Durability is the most pressing issue preventing the efficient commercialization of polymer electrolyte membrane fuel cell (PEMFC) stationary and transportation applications. A big barrier to overcoming the durability limitations is gaining a better understanding of failure modes for user profiles. In addition, durability test protocols for determining the lifetime of PEMFCs are important factors in the development of the technology. These methods are designed to gather enough data about the cell/stack to understand its efficiency and durability without causing it to fail. They also provide some indication of the cell/stack’s age in terms of changes in performance over time. Based on a study of the literature, the fundamental factors influencing PEMFC long-term durability and the durability test protocols for both PEMFC stationary and transportation applications were discussed and outlined in depth in this review. This brief analysis should provide engineers and researchers with a fast... [more]

The commercialization of eco-friendly hydrogen vehicles has elicited attempts to expand hydrogen refueling stations in urban areas; however, safety measures to reduce the risk of jet fires have not been established. The RISKCURVES software was used to evaluate the individual and societal risks of hydrogen refueling stations in urban areas, and the F−N (Frequency−Number of fatalities) curve was used to compare whether the safety measures satisfied international standards. From the results of the analysis, it was found that there is a risk of explosion in the expansion of hydrogen refueling stations in urban areas, and safety measures should be considered. To lower the risk of hydrogen refueling stations, this study applied the passive and active independent protection layers (IPLs) of LOPA (Layer of Protection Analysis) and confirmed that these measures significantly reduced societal risk as well as individual risk and met international standards. In particular, such measures could effe... [more]

In 2007, the US Department of Energy recommended a no-go on NaBH4 hydrolysis for onboard applications; however, the concept of a NaBH4-H2-PEMFC system has the potential to become a primary source for on-demand power supply. Despite the many efforts to study this technology, most of the published papers focus on catalytic performance. Nevertheless, the development of a practical reaction system to close the NaBH4-H2 cycle remains a critical issue. Therefore, this work provides an overview of the research progress on the solutions for the by-product rehydrogenation leading to the regeneration of NaBH4 with economic potential. It is the first to compare and analyze the main types of processes to regenerate NaBH4: thermo-, mechano-, and electrochemical. Moreover, it considers the report by Demirci et al. on the main by-product of sodium borohydride hydrolysis. The published literature already reported efficient NaBH4 regeneration; however, the processes still need more improvements. Moreov... [more]

To meet climate change challenges, the UK government is aiming to reach zero emissions by 2050. The heavy-duty transportation sector contributes 17% to the UKs total emissions, so to combat this, alternative power units to traditional fossil fuel-reliant internal combustion engines (ICEs) are being utilized and investigated. Hydrogen fuel cells are a key area of interest to try and reduce these transportation emissions. To gain a true view of the impact that hydrogen fuel cells can have, this study looks at the impact the manufacturing of a fuel cell has upon the environment, from material extraction through to the usage phase. This was done through the use of a lifecycle assessment following ISO 14040 standards, with hydrogen systems being compared to alternative systems. This study has found that whilst fuel cells depend upon energy intensive materials for their construction, it is possible to reduce emissions by 34−87% compared to ICE systems, depending upon the source of hydrogen u... [more]

In this work, copper oxides-based photocathodes for photoelectrochemical cells (PEC) were produced for the first time by screen printing. A total 7 × 10−3 g/m2 glycerine trioleate was found as optimum deflocculant amount to assure stable and homogeneous inks, based on CuO nano-powder. The inks were formulated considering different binder amounts and deposited producing films with homogenous thickness, microstructure, and roughness. The as-produced films were thermally treated to obtain Cu2O- and Cu2O/CuO-based electrodes. The increased porosity obtained by adding higher amounts of binder in the ink positively affected the electron transfer from the surface of the electrode to the electrolyte, thus increasing the corresponding photocurrent values. Moreover, the Cu2O/CuO system showed a higher charge carrier and photocurrent density than the Cu2O-based one. The mixed Cu2O/CuO films allowed the most significant hydrogen production, especially in slightly acid reaction conditions.

