The Organic Rankine Cycle (ORC) is widely considered as a promising technology to produce electrical power output from low-grade thermal sources. In the last decade, several power plants have been installed worldwide in the MW range. However, despite its market potential, the commercialization of ORC power plants in the kW range did not reach a high level of maturity, for several reasons. Firstly, the specific price is still too high to offer an attractive payback period, and secondly, potential costumers for small-scale ORCs are typically SMEs (Small-Medium Enterprises), generally less aware of the potential savings this technology could lead to. When it comes to small-scale plants, additional design issues arise that still limit the widespread availability of the technology. This review paper presents the state of the art of the technology, from a technical and economic perspective. Working fluid selection and expander design are illustrated in detail, as they represent the bottlenec... [more]

Biomass gasification is a proven technology; however, one of the major obstacles in using product syngas for electric power generation and biofuels is the removal of tar. The purpose of this research was to develop and evaluate effectiveness of tar removal methods by cooling the syngas and using wood shavings as filtering media. The performance of the wood shavings filter equipped with an oil bubbler and heat exchanger as cooling systems was tested using tar-laden syngas generated from a 20-kW downdraft gasifier. The tar reduction efficiencies of wood shavings filter, wood shavings filter with heat exchanger, and wood shavings filter with oil bubbler were 10%, 61%, and 97%, respectively.

A conductive direct-write process of multilayered coils for micro electromagnetic generators is proposed. This novel approach of using silver ink to form the conductive structures largely reduces the fabrication complexity, and it provides a faster alternative to the conventional semiconductor methods. Multi-layered coils with insulation were accurately layered on a micromachined cantilevered diaphragm by a dispenser. Coils several layers thick could be used to increase the power output and double coils were separated by a layer of insulation. Six prototypes, all capable of efficient conversion of vibrational energy into electrical energy, were fabricated. The experimental results, which include measurements of the electromotive force and power output, are presented. Prototypes with two coils and thicker conducting layers had less resistance and the power output was much more than that of a single-coil unit. This generator can produce 82 nW of power at a resonance frequency of 275 Hz u... [more]

Investigation into clean energies has been focused on finding an alternative to fossil fuels in order to reduce global warming while at the same time satisfying the world’s energy needs. Biomass gasification is seen as a promising thermochemical conversion technology as it allows useful gaseous products to be obtained from low-energy-density solid fuels. Air⁻steam mixtures are the most commonly used gasification agents. The gasification performances of several biomass samples and their mixtures were compared. One softwood (pine) and one hardwood (chestnut), their torrefied counterparts, and other Spanish-based biomass wastes such as almond shell, olive stone, grape and olive pomaces or cocoa shell were tested, and their behaviors at several different stoichiometric ratios (SR) and steam/air ratios (S/A) were compared. The optimum SR was found to be in the 0.2⁻0.3 range for S/A = 75/25. At these conditions a syngas stream with 35% of H₂ + CO and a gas yield of 2 L gas/g fuel were obtain... [more]

The high efficiency performance of the Edinburgh Duck wave energy converter (WEC) in 2D regular wave tests makes it a promising wave energy conversion scheme. A solo Duck WEC will be able to apply the point absorber effect to further enhance its performance. Since released degree of freedom will decrease the efficiency, a Duck WEC with fixed pitching axis will be a better option. However, for fixed supported WECs, tide is a non-ignorable consideration. In this paper, a movable mass method is utilized in the whole tidal range to not only balance the Duck to appropriate beak angles, but also follow the variation of hydrodynamic coefficients to keep cancelling the reactance of the system impedance so that complex conjugate control can be realized to optimize the power capture performance of the Duck WEC in tide. Results show that the beak angle should be adjusted to as large a value as possible so that the response amplitude of the Duck at maximum relative capture width will be reasonable... [more]

In the Republic of Korea, efficient biogas-fuelled power systems are needed to use the excess biogas that is currently burned due to a lack of suitable power technology. We examined the performance of a biogas-fuelled micro-gas turbine (MGT) system and a bottoming organic Rankine cycle (ORC). The MGT provides robust operation with low-grade biogas, and the exhaust can be used for heating the biodigester. Similarly, the bottoming ORC generates additional power output with the exhaust gas. We selected a 1000-kW MGT for four co-digestion plants with 28,000-m³ capacity. A 150-kW ORC system was selected for the MGT exhaust gas. We analysed the effects of the system size, methane concentration, and ORC operating conditions. Based on the system performance, we analysed the annual performance of the MGT with a combined heat and power (CHP) system, bottoming ORC, or both a bottoming ORC and CHP system. The annual net power outputs for each system were 7.4, 8.5, and 9.0 MWh per year, respectivel... [more]

