remanufacturing; a franchise contract could make the sustainability supply chain optimized; when the ratio of the environment effect is greater than a certain threshold, centralized decision-making could not only increase th... [more]

Irregularity indices are usually used for quantitative characterization of the topological structures of non-regular graphs. In numerous problems and applications, especially in the fields of chemistry and material engineering, it is useful to be aware of the irregularity of a molecular structure. Furthermore, the evaluation of the irregularity of graphs is valuable not only for quantitative structure-property relationship (QSPR) and quantitative structure-activity relationship (QSAR) studies but also for various physical and chemical properties, including entropy, enthalpy of vaporization, melting and boiling points, resistance, and toxicity. In this paper, we will restrict our attention to the computation and comparison of the irregularity measures of different classes of dendrimers. The four irregularity indices which we are going to investigate are σ irregularity index, the irregularity index by Albertson, the variance of vertex degrees, and the total irregularity index.

The marine controlled-source electromagnetic (CSEM) technique is an application of electromagnetic (EM) waves to image the electrical resistivity of the subsurface underneath the seabed. The modeling of marine CSEM is a crucial and time-consuming task due to the complexity of its mathematical equations. Hence, high computational cost is incurred to solve the linear systems, especially for high-dimensional models. Addressing these problems, we propose Gaussian process (GP) calibrated with computer experiment outputs to estimate multi-frequency marine CSEM profiles at various hydrocarbon depths. This methodology utilizes prior information to provide beneficial EM profiles with uncertainty quantification in terms of variance (95% confidence interval). In this paper, prior marine CSEM information was generated through Computer Simulation Technology (CST) software at various observed hydrocarbon depths (250−2750 m with an increment of 250 m each) and different transmission frequencies (0.12... [more]

This study investigated if biochar, a low-cost carbon-rich material, can be modified with reactive materials for decolorization of dyeing wastewater. Two types of rice husk biochars were produced by using different processes of gasification and pyrolysis in limited air condition. The biochars were first magnetized and then modified with nano-scale zero-valent iron (nZVI) to achieve the final products of magnetic-nZVI biochars. Batch experiments were conducted to investigate the efficiency of the modified biochars for reducing color of the reactive dyes yellow (RY145), red (RR195), and blue (RB19) from dyeing solutions. Results showed that color removal efficiency of the modified biochars was significantly enhanced, achieving the values of 100% for RY145 and RR195 and ≥65% for RB19, while the effectiveness of the original biochar was significantly lower. In addition, with increasing dose of the modified biochars, the color removal efficiency increased accordingly. In contrast, when the... [more]

Renewable energy resources have received increasing attention due to environmental concerns. Biomass, one of the most important renewable energy resources, is abundant in agricultural-based countries. Typically, the biomass supply chain is large due to the huge amount of relevant data required for building the model. As a result, using a standard optimization package to determine the solution for the biomass supply chain model might not be practical. In this study, the focus is on developing and applying advanced methodologies that can be used to determine a solution for the biomass supply chain model efficiently. The decisions related to plant selection, and distribution of biomass from suppliers to plants require optimization. The methodologies considered in this research are based on stochastic programming, parameter search, and simulation-based optimization. Computational results and managerial insights based on case studies from different regions of Vietnam are provided. The resul... [more]

Microwave-assisted pyrolysis is a promising thermochemical technique to convert waste polymers and biomass into raw chemicals and fuels. However, this process involves several issues related to the interactions between materials and microwaves. Consequently, the control of temperature during microwave-assisted pyrolysis is a hard task both for measurement and uniformity during the overall pyrolytic run. In this review, we introduce some of the main theoretical aspects of the microwaves−materials interactions alongside the issues related to microwave pyrolytic processability of materials.

This paper proposes a novel meta-heuristic optimization algorithm called the fine-tuning meta-heuristic algorithm (FTMA) for solving global optimization problems. In this algorithm, the solutions are fine-tuned using the fundamental steps in meta-heuristic optimization, namely, exploration, exploitation, and randomization, in such a way that if one step improves the solution, then it is unnecessary to execute the remaining steps. The performance of the proposed FTMA has been compared with that of five other optimization algorithms over ten benchmark test functions. Nine of them are well-known and already exist in the literature, while the tenth one is proposed by the authors and introduced in this article. One test trial was shown to check the performance of each algorithm, and the other test for 30 trials to measure the statistical results of the performance of the proposed algorithm against the others. Results confirm that the proposed FTMA global optimization algorithm has a competi... [more]

