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Showing records 35637 to 35661 of 36336. [First] Page: 1 1423 1424 1425 1426 1427 1428 1429 1430 1431 Last
35637. LAPSE:2023.1268
Fixed-Time Tracking Control for Nonlinear Cascade Systems with Unknown High Powers
February 21, 2023 (v1)
Subject: Process Control
Keywords: fixed-time stability, nonlinear cascade systems, tracking control, unknown powers
This paper investigates the global fixed-time tracking control problem of nonlinear cascade systems with unknown high powers. In the process of control design, a upper bound and a lower bound of high powers are introduced to compensate the unknown system powers, and a state feedback controller is designed under any initial system conditions. Based on the Lyapunov stability analysis method and the fixed-time stability theory, it is verified that the proposed method can regulate the output tracking error to a disc region of the origin within a fixed-time and all the closed-loop signals are bounded. At last, the effectiveness of the proposed scheme is verified by some simulation results.
35638. LAPSE:2023.1267
Analysis Method and Case Study of the Lightweight Design of Automotive Parts and Its Influence on Carbon Emissions
February 21, 2023 (v1)
Subject: Process Design
Keywords: carbon emissions, lightweight, low carbon benefits, optimization design, wheel hub
The automobile industry, as a representative in pursuing the goals of “emission peak” and “carbon neutrality”, has made low carbon a new industrial practice. With regard to low carbon, the lightweight design proves to be an effective approach to reducing carbon emissions from automobiles. Given the state of research, in which the existing lightweight design schemes of automobiles seldom consider the impact of the lightweight quality on carbon emissions during the whole life cycle of the automobiles, this paper proposes a more comprehensive lightweight design method for automobiles in regard to carbon emissions. First, the finite element method was adopted to analyze the stress, strain and safety factors of the automobile parts based on their stress, so as to identify the positions where the lightweight design was applicable. Subsequently, a lightweight scheme was designed accordingly. Next, the finite element method was re-applied to the parts whose weights had been reduced. In this wa... [more]
35639. LAPSE:2023.1266
Phytofabrication of Silver Nanoparticles and Their Potent Antifungal Activity against Phytopathogenic Fungi
February 21, 2023 (v1)
Subject: Materials
Keywords: antifungal activity, green synthesis, nanofungicide, phytopathogenic fungi, silver nanoparticles
Fungal plant pathogens cause huge losses in agricultural production by decreasing crop yield and quality. To reduce crop loss from fungal damage, various synthetic fungicides are applied indiscriminately in agricultural practice. The majority of synthetic fungicides are non-biodegradable, and several critical human health risks are associated with them. Green synthesis nanotechnology offers an effectual, cost-effective, ecofriendly, and innocuous method for the synthesis of green nanofungicides, an excellent replacement for synthetic chemical fungicides. Origanum majorana is an aromatic herb with immense pharmacological and medicinal properties. In this context, the present study used the leaves of O. majorana to synthesize silver nanoparticles. The biosynthesized particles showed an absorption peak at 441 nm with ultraviolet-visible spectrophotometry (UV-Vis). The spectra obtained from Fourier transform infrared spectroscopy (FT-IR) of O. majorana extract and AgNPs showed a myriad of... [more]
35640. LAPSE:2023.1265
Hierarchical Deep LSTM for Fault Detection and Diagnosis for a Chemical Process
February 21, 2023 (v1)
Subject: Numerical Methods and Statistics
Keywords: autoencoders, classification, deep learning, fault detection and diagnosis, incipient faults, LSTM, statistical process monitoring (SPC), Tennessee Eastman Process
A hierarchical structure based on a Deep LSTM Supervised Autoencoder Neural Network (Deep LSTM-SAE NN) is presented for the detection and classification of faults in industrial plants. The proposed methodology has the ability to classify incipient faults that are difficult to detect and diagnose with traditional and many recent methods. Faults are grouped into different subsets according to the degree of difficulty to classify them accurately in the proposed hierarchical structure. External pseudo-random binary signals (PRBS) are injected in the system to enhance the identification of incipient faults. The approach is illustrated on the benchmark process (Tennessee Eastman Process) in order to compare across different methodologies. The efficacy of the proposed method is shown by a comprehensive comparison between many recent and traditional fault detection and diagnosis methods in the literature for Tennessee Eastman Process. The proposed work results in significant improvements in th... [more]
