We describe a new on-line sensitive and selective procedure for the determination of trivalent and hexavalent chromium in liquid samples by a tailor-made contactor (TMC), specifically a liquid membrane annular TMC, coupled with inductively coupled plasma with optical detection. The TMC was designed and developed to integrate the extraction and stripping phases of the analyte in one module to minimize the membrane solvent’s consumption and maximize the speed of transport through the liquid membrane. Moreover, the particular geometry studied, which consists of two coaxial hollow fibers, allows the TMC to be used for both separating and preconcentrating purposes. Both (−)-N-dodecyl-N-methylephedrinium bromide (30 mM) in dichloroethane and HNO3 (0.75 M) were used as the liquid membrane and receiving solution, respectively. The proposed method’s performance was evaluated in terms of the hexavalent chromium extraction efficiency and the coefficient of variation percentages; these were higher... [more]

This paper describes a procedure and an IT product that combine numerical models, expert knowledge, and data-based models through artificial intelligence (AI)-based hybrid models to enable the integrated control, optimization, and monitoring of processes and plants. The working principle of the hybrid model is demonstrated by NOx reduction through guided oscillating combustion at the pulverized fuel boiler pilot incineration plant at the Institute for Technical Chemistry, Karlsruhe Institute of Technology. The presented example refers to coal firing, but the approach can be easily applied to any other type of nitrogen-containing solid fuel. The need for a reduction in operation and maintenance costs for biomass-fired plants is huge, especially in the frame of emission reductions and, in the case of Germany, the potential loss of funding as a result of the Renewable Energy Law (Erneuerbare-Energien-Gesetz) for plants older than 20 years. Other social aspects, such as the departure of ex... [more]

Solar biomass gasification is an attractive pathway to promote biomass valorization while chemically storing intermittent solar energy into solar fuels. The economic feasibility of a solar gasification process at a large scale for centralized H2 production was assessed, based on the discounted cash-flow rate of return method to calculate the minimum H2 production cost. H2 production costs from solar-only, hybrid and conventional autothermal biomass gasification were evaluated under various economic scenarios. Considering a biomass reference cost of 0.1 €/kg, and a land cost of 12.9 €/m2, H2 minimum price was estimated at 2.99 €/kgH2 and 2.48 €/kgH2 for the allothermal and hybrid processes, respectively, against 2.25 €/kgH2 in the conventional process. A sensitivity study showed that a 50% reduction in the heliostats and solar tower costs, combined with a lower land cost of below 0.5 €/m2, allowed reaching an area of competitiveness where the three processes meet. Furthermore, an increa... [more]

Gasification of organic matter under the conditions of supercritical water (T > 374 °C, p > 221 bar) is an allothermal, continuous flow process suitable to convert materials with high moisture content (<20 wt.% dry matter) into a combustible gas. The gasification of organic matter with water as a solvent offers several benefits, particularly the omission of an energy-intensive drying process. The reactions are fast, and mean residence times inside the reactor are consequently low (less than 5 min). However, there are still various challenges to be met. The combination of high temperature and pressure and the low concentration of organic matter require a robust process design. Additionally, the low value of the feed and the product predestinate the process for decentralized applications, which is a challenge for the economics of an application. The present contribution summarizes the experience gained during more than 10 years of operation of the first dedicated pilot plant for super... [more]

Fluidization technology has found widespread applications for a variety of chemical and physical transformations since its introduction in the first half of the 1900s [...]

This study systematically established the most effective refining process for Moringa oleifera (MO) kernel oil. Acid degumming (20.33 ± 1.37 ppm) removed significantly greater phosphorus than water degumming (31.18 ± 0.90 ppm). Neutralization was more effective than deodorization in decreasing the acid (0.06 mg KOH/g) and p-Anisidine (p-AV, 0.36 ± 0.03) values of the oil. Besides improving its color properties, acid-activated bleaching earth Type B was better than Types A and C in decreasing the oil’s p-AV (0.43 ± 0.02), acid value (3.96 ± 0.02 mg KOH/g), and moisture content (0.01 ± 0.00% w/w). The selected refining stages successfully produced MO kernel oil with acceptable peroxide value (PV, 1.66−3.33 meq/kg), p-AV (1.05−1.49), total oxidation value (TOTOX, 4.38−8.15), acid value (0.03 mg KOH/g), moisture content (0.01% w/w), phosphorus content (1.28−1.94 ppm), iodine value (80.79−81.03), oleic acid (79.52−79.65%), and tocopherol content (65.26−87.00 mg/kg).

