More rigorous environmental rules on hazardous metals release require the implementation of diverse methods to remove them from contaminated streams. The adsorption process is the most attractive method for removal of toxic metal ions from different aqueous solutions. In the present study, batch and fixed bed column experiments were carried out to investigate the performance of permethylated β-cyclodextrin impregnated resin for the removal of As(V) ions from aqueous solutions. Sorption of As(V) ions was performed in groups under a variety of pH and metal concentrations. It was noted that removal efficiency was the highest (98%) at pH 6.0, and at an initial As(V) concentration equal to 0.1 mg/L. Sorption model use for experimental data indicates that the removal mechanism of As(V) by the permethylated β-cyclodextrin impregnated resin was the physical sorption. The adsorption capacity of the cyclodextrin ligand immobilized onto Amberlite XAD-4 resin was 19 mg/g. In addition, the impregna... [more]

Here, we report a new two-step enzymatic polymerization strategy for the synthesis of poly(octamethylene suberate) (POS) using an immobilized Pseudozyma antarctica lipase B (IMM-PBLI). The strategy overcomes the lack of enzymatic POS synthesis in solvent-free systems and increases the final polymer molecular weight. In the first step, the direct polycondensation of suberic acid and 1,8-octanediol was catalyzed by IMM-PBLI at 45 °C, leading to the production of prepolymers with molecular weights (MWs) of 2800, 3400, and 4900 g mol−1 after 8 h in miniemulsion, water, and an organic solvent (cyclohexane: tetrahydrofuran 5:1 v/v), respectively. In the second polymerization step, wet prepolymers were incubated at 60 or 80 °C, at atmospheric pressure, in the presence of IMM-PBLI, and without stirring. The final POS polymers showed a significant increase in MW to 5000, 5800, and 19,800 g mol−1 (previously synthesized in miniemulsion, water, or organic solvent, respectively). FTIR analysis of... [more]

The trend of personalized medicine and the increasing flexibility of drug dosage relevant goals of the 21st century represent the foundation for the current research. To obtain doses smaller than the smallest available, physicians frequently write prescriptions for children and adults, without preserving the integrity of the pill. Moreover, patients purchase large amounts of medication for cost-saving reasons. To support the correct administration of the remedies and the partial alignment to the personalized treatment trend, this paper proposes a flexible and user-friendly solution for determining the medication quantity given to patients, using augmented reality and optical character recognition algorithm capabilities. Via the MATLAB development environment and a Logitech HD Pro C920 webcam, the results were 80% correct in identifying the cutting position of the pill, by means of the Hough transform, and 30% correct in weight recognition exploitation using an optical character recogni... [more]

The protection of human health and the environment (representing the main reason for waste management), as well as the sustainable use of natural resources, requires chemical, biological, physical and thermal treatment of wastes [...]

To study the distribution characteristics of typical pollutants in soil aggregates using different sieving methods, urban and arable soils were collected from Beijing and separated to different sizes by dry and wet sieving methods, to analyze present concentrations of inorganic chlorine and nine typical heavy metals (Cr, Mn, Co, Ni, Cu, Zn, Cd, As, and Pb). Results revealed that the distribution of wet-sieved aggregates was biased towards microaggregates (<250 μm), while the contrary result was found for the dry sieving method. Inorganic chlorine was more likely to be enriched in <53 μm fractions attained by both sieving methods. However, the content of inorganic chlorine in wet-sieved aggregates was significantly lower than in those that were dry sieved, which means the water’s effect on soluble ions was more pronounced. Heavy metals in urban soils were preferentially enriched in microaggregates no matter what kind of sieving method was applied. As for Mn and As found in agricul... [more]