The development of a transition-metal-based catalyst with concomitant high activity and stability due to its distinguishing characteristics, yielding an abundance of active sites, is considered to be the bottleneck for the dry reforming of methane (DRM). This work presents the catalytic activity and durability of SrNiO3 and CeNiO3 perovskites for syngas production via DRM. CeNiO3 exhibits a higher specific surface area, pore volume, number of reducible species, and nickel dispersion when compared to SrNiO3. The catalytic activity results demonstrate higher CH4 (54.3%) and CO2 (64.8%) conversions for CeNiO3, compared to 22% (CH4 conversion) and 34.7% (CO2 conversion) for SrNiO3. The decrease in catalytic activity after replacing cerium with strontium is attributed to a decrease in specific surface area and pore volume, and nickel active sites covered with strontium carbonate. The stability results reveal the deactivation of both the catalysts (SrNiO3 and CeNiO3) but SrNiO3 showed more d... [more]

The steel industry is among the highest carbon-emitting industrial sectors. Since the steel production process is already exhaustively optimized, alternative routes are sought in order to increase carbon efficiency and reduce these emissions. During steel production, three main carbon-containing off-gases are generated: blast furnace gas, coke oven gas and basic oxygen furnace gas. In the present work, the addition of renewable hydrogen by electrolysis to those steelworks off-gases is studied for the production of methane and methanol. Different case scenarios are investigated using AspenPlusTM flowsheet simulations, which differ on the end-product, the feedstock flowrates and on the production of power. Each case study is evaluated in terms of hydrogen and electrolysis requirements, carbon conversion, hydrogen consumption, and product yields. The findings of this study showed that the electrolysis requirements surpass the energy content of the steelwork’s feedstock. However, for the m... [more]

The exhaustion of fossil fuels causes decarbonized industries to be powered by renewable energy sources and, owing to their intermittent nature, it is important to devise an efficient energy storage method. To make them more sustainable, a storage system is required. Modern electricity storage systems are based on different types of chemical batteries, electromechanical devices, and hydrogen power plants. However, the parameters of power plant components vary from one geographical location to another. The idea of the present research is to compare the composition of a solar-powered hydrogen processing closed-cycle power plant among the selected geographical locations (Russia, India, and Australia), assuming the same power consumption conditions, but different insolation conditions, and thus the hydrogen equipment capacity accordingly. The number of solar modules in an array is different, thus the required hydrogen tank capacity is also different. The comparison of equipment requires bu... [more]

The fossil-based energy system is transitioning towards a renewable energy system. One important aspect is the spatial and temporal mismatch between intermitted supply and continuous demand. To ensure a reliable and affordable energy system, we propose an integrated system approach that integrates electricity production, mobility, heating of buildings and water management with a major role for storage and conversion. The minimization of energy transport in such an integrated system indicates the need for local optimization. This study focuses on a comparison between different novel system designs for neighborhood energy and water systems with varying modes of system integration, including all-electric, power-to-heat and power-to-hydrogen. A simulation model is developed to determine the energy and water balance and carry out economic analysis to calculate the system costs of various scenarios. We show that system costs are the lowest in a scenario that combines a hydrogen boiler and he... [more]

Hydrogen is one of the modern energy carriers, but its storage and practical use of the newest hydrogen technologies in real operation conditions still is a task of future investigations. This work describes the experimental hydrogen hybrid energy system (HHS). HHS is part of a laboratory off-grid system that stores electricity gained from photovoltaic panels (PVs). This system includes hydrogen production and storage units and NEXA Ballard low-temperature proton-exchange membrane fuel cell (PEMFC). Fuel cell (FC) loses a significant part of heat during converting chemical energy into electricity. The main purpose of the study was to explore the heat distribution phenomena across the FC NEXA Ballard stack during load with the next heat transfer optimization. The operation of the FC with insufficient cooling can lead to its overheating or even cell destruction. The cause of this undesirable state is studied with the help of infrared thermography and computational fluid dynamics (CFD) mo... [more]

