Mining-induced subsidence is critical for ecological environment reconstruction and damage prevention in coal mining areas. Understanding the characteristics of surface subsidence with multi-seam mining is the first step. Surface subsidence of different mining panel layout configurations was investigated by means of UDEC numerical simulation. Based on the simulation results, it was indicated that mining panel layout configuration had a significant impact on surface subsidence, including ground surface subsidence, horizontal displacement, crack propagation, and ground surface fissure development. The overlapped region of the upper panel and the lower panel is the key region, where existing bedding separations and strata cracks close and activate, the integrity and strength of the interburden layer are reduced, and the subsidence magnitude is enhanced. The subsidence profile of the overlapped region for the stacked configuration, external staggered, the edge of the lower panel internal s... [more]

This paper focuses on the combustion mechanism of furan-based fuels synthesized from lignocellulose. The fuel is a binary alternative fuel consisting of 2-methylfuran and 2,5-dimethylfuran derived from furfural. The key reactions affecting the combustion mechanism of this fuel were identified via path analysis, and the initial reaction kinetic mechanism was constructed using a decoupling methodology. Then, a genetic algorithm was used to optimize the initial mechanism. The final skeleton mechanism consisted of 67 species and 228 reactions. By comparing experimental data on ignition delay, component concentration, and laminar flame velocity under a wide range of conditions over various fundamental reactors, it was shown that the mechanism has the ability to predict the combustion process of this fuel well.

His-tags are widely used for the purification of recombinant proteins. High-cost carriers functionalized with nickel ions are commonly required for the selective immobilization of His-tagged enzymes. In this study, His-tags of varying lengths were fused to the N-terminus of D-amino acid oxidase (DAO) from Trigonopsis variabilis. The attachment of a His6 tag significantly improved the solubility of the recombinant DAO expressed in Escherichia coli. By modulating the tag lengths, a better balance between cell growth and protein solubility was achieved, resulting in a higher volume activity (His3). Furthermore, the fusion of longer tags (His6 and His9) facilitated the rapid immobilization of DAOs onto a commercial epoxy carrier without metal bearing, resulting in more selective immobilization. In conclusion, the modulation of His-tag length was preliminarily demonstrated as a simple and cost-effective approach to achieve efficient expression, as well as fast and selective immobilization o... [more]

The super-growth approach for carbon nanotubes synthesis is frequently used to boost the growth rate, catalyst lifespan, and height of vertically aligned carbon nanotubes. The elimination of amorphous carbon from catalyst particles, commonly made of iron, by injecting water vapor into a chemical vapor deposition process can enhance the purity, alignment, and height of carbon nanotubes and prevent the partial oxidation of the metallic catalyst. We present the development of a modified growth-optimized water-assisted super-growth vertically aligned carbon nanotube process by optimizing the catalyst layer structure and water vapor concentration for a carbon nanotube growth process for 4” diameter Si wafers. A significant finding is that under optimized water-assisted growth conditions over 4 mm, highly uniform tall, vertically aligned carbon nanotube structures can be grown with a minimum top crust layer of about ~5−10 μm thickness. This was achieved with a catalyst film comprising a >400... [more]

Natural gas hydrate reservoir has been identified as a new alternative energy resource which has characteristics of weak cementation, low reservoir strength and shallow overburden depth. Thus, the stability of subsea equipment and formation can be affected during the drilling process. To quantitatively assess the vertical displacement of the formation induced by hydrate decomposition and clearly identify the influence laws of various factors on wellhead stability, this study established a fully coupled thermo-hydro-mechanical-chemical (THMC) model by using ABAQUS software. The important factor that affects the wellhead stability is the decomposition range of hydrates. Based on this, the orthogonal experimental design method was utilized to analyze the influence laws of some factors on wellhead stability, including the thickness of hydrate formation, initial hydrate saturation, overburden depth of hydrate sediment, and mudline temperature. The results revealed that the decomposition of... [more]

The development of an optimized air or O2-assisted multi-wall vertically aligned carbon nanotubes (VACNT) process that adjusts the vertical height profile of a standard H2O vapor-assisted VACNT process is reported. The effect of the air or O2 chemical vapor deposition (CVD) precursor flow rate, the catalytic Fe layer thickness, the process growth temperature, and the H2/C2H4 ratio on VACNT length was first investigated to find the optimum growth conditions. Spatial distribution height mapping of VACNT structures on six patterned 4′′ catalyst Si wafers prepared with a 70−90 min long O2-assisted growth step shows an average growth height of 1.8−2.2 mm, with a standard deviation of less than 10%. Characterization techniques included Raman spectroscopy, scanning electron microscopy (SEM), and spatial height mapping analysis for a range of Fluid channel Array Brick (FAB) components with a length of 30 mm, a width range of 2.5−15 mm, a fluid channel diameter range of d = 5−100 mm, and a flui... [more]