Water hyacinth (WH) is a free-floating perennial aquatic plant that is considered a pest, due to its rapid grown rate and detrimental effects on environment and human health. It is nearly impossible to control WH growth, with mechanical extraction being the most acceptable control method; nevertheless, it is costly and labor-intensive. WH lignocellulosic biomass represents a desirable feedstock for the sustainable production of liquid fuels and chemical products. In this work, optimal conditions of thermochemical pretreatment for the release of reducing sugars (RS) from WH biomass were established: 0.15 mm of particle size, 50 g of dried solid/L of H2SO4 (3% w/v) and 20 min of heating time at 121 °C. Applying this pretreatment, a conversion of 84.12% of the hemicellulose fraction in the raw WH biomass into reducing sugars (277 ± 1.40 mg RS/g DWH) was reached. The resulting pretreated biomass of WH (PBWH) was enzymatically hydrolyzed by using six enzymatic complexes (all from Novozymes)... [more]

Biochar application in the agriculture sector is a practical approach to minimize waste and maintain sustainable farming. However, the information regarding biochar application in tea cultivation is limited and especially rare in field research. In this study, a two-year biochar experiment was conducted in a tea yard subject to tea yield and soil characteristics. According to tea growth, the tea yard for the experiment was divided into weak and normal sectors. Biochar was made from tea processing waste, mainly the twigs. The results showed that biochar application increased tea production by 2.3- and 1.3-fold in the weak and normal sectors, respectively, suggesting that converting tea waste to biochar for soil amendment is beneficial to increasing tea production, particularly in the weak sector. The regression analysis on tea production and soil characteristics revealed that only soil electric conductivity (R2 = 0.6597), soil organic matter (R2 = 0.7024), and soil extractable phosphate... [more]

This study used the EGSB and IC reactors to treat the high-salt and high-concentration organic wastewater (high-salt fatty acid production wastewater) and compared their performances The experimental results showed that the optimal influent water quality thresholds for both bioreactors to treat this wastewater were a COD concentration of 18,000 mg/L and a sulfate ion concentration of about 8000 mg/L. The reactor operated well when C/S was greater than 2.8. In addition, the value of C/S should not be less than 1.5. This is due to that under this condition, the sulfate reduction process has a significant impact on the removal of COD, and MPB may be inhibited by sulfides. The organic load OLR should not be greater than 10 kgCOD/(m3·d). It was also found that the start-up time of the IC reactor with external circulation was slightly shorter, and the COD removal effect, gas production rate, and load tolerance were slightly better than those of the EGSB reactor, the best reflux ratio of the... [more]

A degradation study of diazepam (DZP) in aqueous media by gamma radiation, high frequency ultrasound, and UV radiation (artificial-solar), as well with each process intensified with oxidizing agents (H2O2 and Fenton reagent) was performed. The parameters that influence the degradation of diazepam such as potency and frequency, irradiation dose, pH and concentration of the oxidizing agents used were studied. Gamma radiation was performed in a 60Co source irradiator; an 11 W lamp was used for artificial UV radiation, and sonification was performed at frequency values of 580 and 862 kHz with varying power values. In the radiolysis a 100% degradation was obtained at 2500 Gy. For the sonolysis, 28.3% degradation was achieved after 180 min at 862 kHz frequency and 30 W power. In artificial photolysis, a 38.2% degradation was obtained after 300 min of UV exposure. The intensification of each process with H2O2 increased the degradation of the drug. However, the best results were obtained by co... [more]

Several factors affect how particulate matter and gaseous emissions are formed during the combustion processes of biomass. The amount of combustion air, as well as its redistribution, is one of these factors. This article deals with the performance and emission parameters determined using different distributions of the amount of combustion air of the wood stove with beech wood as a fuel. Eighteen different settings of primary, secondary and tertiary air supplies were realized, while heat output, efficiency, particulate matter, carbon monoxide and nitrogen oxides were measured or determined. The aim of this article is to identify the optimal air distribution between primary, secondary, and tertiary air supplies focused on the mentioned parameters. Based on the results, two settings (25/50/25 and 0/100/0) could be the optimal variant. However, the concentration of particulate matter reached a higher value during the setting with a ratio of 25/50/25, similar to a ratio of 50/25/25. The me... [more]