The review contains a comparative analysis of studies on the production of hydrogen and syngas based on the processes of partial oxidation of natural gas and other types of gas feedstock. The results presented in the literature show the high potential of non-catalytic autothermal processes of partial oxidation of hydrocarbons for the development of gas chemistry and energetics. The partial oxidation of hydrocarbons makes it possible to overcome such serious shortcomings of traditional syngas production technologies as technological complexity and high energy and capital intensity. The features of non-catalytic partial oxidation of hydrocarbon gases, the obtained experimental results and the results of kinetic modeling of various options for the implementation of the process, which confirm the adequacy of the kinetic mechanisms used for the analysis, are considered in detail. Examples of industrial implementation of processes based on partial oxidation and proposed alternative options f... [more]

The present day energy supply scenario is unsustainable and the transition towards a more environmentally friendly energy supply system of the future is inevitable. Hydrogen is a potential fuel that is capable of assisting with this transition. Certain technological advancements and design challenges associated with hydrogen generation and fuel cell technologies are discussed in this review. The commercialization of hydrogen-based technologies is closely associated with the development of the fuel cell industry. The evolution of fuel cell electric vehicles and fuel cell-based stationary power generation products in the market are discussed. Furthermore, the opportunities and threats associated with the market diffusion of these products, certain policy implications, and roadmaps of major economies associated with this hydrogen transition are discussed in this review.

Sustained increase in plastic use has placed a significant burden on waste disposal infrastructure. Pyrolysis is the process of decomposing high-molecular-weight compounds by heating waste plastics at 500−1000 °C without oxygen. This process considerably reduces greenhouse gas emissions and has a high alternative energy effect (0.57 TOE ton−1). After a separation process, the oil produced by pyrolysis (C5−C20) can yield naphtha oil (C6−C7). Subsequently, hydrogen can be produced through a reforming reaction of this naphtha oil. Here, we produced hydrogen from waste plastic pyrolysis oil over a Ni/Ce-Zr-Mg/Al2O3 catalyst using a steam reforming process. A model oil combining the major substances of C6 and C7 (hexane, hexene, heptane, heptene, and toluene) was formed. From the reaction products, the hydrogen yield was obtained based on analysis of H2, CO, and CO2 concentrations using gas chromatography. The effect of N2 and O2 addition on hydrogen yield was analyzed within a temperature... [more]

An energy production system that combines biomass and fuel cells produces much energy with minimal environmental impact. However, the hydrogen sulfide (H2S) contained in gasified biomass degrades fuel cell performance, thus negating the advantages of this combination. In this study, the removal of H2S by adsorption after biomass gasification was investigated. Metal oxides with high adsorption performance are common H2S adsorbents. However, they have a significant environmental impact in terms of metal depletion, which is an environmental impact indicator. Therefore, neutralized sediment materials from mine drainage treatments can be used as H2S adsorbents. A previous study found that the adsorption performance of H2S adsorbents is equivalent to that of metal oxides, especially in the high-temperature zone (300 °C), and the environmental impact is considerably lower than that of metal oxides. However, because the neutralized sediment is a powder (Φ 4.5 μm on average), there is a possibi... [more]

In this work, the influence of H2 addition on the auto-ignition and combustion properties of CH4 is investigated experimentally and numerically. Experimental ignition delay times (IDT) are compared with simulations and laminar burning velocities (LBVs), and extinction limits/extinction strain rates (ESRs) are compared with data from the literature. A wide variety of literature data are collected and reviewed, and experimental data points are extracted for IDT, LBV and ESR. The results are used for the validation of existing reaction mechanisms. The reaction mechanisms and models used are able to reproduce the influence of H2 addition to CH4 (e.g., shortening IDTs, increasing ESRs and increasing LBVs). IDTs are investigated in a range from 6 to 15 bar and temperatures from 929 to 1165 K with H2 addition from 10 to 100 mol%. We show that LBV and ESR are predicted in a wide range by the numerical simulations. Moreover, the numerical simulations using detailed Aramco Mech 3.0 (581 species)... [more]