35641. LAPSE:2023.1264
Study on the Solid Production Mechanism of the Fractured Granite Reservoirs-Example of YL Area in Qiongdongnan Basin
February 21, 2023 (v1)
Subject: Optimization
Keywords: fracture, fracture filling, fractured reservoir, granite buried hill reservoir, shear slip, solid production
The granite buried hill gas reservoir in YL area of Qiongdongnan basin faces a serious problem of solid production, which seriously affects gas well production and reduces economic benefits; however, the solid production mechanism of fractured granite reservoirs is still unclear. In this study, the reasons for solid production were revealed and the mechanism was clarified based on the analysis of geological and mechanical characteristics of the granite buried hill reservoir. The solid production of fractured granite reservoirs can be divided into three modes, those being shedding of fracture filling and solid particles on the fracture wall, shear slip failure along the fracture, and shear failure of granite matrix. Take the YL area in the Qiongdongnan Basin as an example, the solid production of fractured granite reservoirs is mainly based on shedding of fracture filling and solid particles on the fracture wall and shear slip failure along the fracture, the possibility of shear failure... [more]
35642. LAPSE:2023.1263
Diversity and Metabolic Potential of a PAH-Degrading Bacterial Consortium in Technogenically Contaminated Haplic Chernozem, Southern Russia
February 21, 2023 (v1)
Subject: Biosystems
Keywords: anthropogenic impact, long-term contamination, metagenomics, microbial communities, PAH-degrading bacteria, PAHs
Polycyclic aromatic hydrocarbons (PAHs) are chemically recalcitrant carcinogenic and mutagenic compounds with primarily anthropogenic origin. The investigation of the effects of emissions from energy enterprises on soil microbiomes is of a high priority for modern soil science. In this study, metagenomic profiling of technogenic contaminated soils was carried out based on bioinformatic analysis of shotgun metagenome data with PAH-degrading genes identification. The use of prokaryotic consortia has been often used as one of the bio-remediation approaches to degrade PAHs with different molecular weight. Since the process of PAH degradation predominantly includes non-culturable or yet-to-be cultured species, metagenomic approaches are highly recommended for studying the composition and metabolic abilities of microbial communities. In this study, whole metagenome shotgun sequencing of DNA from two soils with varying PAH levels was performed. In the control site, the total content of 12 pri... [more]
35643. LAPSE:2023.1262
Chemical Analysis and Quality Assessment of Honey Obtained from Different Sources
February 21, 2023 (v1)
Subject: Biosystems
Keywords: acidity, carbohydrates, honey, metals, protein
The purpose of this paper was to evaluate the quality of bee honey from different sources: beekeeper, local market and organic honey. Sensory analysis was performed and the water content, pH, acidity, protein content and total metal content (Cu, Cr, Mn, Co, Ni, Pb, Cd, Fe) were determined. The sensory analysis was carried out by a group of untrained panelists for quality assessment of honey. The metal content was determined by graphite atomic absorption spectrometry (GTAAS). Mineralization was carried out in a microwave digestion system, in a high-pressure polytetrafluoroethylene (PTFE) vessel, using a standard acid-digestion protocol. The results regarding the physico-chemical parameters showed that the honey samples were in accordance with the quality regulations for honey as a commercial product. The concentration of metals in the investigated honey samples varied in the order Cu > Cr > Pb > Fe > Ni > Mn > Co > Cd, the values being within the limits established by the EU Commission... [more]
35644. LAPSE:2023.1261
Hypoglycemic Effect and Experimental Validation of Scutellariae Radix based on Network Pharmacology and Molecular Docking
February 21, 2023 (v1)
Subject: Biosystems
Keywords: active ingredient, molecular docking, network pharmacology, Scutellariae Radix, target
