Olive cake, the solid byproduct of three-phase centrifugation olive oil production, has a high organic and polyphenol content, rendering it an environmental threat when landfilled as well as limiting its animal feed potential. This residue can be a good candidate for biomethane production due to its rich polysaccharide content (pectin, hemicellulose, and cellulose). Two strategies were compared to maximize biomethane production: destoning (i.e., removal of the seed fragments via mechanical means) and enzymatic pretreatment of the pulp. After 30 days of batch anaerobic digestion at 35 °C, both enzymatically pretreated and destoned olive cakes produced similar amounts of methane (~295 mL CH4/g volatile solids (VS)), 42% more than the control. A comparison of olive cake’s biomethane yields with a broad range of agricultural residues in the literature demonstrated its suitability for biomethane production. Additionally, the digestate recovered from the anaerobic digestion of olive cake had... [more]

In this study, an industrial biomass-drying wastewater condensate containing > 3200 mg/L NH4+ and >8900 mg/L CH3COO− was treated in ion-exchange columns for the recovery of NH4+. Two commercial resins (CS12GC and CS16GC) were studied on laboratory and pilot scales. CS16GC outperformed CS12GC by achieving better separation at the condensate temperature (60 °C), which was energy-efficient regarding NH4+ removal. K3PO4 was used for regeneration to produce a liquid compound fertilizer containing nutrient elements (N, K, and P) as a byproduct. The N/K ratio in the byproduct was found to be adjustable by varying the operating parameters. Regeneration with 2 mol/L K3PO4 gave a higher regeneration efficiency (97.67% at 3 BV and ~100% at 4 BV). The stability tests performed on a laboratory scale showed that the cyclic runs of the column separation process were steady and repeatable. Based on the outcomes of the laboratory-scale tests, the pilot-scale tests applied a loading volume of 7 BV. The... [more]

The purpose of this work is to develop two types of dietary supplements for celiac (energy-rich and fiber-rich bars) as well as to optimize the formulations of bars made from puffed and non-puffed cereals. To optimize the combination of components, a mixture design was created. Based on sensory evaluation, optimal bars were selected, which were then evaluated in terms of biochemical properties, color and antioxidant properties. The main results indicate that the combination of 37.5 g of cereals, 22.5 g of seeds, and 40 g of binder is optimal for the energy bars with non-puffed cereals, followed by 54.57 g of cereals, 10.43 g of seeds, and 35 g of a binder for fiber-rich bars with non-puffed cereals. In contrast, the optimal recipe for energy bars with puffed cereals consisted of 35.42 g of cereals, 20.07 g of seeds, and 44.51 g of binder, and for fiber-rich bars with puffed cereals, it consisted of 50 g of cereals, 15 g of seeds, and 35 g. The biochemical composition indicates that fib... [more]

The influence of process water recycling during the Supercritical Water Gasification (SCWG) of dry biomasses was investigated. Dry biomass has to be diluted with water to a dry matter content of approximately 10 wt.% to gasify it in the process of supercritical water gasification. The treatment of wastewater in the SCWG process is cost intensive due to organic contaminants; therefore, the recycling of the process effluent is attractive. Salt separation is needed to avoid accumulation of salts in the effluents, since salts enhance corrosion rates and might cause blocking of the flow when the effluent is recycled. The grass Reed Canary Grass and grapevines were gasified. The recycling of the process effluent did not influence the composition of the product gas. In both cases the carbon efficiency decreased by 4% when wastewater was used to dilute the biomass. An increase in organic carbon and potassium in the reactor effluent was observed after gasification of the biomass with recycled p... [more]

In this study, we carried out a para-xylene crystallization experiment at constant temperature and concentration levels. Throughout the process, the kinetics of nucleation, growth, breakage, and aggregation of para-xylene particles were measured and built using a morphological approach. An additional a three-stage continuous suspension crystallization separation experiment was carried out, the process for which was simulated using the population balance model based on correlated kinetic equations. The population balance equation was solved using an extended moment of classes algorithm, and the solving process was implemented in MATLAB. In this case, the predicted particle size distribution of the products matched well with the experiment. In order to provide references for the optimization of the industrial para-xylene crystallization process, a three-stage suspension crystallization separation experiment was designed and conducted, in which each crystallizer had a distinct operating t... [more]

