The aim of the study was to determine the effect of the method and temperature of the sublimation, vacuum and convective drying process on the kinetics of dehydration of the Moldovan dragonhead leaves, as well as on the physical and chemical properties, such as color coordinates, total content of phenolic compounds, antioxidant capacity, total monomeric anthocyanins content, total flavonoids content and content of essential oils. It was shown that the kinetics of the sublimation and vacuum drying process are best described by the logarithmic and Page models. Sublimation and vacuum drying were characterized by comparable process times. An increase in drying temperature caused a decrease in the content of phenolic compounds and antioxidant activity of the dried material and a significant change in the composition of essential oils. The lowest brightness of the dried material and the lowest color saturation was found after sublimation drying at 20 °C. The highest dried material quality wa... [more]

This tutorial and review of multi-objective optimization (MOO) gives a detailed explanation of the 5 steps to create, solve, and then select the optimum result. Unlike single-objective optimization, the fifth step of selection or ranking of solutions is often overlooked by the authors of papers dealing with MOO applications. It is necessary to undertake a multi-criteria analysis to choose the best solution. A review of the recent publications using MOO for chemical process engineering problems shows a doubling of publications between 2016 and 2019. MOO applications in the energy area have seen a steady increase of over 20% annually over the last 10 years. The three key methods for solving MOO problems are presented in detail, and an emerging area of surrogate-assisted MOO is also described. The objectives used in MOO trade off conflicting requirements of a chemical engineering problem; these include fundamental criteria such as reaction yield or selectivity; economics; energy requireme... [more]

(1) Plants, due to their phytochemicals, have long been known for their pharmacological potential and medicinal value. Verjuice, the acidic juice of unripe green grape, is still poorly characterized in terms of its chemical composition and biological activities. (2) In this study, we characterized the chemical composition, antioxidant and antitumor potential of verjuice extract. Folin−Ciocalteu and aluminum chloride reagents were used to identify the total phenol and total flavonoid composition. Various conventional methods were used to quantify the alkaloids and tannins. DPPH (2,2-diphenyl-1-picrylhydrazyl) free radical scavenging assay and Neutral Red assay were used to assess the antioxidant and antitumor activities, respectively. (3) We showed that the verjuice extract contains alkaloids, tannins, and a high quantity of total flavonoids and total phenols. Besides its antioxidant activity, verjuice significantly repressed human pulmonary adenocarcinoma (A549) cells’ viability in bot... [more]

Due to the expanding concern on cleaner production and sustainable development aspects, a technology shift is needed for the hydrogen production, which is commonly derived from natural gas. This work aims to synthesise a large-scale bio-hydrogen network in which its feedstock, i.e., bio-methane, is originated from landfill gas and palm oil mill effluent (POME). Landfill gas goes through a biogas upgrader where high-purity bio-methane is produced, while POME is converted to bio-methane using anaerobic digestor (AD). The generated bio-methane is then distributed to the corresponding hydrogen sink (e.g., oil refinery) through pipelines, and subsequently converted into hydrogen via steam methane reforming (SMR) process. In this work, P-graph framework is used to determine a supply network with minimum cost, while ensuring the hydrogen demands are satisfied. Two case studies in the West and East Coasts of Peninsular Malaysia are used to illustrate the feasibility of the proposed model. In C... [more]

Batch ozonation was performed to assess its efficacy as a pretreatment for reverse osmosis (RO) membranes for treating leachate with high concentrations of recalcitrant organic compounds. Leachate samples from two different landfills were collected and characterized. The modified fouling index (MFI) was used to estimate the fouling potential of raw and ozonized leachates. A response surface experimental design was applied to optimize operational pH and ozone dose. The results demonstrate that the best operational conditions are 1.5 g/L of O3 at pH 12.0 and 1.5 g/L of O3 at pH 9.0 for Landfills 1 and 2, which reduce MFI by 96.22% and 94.08%, respectively. Additionally, they show toxicity factor decays of 98.44% for Landfill 1 and 93.75% for Landfill 2. These results, along with the similar behavior shown by leachate samples from distinct landfills, suggest that ozonation is a promising technology to fit this kind of wastewater into the requirements of RO membranes, enabling their use in... [more]

