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Records with Subject: Energy Systems
3951. LAPSE:2023.23436
Valuation of Decision Flexibility and Strategic Value in Coal Gasification Projects with the Option-To-Switch between Different Outputs
March 27, 2023 (v1)
Subject: Energy Systems
Keywords: binomial lattice, coal gasification, compound options, option-to-switch, real options analysis, strategic value
Coal gasification has been promoted as a sophisticated clean energy technology alternative to coal burning these days. Aside from the usual technical difficulties, economic issues of such projects—especially valuation challenges—are important problems that practitioners usually struggle with. This is because of the major extent of managerial flexibility linked with specific characteristics of coal gasification projects, in particular, possibilities to mothball/restart manufacturing lines, or change between different outputs. The value of such flexibilities may be well assessed by real options valuations. The aim of this paper is to show that for the coal gasification technologies the real options valuation is more suitable than traditional discounted cash flow technique. This approach was applied to calculate an integrated plant that can produce either electricity or methanol. As the valuation approach the multiplicative stochastic process was used. As a consequence, binomial lattices... [more]
3952. LAPSE:2023.23435
Evaluation of Waste Plastic Oil-Biodiesel Blends as Alternative Fuels for Diesel Engines
March 27, 2023 (v1)
Subject: Energy Systems
Keywords: biodiesel, castor oil, diesel engine, emission, waste plastic oil
This study examined the use of waste plastic oil (WPO) combined with biodiesel as an alternative fuel for diesel engines, also commonly known as compression ignition engines, and focused on comparison of the basic physical and chemical properties of fuels, engine performance, combustion characteristics, and exhaust emissions. A preliminary study was conducted to determine the suitable ratio for the fuel blends in consideration of fuel lubricity and viscosity, and these results indicated that 10% biodiesel—derived from either palm oil or castor oil—in waste plastic oil was optimal. In addition, characterization of the basic properties of these fuel blends revealed that they had higher density and specific gravity and a lower flash point than diesel fuel, while the fuel heating value, viscosity, and cetane index were similar. The fuel blends, comprised of waste plastic oil with either 10% palm oil biodiesel (WPOP10) or 10% castor oil biodiesel (WPOC10), were selected for further investig... [more]
3953. LAPSE:2023.23434
Coupled Hydraulic Fracture and Proppant Transport Simulation
March 27, 2023 (v1)
Subject: Energy Systems
Keywords: hydraulic fracturing, numerical simulation, proppant transport
This paper focuses on the study of proppant transport mechanisms in fractures during frac-packing operation. A multi-module, numerical proppant, reservoir and geomechanics simulator has been developed, which improves the current numerical modeling techniques for proppant transport. The modules are linked together and tailored to capture the processes and mechanisms that are significant in frac-pack operations. The proposed approach takes advantage of a robust and sophisticated numerical smeared fracture simulator and incorporates an in-house proppant transport module to calculate propped fracture dimensions and concentration distribution. In the development of software capability, the propped fracture geometry and proppant concentration, which are the output of the proppant module, are imported to the hydraulic fracture simulator through mobility modification. Complex issues of proppant transport in fractures that are addressed in the literature and captured by the current model are: h... [more]
3954. LAPSE:2023.23430
A Sustainable Solution for Energy Efficiency in Italian Climatic Contexts
March 27, 2023 (v1)
Subject: Energy Systems
Keywords: Energy Efficiency, hemp fiber, life-cycle cost analysis, optimum insulation thickness