Deep application of liquid fertilizer is a technique that applies liquid fertilizer deep near the root system of crops, which has many advantages such as high fertilizer utilization rate and low environmental pollution. However, high power and high specific energy consumption caused by soil-engaging components in liquid fertilizer deep application make it difficult to popularize in northeast China. The claw-toe structure of burrowing animals has the characteristics of low resistance and low friction, which has been the focus of many scholars’ research on soil-engaging components. The claw-toe structure of the badger, a widely distributed burrowing animal in northeast China, has good characteristics of low power and low specific energy consumption. Therefore, in this research, a bionic liquid fertilizer deep application spray needle was designed, based on the claw-toe structure of the badger, to improve the operating performance of liquid fertilizer deep application. In this research, t... [more]

Hyperloop technology is a transport mode designed to move passengers anywhere in the world, using electric propulsion to carry passengers through a vacuum/near-vacuum tube for a maximum speed of 1200 km/h. Given this, governments, engineers, researchers, and billionaires have been racing over the past years to obtain the first operational system in the world off the ground and bring it from concept to reality. The paper aimed to maximize the capacity of the Hyperloop’s capsule and identify a suitable design of Hyperloop technology based on the different capacities and speeds of the capsules as well as the assumptions of the initial annual demand. Additionally, significant attention will be paid to the interior design of the capsules in which people travel to make the journey more comfortable and enjoyable. The design will be conducted in AutoCAD and Autodesk Revit models based on the allocation of different components such as capacity, compressor fan, batteries, compressor motor, etc.... [more]

The effect of temperature was studied on the synthesis of fatty acid alkyl esters by means of transesterification of waste beef tallow using ethanol and, iso-butanol and 1-butanol at supercritical conditions. These alcohols are proposed for the synthesis of biodiesel in order to improve the cold flow properties of alkyl esters. Alcohol−beef tallow mixtures were fed to a high-pressure high-temperature autoclave at a constant molar ratio of 45:1. Reactions were carried out in the ranges of 310−390 °C and 310−420 °C for ethanol and iso-butanol, respectively; meanwhile, synthesis using 1-butanol was assessed only at 360 °C. After separation of fatty acid alkyl esters, these samples were characterized by nuclear magnetic resonance (NMR) and gas chromatography coupled to mass spectrometry (GC-MS) to quantify yields, chemical composition, and molecular weight. Results indicated that yields enhanced as temperature increased; the maximum yields for fatty acid ethyl esters (FAEEs) were attained... [more]

The design parameters of a mixing system have a major impact on the quality of the final product. Therefore, identifying the optimum parameters of mixing systems is highly relevant to various industrial processes dealing with particulate flows. However, the studies on the influences of the mixer’s design features are still insufficient. In this study, the Discrete Element Method (DEM) is used to examine the impact of paddle angle, width, and gap on the mixing performance of a twin paddle blender. The mixing performance and particle flow are assessed using the relative standard deviation (RSD) mixing index, velocity field, diffusivity coefficient, granular temperature, the force acting on particles, and the mixer’s power consumption. The mixing performance is highest for a paddle angle of 0° at the cost of the highest forces acting on particles. The paddle width is indicated as a critical factor for achieving better mixing quality. In contrast, the powder mixing efficiency and the mixer... [more]

The technology for reproducing orchids in vitro has had to evolve due to the demand for these plants and the high cost of the biotechnology used due to the agar, the gelling agent. Consequently, research has tended to search for natural substitutes for agar. Our work describes the use of pectin and mucilage hydrocolloids extracted from the local waste matter of two species of Opuntia (O. ficus-indica and O. robusta) to study as a gelling agent in vitro culture media for Cattleya sp. These hydrocolloids were obtained by alkaline hydrolysis. Subsequently, these were used in proportions of 0.8%, 0.6%, 0.4%, and 0.2% in combination with agar to study the gelation time, texture profile analysis (TPA), seed germination under light and dark conditions, and a phenological study, including orchid analyses of leaves and roots, root and leaf length, seedling height, and width of the best-designed treatment were studied. Our results demonstrate that the treatment composed of 0.4% O. ficus-indica p... [more]