One of the most important environmental and safety concerns in nuclear fusion plants is the confinement of radioactive substances into the reactor buildings during both normal operations and accidental conditions. For this reason, hydrogen build-up and subsequent ignition must be avoided, since the pressure and energy generated may threaten the integrity of the confinement structures, causing the dispersion of radioactive and toxic products toward the public environment. Potentially dangerous sources of hydrogen are related to the exothermal oxidation reactions between steam and plasma-facing components or hot dust, which could occur during accidents such as the in-vessel loss of coolant or a wet bypass. The research of technical solutions to avoid the risk of a hydrogen explosion in large fusion power plants is still in progress. In the safety and environment work package of the EUROfusion consortium, activities are ongoing to study solutions to mitigate the hydrogen explosion risk. T... [more]

Hydrogen is the energy vector that will lead us toward a more sustainable future. It could be the fuel of both fuel cells and internal combustion engines. Internal combustion engines are today the only motors characterized by high reliability, duration and specific power, and low cost per power unit. The most immediate solution for the near future could be the application of hydrogen as a fuel in modern internal combustion engines. This solution has advantages and disadvantages: specific physical, chemical and operational properties of hydrogen require attention. Hydrogen is the only fuel that could potentially produce no carbon, carbon monoxide and carbon dioxide emissions. It also allows high engine efficiency and low nitrogen oxide emissions. Hydrogen has wide flammability limits and a high flame propagation rate, which provide a stable combustion process for lean and very lean mixtures. Near the stoichiometric air−fuel ratio, hydrogen-fueled engines exhibit abnormal combustions (ba... [more]

Carbon-free fuels, in particular ammonia and hydrogen, could play a significant role in the decarbonization of the mobility sector. In this work, the authors assessed the operation of a light-duty spark-ignition engine fueled with an ammonia−hydrogen blend (85% ammonia and 15% hydrogen by volume) using a 1D predictive model. Three-dimensional computations have been used in order to verify the reliability of the 1D model. The addition of hydrogen to the air−fuel mixture allows the operating capacity of the engine to be extended with respect to neat ammonia fueling. The engine can be properly regulated between 1500 rpm and 3000 rpm. Its operating range reduces as engine speed increases, and it cannot run at 6000 rpm. This is due to different engine operating constraints being exceeded. The maximum engine torque is about 240 Nm and is reached at 1500 rpm. The engine efficiency ranges between 42% and 19%, and the specific fuel consumption varies from about 350 g/kWh to about 750 g/kWh. The... [more]

This study investigates the global allocation of hydrogen and synfuels in order to achieve the well below 2 °C, preferably 1.5 °C target set in the Paris Agreement. For this purpose, TIMES Integrated Assessment Model (TIAM), a global energy system model is used. In order to investigate global hydrogen and synfuel flows, cost potential curves are aggregated and implemented into TIAM, as well as demand technologies for the end use sectors. Furthermore, hydrogen and synfuel trades are established using liquid hydrogen transport (LH2), and both new and existing technologies for synfuels are implemented. To represent a wide range of possible future events, four different scenarios are considered with different characteristics of climate and security of supply policies. The results show that in the case of climate policy, the renewable energies need tremendous expansion. The final energy consumption is shifting towards the direct use of electricity, while certain demand technologies (e.g., a... [more]

Hydrogen can play a key role in the gradual transition towards a full decarbonization of the combustion sector, e.g., in power generation. Despite the advantages related to the use of this carbon-free fuel, there are still several challenging technical issues that must be addressed such as the thermoacoustic instability triggered by hydrogen. Given that burners are usually designed to work with methane or other fossil fuels, it is important to investigate their thermoacoustic behavior when fueled by hydrogen. In this framework, the present work aims to propose a methodology which combines Computational Fluid Dynamics CFD (3D Reynolds-Averaged Navier-Stokes (RANS)) and Finite Element Method (FEM) approaches in order to investigate the fluid dynamic and the thermoacoustic behavior introduced by hydrogen in a burner (a lab-scale bluff body stabilized burner) designed to work with methane. The case of CH4-air mixture was used for the validation against experimental results and benchmark CF... [more]