The nickel-based catalyst was more active in the reverse water-gas shift reaction, but it is easy to sinter and deactivate in high temperature reaction (≥600 °C). A urea-assisted impregnation method was utilized to create a Ni/SiO2-N catalyst to increase the catalytic stability of Ni-based catalysts. For at least 20 h, the Ni/SiO2-N catalyst in the reverse water-gas shift process at 700 °C remained stable, and in the high temperature RWGS reaction, the conversion rate of CO2 of the catalyst is close to the equilibrium conversion rate. The catalysts were characterized by BET, XRD, H2-TPR, and TEM, and the results demonstrate that the Ni particles had a small particle size and exhibited strong interaction with the SiO2 support in the Ni/SiO2-N catalyst, which led to the catalyst’s good activity and stability. Urea-assisted impregnation is a facile method to prepare stable Ni/SiO2 catalysts with high Ni dispersion.

The sustained casing pressure (SCP) phenomenon of shale gas and oil wells occurs frequently after fracturing; therefore, in order to assess the cement sheath’s integrity in the vertical well portion, the cement stones were subjected to a compression test under different temperatures and confining pressures to obtain the mechanical parameters of the cement sheath at different well depths. The integrity of the cement ring between the production casing and the intermediate casing was then investigated using the Moore−Coulomb criterion. We also took into account other elements including pump pressure, production casing wall thickness, and cement ring mechanical properties. The results show that (1) the compressive strength, Poisson’s ratio, and Young’s modulus of cement stone vary obviously under different confining pressures and temperature conditions, and the cement stone shows elastic−brittle failure characteristics at 20 °C. The compressive strength, Poisson’s ratio, and Young’s modulu... [more]

Anaerobic ammonium oxidation (anammox, A) has become an appealing bioprocess for the water sector as a method to remove nitrogen (N) from wastewater using low-energy and organic carbon inputs [...]

Ru catalysts supported on activated carbon obtained by hydrothermal treatment of rice husk were evaluated in the hydrogenation reaction of levulinic acid to γ-valerolactone. The hydrothermally treated carbon was characterized by nitrogen physisorption, elemental analysis, and thermogravimetric analysis, and the catalysts were characterized by FTIR spectroscopy, X-ray photoelectron spectroscopy, temperature-programmed reduction, and temperature-programmed desorption of pyridine (acidic properties). Prior to the reaction, the catalysts were reduced at different temperatures in the range of 100−350 °C to evaluate the effect of the reduction temperature on the performance in the hydrogenation of levulinic acid. The reaction was carried out in a batch reactor at 70 °C and 1.5 MPa. The results of conversion and selectivity to γ-valerolactone showed that the catalyst with the best performance was the sample reduced at 200 °C. After 2 h of reaction, a γ-valerolactone yield of 74% was achieved.... [more]

As wind energy is widely available, an increasing number of individuals, especially in off-grid rural areas, are adopting it as a dependable and sustainable energy source. The energy of the wind is harvested through a device known as a wind energy harvesting system (WEHS). These systems convert the kinetic energy of wind into electrical energy using wind turbines (WT) and electrical generators. However, the output power of a wind turbine is affected by various factors, such as wind speed, wind direction, and generator design. In order to optimize the performance of a WEHS, it is important to track the maximum power point (MPP) of the system. Various methods of tracking the MPP of the WEHS have been proposed by several research articles, which include traditional techniques such as direct power control (DPC) and indirect power control (IPC). These traditional methods in the standalone form are characterized by some drawbacks which render the method ineffective. The hybrid techniques com... [more]

In this paper, we show that an analytical solution based on the Finite Line Source and G-function approach is both sufficiently fast and accurate for design calculations of ground heat exchangers with a complex (spiral) geometry. Detailed validations were performed for the steady-state and transient responses of analytical models with different time scales (10 h and 250 h). A comparison with a detailed computational fluid dynamics model (Ansys Fluent) and the analytical method for different boundary conditions showed a very good agreement (maximum root mean square error) smaller than 0.25 K.