In the European Union, about 40% of energy consumption and 36% of CO2 emissions come from buildings; therefore, the improvement of their energy performance is a strongly focused issue. In particular, the energy efficiency of the building envelope is a very important element to pay attention to. Many studies have been conducted on this field of research, and the study illustrated in this paper also belongs to this topic. In particular, this article presents a multidisciplinary method to find sustainable solutions for energy efficiency in Italian climatic contexts using the Life Cycle Cost Analysis approach. In detail, this paper defines the reference scenario and then deepens the methodology used to determine the economically optimal thickness of a specific insulating material—hemp fiber—applied to a specific type of wall—uninsulated cavity walls made of hollow bricks, which are very widespread in Italy. The analysis is developed in relation to three different regions—Piedmont, Abruzzo,... [more]
3955. LAPSE:2023.23427
Water Preservation and Conservation above Coal Mines Using an Innovative Approach: A Case Study
March 27, 2023 (v1)
Subject: Energy Systems
Keywords: “five maps, and two zoning plans”, influencing factors, three zones, water conductive fractured zone (WCFZ), water protection, water-conservation coal mining (WCCM)
To better protect the ecological environment during large scale underground coal mining operations in the northwest of China, the authors have proposed a water-conservation coal mining (WCCM) method. This case study demonstrated the successful application of WCCM in the Yu-Shen mining area. Firstly, by using the analytic hierarchy process (AHP), the influencing factors of WCCM were identified and the identification model with a multilevel structure was developed, to determine the weight of each influencing factor. Based on this, the five maps: overburden thickness contour, stratigraphic structure map, water-rich zoning map of aquifers, aquiclude thickness contour and coal seam thickness contour, were analyzed and determined. This formed the basis for studying WCCM in the mining area. Using the geological conditions of the Yu-Shen mining area, the features of caved zone, water conductive fractured zone (WCFZ) and protective zone were studied. The equations for calculating the height of... [more]
3956. LAPSE:2023.23426
Hyperthermophilic Treatment of Grass and Leaves to Produce Hydrogen, Methane and VFA-Rich Digestate: Preliminary Results
March 27, 2023 (v1)
Subject: Energy Systems
Keywords: grass, Hydrogen, hyperthermophilic treatment, leaves, methane
In this study, the feasibility of hydrogen and methane production from grass and leaves via hyperthermophilic anaerobic digestion was investigated. The hyperthermophilic treatment of grass at 70 °C resulted in the highest concentrations of volatile fatty acids (TVFA) and reducing sugars in the supernatant of over 21 and 6.5 g/L reported on day 3 and 4 of the experiment. In contrast, hydrolysis and acidification of leaves performed slower and with lower efficiency, as the peak concentrations of TVFA and reducing sugars were observed at the end of the process. However, the highest cumulative hydrogen and methane yields of 69.64 mLH2/gVS and 38.63 mLCH4/gVS were reported for leaves digested at 70 °C, whereas the corresponding maximum productions observed for grass were 50 mLH2/gVS and 1.98 mLCH4/gVS, respectively. A temperature increase to 80 °C hampered hydrogen and methane production and also resulted in lower yields of volatile fatty acids, reducing sugars and ammonia as compared to th... [more]
3957. LAPSE:2023.23425
Multidispatch for Microgrid including Renewable Energy and Electric Vehicles with Robust Optimization Algorithm
March 27, 2023 (v1)
Subject: Energy Systems
Keywords: electric vehicle, microgrid, photovoltaic, robust optimization, Stochastic Optimization
With the deterioration of the environment and the depletion of fossil fuel energy, renewable energy has attracted worldwide attention because of its continuous availability from nature. Despite this continuous availability, the uncertainty of intermittent power is a problem for grid dispatching. This paper reports on a study of the scheduling and optimization of microgrid systems for photovoltaic (PV) power and electric vehicles (EVs). We propose a mathematical model to address the uncertainty of PV output and EV charging behavior, and model scheduling optimization that minimizes the economic and environmental cost of a microgrid system. A semi-infinite dual optimization model is then used to deal with the uncertain variables, which can be solved with a robust optimization algorithm. A numerical case study shows that the security and stability of the solution obtained by robust optimization outperformed that of stochastic optimization.
