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Records Added in March 2023
Records added in March 2023
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4626. LAPSE:2023.21569
Modelling Heat Pumps with Variable EER and COP in EnergyPlus: A Case Study Applied to Ground Source and Heat Recovery Heat Pump Systems
March 22, 2023 (v1)
Subject: Modelling and Simulations
Keywords: buildings, EnergyPlus, heat pumps
Dynamic energy modelling of buildings is a key factor for developing new strategies for energy management and consumption reduction. For this reason, the EnergyPlus software was used to model a near-zero energy building (Smart Energy Buildings, SEB) located in Savona, Italy. In particular, the focus of the present paper concerns the modeling of the ground source water-to-water heat pump (WHP) and the air-to-air heat pump (AHP) installed in the SEB building. To model the WHP in EnergyPlus, the Curve Fit Method was selected. Starting from manufacturer data, this model allows to estimate the COP of the HP for different temperature working conditions. The procedure was extended to the AHP. This unit is a part of the air-handling unit and it is working as a heat recovery system. The results obtained show that the HP performance in EnergyPlus can closely follow manufacturer data if proper input recasting is performed for EnergyPlus simulations. The present paper clarifies a long series of mi... [more]
4627. LAPSE:2023.21568
Multi-State Household Appliance Identification Based on Convolutional Neural Networks and Clustering
March 22, 2023 (v1)
Subject: System Identification
Keywords: non-intrusive load monitoring, the identification of appliances states, the identification of appliances types
Non-intrusive load monitoring, a convenient way to discern the energy consumption of a house, has been studied extensively. However, most research works have been carried out based on a hypothetical condition that each electric appliance has only one running state. This leads to low identification accuracy for multi-state electric appliances. To deal with this problem, a method for identifying the type and state of electric appliances based on a power time series is proposed in this paper. First, to identify the type of appliance, a convolutional neural network model was constructed that incorporated residual modules. Then, a k-means clustering algorithm was applied to calculate the number of states of the appliance. Finally, in order to identify the states of the appliances, different k-means clustering models were established for different multi-state electric appliances. Experimental results show effectiveness of the proposed method in identifying both the type and the running state... [more]
4628. LAPSE:2023.21567
Analysis of the Dissolution of CH4/CO2-Mixtures into Liquid Water and the Subsequent Hydrate Formation via In Situ Raman Spectroscopy
March 22, 2023 (v1)
Subject: Materials
Keywords: Carbon Dioxide, gas hydrates, in situ Raman spectroscopy, methane, molar ratio
We report an experimental study for the investigation into the suitability of hydrate formation processes for the purification of methane (CH4) from carbon dioxide (CO2) at a sub-cooling temperature of 6 K and a pressure of 4 MPa. The experiments were conducted in a stirred batch reactor. Three different initial CH4/CO2 mixtures with methane fractions of 70.1 mol%, 50.3 mol%, and 28.5 mol% were tested. The separation efficiency was quantified by measuring in situ via Raman spectroscopy the ratios of CH4/CO2 in the gas mixture, the liquid water-rich phase before hydrate formation, and the solid hydrate phase after the onset of the hydrate formation. The results indicated that the main separation effect is obtained due to the preferential dissolution of CO2 into the liquid water-rich phase before the onset of the hydrate formation.