For efficient application of solar energy, a pebble bed energy storage heating system in a solar attic is optimally designed and operated. To study the characteristics of the heating system, a numerical model for the system is presented and is validated with the experiment data in the literature. Based on the model, the influence of the envelopes of the solar house and the meteorological condition on the system performance is investigated. The results show that the envelopes, except those on the north face, with more glazed exterior surfaces can be beneficial to raise the temperature of the solar house. It is also found that outdoor temperature may have less impact on the energy storage in the system compared with solar radiation. Furthermore, through optimizing the system design and operation, solar energy can account for 56% of the energy requirement in the heating season in Xi’an (about 34° N, 108° E), which has an average altitude of 397.5 m and moderate solar irradiation. Also, th... [more]

Under the inspiration of polar coordinates, a novel parametric modeling and optimization method for Savonius wind turbines was proposed to obtain the highest power output, in which a quadratic polynomial curve was bent to describe a blade. Only two design parameters are needed for the shape-complicated blade. Therefore, this novel method reduces sampling scale. A series of transient simulations was run to get the optimal performance coefficient (power coefficient C p) for different modified turbines based on computational fluid dynamics (CFD) method. Then, a global response surface model and a more precise local response surface model were created according to Kriging Method. These models defined the relationship between optimization objective Cp and design parameters. Particle swarm optimization (PSO) algorithm was applied to find the optimal design based on these response surface models. Finally, the optimal Savonius blade shaped like a “hook” was obtained. Cm (torque coefficient), C... [more]

The energy consumption increase in the last few years has contributed to developing energy efficiency policies in many countries, the main goal of which is decreasing CO 2 emissions. One of the reasons for this increment has been caused by the use of air conditioning systems due to new comfort standards. In that regard, cooling towers and evaporative condensers are presented as efficient devices that operate with low-level water temperature. Moreover, the energy consumption and the cost of the equipment are lower than other systems like air condensers at the same operation conditions. This work models an air conditioning system in TRNSYS software, the main elements if which are a cooling tower, a water-water chiller and a reference building. The cooling tower model is validated using experimental data in a pilot plant. The main objective is to implement an optimizing control strategy in order to reduce both energy and water consumption. Furthermore a comparison between three ty... [more]

Italy is a leading country in the biogas sector. Energy crops and manure are converted into biogas using anaerobic digestion and, then, into electricity using internal combustion engines (ICEs). Therefore, there is an urgent need for improving the efficiency of these engines taking the real operation into account. To this purpose, in the present work, the organic Rankine cycle (ORC) technology is used to recover the waste heat contained in the exhaust gases of a 1 MWel biogas engine. The ICE behavior being affected by the biogas characteristics, the ORC unit is designed, firstly, using the ICE nameplate data and, then, with data measured during a one-year monitoring activity. The optimum fluid and the plant configuration are selected in both cases using an “in-house” optimization tool. The optimization goal is the maximization of the net electric power while the working fluid is selected among 115 pure fluids and their mixtures. Results show that a recuperative ORC designed using real... [more]

GaN-based transistors with p-GaN gate are commonly accepted as promising devices for application in power converters, thanks to the positive and stable threshold voltage, the low on-resistance and the high breakdown field. This paper reviews the most recent results on the technology and reliability of these devices by presenting original data. The first part of the paper describes the technological issues related to the development of a p-GaN gate, and the most promising solutions for minimizing the gate leakage current. In the second part of the paper, we describe the most relevant mechanisms that limit the dynamic performance and the reliability of GaN-based normally-off transistors. More specifically, we discuss the following aspects: (i) the trapping effects specific for the p-GaN gate; (ii) the time-dependent breakdown of the p-GaN gate during positive gate stress and the related physics of failure; (iii) the stability of the electrical parameters during operation at high drain vo... [more]

Hydrogen production via two-step thermochemical cycles over fluorite-structure ceria (CeO2) and ceria-zirconia (Ce0.75Zr0.25O2) materials was studied in packed-bed and micro-channel reactors for comparison purposes. The H2-temperature program reduction (H2-TPR) results indicated that the addition of Zr4+ enhanced the material’s reducibility from 585 µmol/g to 1700 µmol/g, although the reduction temperature increased from 545 to 680 °C. Ce0.75Zr0.25O2 was found to offer higher hydrogen productivity than CeO2 regardless of the type of reactor. The micro-channel reactor showed better performance than the packed-bed reactor for this reaction.