Scutellariae Radix (SR) is a well-known traditional herb that has good pharmacological effects against diabetes. However, the mechanism of SR against diabetes is not clear. In this study, the ingredient−target−pathway relationship and hypoglycemic effect of SR on diabetes were explored using network pharmacology, molecular docking and an animal experiment. The targets of SR and diabetes were mined. The selected targets were studied using Gene Ontology (GO) enrichment analysis and pathway enrichment analysis. The network of active components, targets and pathways was integrated to analyze the ingredient−target−pathway relationship. Then, the correspondence between the active components and targets was verified using molecular docking. Finally, an animal experiment was used to verify the hypoglycemic effect of SR. There were 52 components and 22 targets for the hypoglycemic effect of SR. We identified 18 biological processes, 9 cellular components, 15 molecular functions and 25 signaling... [more]
35645. LAPSE:2023.1260
Anaerobic Digestion of the Residue (Combination of Wastewater and Solid Waste) from a New Olive-Oil Manufacturing Process Based on an Olive Cold-Pressing System: Kinetic Approach and Process Performance
February 21, 2023 (v1)
Subject: Process Control
Keywords: anaerobic digestion, cold-pressing olive-oil manufacturing process, kinetics, mixture waste, process performance, wastewater and solid waste
This research evaluates the anaerobic digestion (AD) process of the residue generated in a new olive-oil manufacturing process for cold-pressed olive, a residue consisting of a mixture of the wastewater and solid waste obtained from this process. Additionally, in order to assess the possible influence of the level of ripening of the olives on the performance of anaerobic processing, olives of the Picual variety were collected at two stages, i.e., green olives and olives in veraison. The AD processes of the residues obtained from the cold-pressing process and the process without pressure (control) were comparatively assessed by means of biochemical methane potential (BMP) assays conducted at mesophilic temperature (35 ± 1 °C). Maximum values for methane yield (390 ± 1 NL CH4/kg VSadded) and biodegradability (84.5%) were obtained from the cold-pressed green olive residues. For the rest of the wastes studied, biodegradability also reached high values, ranging from 79.1 to 79.6%. The logis... [more]
35646. LAPSE:2023.1259
Dysregulation of Mir-193B and Mir-376A as a Biomarker of Prediabetes in Offspring of Gestational Diabetic Mice
February 21, 2023 (v1)
Subject: Biosystems
Keywords: diabetic offspring, gestational diabetes, miR-193b, miR-376a, prediabetes markers’
Gestational diabetes mellitus (GDM) is a type of diabetes initiated during pregnancy and is characterized by maternal hyperglycemia that induces complications in mothers and children. In the current study, we used a GDM mouse model (through i.p. injection of a single dose of streptozocin, STZ, 60 mg/kg/bw) to investigate the biochemical and immunological changes in the blood and brain of diabetic mothers and their offspring relative to their appropriate controls. In addition, we estimated the expression levels of a set of microRNAs (miRNAs) to link between the dysregulation in the levels of miRNAs and the exposure to oxidative stress during embryonic development, as well as metabolic changes that occur after birth and during puberty in offspring (5-weeks-old). At the biochemical level, newborn pups appeared mostly to suffer from the same oxidative stress conditions of their mothers as shown by the significant increase in nitric oxide (NO) and malondialdehyde (MDA) in blood and brain of... [more]
35647. LAPSE:2023.1258
Study of the Possibilities of Improving Maintenance of Technological Equipment Subject to Wear
February 21, 2023 (v1)
Subject: Planning & Scheduling
Keywords: maintenance, reliability, repair planning, shearer machine, spare parts, wear
The rapid development of science and technology, and the restructuring of the mining extraction industry, bring about profound changes in the structure and complexity of technological equipment used in mining. In this paper, the Reliability Centered Maintenance (RCM) method has been applied to analyze the components of the KSW-460NE shearer machine, which fails quite frequently. The cutter drums do not match from a constructive point of view, and the concrete operation conditions, alongside the picks (being in direct contact with coal and hard inclusions) and guides are submitted to intense abrasion wear, showing a great number of failures. The data collected following the machine’s exploitation allowed parameter determination characterizing the reliability of the components mentioned, the manner of failure, and the effects. Using calculation methods, it has been possible to facilitate the interpretation of the result in view of establishing measures required to improve maintenance of... [more]