4629. LAPSE:2023.21566
Limitations and Characterization of Energy Storage Devices for Harvesting Applications
March 22, 2023 (v1)
Subject: Materials
Keywords: energy harvesting, LiPo batteries, self-discharge, storage devices, super-capacitors
This paper aims to study the limitations and performances of the main energy storage devices commonly used in energy harvesting applications, namely super-capacitors (SC) and lithium polymer (LiPo) batteries. The self-discharge phenomenon is the main limitation to the employment of SCs to store energy for a long time, thus reducing efficiency and autonomy of the energy harvesting system. Therefore, the analysis of self-discharge trends was carried out for three different models of commercial SCs, describing the phenomenon in terms of self-discharge rate and internal resistance. In addition, physical interpretations concerning the self-discharge mechanism based on the experimental data are provided, thus explaining the two super-imposed phenomena featured by distinct time constants. Afterwards, the dependence of self-discharge phenomenon from the charging time duration (namely, SCs charged at 5 V and then kept under charge for one or five hours) was analyzed; by comparing the voltage dr... [more]
4630. LAPSE:2023.21565
Production and Characterization of Biodiesel Derived from a Novel Source Koelreuteria paniculata Seed Oil
March 22, 2023 (v1)
Subject: Energy Systems
Keywords: Koelreuteria paniculata biodiesel, non-edible feedstock, Optimization, physicochemical characterization, transesterification
Biodiesel is a clean and renewable fuel, which is considered as the best alternative to diesel fuel, but the feedstock contributes more than 70% of the cost. The most important constituent essential for biodiesel development is to explore cheap feedstock with high oil content. In this work, we found novel non-edible plant seeds of Koelreuteria paniculata (KP) with high oil contents of 28−30 wt.% and low free fatty acid contents (0.91%), which can serve as a promising feedstock for biodiesel production. KP seed oil can convert into biodiesel/fatty acid methyl esters (FAMEs) by base-catalyzed transesterification with the highest biodiesel production of 95.2% after an optimization process. We obtained the optimal transesterification conditions, i.e., oil/methanol ratio (6:1), catalyst concentration (0.32), reaction temperature (65 °C), stirring rate (700 rpm), and reaction time (80 min). The physico-chemical properties and composition of the FAME were investigated and compared with minera... [more]
4631. LAPSE:2023.21564
Eggshell-Membrane-Derived Carbon Coated on Li2FeSiO4 Cathode Material for Li-Ion Batteries
March 22, 2023 (v1)
Subject: Materials
Lithium iron orthosilicate (LFS) cathode can be prepared via the polyol-assisted ball milling method with the incorporation of carbon derived from eggshell membrane (ESM) for improving inherent poor electronic conduction. The powder X-ray diffraction (XRD) pattern confirmed the diffraction peaks without any presence of further impure phase. Overall, 9 wt.% of carbon was loaded on the LFS, which was identified using thermogravimetric analysis. The nature of carbon was described using parameters such as monolayer, and average surface area was 53.5 and 24 m2 g−1 with the aid of Langmuir and Brunauer−Emmett−Teller (BET) surface area respectively. The binding energy was observed at 285.66 eV for C−N owing to the nitrogen content in eggshell membrane, which provides more charge carriers for conduction. Transmission electron microscopy (TEM) images clearly show the carbon coating on the LFS, the porous nature of carbon, and the atom arrangements. From the cyclic voltammetry (CV) curve, the ra... [more]
4632. LAPSE:2023.21563
The Senescence (Stay-Green)—An Important Trait to Exploit Crop Residuals for Bioenergy
March 22, 2023 (v1)
Subject: System Identification
Keywords: bioenergy, breeding, chlorophyll, genetics, high-throughput phenotyping, maize and rice, quantitative genetics, senescence, stay-green
In this review, we present a comprehensive revisit of past research and advances developed on the stay-green (SG) paradigm. The study aims to provide an application-focused review of the SG phenotypes as crop residuals for bioenergy. Little is known about the SG trait as a germplasm enhancer resource for energy storage as a system for alternative energy. Initially described as a single locus recessive trait, SG was shortly after reported as a quantitative trait governed by complex physiological and metabolic networks including chlorophyll efficiency, nitrogen contents, nutrient remobilization and source-sink balance. Together with the fact that phenotyping efforts have improved rapidly in the last decade, new approaches based on sensing technologies have had an impact in SG identification. Since SG is linked to delayed senescence, we present a review of the term senescence applied to crop residuals and bioenergy. Firstly, we discuss the idiosyncrasy of senescence. Secondly, we present... [more]
4633. LAPSE:2023.21562
New Criteria to Characterize the Waste Heat Recovery
March 22, 2023 (v1)
Subject: Energy Systems
Waste heat recovery is an actual goal. The best way to valorize waste heat is to use it directly with the appropriate level of temperature. If the temperature level is insufficient, many reverse machine configurations are available in order to obtain the appropriate conditions (the most known are heat pumps and heat transformers). Finally, the remaining unused heat could be converted to any noble form of energy (mechanical, electrical essentially). We propose here to examine, with a new point of view, the thermomechanical conversion limit of waste heat. This limit corresponds to adiabatic conversion for an endo-reversible Carnot engine, with a perfect thermal contact at the atmospheric sink (supposed infinite). The Carnot−Chambadal model version is applied to latent and sensible heat recovery cases. The results associated with these two cases differ fundamentally. Comments are provided on the two studied cases, and new criteria to characterize the corresponding waste heat recovery are... [more]
4634. LAPSE:2023.21561
Sustainable Solutions for Green Financing and Investment in Renewable Energy Projects
March 22, 2023 (v1)
Subject: Energy Systems
Keywords: community-based trust funds, green credit guarantee scheme, green finance, green investment, Renewable and Sustainable Energy
The lack of long-term financing, the low rate of return, the existence of various risks, and the lack of capacity of market players are major challenges for the development of green energy projects. This paper aimed to highlight the challenges of green financing and investment in renewable energy projects and to provide practical solutions for filling the green financing gap. Practical solutions include increasing the role of public financial institutions and non-banking financial institutions (pension funds and insurance companies) in long-term green investments, utilizing the spillover tax to increase the rate of return of green projects, developing green credit guarantee schemes to reduce the credit risk, establishing community-based trust funds, and addressing green investment risks via financial and policy de-risking. The paper also provides a practical example of the implementation of the proposed tools.