This paper handles a hybrid multiple optimization technique to concurrently enhance hydraulic efficiency and decrease unsteady radial forces resulting from fluid-induced vibration of a single-channel pump for wastewater treatment. A single-channel impeller and volute was optimized systematically by using a hybrid particle swarm optimization and genetic algorithm coupled with surrogate modeling. Steady and unsteady Reynolds-averaged Navier−Stokes analyses were conducted to optimize the internal flow path in the single-channel pump. Design variables for controlling the internal flow cross-sectional area of the single-channel impeller and volute in the single-channel pump were chosen to concurrently optimize objective functions with hydraulic efficiency and the unsteady radial forces resulting from impeller−volute interaction. The optimization results clearly showed that the arbitrary cluster optimum design considerably enhanced hydraulic efficiency and decreased the unsteady radial force... [more]

In an ethylene plant, steam system provides shaft power to compressors and pumps and heats the process streams. Modeling and optimization of a steam system is a powerful tool to bring benefits and save energy for ethylene plants. However, the uncertainty of device efficiencies and the fluctuation of the process demands cause great difficulties to traditional mathematical programming methods, which could result in suboptimal or infeasible solution. The growing data-driven optimization approaches offer new techniques to eliminate uncertainty in the process system engineering community. A data-driven robust optimization (DDRO) methodology is proposed to deal with uncertainty in the optimization of steam system in an ethylene plant. A hybrid model of extraction−exhausting steam turbine is developed, and its coefficients are considered as uncertain parameters. A deterministic mixed integer linear programming model of the steam system is formulated based on the model of the components to min... [more]

Synthesis of magnesium aluminate spinel (MgAl2O4) was investigated by employing ball milling and co-precipitation methods. The starting materials (aluminum hydroxides) were obtained from the purified sodium hydroxide leaching solution of black dross. The characteristics of the synthesized spinel was analyzed through X-ray diffraction (XRD), scanning electron microscopy (SEM) images. In this work, the effect of calcination temperature and time on the formation of spinel by the two methods was compared. Calcination temperature showed a great effect on the formation of spinel in both methods. The results showed that the co-precipitation method has many advantages over the ball milling method. In ball milling method, complete conversion of the starting materials to spinel was impossible even at 1500 °C, while complete conversion to spinel was accomplished at 1000 °C for 5 h by the co-precipitation method. The average size of the spinel synthesized at these optimum conditions of the co-prec... [more]

The pressure swing distillation (PSD) with two different energy-saving modes are put forward to separate a binary azeotrope containing lower alcohols: benzene/methanol. A comparison of the economy and controllability for the partial and fully heat integrated pressure swing distillation (HIPSD) is made by detailed simulation analysis. The optimal operating parameters of partial and fully HIPSD processes are obtained by minimizing total annual cost (TAC). These results show that the fully HIPSD mode saves 5.88% TAC compared with the partial HIPSD mode. Meanwhile, this paper proposes that the composition slope profile can help to select the temperature control stage (TCS), when the temperature profile in the column is rising rapidly near the bottom and the maximum of temperature slope value occurs in the bottom of the column. Several control structures are developed to check the rationality of the selection of the TCS and evaluate the industrial application. These results illustrate the c... [more]

Limiting global temperature rise to well below 2 °C according to the Paris climate accord will require accelerated development, scale-up, and commercialization of innovative and environmentally friendly reactor concepts. Simulation-based design can play a central role in achieving this goal by decreasing the number of costly and time-consuming experimental scale-up steps. To illustrate this approach, a multiscale computational fluid dynamics (CFD) approach was utilized in this study to simulate a novel internally circulating fluidized bed reactor (ICR) for power production with integrated CO2 capture on an industrial scale. These simulations were made computationally feasible by using closures in a filtered two-fluid model (fTFM) to model the effects of important subgrid multiphase structures. The CFD simulations provided valuable insight regarding ICR behavior, predicting that CO2 capture efficiencies and purities above 95% can be achieved, and proposing a reasonable reactor size. The... [more]

In a biological treatment process, hydraulic retention time (HRT) has a certain effect on the operation of the reactor. This study investigated the effect of HRT on carbon sequestration in a two-stage anaerobic ammonium oxidation (anammox) process using a partial nitrification reactor and anammox reactor to determine the optimal carbon sequestration operating conditions. Molecular biotechnology was used to analyze the sludge in the reactor in order to explore the denitrification performance and to determine the carbon sequestration pathway of the microorganisms. The results show that the partial nitrification stage had the highest carbon sequestration rate (0.319 mg/mg·N) when the nitrogen loading rate (NLR) was 0.44 kg·N/m3/d. The NLR of the anammox stage was 0.13 kg·N/m3/d. When the HRT was 33.4 h, the carbon sequestration of the anammox reaction was at its highest, reaching 0.183 mg/mg·N. The results of microbial analysis show that the carbon-fixing gene cbbLR1 was present in the sl... [more]

The attainable region (AR) is a region in a performance space in which all physically realizable reactor network designs must exist. ARs have been used since the 1960s for solving reactor network synthesis problems. The benefits of these methods are that the feasibility of a performance target can be assessed prior to running a synthesis routine, the solutions they give are guaranteed to be physically realizable, and a design can be made robust to uncertainties in feed and performance targets by assessing whether a solution and the range of its possible values lie within the AR, just to name a few. In this article, the theory of attainable regions is extended to bring these benefits to the heat exchanger network (HEN) synthesis problem. Basic properties of the HEN-AR are proven and a synthesis method using the AR is presented with examples.