35648. LAPSE:2023.1257
Application of Stable Isotope Techniques in Tracing the Sources of Atmospheric NOX and Nitrate
February 21, 2023 (v1)
Subject: Environment
Keywords: atmospheric nitrate, nitrogen cycle, nitrogen oxide, stable isotope
Nitrate is an important component of PM2.5, and its dry deposition and wet deposition can have an impact on ecosystems. Nitrate in the atmosphere is mainly transformed by nitrogen oxides (NOX = NO + NO2) through a number of photochemical processes. For effective management of the atmosphere’s environment, it is crucial to understand the sources of atmospheric NOX and the processes that produce atmospheric nitrate. The stable isotope method is an effective analytical method for exploring the sources of NO3− in the atmosphere. This study discusses the range and causes of δ15N data from various sources of NOX emissions, provides the concepts of stable isotope techniques applied to NOX traceability, and introduces the use of Bayesian mixture models for the investigation of NOX sources. The combined application of δ15N and δ18O to determine the pathways of nitrate formation is summarized, and the contribution of Δ17O to the atmospheric nitrate formation pathway and the progress of combining... [more]
35649. LAPSE:2023.1256
Non-Inverting Quadratic Buck−Boost Converter with Common Ground Configuration for Supercapacitor Applications
February 21, 2023 (v1)
Subject: Process Design
Keywords: buck–boost, continuous current, DC–DC, non-inverting, supercapacitor, wide range converter
This article presents a novel buck−boost converter-based topology suitable for supercapacitors and grid-connected solar PV system applications. The proposed converter can handle a wide range of voltage variations at the input side, making it ideal for extracting most of the energy from supercapacitors or a solar PV system connected to the input side of the converter. The output voltage of the converter is non-inverting which makes the control easier. The design of passive components, continuous mode operation, and discontinuous mode operation are all thoroughly discussed. A low-power hardware prototype of three hundred watts is developed and tested in the laboratory to validate the theoretical aspects of the converter.
35650. LAPSE:2023.1255
Investigation of Low Cycle Fatigue Behaviors of Inertia-Friction-Welded Joints of the TC21 Titanium Alloy
February 21, 2023 (v1)
Subject: Materials
Keywords: inertia friction welding, low cycle fatigue, mechanical properties, microhardness, TC21 titanium alloy
As a new highly damage-tolerant structural material, the TC21 titanium alloy has been widely used in aerospace applications. Inertial friction welding (IFW) is a form of pressure welding technology with less welding parameters and high welding joint performance, which is especially suitable for the connection of rotors of aero-compressors and engines. In this paper, inertia friction welding of TC21 titanium alloys was successfully carried out, and the microhardness, tensile properties and low cycle fatigue (LCF) behaviors of IFW joints were studied. Based on the mechanical parametric results of the tensile test, the true stress−strain curves of the IFW joint of TC21 titanium alloys are obtained by further calculation. Based on the LCF test results under different strain amplitudes, life prediction of IFW joints was investigated. The results of the LCF test show that there is no obvious cyclic hardening and cyclic softening of the IFW joints. Moreover, the fracture morphology of LCF sam... [more]
35651. LAPSE:2023.1254
Research on Process of SCV Flue Gas Carbon Capture Based on LNG Cold Energy
February 21, 2023 (v1)
Subject: Energy Systems
Keywords: Carbon Capture, exergy analysis, LNG cold energy, parametric analysis, SCV