Research in the field of industrial heritage regeneration suffers from high subjectivity and low reliability in design and evaluation. The study takes seven regeneration projects of the Kailuan family of industrial heritage as examples, designs four optimisation and improvement strategies and constructs an evaluation system containing four intermediate layers and 23 indicator layers based on the evaluation factor method to realise the evaluation of design solutions. The average evaluation value of the four intermediate layers was approximately 0.65, and the average evaluation value of the 23 evaluation indicators was approximately 0.68. The evaluation values of the four intermediate layers for the seven Kailuan projects showed that the evaluation of the park and the evaluation of the participants’ perceptions were roughly higher than the standard values, while the evaluation of the buildings and the evaluation of the environmental image had lower evaluation values. The correlations bet... [more]

Ammonia is a promising carbon-free energy vector, hydrogen carrier, and efficient means for long-time hydrogen storage. Power-to-ammonia-to-power concepts, powered exclusively by electricity from renewable sources, will leave the carbon economy behind and enter a truly renewable era. However, the fluctuating nature of renewables requires a good dynamic behavior of such concepts. Employing the software Aspen Plus Dynamics®, this paper investigates the dynamic behavior of a novel containerized power-to-ammonia solution to be tested at the University of Genova in 2023. Implementing a novel kinetic reaction model, the impacts of several deviations from the optimal values of the cycle parameters are investigated. The simulations provide practical guidance on how to best and safely operate the cycle. A total of ten scenarios were simulated, of which six are acceptable, two are desirable, and two should be avoided. However, all scenarios can be safely controlled by the control infrastructure.

Non-processed kaolin (flint kaolin) from a mine located in the Capim area (Amazon region, northern Brazil), usually considered as waste, was selected as a source of silicon and aluminum in the synthesis of SAPO-34. This is a molecular sieve and cationic exchanger chosen for tests focusing on the removal of methylene blue in aqueous solutions, which is a cationic dye widely used by textile industries in Brazil. The results revealed that the SAPO-34 has been successfully synthesized with typical cubic morphology, good crystallinity (>90%), and thermal stability (~998 °C). Although the oxidized Fe/Ti impurities contained in the flint kaolin affect the degree of crystallinity of the zeolitic product, its adsorptive properties are not significantly affected, which demonstrates the excellent adsorption results (pH = 11; % removal > 90%). It proved to be an adsorbent with considerable adsorption capacity (9.83 mg·g−1). The pH test confirmed the acidic surface characteristics (pH solution 2−4;... [more]

Energy performance of buildings is a worldwide increasing investigated field, due to ever more stringent energy standards aimed at reducing the buildings’ impact on the environment. The purpose of this paper is to assess the impact that occupant behavior and climate change have on the heating and cooling needs of residential buildings. With this aim, data of a questionnaire survey delivered in Southern Italy were used to obtain daily use profiles of natural ventilation, heating, and cooling, both in winter and in summer. Three climatic scenarios were investigated: The current scenario (2020), and two future scenarios (2050 and 2080). The CCWorldWeatherGen tool was used to create the weather files of future climate scenarios, and DesignBuilder was applied to conduct dynamic energy simulations. Firstly, the results obtained for 2020 demonstrated how the occupants’ preferences related to the use of natural ventilation, heating, and cooling systems (daily schedules and temperature setpoint... [more]

The food manufacturing sector is one of the most dominant consumers of energy across the globe. Food processing methods such as drying, baking, frying, malting, roasting, etc. rely heavily on the heat released from burning fossil fuels, mainly natural gas or propane. Less than half of this heat contributes to the actual processing of the product and the remaining is released to the surroundings as waste heat, primarily through exhaust gases at 150 to 250 °C. Recovering this waste heat can deliver significant fuel, cost and CO2 savings. However, selecting an appropriate sink for this waste heat is challenging due to the relatively low source temperature. This study investigates a novel application of gas-to-air low temperature waste heat recovery technology for a confectionary manufacturing process, through a range of experiments. The recovered heat is used to preheat a baking oven’s combustion air at inlet before it enters the fuel-air mixture. The investigated technology is compared w... [more]