3958. LAPSE:2023.23422
A Multi-Input-Port Bidirectional DC/DC Converter for DC Microgrid Energy Storage System Applications
March 27, 2023 (v1)
Subject: Energy Systems
Keywords: bidirectional, DC/DC converter, Energy Storage, multi-input-port
A multi-input-port bidirectional DC/DC converter is proposed in this paper for the energy storage systems in DC microgrid. The converter can connect various energy storage batteries to the DC bus at the same time. The proposed converter also has the advantages of low switch voltage stress and high voltage conversion gain. The working principle and performance characteristics of the converter were analyzed in detail, and a 200 W, two-input-port experimental prototype was built. The experimental results are consistent with the theoretical analysis.
3959. LAPSE:2023.23419
A Comparison of the Risk Quantification in Traditional and Renewable Energy Markets
March 27, 2023 (v1)
Subject: Energy Systems
Keywords: Energy, forecasting, risk and portfolio modeling, volatility modeling
The transition from traditional energy to cleaner energy sources has raised concerns from companies and investors regarding, among other things, the impact on financial downside risk. This article implements backtesting techniques to estimate and validate the value-at-risk (VaR) and expected shortfall (ES) in order to compare their performance among four renewable energy stocks and four traditional energy stocks from the WilderHill New Energy Global Innovation and the Bloomberg World Energy for the period 2005-2016. The models used to estimate VaR and ES are AR(1)-GARCH(1,1), AR(1)-EGARCH(1,1), and AR(1)-APARCH(1,1), all of them under either normal, skew-normal, Student’s t, skewed-t, Generalized Error or Skew-Generalized Error distributed innovations. Backtesting performance is tested through traditional Kupiec and Christoffersen tests for VaR, but also through recent backtesting ES techniques. The paper extends these tests to the skewed-t, skew-normal and Skew-Generalized Error distr... [more]
3960. LAPSE:2023.23418
Effect of Fins on the Internal Flow Characteristics in the Draft Tube of a Francis Turbine Model
March 27, 2023 (v1)
Subject: Energy Systems
Keywords: anti-cavity fins, draft tube, Francis turbine, internal flow characteristics, low flow rates, unsteady pressure, vortex rope
Undesirable flow phenomena in Francis turbines are caused by pressure fluctuations induced under conditions of low flow rate; the resulting vortex ropes with precession in the draft tube (DT) can degrade performance and increase the instability of turbine operations. To suppress these DT flow instabilities, flow deflectors, grooves, or other structures are often added to the DT into which air or water is injected. This preliminary study investigates the effects of anti-cavity fins on the suppression of vortex ropes in DTs without air injection. Unsteady-state Reynolds-averaged Navier−Stokes analyses were conducted using a scale-adaptive simulation shear stress transport turbulence model to observe the unsteady internal flow and pressure characteristics by applying anti-cavity fins in the DT of a Francis turbine model. A vortex rope with precession was observed in the DT under conditions of low flow rate, and the anti-cavity fins were confirmed to affect the mitigation of the vortex rop... [more]
3961. LAPSE:2023.23416
Maintenance of Passive House Standard in the Light of Long-Term Study on Energy Use in a Prefabricated Lightweight Passive House in Central Europe
March 27, 2023 (v1)
Subject: Energy Systems
Keywords: energy consumption, long-term measurements, passive architecture
This article presents the results of experimental research on energy consumption of a prefabricated lightweight passive house located in the south of Poland. The key design parameters of the building were as follows: orientation maximizing heat gains from solar radiation, high thermal insulation of partitions, heat provided by ground source heat pump, and mechanical ventilation system with the heat exchanger. The measurements were performed in normal operating conditions in an inhabited building, throughout the years 2011−2019. For the year 2012, the article also presents the detailed structure of electricity used for particular devices. The objective of the research was to verify whether, in the long term, the building fulfils the energy consumption requirements for passive buildings. The measurements showed that energy consumption for heating was 50% lower than the value required from passive buildings. However, primary energy consumption for the entire building was exceeded already... [more]
3962. LAPSE:2023.23413
Climate Change Mitigation in Households between Market Failures and Psychological Barriers