Owing to their peculiar structural characteristics and potential applications in various fields, the ultrathin MoS2 nanosheets, a typical two-dimensional material, have attracted numerous attentions. In this paper, a hybrid strategy with combination of quenching process and liquid-based exfoliation was employed to fabricate the ultrathin MoS2 nanosheets (MoS2 NS). The obtained MoS2 NS still maintained hexagonal phase (2H-MoS2) and exhibited evident thin layer-structure (1−2 layers) with inconspicuous wrinkle. Besides, the MoS2 NS dispersion showed excellent stability (over 60 days) and high concentration (0.65 ± 0.04 mg mL−1). The MoS2 NS dispersion also displayed evident optical properties, with two characteristic peaks at 615 and 670 nm, and could be quantitatively analyzed with the absorbance at 615 nm in the range of 0.01−0.5 mg mL−1. The adsorption experiments showed that the as-prepared MoS2 NS also exhibited remarkable adsorption performance on the dyes (344.8 and 123.5 mg g−1 o... [more]

The aim of this study was preparation of new derivatives based on 2-((4-chlorophenoxy)methyl)-N-(arylcarbamothioyl)benzamide structure; the new compounds were characterized by IR, NMR (1H, 13C) spectroscopy, and elemental analysis. The obtained compounds were evaluated for their in vitro antimicrobial activity against planktonic and biofilm-embedded microbial cells (Staphylococcus aureus, Enterococcus faecalis, Escherichia coli, Pseudomonas aeruginosa, Candida albicans), by qualitative and quantitative assays. Some of the compounds revealed promising antibacterial and antifungal activities, with low minimum inhibitory concentration values between 0.15 and 2.5 mg/mL and minimal biofilm eradication concentrations of 0.019−2.5 mg/mL. To investigate the potential target of their antibacterial activity, in silico drug-likeness and molecular docking screenings on Staphylococcus aureus DNA gyrase were performed. The compound with the best antibacterial activity (1g) was docked into topoisomer... [more]

The catalytic activity of the partial oxidation reforming reaction for hydrogen production over 10% Ni supported on high and low surface area alumina and zirconia was investigated. The reforming reactions, under atmospheric pressure, were performed with a feed molar ratio of CH4/O2 = 2.0. The reaction temperature was set to 450−650 °C. The catalytic activity, stability, and carbon formation were determined via TGA, TPO, Raman, and H2 yield. The catalysts were calcined at 600 and 800 °C. The catalysts were prepared via the wet-impregnation method. Various characterizations were conducted using BET, XRD, TPR, TGA, TPD, TPO, and Raman. The highest methane conversion (90%) and hydrogen yield (72%) were obtained at a 650 °C reaction temperature using Ni-Al-H-600, which also showed the highest stability for the ranges of the reaction temperatures investigated. Indeed, the time-on-stream for 7 h of the Ni-Al-H-600 catalyst displayed high activity and a stable profile when the reaction tempera... [more]

PET/PTT bicomponent filaments yarn is produced by two polymers: the polyethylene terephthalate (PET) and the polytrimethylene terephtalate (PTT) extruded side by side. This yarn is known for its high mechanical properties in particular elasticity and elastic recovery. However, differences between physical and chemical properties of the two components make the dyeing step of this yarn complicated. The aim of this work is the development of a dyeing process for bicomponent filaments without altering their physical and chemical properties. Different techniques such as SEM, FTIR, and differential scanning calorimetry (DSC) were used to characterize the studied yarn. For dyeing, three different disperse dyes CI Disperse Red 167.1, CI Disperse Yellow 211, and CI Disperse Red 60 with different energy classes were studied. The influence of dyeing conditions in particular dyeing temperature, pH of dye bath, dyeing time, and carrier concentration in the dye bath was evaluated. Responses analyzed... [more]