This paper proposes a trading system (TS) based on a multicriteria decision aid (MCDA) process known as TODIM, (Multicriteria Interactive Decision Making) a Portuguese acronym for interactive and multicriteria decision-making. MCDA has been employed to solve financial questions because of its ability to deal with a complex environment populated with different sorts of criteria and alternatives, such as financial markets. The aim is to propose a general and adaptive tool for supporting the trading strategies of investors and market practitioners in such an environment. The reason for selecting TODIM among the different MCDA methods is that it is based on prospect theory, which assumes that the risk profile of the investor varies according to different situations, considering the risk of loss or gain. A list of simulations using some of the most prominent Brazilian stocks is performed, and the results are compared with the Buy-and-Hold benchmark and a TS based on an ensemble method for s... [more]

The pollution of aquatic ecosystems is a big problem that has its impact on river sediments. In recent decades, an effective solution to this problem has been the application of bioremediation technologies. Nanoremediation is an innovative part of these technologies. We still know little about the efficiency of nanoparticles, especially nanodiamonds, in modelled conditions. The aim of the present study is to investigate the effect of nanodiamonds on the key parameters of modelled bioremediation of river sediments that are polluted with phenol, as well their effect on the structures and functions of microbial communities. An important indicative mechanism that was used is the application of fluorescent in situ hybridization for sediment microbial communities. The results of this study revealed the positive role of nanodiamonds that is associated with their intoxication with high concentrations of phenol. Readaptation was also found, in which the xenobiotic biodegradation potential evolv... [more]

The intermittent heating mode of Kang plays an important role in the heat storage and release in cave dwellings. However, research on the effect of Kang heating on the thermal process of traditional buildings is rare. Therefore, based on long-term monitoring of cave dwellings, regular conclusions about the influence of Kang heating on the thermal environment were obtained. Furthermore, an unsteady heat transfer model of the envelope was proposed for the first time. Then, based on this model, the thermal storage performance of cave dwellings during the period of Kang intermittent heating was explored. The results showed that, due to Kang heating, the indoor air temperature of cave dwellings could be increased by an average of 3.1 °C. Furthermore, the inner walls had a large thermal mass and the maximum heat storage in a single day was 487.75 kJ/m2, while the maximum heat release was 419.02 kJ/m2. The heat release at night could reach 87%. In this paper, the law of thermal storage and re... [more]

Naphthalene (NAP) is a typical gaseous polycyclic aromatic hydrocarbons (PAHs) pollutant that displays toxicological effects on biosystems. Ordered mesoporous carbon has relatively adequate adsorption capacity; however, the attached hydrophilic functional groups were proven to affect the adsorption performance in the presence of moisture. In this paper, trimethylchlorosilane (TMCS) is used to carry out the hydrophobic modification of ordered mesoporous carbon FDU-15, and the adsorption and desorption properties of FDU-15 were studied. Furthermore, the adsorption isotherms of naphthalene on FDU-15 and modified FDU-15 were fitted by L-F equation, and the kinetic parameters of desorption of naphthalene on modified FDU-15 were analyzed based on the method of temperature programming desorption (TPD). The results showed that the micropore volume and specific surface area of FDU-15 were significantly increased after hydrophobically modified by TMCS, and the polar functional groups of the hydr... [more]

In the oil and gas industry, there has not been a consistent, concerted effort to reduce global greenhouse gas (GHG) emissions across the supply chain. In addressing this challenge, this study evaluates the potential GHG emissions reduction that may be realized through deployment of a geothermal power co-production system in two Colombian oil fields, compared to a base case where energy needs are derived through non-renewable sources such as gas and diesel. These geothermal power co-production systems make use of organic Rankine cycle (ORC) engines to convert the heat from produced oilfield fluids into electrical energy. The energy potential of this resource is evaluated through the exergy concept, and a life cycle analysis is implemented to calculate the carbon footprint using the Intergovernmental Panel on Climate Change (IPCC) 2013 methodology. In the two oil fields of interest, OFA and OFB, the results show a maximum potential energy production of 2260 kWe for OFA and 657 kWe for O... [more]