The implementation of network codes within the framework of European Transmission System Operators (TSOs), involves redesigning the process of executing remedial actions aimed at maintaining the power system on a daily basis. One of the key elements of this redesign is the co-optimisation of all accessible measures, bringing a cost-optimal result and providing network security for the entire Capacity Calculation Region (CCR). This specifically means that the currently installed Phase Shifting Transformers (PSTs) are expected to be utilised for the benefit of the whole CCR, with no special priority to any issues incurred by the owner. Therefore, this paper addresses any questions regarding the rules of financing (investment shares per TSO) to be applied for future PST installations. The investment shares are calculated based on the exemplary implementation of a new European procedure − cost-sharing of remedial actions. Consequently, another long-term application of this process is postu... [more]

Heliostats are critical components of solar tower technology and different strategies have been proposed to reduce their costs; among them diminishing their size to reduce wind loads or linking nearby heliostats mechanically, to reduce the overall number of actuators. This document aims to describe the development of a linked array of mini-heliostats which move together in an elevation−Fresnel configuration. This configuration consists of an array of mirrors rotating around linked parallel axes, in a linear Fresnel style with an added elevation mechanism allowing all axes to incline simultaneously in the plane North−South−Zenith; that is equivalent to an array of N linked mini-heliostats moved by only two drives instead of 2N. A detailed analytical study of the Sun-tracking performance of this kind of heliostat arrays was carried out, and an 8-mirror prototype based on optical and mechanical analyses was designed, built and tested. Even though the mirrors are flat, the array produced a... [more]

A new non-isolated modified SEPIC front-end dc-dc converter for the low power system is proposed in this paper, and this converter is the next level of the traditional SEPIC converter with additional devices, such as two diodes and splitting of the output capacitor into two equal parts. The circuit topology proposed in this paper is formulated by combining the boost structure with the traditional SEPIC converter. Therefore, the proposed converter has the benefit of the SEPIC converter, such as continuous input current. The proposed circuit structure also improves the features, such as high voltage gain and high conversion efficiency. The converter comprises one MOSFET switch, one coupled inductor, three diodes, and two capacitors, including the output capacitor. The converter effectively recovers the leakage energy of the coupled inductor through the passive clamp circuit. The operation of the proposed converter is explained in continuous conduction mode (CCM) and discontinuous conduct... [more]

Technologies for the isolation of lignin from pulping process streams are reviewed in this article. Based on published data, the WestVaco process, the LignoBoost process, the LigoForce SystemTM and the SLRP process are reviewed and discussed for the isolation of lignin from Kraft black liquor. The three new processes that have now joined the WestVaco process are compared from the perspective of product quality. Further, isolation processes of lignosulfonates from spent sulfite liquor are reviewed. The limitation for this review is that data are only available from lab scale and pilot scale experiments and not from industrial processes. Key output of this paper is a technology summary of the state of the art processes for technical lignins, showing the pros and cons of each process.

This paper considers supersonic oscillators, in which the widths of the power nozzle and throat are the significant geometric parameters in characterizing the different internal flow characteristics. Supersonic fluidic oscillators with different power nozzle and throat widths are studied through time-dependent numerical computations. Two characteristic parameters, namely the delay time for the initiation of oscillation t0 and the oscillation period T, are selected to describe the physical mechanisms of the various oscillators. The Mach numbers and streamlines at different times are also used to investigate the flow characteristics. The results show that, when the power nozzle exit width is much smaller than the inlet width of the mixing chamber, the delay time decreases as the throat width increases. Changing the throat width of the oscillator does not significantly affect the delay time t0 when the power nozzle exit width is equal to the inlet width of the mixing chamber. The oscillat... [more]

During the last few decades, unheated attic spaces (so-called “cold attics”) have been one of the most moisture-problematic spaces in the building practices of Europe and North America. Problems with such spaces are usually associated with condensation, frost formation, and mould growth on the lower surfaces of the roof deck. To solve these problems, a number of qualitative studies were performed. Although these studies revealed many important pieces of information, some of them are seemingly not in accordance with one another. Therefore, there has not yet been presented cold attic design which is suitable (especially moisture-safe) for the whole target region. The aim of this paper is to determine whether such a design can be determined or state the reasons why it is not possible. Based on a review of published studies, 38 cold attic designs were selected for detailed analysis. Their comparative parameters were established, quantified, and compared. The moisture-safeness of each desig... [more]