March 27, 2023 (v1)
Subject: Energy Systems
Keywords: climate change mitigation, energy consumption, households, policies and measures
Though there are areas of climate change mitigation linked to household’s energy consumption having huge greenhouse gas (GHG) emission reduction potential as energy renovation or installation of micro generation technologies using renewable energy sources, these GHG emission reduction potentials are not realized so far. The main input of the paper is to overcome this gap and to provide a systematic review of the main barriers of climate change mitigation behavior linked to energy consumption in households and to develop policies to overcome these barriers. The main policies and measures to reduce GHG emissions of energy combustion in households are promotion of renewable energy consumption and energy efficiency improvements however, these policies have been not successful in overcoming some important barriers of climate change mitigation in households. The empirical evidence of behavioral failures is deepened in this paper and the correlation between market barriers, unsuccessful clima... [more]
3963. LAPSE:2023.23409
Analysis of Yearly Effectiveness of a Diaphragm Ground Heat Exchanger Supported by an Ultraviolet Sterilamp
March 27, 2023 (v1)
Subject: Energy Systems
Keywords: biopollution, ground heat exchanger, sterilamp, UV-C
Ground heat exchangers supplement ventilation systems and provide notable power gains by heating ventilated air during winter and cooling it in summer. Additionally, they prevent recuperator exchangers from freezing. In atmospheric air, there are many types of contaminants and microorganisms that significantly affect the quality of ventilated air. The air that flows through the system of pipes of the heat exchanger may also become contaminated. In order to remove contamination from ventilated air, ultraviolet radiation may be used. This article presents a concept of using a UV-C (ultraviolet with a wavelength of 200−280 nm) lamp in the air duct in front of the air handling unit connected to the ground heat exchanger. The UV-C lamp, apart from clearing the air, may also decrease operational costs thanks to eliminating contamination that forms bacterial jelly on heat exchanger elements.
3964. LAPSE:2023.23408
Analysis of the Building Smart Readiness Indicator Calculation: A Comparative Case-Study with Two Panels of Experts
March 27, 2023 (v1)
Subject: Energy Systems
Keywords: building performance assessment, smart buildings, Smart Readiness Indicator
The last release of the Energy Performance of Buildings Directive 2018/844/EU stated that smart buildings will play a crucial role in the future energy systems. Consequently, the Directive introduced the Smart Readiness Indicator in order to provide a common framework to highlight the value of building smartness across Europe. The methodology for the calculation of the Smart Readiness Indicator is currently under development and therefore not yet officially adopted at the European Union level. In this context, the current research analyzed the second public release of the proposed methodology, discussing the feasibility of its implementation and the obtained results through a practical application. Specifically, the methodology was applied to a nearly zero-energy office building located in Italy, and the evaluation was carried out in parallel by two different expert groups composed by researchers and technical building systems specialists. With the aim of analyzing the impact of subjec... [more]
3965. LAPSE:2023.23404
Recent Developments and Future Challenges in Designing Rechargeable Potassium-Sulfur and Potassium-Selenium Batteries
March 27, 2023 (v1)
Subject: Energy Systems
Keywords: anode, cathode, electrochemical reaction, K–S battery, K–Se battery, potassium
The use of chalcogenide elements, such as sulfur (S) and selenium (Se), as cathode materials in rechargeable lithium (Li) and sodium (Na) batteries has been extensively investigated. Similar to Li and Na systems, rechargeable potassium−sulfur (K−S) and potassium−selenium (K−Se) batteries have recently attracted substantial interest because of the abundance of K and low associated costs. However, K−S and K−Se battery technologies are in their infancy because K possesses overactive chemical properties compared to Li and Na and the electrochemical mechanisms of such batteries are not fully understood. This paper summarizes current research trends and challenges with regard to K−S and K−Se batteries and reviews the associated fundamental science, key technological developments, and scientific challenges to evaluate the potential use of these batteries and finally determine effective pathways for their practical development.