Poultry litter is one type of biomass and waste generated from the farming process. This study performed a performance and process analysis of poultry litter to energy using the lab-scale shell and tube heat exchanger (STHE) system along with a Stirling engine and a swirling fluidized bed combustor (SFBC). The effects of tube shape, flow direction, and water flow rates on water and trailer temperature changes were investigated during the poultry litter co-combustion process. Energy flow analysis and emissions were also studied. Results showed that the water outlet temperature of 62.8 ° C in the twisted tube was higher than the straight tube case (58.3 ° C ) after 130 min of the co-combustion process. It was found that the counter-current direction had higher water temperature changes, higher logarithmic mean temperature difference (LMTD), and higher trailer temperature changes than the co-current direction. A water flow rate of 4.54 L/min showed adequate heat absorption... [more]

The purpose of this work is to develop a strategy for the surface modification of Bombyx mori silk fibroin (SF) film, via a thiol-ene click reaction, in order to expand its potential applicability. To achieve this goal, terminal thiol groups, from reduced glutathione, were introduced onto the surface of the SF film via a carbodiimide coupling reaction. These immobilized thiol groups act as robust crosslinkers and allow us to rapidly functionalize the surface with alkene group-containing molecules via ultraviolet (UV) light-initiated thiol-ene click chemistry. The X-ray photoelectron spectroscopy results specifically determined that alkene group-containing molecules and UV illumination are required for the thiol-ene click modification to take place on thiolated SF films. Fourier-transform infrared spectroscopy characterization of SF films indicated that the β-sheet conformation of SF was hampered throughout the modification process. Furthermore, it was found that the processes for thiol... [more]

Solid oxide fuel cells (SOFCs) are a promising next-generation technology for power production from fossil fuels. Because they convert chemical energy into electricity electrochemically, they are generally more efficient than combustion-based power plants due to the thermodynamic limitations of combustion cycles, and accordingly, have lower carbon intensities [1]. However, one of the main drawbacks of SOFCs (and SOFC stacks) is that they can degrade over time in a variety of ways, including accruing damage to the anode, cathode, interconnects, and other cell or stack components. SOFCs are most commonly used in “constant power” mode, in which the fuel flow rate and current density are increased over time to counteract the degradation effects and yield a constant power output. However, higher flow rates cause the degradation rates to grow even faster, resulting in a lifetime potentially as short as 1.5 years [2].

Recent research has found that by operating in “constant voltage” mode,... [more]

This study assessed a variable flow rate control method for a circulation pump based on the geothermal water temperature difference in a geothermal heat pump system. As interest in energy conservation and efficient use is increasing around the world, the development and use of renewable energy is increasing and various related studies are currently underway. Among the renewable energy systems, the interest in geothermal energy system is high because of its efficient year-round operation. Geothermal heat pump system installations have increased in number, but the systems operate inefficiently. Generally in Korea, geothermal heat pump system operates under partial load conditions, but the circulation pump operates at constant speed and supplies a constant flow rate. Therefore, this study examined the operation of the current problems of a geothermal heat pump system. A variable flow rate control method of the circulation pump is proposed to improve the efficiency of the geothermal heat p... [more]

In this paper, a small-area and high-efficiency single-inductor multiple output (SIMO) boost converter with digital pulse-width modulation (DPWM) is proposed. The DPWM comprises a delay line using interlaced hysteresis delay cells (IHDCs) that occupy a small area while consuming a low power amount. These proposed IHDCs are applied to replace the conventional delay cells of the prior works for both the power and area reductions. Regarding the DC-DC converter, this technique comprises fewer digital blocks in the feedback path compared with the conventional DC-DC converter, and the DPWM architecture uses IHDCs. The purpose of the digital limiter block is to concede some helpful code for the DPWM. The IHDC topology used for delay in DPWM is of the simplest architecture. The high-side power switch gate drivers need individual phases which are generated by phase control. The Complementary Metal Oxide Semiconductor (CMOS)-fabrication process is 55 nm, with a standard supply voltage of 1.8 V a... [more]