Murals are one of the important cultural heritages of mankind. The microbial control of murals is an important subject in mural painting conservation. In recent years, electron beam radiation sterilization has attracted more and more attention in the field of cultural relic protection. Murals are immovable cultural relics, so conventional electron beam irradiation equipment can not be used. However, the development of small mobile electron beam irradiation equipment shows the potential of radiation’s application in the sterilization protection of immovable cultural relics such as murals. A feasibility study of radiation sterilization in mural paintings is needed to investigate the effect of sterilization and the influence of sterilization dose on the stability of mural painting pigments and bonding materials. In this paper, the radiation effects of typical bacteria in tomb murals and mineral pigment powder in ancient Chinese paintings were studied in a laboratory. Firstly, aeromonas hy... [more]

To maximize the potential energy utilization of agricultural and forestry wastes and sludge, experimental studies were conducted on the co-gasification characteristics of two types of sludge (municipal sludge, MS; paper-mill sludge, PS) and a typical biomass straw (ST) under CO2 atmosphere. In this paper, the main two stages of the gasification process, the pyrolysis in the low-temperature region and the CO2-gasification in the high-temperature region, were separately studied and analyzed. The experimental results showed that biomass could effectively promote the pyrolysis of the sludge in the low-temperature region and improve the gasification in the high-temperature region. Due to the complex interactions between components, the characteristic parameters presented obvious nonlinear rules during the co-pyrolysis and co-gasification processes. For the MS-ST mixtures, when increasing the ST content, (i) in the pyrolysis process, the initial reaction temperature gradually decreased, but... [more]

Optimizing or debottlenecking existing production plants is a challenging task. In this case study, an existing reversed phased chromatography polishing step for peptide purification was optimized with the help of a digital twin. The existing batch chromatography was depicted digitally with the general rate model. Model parameter determination and model validation was done with dedicated experiments. The digital twin was then used to identify optimized process variants, especially continuous chromatography steps. MCSGP was found to achieve high purities and yield but at the cost of productivity due to column synchronization. An alternative Continuous Twin Column chromatography process (CTCC) was established that eliminates unnecessary waiting times. Ensuring the same or higher purity compared to the batch process, the continuous process achieved a yield increase of 31% and productivity increase of 27.6%. Experimental long runs confirmed these results.

Sonication is a relatively new and eco-friendly method used to extend the shelf life of food products. This study aimed to investigate the effects of ultrasonication and thermal treatments on the physical and sensory properties of an energy drink made from dates during cold storage at 4 °C. The study compared the effects of ultrasonication for 20, 30, and 40 min at 50% amplitude with thermal treatment at 90 °C for 5 min, aiming to model the changes in properties of processed drinks over time and predict their shelf life by integrating quality attributes. The results showed that total soluble solids (TSS) and electrical conductivity (EC) were not affected by cold storage and did not differ significantly between sonicated, thermally processed, and untreated samples. However, significant differences in pH; L*, a*, and b* values; Chroma; and sensory attributes were detected among the sonicated, thermally processed, and untreated samples. The sensory properties of the sonicated samples for... [more]

The valve is a key control component in the oil and gas transportation system, which, due to the environment, transmission medium, and other factors, is susceptible to internal leakage, resulting in valve failure. Conventional testing methods cannot judge the service life of valves. Therefore, it is important to carry out valve life prediction research for oil and gas transmission safety. In this work, a valve service life prediction method based on the PCA-PSO-LSSVM algorithm is proposed. The main factors affecting valve service life are obtained by principal component analysis (PCA), the least squares support vector machine (LSSVM) is used to predict the valve service life, the parameters are optimized by using particle swarm optimization (PSO), and the valve service life prediction model is established. The results show that the predicted valve service life based on the PCA-PSO-LSSVM algorithm is closer to the actual value, with an average relative error (MRE) of 16.57% and a root m... [more]

It is quite essential to obtain an excellent CO2 adsorption capacity, CO2 adsorption selectivity and water vapor stability at the same time for practical CO2 capture after combustion. Through the combination of ultramicropore and the high density of CO2-philic sites without OMSs, an ultra-microporous Cu-based metal−organic framework has been designed and synthesized, featuring a high CO2 capacity (99 cm3 g−1 and 56.6 cm3 g−1 at 273 K and 298 K, respectively), high selectivity over N2 (118 at a scale of CO2/N2 15/85, 298 K) and excellent water vapor stability, simultaneously. Theoretical calculations indicate that neighboring ketonic O atoms with suitable distance play vital roles in boosting CO2 selective capture.