The concept of techno-economic pathways is used to investigate the potential implementation of CO2 abatement measures over time towards zero-emission steelmaking in Sweden. The following mitigation measures are investigated and combined in three pathways: top gas recycling blast furnace (TGRBF); carbon capture and storage (CCS); substitution of pulverized coal injection (PCI) with biomass; hydrogen direct reduction of iron ore (H-DR); and electric arc furnace (EAF), where fossil fuels are replaced with biomass. The results show that CCS in combination with biomass substitution in the blast furnace and a replacement primary steel production plant with EAF with biomass (Pathway 1) yield CO2 emission reductions of 83% in 2045 compared to CO2 emissions with current steel process configurations. Electrification of the primary steel production in terms of H-DR/EAF process (Pathway 2), could result in almost fossil-free steel production, and Sweden could achieve a 10% reduction in total CO2 e... [more]

Inconel 601 is one material of choice for intermediate- to high-temperature protective coatings for spark plugs’ ground electrodes. Production of ground electrodes of spark plugs implies the following operations: the tamping of the copper core in an Inconel 601 cup, cold-forming of the assembly, annealing, welding, and bending of the final spark plug. On the production line, the use of Inconel 601 as a protective coating for ground electrodes leads to possible cracking in the welded area after bending. In the present paper, possible causes of cracking are analyzed. It is clearly shown that a combination of Copper −Inconel interface oxidation, Inconel yielding during the heat treatment, and micro-movements during bending lead to cracks in the welded area of the ground electrode. First, the detrimental effect of gaps, between Copper and Inconel 601, is shown experimentally. Second, a thermo-mechanical analysis combined with SEM (Scanning Electron Microscopy) observations identified the a... [more]

Among various photovoltaic devices, the poly 3, 4-ethylenedioxythiophene:poly styrenesulfonate (PEDOT:PSS) and silicon nanowire (SiNW)-based hybrid solar cell is getting momentum for the next generation solar cell. Although, the power-conversion efficiency of the PEDOT:PSS−SiNW hybrid solar cell has already been reported above 13% by many researchers, it is still at a primitive stage and requires comprehensive research and developments. When SiNWs interact with conjugate polymer PEDOT:PSS, the various aspects of SiNW array are required to optimize for high efficiency hybrid solar cell. Therefore, the designing of silicon nanowire (SiNW) array is a crucial aspect for an efficient PEDOT:PSS−SiNW hybrid solar cell, where PEDOT:PSS plays a role as a conductor with an transparent optical window just-like as metal-semiconductor Schottky solar cell. This short review mainly focuses on the current research trends for the general, electrical, optical and photovoltaic design issues associated wi... [more]

Chemistry plays an essential role in our modern society [...]

A general approach for the analysis and design of self-oscillating resonant converters is presented in this paper, for a particular class of circuits in which the change of input voltage polarity is caused by the zero-crossings of the input inductor current. The key features of the method are an analytical description in the time-domain of a spiral that eventually converges into an ellipse, and a frequency−domain analysis that explains the behavior of the ellipse as a limit cycle. On a theoretical basis, this class of circuits behaves as loss-free resistors (LFR) because in steady-state the input inductor current is in phase with the first harmonic of the input voltage. The proposed analytical procedure predicts accurately the amplitude and frequency of the limit cycle and justifies the stability of its generation. This accuracy is reflected in the close agreement between the theoretical expressions and the corresponding simulated and measured waveforms. Third and fourth order resonant... [more]

In China, the non-exploitation of bioenergy poses major problems and challenges. To solve bioenergy problems, considerable efforts have been made to expedite the construction of large-scale crop residue utilization projects. In this study, three principal supported modes of large-scale crop residue utilization projects were taken as empirical cases in Hubei province bioenergy planning. In terms of the overall benefit and sustainable development, a third-grade evaluation index system was established. The analysis was carried out using the analytical hierarchy process, principal component projection, and grey relational analysis. The conclusion indicates that according to the evaluation values, the sequence from best to worst was crop residue biogas project, crop residue briquette fuel project, and crop residue gasification project. Nevertheless, there was no remarkable difference in the overall evaluation values. The biogas project had certain advantages in terms of the production cost,... [more]

Sustainable construction is an important part of sustainable development because of its contribution to the economy as well as the environmental and social impact of buildings on our lives. Steel is one of the most basic materials, both in the structures and for the finishes. It enables efficiency, durability, and recyclability, especially for office buildings. All these features of steel show its sustainable potential. Consumers are becoming increasingly concerned about the environment. They need to be able to make informed decisions about the impact of their actions. This publication is aimed at setting out key themes for the design and construction of sustainable buildings. Examples of office building environmental analyses are presented to illustrate how this is being achieved in steel construction.