Both computational performances and energy efficiency are required for the development of any mobile or embedded information processing system. The Internet of Things (IoT) is the latest evolution of these systems, paving the way for advancements in ubiquitous computing. In a context in which a large amount of data is often analyzed and processed, it is mandatory to adapt node logic and processing capabilities with respect to the available energy resources. This paper investigates under which conditions a partially reconfigurable hardware accelerator can provide energy saving in complex processing tasks. The paper also presents a useful analysis of how the dynamic partial reconfiguration technique can be used to enable energy efficiency in a generic IoT node that exploits a Field Programmable Gate Array (FPGA) device. Furthermore, this work introduces a hardware infrastructure and new energy metrics tailored for the energy efficiency evaluation of the dynamic partial reconfiguration pr... [more]

The now over a decade-long electricity crisis in Pakistan has adversely affected the socio-economic development of the country. This situation is mainly due to a lack of sustainable energy planning and policy formulation. In this context, energy models can be of great help but only a handful of such efforts have been undertaken in Pakistan. Two key shortcomings pertaining to energy models lead to their low utilization in developing countries. First, the models do not effectively make decisions, but rather provide a set of alternatives based on modeling parameters; and secondly, the complexity of these models is often poorly understood by the decision makers. As such, in this study, the Analytical Hierarchy Process (AHP) methodology of Multi-Criteria Decision-Making (MCDM) has been used for the sustainability assessment of energy modeling results for long-term electricity planning. The four scenario alternatives developed in the energy modeling effort, Reference (REF), Renewable Energy... [more]

This study proposes an innovative installation concept for the sustainable utilization of sewage sludge. The aim of the study is to prove that existing devices and technologies allow construction of such an installation by integration of a dryer, torrefaction reactor and gasifier with engine, thus maximizing recovery of the waste heat by the installation. This study also presents the results of drying tests, performed at a commercial scale paddle dryer as well as detailed analysis of the torrefaction process of dried sewage sludge. Both tests aim to identify potential problems that could occur during the operation. The scarce literature studies published so far on the torrefaction of sewage sludge presents results from batch reactors, thus giving very limited data of the composition of the torgas. This study aims to cover that gap by presenting results from the torrefaction of sewage sludge in a continuously working, laboratory scale, isothermal rotary reactor. The study confirmed the... [more]

In order to support the future thermal control and energy conservation design for the Mars rover, numerical studies on natural convection in CO₂ enclosures on Mars’ surface were conducted for both horizontal and vertical enclosures. The parameters are as follows: the atmospheric pressure was 1000 Pa, the gravitational acceleration was 3.62 m/s², and the Prandtl number was 0.77. The heat flux, temperature, and velocity fields of the CO₂ enclosures were obtained with the aspect ratio ranging from 5.56 to 200 and the Grashof number ranging from 430 to 2.6 × 10⁴. It was found that natural convection formed more easily in the horizontal enclosures than that in the vertical enclosures when the enclosures had same thickness. With the increasing thickness of the enclosures, Rayleigh⁻Bénard convections formed in the horizontal enclosures, while only single-cell convections formed in the vertical enclosures. The heat flux through the horizontal enclosures was greater than that through the vertic... [more]

In this paper, an on-line parameter identification algorithm to iteratively compute the numerical values of inertia and load torque is proposed. Since inertia and load torque are strongly coupled variables due to the degenerate-rank problem, it is hard to estimate relatively accurate values for them in the cases such as when load torque variation presents or one cannot obtain a relatively accurate priori knowledge of inertia. This paper eliminates this problem and realizes ideal online inertia identification regardless of load condition and initial error. The algorithm in this paper integrates a full-order Kalman Observer and Recursive Least Squares, and introduces adaptive controllers to enhance the robustness. It has a better performance when iteratively computing load torque and moment of inertia. Theoretical sensitivity analysis of the proposed algorithm is conducted. Compared to traditional methods, the validity of the proposed algorithm is proved by simulation and experiment resu... [more]

Ecocities can provide solutions for the improvement of human settlements around the world and the living conditions therein, but in the authors’ experience, only as long as they are able to address the following questions correctly: How to formulate an ecocity concept that, considering issues of general concern, can be at the same time adapted to different local conditions? What are the instruments supporting the development and implementation of ecocity solutions? VTT’s EcoCity concept for sustainable community and neighbourhood regeneration and development has been designed in response to the first question. Likewise, specific methodologies and effective facilitation processes and skills have been developed in response to the second question. Since the methodologies have been discussed in a previous scientific article, the present one focuses on the facilitation processes and skills, and also on other related, fundamental aspects like participation, adaptation, capacity building, etc... [more]