Throughout the last decades the developments on desalination field have been focused on energy consumption and costs reduction. However, water recovery and brine disposal are becoming a matter of concern to desalination industry. In this work, a Zero Liquid Discharge (ZLD) unit coupled with a Solar Micro Gas Turbine (SMGT) system is presented to address, among others, the challenges of mining industry in remote areas, in particular, fossil fuel dependence, water availability and pollution derived from effluents disposal. As a way to assess the feasibility of the proposal, a techno-economic analysis of the application in two Southern American regions (Chile and Ecuador) of photovoltaic modules, wind turbines and Solar Micro Gas Turbines is performed. Afterwards, the main novel feature of the new system—i.e., the ZLD unit—is described and a sensitivity analysis on its functioning whilst coupled with the SMGT is carried out. The aim is to propose a preliminary design of the ZLD process. T... [more]

The transformation of our linear “take-make-waste” system to a cyclic flow of materials and energy is a priority task for society, but the circular use of waste streams from one industry/sector as a material input for another must be completely safe. The need for new advanced technologies and methods ensuring both microbiological safety and the removal of potential chemical residues in used materials and products is urgent. Non-thermal atmospheric plasma (cold atmospheric plasma—CAP) has recently attracted great research interest as an alternative for operative solutions of problems related to safety and quality control. CAP is a powerful tool for the inactivation of different hazardous microorganisms and viruses, and the effective decontamination of surfaces and liquids has been demonstrated. Additionally, the plasma’s active components are strong oxidizers and their synergetic effect can lead to the degradation of toxic chemical compounds such as phenols and azo-dyes.

The problem of eliminating petroleum pollution and its consequences is currently very relevant for Kazakhstan, which is among the ten largest oil-producing countries. The specifics of natural conditions—the sharply continental arid climate—necessitate the development and application of adequate technologies for the restoration of oil-contaminated territories and the Caspian seashore. The key factors (temperature, moisture, alkalinity, salinity, low mineral and organic matter content) affect the self-purification processes and microbiological status of oil-contaminated soils of Kazakhstan. The assessment of taxonomic diversity and characteristics of oil-degrading microorganisms isolated from samples of soils and reservoirs contaminated with hydrocarbons are given. The review of biopreparations and biotechnologies developed and used in Kazakhstan for cleaning environments from oil pollution is made, and their effectiveness is shown. The analysis of the current state of research in the fi... [more]

Today’s customer no longer wants one-size-fits-all products but expects products and services to be as tailored as possible. Mass customization and personalization are becoming a trend in the digitalization strategy of enterprises and manufacturing in Industry 4.0. The purpose of the paper is to develop and validate a conceptual model for leveraging Industry 4.0 and digitalization to support product customization. We explored the implications and impacts of Industry 4.0 and digitalization on product customization processes and determine the importance of variables. We applied structural equation modeling (SEM) to test our hypotheses regarding the antecedents and consequences of digitalization and Industry 4.0. We estimated the process model using the partial least squares (PLS) method, and goodness of fit measures show acceptable values. The proposed model considers relationships between technology readiness, digitalization, internal and external integration, internal value chain, and... [more]