Many widely-used polymers are made via free-radical polymerization. Mathematical models of polymerization reactors have many applications such as reactor design, operation, and intensification. The method of moments has been utilized extensively for many decades to derive rate equations needed to predict polymer bulk properties. In this article, for a comprehensive list consisting of more than 40 different reactions that are most likely to occur in high-temperature free-radical homopolymerization, moment rate equations are derived methodically. Three types of radicals—secondary radicals, tertiary radicals formed through backbiting reactions, and tertiary radicals produced by intermolecular chain transfer to polymer reactions—are accounted for. The former tertiary radicals generate short-chain branches, while the latter ones produce long-chain branches. In addition, two types of dead polymer chains, saturated and unsaturated, are considered. Using a step-by-step approach based on the me... [more]

An intensified three-step reaction-separation process for the production of bio-jet diesel from tryglycerides and petro-diesel mixtures is proposed. The intensified reaction-separation process considers three sequentially connected sections: (1) a triglyceride hydrolysis section with a catalytic heterogeneous reactor, which is used to convert the triglycerides of the vegetable oils into the resultant fatty acids. The separation of the pure fatty acid from glycerol and water is performed by a three-phase flash drum and two conventional distillation columns; (2) a co-hydrotreating section with a reactive distillation column used to perform simultaneously the deep hydrodesulphurisation (HDS) of petro-diesel and the hydrodeoxigenation (HDO), decarbonylation and decarboxylation of the fatty acids; and (3) an isomerization-cracking section with a hydrogenation catalytic reactor coupled with a two-phase flash drum is used to produce bio-jet diesel with the suitable fuel features required by t... [more]

Nitrogen is an inert gas available in the air and is widely used in industry and food storage technology. Commonly, it is separated by air refrigerant liquefaction and fractional distillation techniques based on different boiling temperatures of components in the mixed air. Currently, selective adsorption techniques by molecular sieve materials are studied and applied to separate gases based on their molecular size. In this paper, we simulate and investigate the effect parameters in a single fixed-bed model of a nitrogen gas generator using carbon molecular sieves, following pressure swing adsorption. This study aims to identify the effect of changing parameters so as to select the optimal working conditions of a single fixed-bed model, used as a basis for equipment optimization. This equipment was designed, manufactured, and installed at the Institute of Technology, General Department of Defense Industry, Vietnam to investigate, simulate, and optimize the industrial scale-up.

Bioleaching is an environment-friendly and low-investment process for the extraction of metals from flotation concentrate. Surfactants such as collectors and frothers are widely used in the flotation process. These chemical reagents may have inhibitory effects on the activity of microorganisms through a bioleaching process; however, there is no report indicating influences of reagents on the activity of microorganisms in the mixed culture which is mostly used in the industry. In this investigation, influences of typical flotation frothers (methyl isobutyl carbinol and pine oil) in different concentrations (0.01, 0.10, and 1.00 g/L) were examined on activates of bacteria in the mesophilic mixed culture (Acidithiobacillus ferrooxidans, Leptospirillum ferrooxidans, and Acidithiobacillus thiooxidans). For comparison purposes, experiments were repeated by pure cultures of Acidithiobacillus ferrooxidans and Leptospirillum ferrooxidans in the same conditions. Results indicated that increasing... [more]

There is a burgeoning interest in reliably characterizing the intrinsic reactivity of metallic iron materials (Fe0) or zero-valent iron materials (ZVI) used in the water treatment industry. The present work is a contribution to a science-based selection of Fe0 for water treatment. A total of eight (8) granular ZVI materials (ZVI1 to ZVI8) were tested. Fe0 dissolution in ethylenediaminetetraacetic acid (EDTA test) and 1,10-Phenanthroline (Phen test) is characterized in parallel experiments for up to 250 h (10 days). 50 mL of each solution and 0.1 g of each Fe0 material are equilibrated in quiescent batch experiments using 2 mM EDTA or Phen. Results indicated a far higher extent of iron dissolution in EDTA than in Phen under the experimental conditions. The tested materials could be grouped into three reactivity classes: (i) low (ZVI4, ZVI6, ZVI7, and ZVI8), (ii) moderate (ZVI1 and ZVI5) and (iii) high (ZVI2 and ZVI3). The order of reactivity was the same for both tests: ZVI2 ≅ ZVI3 > ZV... [more]

The main objective of any bioenvironmental controller is to create favourable bioenvironmental conditions around the living-system. In industrial incubation practice of chicken embryo, it is sometimes difficult to fill large incubators with uniform eggs, which leads to suboptimal results. The ideal incubation solution is a machine that is capable of coping with all sorts of variabilities in eggs. This can be realised in practice by creating different zones of different environmental conditions within the same machine. In the present study, a two-levels controller was designed and implemented to combine both convective and radiative heating to incubate eggs. On the higher level, three model-predictive-control (MPC) constrained controllers were developed to regulate the power applied to nine IR-radiators divided into three zones based on continuous feedback of the eggshell temperatures in each zone. On the lower level, a PID controller was used to maintain the air temperature within an e... [more]