Large electric superconducting machines are being sought to solve emissions challenges in aircraft and provide a solution to >12 MW wind turbine electricity generation. Superconducting motors with only high temperature superconducting (HTS) armatures can offer advantages of high reliability, high power density, and high efficiency compared with conventional superconducting motors. In this paper, a novel HTS squirrel-cage induction motor is proposed for high speed operation, which adopts the structure of HTS windings with a certain inclination angle in the stator slots. Due to the limitation of curvature radius of superconducting tapes, the pitch of HTS windings can be only set to 1 and adopt the short pitch arrangement structure, which such design details of the HTS motor would ensure the superconducting coils can undertake larger current and reduce AC losses. In order to keep the HTS windings in superconducting state and larger current density, a special fixed cryogenic cooling system... [more]

Energy retrofitting of the housing stock is a priority in current regulatory standards as a means of reducing energy consumption. The strategies used in retrofitting housing stock ought to respond both to regulatory conditions and to two challenges: specific climate conditions and the improvement of comfort conditions. These issues are especially important in the warmer regions of the Mediterranean, and will be even more so in the future due to climate change. The aim of this paper is to assess the influence that the improvement of facade insulation and the use of ventilation have on the existing housing stock. To do so, an energy evaluation is conducted using on-site monitoring of free-running conditions in test cells reproducing a residential room, both in current condition and with the retrofitted proposal, in Seville (Spain). The results obtained show limited improvement of the facade insulation when outdoor temperatures are high, as well as the influence of ventilation, mainly noc... [more]

Coal continues to dominate in the structure of the heat production system in some European countries. Coal-fired boilers in district heating and power generation systems are accompanied by the formation of large quantities of slag and ash. Due to considerable high temperature, slag may be used as a source of waste energy. In this study, the technical possibilities of recovery slag’s physical enthalpy from grate-fired district heating boiler of 45 MW thermal capacity are analyzed. The aim of the work is to estimate the waste energy potential of the slag in analyzed boiler and proposition of the heat recovery system. The construction and design of the existing deslagging system was examined. Studies have shown that high water temperature accelerates system wear. Recovering heat from this system decreases the water temperature, which extends the trouble-free working time. The slag parameters were determined, including the temperature at the outlet of the boiler and the temperature after l... [more]

The increasing demand for miniaturized radio-controlled vehicles inspired the following research. The uses of these unmanned miniaturized/micro vehicles range from aero-modeling to drones for urban control and military applications too. The common characteristic of these vehicles is the need for a light and compact propulsion system. The radio-controlled (RC) turbines for modeling are ideally suited for this purpose, guaranteeing the necessary thrust with compactness and lightness. This device is a miniaturized turbojet, and it is generally composed of three basic elements: compressor, combustion chamber and turbine. The main goal of the paper is to evaluate the turbojet performance for considering the possibility of its use as a range extender in a hybrid vehicle. Considering the total volume constraints, it will be important to evaluate the specific fuel consumption. Also from the environmental point of view, the possibility of feeding the device with gas has been considered and, con... [more]

The aim of this paper is to conduct a generalised assessment of both optimal working fluids and radial turbine designs for small-scale organic Rankine cycle (ORC) systems across a range of heat-source temperatures. The former has been achieved by coupling a thermodynamic model of subcritical, non-recperated cycles with the Peng⁻Robinson equation of state, and optimising the working-fluid and cycle parameters for heat-source temperatures ranging between 80 ° C and 360 ° C . The critical temperature of the working fluid is found to be an important parameter governing working-fluid selection. Moreover, a linear correlation between heat-source temperature and the optimal critical temperature that achieves maximum power output has been found for heat-source temperatures below 300 ° C ( T cr = 0.830 T hi + 41.27 ). This correlation has been validated against cycle calculations completed for nine predefined working fluids using both the Peng⁻Robinson equation... [more]