Under the guidance of China’s goal of achieving carbon neutrality by 2060, the petrochemical industry is increasingly adopting energy-saving and emission-reduction technologies. To realize the low carbon operation of the LNG (liquefied natural gas) receiving terminal, an innovative SCV (submerged combustion vaporizer) flue gas carbon capture system using LNG cold energy was established, and the system also combined with an ORC (organic Rankine cycle). HYSYS software was used to simulate the process of the SCV flue gas carbon capture system and the LNG regasification system. The simulation results showed that the proposed system has low carbon emission and low energy consumption performance. Moreover, the sensitivity analysis of the evaporation pressure of working fluids, CO2 capture pressure, and CO2 capture temperature was carried out. The key parameters were optimized by HYSYS software to achieve the optimal operation cost of the system. When the evaporation pressure of working fluid... [more]
35652. LAPSE:2023.1253
Applicability of Convolutional Neural Network for Estimation of Turbulent Diffusion Distance from Source Point
February 21, 2023 (v1)
Subject: Numerical Methods and Statistics
Keywords: convolutional neural network, estimating diffusion source distance, leaking gas detection, Machine Learning, passive scalar, turbulence
For locating the source of leaking gas in various engineering fields, several issues remain in the immediate estimation of the location of diffusion sources from limited observation data, because of the nonlinearity of turbulence. This study investigated the practical applicability of diffusion source-location prediction using a convolutional neural network (CNN) from leaking gas instantaneous distribution images captured by infrared cameras. We performed direct numerical simulation of a turbulent flow past a cylinder to provide training and test images, which are scalar concentration distribution fields integrated along the view direction, mimicking actual camera images. We discussed the effects of the direction in which the leaking gas flows into the camera’s view and the distance between the camera and the leaking gas on the accuracy of inference. A single learner created by all images provided an inference accuracy exceeding 85%, regardless of the inflow direction or the distance b... [more]
35653. LAPSE:2023.1252
Vapor−Liquid Equilibria of Quaternary Systems of Interest for the Supercritical Antisolvent Process
February 21, 2023 (v1)
Subject: Process Design
Keywords: dimethyl sulfoxide, optical high-pressure cell, supercritical antisolvent precipitation, supercritical carbon dioxide, vapor–liquid equilibria
In the Supercritical Antisolvent process (SAS), the thermodynamic behavior of complex multicomponent systems can influence the particles’ morphology. However, due to the limited thermodynamic data for multicomponent systems, the effect of solutes is often neglected, and the system is considered as pseudo-binary. It has been demonstrated that the presence of a solute can significantly influence the thermodynamic behavior of the system. In particular, when the SAS process is adopted for the production of drug/polymer coprecipitated microparticles, the effect of both the drug and the polymer in the solvent/CO2 mixture should be considered. In this work, the effect of polyvinylpyrrolidone (PVP), used as the carrier, and of the liposoluble vitamins menadione (MEN) and α-tocopherol (TOC), as model drugs, was investigated as a deviation from the fundamental thermodynamic behavior of the DMSO/CO2 binary system. Vapor−liquid equilibria (VLE) were evaluated at 313 K, with a PVP concentration in... [more]
35654. LAPSE:2023.1251
Study on the Influence of Pressure Reduction and Chemical Injection on Hydrate Decomposition
February 21, 2023 (v1)
Subject: Energy Systems
Keywords: depressurization and chemical injection combined method, hydrate decomposition efficiency, hydrate recovery efficiency, natural gas hydrate
This study simulated seabed high pressure and low temperature conditions to synthesize natural gas hydrates, multi-stage depressurization mode mining hydrates as the blank group, and then carried out experimental research on the decomposition and mining efficiency of hydrates by depressurization and injection of different alcohols, inorganic salts, and different chemical agent concentrations. According to the experimental results, the chemical agent with the best decomposition efficiency is preferred; the results show that: the depressurization and injection of a certain mass concentration of chemical agents to exploit natural gas hydrate is more effective than pure depressurization to increase the instantaneous gas production rate. This is because depressurization combined with chemical injection can destroy the hydrate phase balance while effectively reducing the energy required for hydrate decomposition, thereby greatly improving the hydrate decomposition efficiency. Among them, dep... [more]
35655. LAPSE:2023.1250