Thermochemical conversion of solid wastes through gasification offers the dual benefit of production of high-value fuels and
environmentally friendly waste disposal. Waste tires in particular may be a suitable feedstock for gasification as a result of their
high energy content (LHV of approximately 34 MJ/kg, higher than coal), high volatile matter content, and low ash content. Rotary
kilns for steam gasification are a promising and technologically mature option to handle such difficult solid wastes that have a
wider range of compositions, particle sizes, and moisture contents. In this paper, we propose a novel process for production of
liquefied synthetic natural gas (SNG) from waste tires. We use experimental data available in the open literature to represent the
complex steam gasification unit operation and study three design cases: Without CCS, with precombustion CCS and with preand postcombustion CCS in two locations: USA and Norway. The thermodynamic, economic and environmen... [more]

This paper presents the process design and assessment of a sugarcane-based ethanol production system that combines the usage of both mass and heat integration (pinch analysis) strategies to enhance the process efficiency and renewability performance. Three configurations were analyzed: (i) Base case: traditional ethanol production (1G); (ii) mass-integrated (1G2G); and (iii) mass and heat-integrated system (1G2G-HI). The overall assessment of these systems was based on complementary approaches such as mass and mass−heat integration, energy and exergy analysis, exergy-based greenhouse gas (GHG) emissions, and renewability exergy criteria. The performances of the three cases were assessed through five key performance indicators (KIPs) divided into two groups: one is related to process performance, namely, energy efficiency, exergy efficiency, and average unitary exergy cost (AUEC), and the other one is associated to environmental performance i.e., exergy-based CO2-equation emissions and... [more]

Renewable liquid biofuels for transportation have recently attracted enormous global attention due to their potential to provide a sustainable alternative to fossil fuels. In recent years, the attention has shifted from first-generation bioethanol to the production of higher molecular weight alcohols, such as biobutanol, from cellulosic feedstocks. The economic feasibility of such processes depends on several parameters such as the cost of raw materials, the fermentation performance and the energy demand for the pretreatment of biomass and downstream processing. In this work, two conceptual process scenarios for isobutanol production, one with and one without integrated product removal from the fermentor by vacuum stripping, were developed and evaluated using SuperPro Designer®. In agreement with previous publications, it was concluded that the fermentation titer is a crucial parameter for the economic competitiveness of the process as it is closely related to the energy requirements f... [more]

An intensified three-step reaction-separation process for the production of bio-jet diesel from tryglycerides and petro-diesel mixtures is proposed. The intensified reaction-separation process considers three sequentially connected sections: (1) a triglyceride hydrolysis section with a catalytic heterogeneous reactor, which is used to convert the triglycerides of the vegetable oils into the resultant fatty acids. The separation of the pure fatty acid from glycerol and water is performed by a three-phase flash drum and two conventional distillation columns; (2) a co-hydrotreating section with a reactive distillation column used to perform simultaneously the deep hydrodesulphurisation (HDS) of petro-diesel and the hydrodeoxigenation (HDO), decarbonylation and decarboxylation of the fatty acids; and (3) an isomerization-cracking section with a hydrogenation catalytic reactor coupled with a two-phase flash drum is used to produce bio-jet diesel with the suitable fuel features required by t... [more]

This paper presents a web-based tool for the optimization of biomass-to-chemicals processing pathways. The tool provides a user-friendly grpahical user interface (GUI) for building a process superstructure, offers the possibility of uploading data from Aspen Plus simulations and generates an optimization code to find the pathway that minimizes the annualized costs or maximizes the net present value. A processing pathway from residues to lactic acid is used to discuss and illustrate the main features of the tool.

A new process for conversion of sugarcane bagasse to ethanol was analyzed for production costs and energy consumption using experimental results. The process includes a sequential three-stage deacetylation, hot water, and disk-refining pretreatment and a commercial glucose-xylose fermenting S. cerevisiae strain. The simultaneous saccharification and co-fermentation (SScF) step used was investigated at two solids loadings: 10% and 16% w/w. Additionally, a sensitivity analysis was conducted for the major operating parameters. The minimum ethanol selling price (MESP) varied between $4.91and $4.52/gal ethanol. The higher SScF solids loading (16%) reduced the total operating, utilities, and production costs by 9.5%, 15.6%, and 5.6%, respectively. Other important factors in determining selling price were costs for fermentation medium and enzymes (e.g., cellulases). Hence, these findings support operating at high solids and producing enzymes onsite as strategies to minimize MESP.