The filamentous fungus Penicillium canescens, isolated from oil-polluted soil, was evaluated for its ability to dissipate high-molecular-weight polycyclic aromatic hydrocarbons (PAH). The study was conducted in a microcosm containing 180 g of historical PAH-contaminated soil under non-sterile conditions with two incubation temperatures (14 °C and 18 °C) on a 12-h cycle. The experiment was conducted over 8 months, with four experimental conditions created by varying the volumes of the bulking agent and vegetable oil (olive oil) and the time of addition of these compounds. The PAH dissipation performance of the fungal augmentation treatment was compared with that achieved with a biostimulated soil (bulking agent and vegetable oil) and with the untreated soil as control. The greatest PAH dissipation was obtained with P. canescens bioaugmentation (35.71% ± 1.73), with 13 of the 16 US EPA PAH significantly dissipated, at rates above 18%, and particularly high-molecular-weight PAH, composed... [more]

In modern enterprises, all processes that are understood as structured activities intended for production, i [...]

The results obtained from the exergoeconomic and exergy analysis of a model of a generic air conditioning (A/C) system without and with an air membrane exchanger using three commercially available refrigerants: R410A, R407C, and R134a, are reported. The model used specialized software that was validated against recently published data and showed good agreement. A/C systems are energy intensive and consume a significant portion of global electricity. Improving their efficiency by even a small amount will produce considerable savings, reduce running costs, and lower pollution emissions. The efficiency of the same A/c system without and with a membrane was investigated for different ambient temperatures, relative humidities (RHs), and pressure ratios of the compressor. It was shown that the inclusion of a membrane improved the efficiency of the system for all three refrigerants tested, particularly at higher ambient temperature. Both the coefficient of performance and exergetic efficiency... [more]

This paper intends to propose options for climate neutrality concepts by taking non-German international experiences and decisions made into account. Asia-Pacific and Arabic countries do have already same lessons learned by large-scale projects with regard to economic evaluations. Quite a few conceptual studies to generate the climate neutrality of the chemical−pharmaceutical industry in Germany have been published recently. Most of the studies differ even in magnitude but do not refer to or evaluate the other ones. These are all first theoretical feasibility studies. Experimental piloting is not far developed; only few and only stand-alone parts are operated, with no overall concepts. Economic evaluation is missing nearly completely. Economic analysis shows a factor 3 more expensive green technologies. Even if a large optimization potential of about 30% during manufacturing optimization is assumed as significant, cost increases would result. To make green products nevertheless competi... [more]

Development and application of novel technologies in food processing is vital for ensuring the availability of adequate, safe, and convenient food with the desired quality and functional properties. Environmental and economic sustainability of technologies is essential prior to their application in the food processing sector. The objective of this research is to determine the environmental and economic feasibility of ultrasound-assisted extraction (UAE) for recovering functional food ingredients from seaweed. Experimental data is used to conduct a life cycle assessment (LCA) to investigate the environmental performance with a functional unit (FU) of obtaining 1 g of extracted polyphenols, measured as gallic acid equivalents (mg GAE)/g seaweed. A life cycle impact assessment is performed with ReCiPe 2016 at midpoint. The cost of manufacturing (COM) of phenolic-rich extracts (as functional ingredient, bioactive, or nutraceutical) is estimated using time-driven activity-based costing (TDA... [more]

Chlorination disinfection byproducts (CDBPs) can exert adverse human health effects. Many toxicology-based studies confirmed the health hazards of CDBPs, but little research has been done on gut microbiome. We explored the effect of CDBPs on intestinal microbiota in the Simulator of the Human Intestinal Microbial Ecosystem (SHIME). The results showed that CDBPs slightly inhibited the production of short-chain fatty acids, and the abundance of Actinobacteria decreased in the transverse colon and descending colon. The abundance of Proteobacteria increased in the ascending colon and descending colon, while it decreased in the transverse colon. The abundance of Firmicutes decreased in both the ascending colon and descending colon. In particular, the abundance of Lachnospiraceae members, Bilophila, Oscillospira, Parabacteroides, Desulfovibrio, and Roseburia increased in the ascending colon, while the abundance of Sutterella, Bacteroides, Escherichia, Phascolarctobacterium, Clostridium, Citr... [more]