The current study is focused on the economic and financial assessments of solar and wind power potential for nine selected regions in Libya for the first time. As the existing meteorological data, including wind speed and global solar radiation, are extremely limited due to the civil war in the country, it was therefore decided to use the NASA (National Aeronautics and Space Administration) database as a source of meteorological information to assess the wind and solar potential. The results showed that the country has huge solar energy potential compared to wind energy potential. Additionally, it is found that Al Kufrah is a suitable region for the future installation of the Photovoltaic (PV) power plant due to high annual solar radiation. Based on the actual wind speed analysis, Benghazi and Dernah are the best regions for large-scale wind farm installation in the future taking into account existing meteorological data limitations. The values of the wind power density in all regions... [more]

In order to understand the pressure fluctuation characteristics of a semi-open cutting pump, the three-dimensional unsteady flow fields were calculated. External and internal flow characteristics of four schemes with different relative angles between the rotary cutter and the impeller were studied. The pressure fluctuations in the lower plate, the upper plate, the clearance between the rotary cutter and the fixed cutter, the first section in volute and nearby parts of the tongue were all analyzed, which are all the places that pressure distributions are greatly affected by the static and dynamic interaction, and at the same time, the force on the impeller was also analyzed. The results show that the fluctuations at different positions change periodically; the main frequency is blade frequency. The amplitude of pressure fluctuation decreases from near the rotating part to far away, from near the tongue to far from the tongue. Due to the influence of both impeller and rotary cutter, the... [more]

A power electronic transformer (PET) is applied to the high-speed train for lightweight demand. A 300 kW/5 kHz high-power medium-frequency transformer (HPMFT) using hollow conductors in a power unit of the PET is optimally designed in this paper. The target of the design is to balance the loss, leakage inductance, and weight of the HPMFT. For this purpose, the design parameters of the HPMFT are firstly confirmed according to the system structure and parameters of the PET. Secondly, the design process of HPMFT is developed. Finally, the results of 48 design schemes of core-type and shell-type structures are compared by the comprehensive evaluation standard, which equilibrates the three above objective parameters of the HPMFT. According to the optimal scheme, a prototype is manufactured, whose test results verify the correctness of the optimal design method.

To realize the best performances of the distributed energy system (DES), many uncertainties including demands, solar radiation, natural gas, and electricity prices must be addressed properly in the planning process. This study aims to study the optimal sizing and performances of a hybrid combined cooling, heating, and power (CCHP) system under uncertainty in consideration of the operation parameters, including the lowest electric load ratio (LELR) and the electric cooling ratio (ECR). In addition, the ability of the system to adapt to uncertainty is analyzed. The above works are implemented separately under three operation strategies with multi-objectives in energy and cost saving, as well as CO2 reducing. Results show that the system with optimized operation parameters performs better in both the deterministic and uncertain conditions. When the ECRs in the summer and in mid-season as well as the LELR are set at 50.00%, 50.00%, and 20.00% respectively, the system operating in the strat... [more]

The request for high efficiency motor paves the way for the replacement of induction motors with permanent magnet synchronous motors. Although the efficiency is increased, for medium and high power, the current ripple causes significant additional losses in the magnet and lamination; and, high temperature can lead to demagnetization. In this paper, a new rotor topology is proposed and compared to a traditional surface permanent magnet rotor to reduce the magnet losses and protect them from demagnetization. A reference surface permanent magnet machine is compared with the proposed one in terms of performance and magnet losses. Both analytical and experimental analysis are carried out and discussed.

The article presents methods of securing mining excavations using wooden cribs. For the underground room and pillar method used to excavate zinc and lead ore body in the Olkusz-Pomorzany mine in Poland, model tests for the replacement of rock pillars by wooden cribs are presented. In the first stage of research, the results of laboratory strength tests carried out on models of four-point, six-point and eight-point cribs made of wooden beech beams at a 1:28 scale arranged horizontally were determined. For the first time, a concave round notch connection was used to connect the beams of the wooden cribs. The maximal capacity of cribs consisting only of beams and filled with waste rocks taken from underground mining excavations was determined. In addition, the vertical deformations of the cribs at maximal loading force and their specific deformations are presented. Additionally, on the basis of load-displacement characteristics, the range in variability of the stiffness of empty cribs and... [more]