The Pisum sativum (PS), known as the green pea, was used in this investigation to produce a novel green surfactant. The performance of the PS green surfactant was also evaluated using various tests, including contact angle, IFT, emulsion, zeta potential, and oil recovery factor measurement in the presence of formation brine (FB) with a total dissolved solid (TDS) of 150,000 ppm. The characterization study using various tests revealed that the PS green surfactant was nonionic. The critical micelle concentration (CMC) measurement results indicated that the PS green surfactant’s CMC value is 1500 ppm. The IFT and contact angle measurements showed that the green surfactant significantly lowered the IFT and contact angles. The lowest IFT value of 3.71 mN/m and the contact angle of 57.37° were achieved at the FB concentration of 12,500 ppm (optimum salinity). The results of the emulsion tests showed that Winsor type III emulsions were achieved using PS green surfactant and crude oil. The cor... [more]

Air source heat pump (ASHP) is a good new energy heating system. To explore the effect of ASHP on the production of yellow-feather broiler chicks, 31,500 one-day-old yellow broiler chicks were divided into three chicken houses with the same building structure but different heating methods (ASHP, CCF, CB). During the experiment, the parameters of heating time, temperature uniformity, gas concentration, weight gain, survival rate and production benefit were analyzed and evaluated. Results showed that the difference in NH3, CO2, and H2S concentrations was not significant in all test groups (p > 0.05). Only group II detected the CO gas. In winter and spring, the weight of the chickens in group II were weighed the least at 35 days of age, and were significantly different from the ASHP and CB system (p < 0.05). There was no significant difference in body weight between ASHP and CB (p > 0.05). Group II had the lowest evenness and survival, the slowest warming, the worst uniformity of temperat... [more]

The desired changes in flow characteristics are obtained by flow control, which implies manipulating flow behavior such as drag reduction, mixing augmentation, or noise attenuation, employing active or passive devices [...]

This paper describes the findings of detailed simulations performed to investigate the impact of seal teeth cavity leakage flow on the aerodynamic and thermal performance of a three-stage supercritical CO2 axial compressor. The study compares a shrouded stator configuration (with cavities) to a cantilevered stator configuration (without cavities) to highlight their differences. High-fidelity computational fluid dynamics simulations were performed using non-linear harmonic (NLH) and mixing plane assumptions, considering various possible rotor/stator interface configurations for mixing plane calculations. The key performance parameters for each case were compared, and the best-performing configuration selected for further analysis. The individual stage performance parameters are also examined and compared between the cantilevered and shrouded configurations. It was observed that in the shrouded case, the leakage flow enters the cavity downstream of the stator trailing edge and gets entra... [more]

Steel surface defect detection is an important issue when producing high-quality steel materials. Traditional defect detection methods are time-consuming and uneconomical and require manually designed prior information or extra supervisors. Surface defects have different representations and features at different scales, which make it challenging to automatically detect the locations and defect types. This paper proposes a real-time steel surface defect detection technology based on the YOLO-v5 detection network. In order to effectively explore the multi-scale information of the surface defect, a multi-scale explore block is especially developed in the detection network to improve the detection performance. Furthermore, the spatial attention mechanism is also developed to focus more on the defect information. Experimental results show that the proposed network can accurately detect steel surface defects with approximately 72% mAP and satisfies the real-time speed requirement.

A new energy material, a high-energy expansion agent (HEEA), was proposed for the harsh engineering environment of a mine. A safety test and field engineering test were carried out. The results showed that the mechanical sensitivity of the HEEA was extremely low, and no combustion and explosion occurred in multiple impact and friction tests. Meanwhile, the HEEA only burns in open spaces without detonation. Through field experiments, the HEEA can achieve a good blasting effect, providing strong support for its promotion in low-disturbance environmental engineering applications.

As the four-way shuttle vehicle is prone to overturning in finished grain storage during acceleration and deceleration, an overturning mechanical model is constructed. The design factors analyzed include grain bag height, vehicle and grain bag mass, and the type of grain’s effect on the vehicle’s anti-overturning stability. The critical overturning condition of the shuttle vehicle during operation is also determined as a result of this analysis. With the critical overturning condition, the speed control of the shuttle vehicle based on the fuzzy PID method is carried out to improve the anti-overturning stability. Significant details are made about the fuzzification of input and output variables, determination of membership function, establishment of the fuzzy rule base, fuzzy reasoning, and defuzzification. Finally, the comparative simulation model of fuzzy PID and conventional PID in the MATLAB/Simulink platform showed that the fuzzy PID control method had the advantages of fast conver... [more]