3966. LAPSE:2023.23400
Traction Power Substation Load Analysis with Various Train Operating Styles and Substation Fault Modes
March 27, 2023 (v1)
Subject: Energy Systems
Keywords: energy consumption, fault analysis, load demand, railway, traction power systems
The simulation of railway systems plays a key role in designing the traction power supply network, managing the train operation, and making changes to timetables. Various simulation technologies have been developed to study the railway traction power network and train operation independently. However, the interactions between the load performance, train operation, and fault conditions are not fully understood. This paper proposes a mathematical modeling method to simulate the railway traction power network with a consideration of a multi-train operation, driving controls, under-voltage traction, and substation fault modes. The network voltage, power load demands, and energy consumption according to the existing operation are studied. The hotspots of the power supply network are identified based on an evaluation of the train operation and power demand. The impact of traction power substation (TPSS) outage and a short circuit on the power supply network have been simulated and analyzed.... [more]
3967. LAPSE:2023.23396
Dynamic Response of Articulated Offshore Wind Turbines under Different Water Depths
March 27, 2023 (v1)
Subject: Energy Systems
Keywords: aerodynamic load, articulated offshore wind turbine, dynamic response, hydrodynamics, power generation
Focusing on the transitional depth offshore area from 50 m to 75 m, types of articulated foundations are proposed for supporting the NREL 5 MW offshore wind turbine. To investigate the dynamic behaviors under various water depths, three articulated foundations were adopted and numerical simulations were conducted in the time domain. An in-house code was chosen to simulate the dynamic response of the articulated offshore wind turbine. The aerodynamic load on rotating blades and the wind pressure load on tower are calculated based on the blade element momentum theory and the empirical formula, respectively. The hydrodynamic load is simulated by 3D potential flow theory. The motions of foundation, the aerodynamic performance of the wind turbine, and the loads on the articulated joint are documented and compared in different cases. According to the simulation, all three articulated offshore wind turbines show great dynamic performance and totally meet the requirement of power generation un... [more]
3968. LAPSE:2023.23394
An Evaluation Model of Quantitative and Qualitative Fuzzy Multi-Criteria Decision-Making Approach for Hydroelectric Plant Location Selection
March 27, 2023 (v1)
Subject: Energy Systems
Keywords: FANP, fuzzy theory, hydroelectric, MCDM, optimization techniques, Renewable and Sustainable Energy, TOPSIS
Over the past few decades, Vietnam has been one of the fastest growing economies in Asia, experiencing a GDP growth rate of more than 6% per year. The energy industry plays an important role in Vietnam’s continuous development, so access to reliable and low-cost energy sources will be an important factor for sustainable economic growth. Achieving the goal of reducing global greenhouse gas emissions, as set out in the Paris agreement on climate change, will depend heavily on the development roadmap of emerging economies, such as Vietnam. Currently, developing hydroelectric plants is Vietnam’s optimal choice in order to meet its target of renewable energy development. Hydroelectricity in Vietnam is favorable thanks to the high average annual rainfall, about 1800−2000 mm, and the dense river system, with more than 3450 systems. In addition to providing electricity, hydropower plants are also responsible for cutting and fighting floods for downstream areas in the rainy season, at the same... [more]
3969. LAPSE:2023.23393
A Harmony Search Method for the Estimation of the Optimum Number of Wind Turbines in a Wind Farm
March 27, 2023 (v1)
Subject: Energy Systems
Keywords: harmony research method, installation costs, Optimization, wind farm