Study on Three-Stage Counter-Current Water Washing Desalination Characteristics and Mechanism of High Chlorine Waste Incineration Fly Ash
February 21, 2023 (v1)
Subject: Process Design
Keywords: chlorine salt, dechlorination, desalination, hazard waste incineration fly ash, heavy metal, municipal solid waste incineration fly ash, water washing
The high chloride content of municipal solid waste incineration (MSWI) fly ash and hazardous waste incineration (HWI) fly ash has considerably affected their disposal. This study focused on investigating the three-stage counter-current (TSC) water-washing process to reduce the chlorine content efficiently under the premise of low water consumption. The liquid−solid ratio (LSR) and washing time were investigated, a chloride migration model was established, and the characteristics of the water-washing solution (WWS) and washed fly ash were investigated. The results showed that the dechlorination effect of TSC washing could reach more than 99% in a low liquid−solid ratio (LSR) of 2−4 kg/L. The most appropriate LSR and washing time were found to be around 3:1 L/kg and 15 min per stage, respectively. The concentration of Cl− in WWS reached over 90 g/L, which is very high among industrial saline wastewater. Some heavy metals were also contained in the WWS, and lead was the main heavy metal,... [more]
35656. LAPSE:2023.1249
Supporting Management Disciplines for Research and Development in Public Organizations
February 21, 2023 (v1)
Subject: Intelligent Systems
Keywords: innovation management (IM), knowledge management (KM), technology management (TM)
In practice, R&D in public organizations in developing countries is confronted with a variety of failures related to supporting management disciplines. The primary goal of this study is to address this issue through multiple-criteria decision making, which includes the DANP (DEMATEL-based ANP) approach. The DANP approach helps to resolve the classification issue that arises as a result of interdependence and feedback characteristics among the capabilities related to supporting management disciplines, allowing weak capabilities to be prioritized based on their interdependence. In the case of criteria weighting, the empirical result in terms of the degree of the net causal relationship had a greater influence on other criteria; however, in terms of dimensions, the technology management process capability had a greater significance on other dimensions, while the innovation management process capability had the least significance on other dimensions. The studies were based on relevant capa... [more]
35657. LAPSE:2023.1248
Effect of Acidic Hydrochar on Plastic Crude Oil Produced from Hydrothermal Liquefaction of Waste PVC
February 21, 2023 (v1)
Subject: Materials
Keywords: crude oil, hydrochar, hydrothermal liquefaction, subcritical water, waste plastics
In this study, the effect of hydrothermal liquefaction (HTL) of waste PVC was investigated in the presence of acidic hydrochar. The hydrochar was prepared by hydrothermal carbonization of pineapple waste at 250 °C and at 1 h in the presence of citric acid. Hydrochar was acidic, stable, and porous and contained acidic functional groups. Hydrochar was co-fed with PVC during HTL to enhance HTL conversion and quality of the plastic crude oil. HTL experiments were performed at 300−350 °C, 0.25−4 h of reaction times, and 0−20 wt% hydrochar-to-PVC ratio. The plastic crude oil was separated from the solid residue to evaluate HTL conversion and to analyze elemental compositions, boiling point distribution, alteration of chemical bonds, and chemical compositions. The results showed that acidic hydrochar enhances HTL conversion with a maximum value of 28.75 at 5 wt% hydrochar content at 350 °C and 0.5 h. Furthermore, plastic crude oils contained no chloride but contained significantly high carbon... [more]
35658. LAPSE:2023.1247
Power Control Strategy for Hybrid System Using Three-Level Converters for an Insulated Micro-Grid System Application
February 21, 2023 (v1)
Subject: Energy Systems
Keywords: energy management strategy, Energy Storage, micro-grid, Renewable and Sustainable Energy, three-level converter