A non-linear three-dimensional inverse shape design problem was investigated for a pipe type heat exchanger to estimate the design variables of continuous lateral ribs on internal Z-shape lateral fins for maximum thermal performance factor η. The design variables were considered as the positions, heights, and number of ribs while the physical properties of air were considered as a polynomial function of temperature; this makes the problem non-linear. The direct problem was solved using software package CFD-ACE+, and the Levenberg−Marquardt method (LMM) was utilized as the optimization tool because it has been proven to be a powerful algorithm for solving inverse problems. Z-shape lateral fins were found to be the best thermal performance among Z-shape, S-shape, and V-shape lateral fins. The objective of this study was to include continuous lateral ribs to Z-shape lateral fins to further improve η. Firstly, the numerical solutions of direct problem were solved using both polynomial and... [more]

Cryogenic air separation processes are widely used for the large-scale production of nitrogen and oxygen. The most widely used design for this process involves two distillation columns operating at different pressures. This work focuses on the selection of suitable cryogenic air separation process by evaluating seven alternative designs of the two-column air separation process based on detailed exergy analysis. The feed conditions (500 tons/h, and 50% relative humidity of air), product purities (99 mole% for both nitrogen and oxygen), and operational conditions (pressures of both distillation columns) are kept same in all designs. The two cryogenic distillation columns in each configuration are heat-integrated to eliminate the need for external utilities. Steady-state simulation results are used to calculate the exergy efficiency (%) of each equipment as well as its contribution toward the overall exergy destruction rate (kW) of the process. The results show that the compression sectio... [more]

In order to prevent solids from forming during the transportation and handling of liquid propane, C3H8(l), the fluid is dehydrated to a level below the water dew point concentration for the coldest operating temperature. Thus, accurate calculation of the saturation water content for C3H8 is important to determine the designed allowable concentration in liquid C3H8. In this work, we measured the water content of liquid C3H8 in the presence of the structure II hydrate from p = 1.081 to 40.064 MPa and T = 241.95 to 276.11 K using a tunable diode absorption spectroscopy technique. The water content results were modelled using the reference quality reduced Helmholtz equations and the Sloan et al. model for the non-hydrate and hydrate phases, respectively. Calculations show a good agreement (an average difference of less than 12 ppm) when compared to our measurements. Furthermore, the model was also used for calculating the dissociation temperatures for three phase loci, where a relative dif... [more]

In the residential sector, a great part of the electricity goes into heating water by electric water heaters, which results in high CO2 emissions as well as an unprecedented increase in electricity demand leading to an energy crisis. This study offers solar water heaters as a more economical and efficient replacement for electric water heaters. The present study is aimed at investigating the potential for solar water heaters in the subcontinent, especially in India. A feasibility analysis is performed for seven cities in the subcontinent, namely Mumbai, New Delhi, Kolkata, Assam, Gujrat and Madhya Pradesh. Simulated results are based on a solar fraction, equity payback, multiple collectors (one, two or three), horizontal and tilted, type of collector (evacuated tube, glazed and unglazed), electricity saved and greenhouse gas (GHG) emission reduction. The collector’s area is made such that it should receive at least 50% of the solar fraction. The range of payback period varies from five... [more]

The present study addresses the coupling of hydrothermal carbonization (HTC) with anaerobic digestion (AD) in wastewater treatment plants. The improvement in biomethane production due to the recycling back to the anaerobic digester of HTC liquor and hydrochar generated from digested sludge is investigated and proved. Mixtures of different compositions of HTC liquor and hydrochar, as well as individual substrates, were tested. The biomethane yield reached 102 ± 3 mL CH4 g−1 COD when the HTC liquor was cycled back to the AD and treated together with primary and secondary sludge. Thus, the biomethane production was almost doubled compared to that of the AD of primary and secondary sludge (55 ± 20 mL CH4 g−1 COD). The benefit is even more significant when both the HTC liquor and the hydrochar were fed to the AD of primary and secondary sludge. The biomethane yield increased up to 187 ± 18 mL CH4 g−1 COD when 45% of hydrochar, with respect to the total feedstock, was added. These results hi... [more]