Hydrogen has recently been proposed as a versatile energy carrier to contribute to archiving universal access to clean cooking. In hard-to-reach rural settings, decentralized produced hydrogen may be utilized (i) as a clean fuel via direct combustion in pure gaseous form or blended with Liquid Petroleum Gas (LPG), or (ii) via power-to-hydrogen-to-power (P2H2P) to serve electric cooking (e-cooking) appliances. Here, we present the first techno-economic evaluation of hydrogen-based cooking solutions. We apply mathematical optimization via energy system modeling to assess the minimal cost configuration of each respective energy system on technical and economic measures under present and future parameters. We further compare the potential costs of cooking for the end user with the costs of cooking with traditional fuels. Today, P2H2P-based e-cooking and production of hydrogen for utilization via combustion integrated into the electricity supply system have almost equal energy system costs... [more]

Hydrogen production from biogas over alumina-supported Ce1−xNixO2−x catalysts was studied in a temperature range of 600−850 °C with an initial gas composition of CH4/CO2/H2O of 1/0.8/0.4. To achieve a high and stable hydrogen yield, highly dispersed Ni catalysts were prepared through the exsolution approach. A solid solution of Ce1−xNixO2−x was firstly formed on the surface of Al2O3 and then activated in H2/Ar at 800 °C. The genesis and properties of the Ce1−xNixO2−x/Al2O3 catalysts were established using X-ray fluorescence analysis, thermal analysis, N2 adsorption, ex situ and in situ X-ray diffraction, Raman spectroscopy, electron microscopy, EDX analysis, and temperature-programmed hydrogen reduction. The performance of Ce1−xNixO2−x/Al2O3 catalysts in biogas conversion was tuned by regulation of the dispersion and reducibility of the active component through variation of content (5−20 wt.%) and composition (x = 0.2, 0.5, 0.8) of Ce1−xNixO2−x as well as the mode of its loading (co-im... [more]

The last Intergovernmental Panel on Climate Change (IPPC) assessment report highlighted how actions to reduce CO2 emissions have not been effective so far to achieve the 1.5 C limit and that radical measures are required. Solutions such as the upgrading of waste biomass, the power-to-X paradigm, and an innovative energy carrier such as hydrogen can make an effective contribution to the transition toward a low-carbon energy system. In this context, the aim of this study is to improve the hydrogen production process from wet residual biomass by examining the advantages of an innovative integration of anaerobic digestion with thermochemical transformation processes. Furthermore, this solution is integrated into a hybrid power supply composed of an electric grid and a photovoltaic plant (PV), supported by a thermal energy storage (TES) system. Both the performance of the plant and its input energy demand—splitting the power request between the photovoltaic system and the national grid—are... [more]

The power industry is rapidly changing as demand for eco-friendly and stable power supply increases along with global greenhouse gas emission regulations. Small-capacity renewable power sources represented by photovoltaics and wind are continuously increasing as a form of microgrid to supply electric power to a community or island. As a result, microgrids based on renewable resources have come into wide usage around small areas or islands in Korea. In particular, the microgrid development policy of Korea is focused on electric power quality, as well as expansion in renewable energy supply for reducing greenhouse gas emissions. From 2009, the government began to develop independent carbon-free microgrids with photovoltaic and wind powers instead of traditional power diesel generators for small islands. The goal of this paper is to investigate a feasible economic microgrid topology for implementing the carbon-free island (CFI) under an acceptable level of reliability. First, we derive th... [more]

To deal with energy transition due to climate change and a rise in average global temperature, photovoltaic (PV) conversion appears to be a promising technology in sunny regions. However, PV production is directly linked with weather conditions and the day/night cycle, which makes it intermittent and random. Therefore, it makes sense to combine it with Energy Storage Systems (ESS) to ensure long-term energy availability for non-interconnected micro-grids. Among all technological solutions, electrolytic hydrogen produced by renewable energies seems an interesting candidate. In this context, this paper proposes a control strategy dedicated to hydrogen storage integration in micro-grids for a better use of PV production. The objective is to optimize the management of the micro-grid with proton exchange membrane Fuel Cell (FC), alkaline Electrolyzer (El), lithium-ion Batteries Energy Storage System (BESS) and PV, according to the system state and PV production intermittency. First, a contr... [more]