This paper presents a simulation of an insulated micro-grid system based on the three-level converters control for energy management. Different renewable power sources (wind turbine and Photovoltaic (PV) energy systems) are used to energize the micro-grid. However, a battery energy storage system (BESS) and a variable diesel generator are also used to improve the reliability of the system. The contribution of this research is focused on the power control method based on improving the quality of energy transfer, mastering dynamic interactions and maximum energy production from renewable energies to reduce the fuel consumption by the diesel. Firstly, the proposed control model for each renewable energy was carried out through simulation in the environments of Matlab and Simulink to test the robustness and performance. The second part of this research is dedicated to managing the sharing of power between load, generators, and storage systems by extracting the references of power. The thre... [more]
35659. LAPSE:2023.1246
Design of Soft-Sensing Model for Alumina Concentration Based on Improved Deep Belief Network
February 21, 2023 (v1)
Subject: Optimization
Keywords: alumina concentration, aluminum electrolysis, empirical model decomposition, Particle Swarm Optimization, soft-sensing model
Alumina concentration is an important parameter in the production process of aluminum electrolysis. Due to the complex production environment in the industrial field and the complex physical and chemical reactions in the aluminum reduction cell, nowadays it is still unable to carry out online measurement and real-time monitoring. For solving this problem, a soft-sensing model of alumina concentration based on a deep belief network (DBN) is proposed. However, the soft-sensing model may have some limitations for different cells and different periodic working conditions such as local anode effect, pole changing, and bus lifting in the same cell. The empirical mode decomposition (EMD) and particle swarm optimization (PSO) with the DBN are combined, and an EMD−PSO−DBN method that can denoize and optimize the model structure is proposed. The simulation results show that the improved soft-sensing model improves the accuracy and universality of prediction.
35660. LAPSE:2023.1245
Improving the Efficiency and Antioxidant Activity of Essential Oil Extraction from Abies sachalinensis by Underwater Shockwave Pretreatment for the Construction of Low-Energy and Sustainable Essential Oil Extraction System
February 21, 2023 (v1)
Subject: Food & Agricultural Processes
Keywords: Abies sachalinensis essential oil, antioxidant activity, essential oil yield, underwater shockwave pretreatment
Essential oils (EOs) from Abies sachalinensis (Sakhalin fir), a conifer species found in Sakhalin Island and Hokkaido in Japan, effectively remove nitrogen dioxide and possess antifungal activity. EOs also exert a relaxing effect and enhance air quality. Underwater shock waves generate instantaneous high pressure that ruptures cell walls, enhancing the performance of steam distillation and oil extraction. In this study, we aimed to increase the yield and quality of A. sachalinensis extracts using shockwaves. Leaves and branches were subjected to shockwave pretreatment or left untreated before EO extraction by steam distillation. EO yield of untreated dried leaves was 2.4 g/kg of dry leaf weight (DW). Upon application of a 3.0 kV, 3.6 kJ shockwave, the yield increased with the number of shockwave cycles. After ten cycles, yield increased 13.6-fold. Pretreatment with shockwaves for 10 cycles resulted in approximately 6- and 13-fold reductions in total energy consumption relative to fresh... [more]
35661. LAPSE:2023.1244
Synthesis, Hydration Processes and Ionic Conductivity of Novel Gadolinium-Doped Ceramic Materials Based on Layered Perovskite BaLa2In2O7 for Electrochemical Purposes
February 21, 2023 (v1)
Subject: Materials
Keywords: BaLa2In2O7, layered perovskite, proton conductivity, Ruddlesden-Popper structure
The search for novel highly effective materials with target properties for different electrochemical purposes is active for now. Ceramic materials with high levels of ionic conductivity can be applied as electrolytic materials in solid oxide fuel cells and in electrolyzers. Layered perovskites are a novel class of ionic conductors demonstrating almost-pure proton transportation at mid-temperatures. Gadolinium-doped ceramic materials based on layered perovskite BaLa2In2O7 were obtained and investigated for the first time in this study. The effect of the dopant concentrations on the hydration processes and on ionic conductivity was revealed. It was shown that compositions 0 ≤ x ≤ 0.15 of BaLa2−xGdxIn2O7 exhibited proton conductivity when under wet air and at mid-temperatures (lower than ~450 °C). Gadolinium doping led to an increase in the conductivity values up to an order of magnitude of ~0.5. The protonic conductivity of the most conductive composition BaLa1.85Gd0.15In2O7 was 2.7∙10−6... [more]
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