During the last decades, renewable energy production has significantly increased in an effort to produce clean energy that will not affect the environment. Governments around the world are focusing on reducing greenhouse gas emissions by increasing the utilization of renewable energy sources in the power chain. Wind farms and wind generators are the main renewable technology that are used worldwide. The main scope of wind farm designers is the achievement of the maximum possible power, restraining the installation cost that is related to the use of a specific number of wind turbines for specific power production, and considering the area of land to be occupied. A harmony search method is presented in this paper for the determination of the optimum number of wind turbines in a wind farm and the total electric power produced. The method is applied for comparison purposes on data from previously published methodologies proving its accuracy and effectiveness. The harmony research method ca... [more]
3970. LAPSE:2023.23392
A Disturbance Rejection Control Strategy of a Single Converter Hybrid Electrical System Integrating Battery Degradation
March 27, 2023 (v1)
Subject: Energy Systems
Keywords: anti-windup scheme, battery degradation, disturbance rejection, hybrid power system, super twisting controller, supercapacitors
In order to improve the durability and economy of a hybrid power system composed of a battery and supercapacitors, a control strategy that can reduce fluctuations of the battery current is regarded as a significant tool to deal with this issue. This paper puts forwards a disturbance rejection control strategy for a hybrid power system taking into account the degradation of the battery. First, the degradation estimation of the battery is done by the model-driven method based on the degradation model and Cubature Kalman Filter (CKF). Considering the transient and sinusoidal disturbance from the load in such a hybrid system, it is indispensable to smooth the behavior of the battery current in order to ensure the lifespan of the battery. Moreover, the constraints for the hybrid system should be considered for safety purposes. In order to deal with these demands, a cascaded voltage control loop based on a super twisting controller and proportional integral controller with an anti-windup sch... [more]
3971. LAPSE:2023.23385
Experimental Study on Energy Efficiency of Multi-Functional BIPV Glazed Façade Structure during Heating Season
March 27, 2023 (v1)
Subject: Energy Systems
Keywords: dynamic thermal insulation, multi-parametric model, nZEB, BIPV, room ventilation
Building integrated photovoltaics (BIPV) is technology that can significantly increase the share of renewable energy in final energy supply and are one of essential technologies for the nearly zero-energy buildings (nZEB), new build and refurbished. In the article (a) an experimental semitransparent BIPV glazed façade structure with 60% of PV cell coverage is shown; (b) energy efficiency indicators were developed based on identified impact parameters using experimental data; and (c) multi-parametric models of electricity generation, preheating of air for space ventilation, and dynamic thermal insulation features that enable prediction of solar energy utilization in different climate conditions are shown. The modeled efficiency of electricity production of BIPV was in the range between 8% and 9.5% at daily solar radiation above 1500 Wh/day, while low impact of outdoor air temperature and ventilation air flow rate on PV cell cooling was noticed. Between 35% and 75% of daily solar radiati... [more]
3972. LAPSE:2023.23380
Electrochemically Reduced Titania Nanotube Synthesized from Glycerol-Based Electrolyte as Supercapacitor Electrode
March 27, 2023 (v1)
Subject: Energy Systems
Keywords: anodization, cathodic reduction, electrochemical capacitance, glycerol, morphology, titania nanotubes
In this paper the synthesis of self-organized Titania nanotubes (TNTs) by a facile potentiostatic anodization in a glycerol-based electrolyte is reported. The optimized TNTs were subsequently reduced through a cathodic reduction process to enhance its capacitive performance. FESEM and XRD were used to characterize the morphology and crystal structure of the synthesized samples. XPS analysis confirmed the reduction of Ti4+ to Ti3+ ions in the reduced Titania nanotubes (R-TNTs). The tube diameter and separation between the tubes were greatly influenced by the applied voltage. TNTs synthesized at voltage of 30 V for 60 min exhibited 86 nm and 1.1 µm of tube diameter and length, respectively and showed high specific capacitance of 0.33 mF cm−2 at current density of 0.02 mA cm−2. After reduction at 5 V for 30 s, the specific capacitance increased by about seven times (2.28 mF cm−2) at 0.5 mA cm−2 and recorded about 86% capacitance retention after 1000 continuous cycling at 0.2 mA cm−2, as c... [more]