In this study, wafer cleaning equipment was designed and fabricated using the induction heating (IH) method and a short-time superheated steam (SHS) generation process. To prevent problems arising from the presence of particulate matter in the fluid flow region, pure grade 2 titanium (Ti) R50400 was used in the wafer cleaning equipment for heating objects via induction. The Ti load was designed and manufactured with a specific shape, along with the resonant network, to efficiently generate high-temperature steam by increasing the residence time of the fluid in the heating object. The IH performance of various shapes of heating objects made of Ti was analyzed and the results were compared. In addition, the heat capacity required to generate SHS was mathematically calculated and analyzed. The SHS heating performance was verified by conducting experiments using the designed 2.2 kW wafer cleaning equipment. The performance of the proposed pure Ti-based SHS generation system was found to be... [more]

Ammonia has strong potentialities as sustainable fuel for energy applications. NH3 is carbon free and can be synthetized from renewable energy sources (RES). In Solid Oxide Fuel Cells, NH3 reacts electrochemically thereby avoiding the production of typical combustion pollutants such as NOx. In this study, an ammonia-fueled solid oxide fuel cells (SOFC) system design is proposed and a thermodynamic model is developed to evaluate its performance. A SOFC short stack was operated with NH3 in a wide range of conditions. Experimental results are implemented in the thermodynamic model. Electrical efficiency of 52.1% based on ammonia Lower Heating Value is calculated at a net power density of 0.36 W cmFC−2. The operating conditions of the after burner and of the ammonia decomposition reactor are studied by varying the values of specific parameters. The levelized cost of energy of 0.221 $ kWh−1 was evaluated, as introduced by the International Energy Agency, for a system that operates at nomina... [more]

In developing countries, electrification in remote areas, where access to energy is limited or null, has been one of the biggest challenges in recent years. Isolated microgrids with renewable generation are an efficient alternative for the energy supply in these areas. The objective of this work was to analyse the techno-economic viability of 6 isolated microgrids in different locations in the non-interconnected zone of Colombia, considering different climatic conditions, the availability of renewable resources, the current consumption profile, and a modified profile applying demand-side management. Modelling and simulation were performed considering storage systems based on lithium and lead-acid batteries. The resulting simulations provide the optimal system cost, emissions levels, electricity cost and battery lifetime. This study demonstrates that isolated hybrid microgrids with renewable energy are a feasible alternative to solve access to energy problems, reducing the need for dies... [more]

Through applying an exemplary design study, the dependencies between current density, temperatures, and weight in an electrical drive system for a small range aircraft with conventional electrical fan or propeller drives are evaluated. This study applies a combined numerical (Finite Element Method FEM) and analytical approach to the machine design, calculation of temperatures, and cooling system design (cooler, pumps, piping). A design scenario was defined using start and climb flight in a warm tropical surrounding as the worst load case. The design has to move between two fixed temperature limits: The maximum allowable temperature in the machine insulation and the ambient temperature. The implemented method facilitates a comparatively fast-medium depth design of the drive system. The derived results show, in fact, a minimum of weight at a certain current density, which is one of the key interests for the designers of the electrical machine. The main influences on this minimum are the... [more]

The German Energiewende is a deliberate transformation of an established industrial economy towards a nearly CO2-free energy system accompanied by a phase out of nuclear energy. Its governance requires knowledge on how to steer the transition from the existing status quo to the target situation (transformation knowledge). The energy system is, however, a complex socio-technical system whose dynamics are influenced by behavioural and institutional aspects, which are badly represented by the dominant techno-economic scenario studies. In this paper, we therefore investigate and identify characteristics of model studies that make agent-based modelling supportive for the generation of transformation knowledge for the Energiewende. This is done by reflecting on the experiences gained from four different applications of agent-based models. In particular, we analyse whether the studies have improved our understanding of policies’ impacts on the energy system, whether the knowledge derived is u... [more]