3973. LAPSE:2023.23378
The Evaluation and Sensitivity of Decline Curve Modelling
March 27, 2023 (v1)
Subject: Energy Systems
Keywords: decline curve analysis (DCA), decline curve models, estimated ultimate recovery (EUR), shale gas reservoirs (SGR), valuation
The development of prediction tools for production performance and the lifespan of shale gas reservoirs has been a focus for petroleum engineers. Several decline curve models have been developed and compared with data from shale gas production. To accurately forecast the estimated ultimate recovery for shale gas reservoirs, consistent and accurate decline curve modelling is required. In this paper, the current decline curve models are evaluated using the goodness of fit as a measure of accuracy with field data. The evaluation found that there are advantages in using the current DCA models; however, they also have limitations associated with them that have to be addressed. Based on the accuracy assessment conducted on the different models, it appears that the Stretched Exponential Decline Model (SEDM) and Logistic Growth Model (LGM), followed by the Extended Exponential Decline Model (EEDM), the Power Law Exponential Model (PLE), the Doung’s Model, and lastly, the Arps Hyperbolic Declin... [more]
3974. LAPSE:2023.23367
Development of Magnetic Multi-Shelled Hollow Catalyst for Biodiesel Production
March 27, 2023 (v1)
Subject: Energy Systems
Keywords: biodiesel, CaO, multi-shelled hollow, RSM, transesterification, γ-Fe2O3
The magnetic CaO-based catalyst has endorsed great enhancements in biodiesel synthesis. In the present work, novel multi-shelled hollow γ-Fe2O3 stabilized CaO microspheres were synthesized using a facile one-step hydrothermal method. The strategy revealed that the well-defined multi-shelled hollow structures were formed with magnetism; the presence of γ-Fe2O3 was the key for the effective structural stabilization, and the multi-shelled hollow structures provided the sites for the active material. The synthesized catalyst was employed for the preparation of biodiesel by transesterification of palm oil and methanol. A four factors response surface methodology was adopted for optimizing the reaction conditions. Ca80Fe20 with a yield of 96.12% performed the highest catalytic activity under reaction conditions of 2 h, a methanol to oil ratio of 12:1, 65 °C and 11 wt. % of catalyst dosage. The catalyst under the optimum transesterification conditions also performed a better recyclability (>8... [more]
3975. LAPSE:2023.23364
Designing an AB2-Type Alloy (TiZr-CrMnMo) for the Hybrid Hydrogen Storage Concept
March 27, 2023 (v1)
Subject: Energy Systems
Keywords: AB2 alloy, compressed hydrogen, hybrid, hydrogen storage, kinetics, metal hydride, thermodynamics
The hybrid hydrogen storage method consists of the combination of both solid-state metal hydrides and gas hydrogen storage. This method is regarded as a promising trade-off solution between the already developed high-pressure storage reservoir, utilized in the automobile industry, and solid-state storage through the formation of metal hydrides. Therefore, it is possible to lower the hydrogen pressure and to increase the hydrogen volumetric density. In this work, we design a non-stoichiometric AB2 C14-Laves alloy composed of (Ti0.9Zr0.1)1.25Cr0.85Mn1.1Mo0.05. This alloy is synthesized by arc-melting, and the thermodynamic and kinetic behaviors are evaluated in a high-pressure Sieverts apparatus. Proper thermodynamic parameters are obtained in the range of temperature and pressure from 3 to 85 °C and from 15 to 500 bar: ΔHabs. = 22 ± 1 kJ/mol H2, ΔSabs. = 107 ± 2 J/K mol H2, and ΔHdes. = 24 ± 1 kJ/mol H2, ΔSdes. = 110 ± 3 J/K mol H2. The addition of 10 wt.% of expanded natural graphite (... [more]
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