4635. LAPSE:2023.21560
Research on Down-Regulation Cost of Flexible Combined Heat Power Plants Participating in Real-Time Deep Down-Regulation Market
March 22, 2023 (v1)
Subject: Energy Systems
Keywords: combined heat and power plant, cost of down-regulation, flexibility, real-time deep down-regulation market
The issue of real-time deep down-regulation ancillary service has received increasing attention in the Northeast of China. Participation of combined heat and power plants with multitype units and flexible heating devices in the market is investigated. This paper establishes a model of feasible operating region and the coal consumption function for the combined heat and power plant. An internal optimal dispatch model and the minimum overall electric power output model for the plant satisfying a given heat load are presented. Furthermore, the models of total cost for down-regulation and average cost for deep down-regulation in two levels are established. These models are validated based on the realistic data of the plant in the Northeast of China. In case studies, the influence factors and change rules of the minimum electric power output, the total cost, and the average cost of plants are analyzed.
4636. LAPSE:2023.21559
Natural Dyes from Mortiño (Vaccinium floribundum) as Sensitizers in Solar Cells
March 22, 2023 (v1)
Subject: Energy Systems
Keywords: anthocyanins, dye, efficiency, mortiño, sensitizer, solar cells
Photovoltaic energy presents environmental advantages; however, these advantages are limited by the cost of manufacturing solar cells and in many cases, scarce or dangerous materials are incorporated. Therefore, the use of natural dyes from mortiño (Vaccinium floribundum) as sensitizers in solar cells is proposed. The dyes were extracted by maceration in acidified methanol (HCl, citric acid and trifluoroacetic acid TFA) and were characterized by High-Performance Liquid Chromatography (HPLC), Thin-Layer Chromatography (TLC) and spectrometric methods (UV-Vis, IR and MS-MALDI). The construction and characterization of cells were in standard conditions. The study confirms that pigments in mortiño are flavonoids of the anthocyanidin group as: cyanidin-3-galactoside, and cyanidin-3-arabinoside. The efficiency of solar cells was between 0.18−0.26%; the extraction with TFA in methanol leads to the best performance. Although they have low power conversion efficiency, mortiño dyes could be an al... [more]
4637. LAPSE:2023.21558
Real-time Energy Management Strategy for Oil-Electric-Liquid Hybrid System based on Lowest Instantaneous Energy Consumption Cost
March 22, 2023 (v1)
Subject: Optimization
Keywords: energy management, global optimization, lowest instantaneous energy costs, oil–electric–hydraulic hybrid system
For the oil−electric−hydraulic hybrid power system, a logic threshold energy management strategy based on the optimal working curve is proposed, and the optimal working curve in each mode is determined. A genetic algorithm is used to determine the optimal parameters. For driving conditions, a real-time energy management strategy based on the lowest instantaneous energy cost is proposed. For braking conditions and subject to the European Commission for Europe (ECE) regulations, a braking force distribution strategy based on hydraulic pumps/motors and supplemented by motors is proposed. A global optimization energy management strategy is used to evaluate the strategy. Simulation results show that the strategy can achieve the expected control target and save about 32.14% compared with the fuel consumption cost of the original model 100 km 8 L. Under the New European Driving Cycle (NEDC) working conditions, the energy-saving effect of this strategy is close to that of the global optimizati... [more]
4638. LAPSE:2023.21557
Demand Forecasting for a Mixed-Use Building Using Agent-Schedule Information with a Data-Driven Model
March 22, 2023 (v1)
Subject: Planning & Scheduling
Keywords: buildings, data driven, demand prediction, electricity demand, thermal demand
There is great interest in data-driven modelling for the forecasting of building energy consumption while using machine learning (ML) modelling. However, little research considers classification-based ML models. This paper compares the regression and classification ML models for daily electricity and thermal load modelling in a large, mixed-use, university building. The independent feature variables of the model include outdoor temperature, historical energy consumption data sets, and several types of ‘agent schedules’ that provide proxy information that is based on broad classes of activity undertaken by the building’s inhabitants. The case study compares four different ML models testing three different feature sets with a genetic algorithm (GA) used to optimize the feature sets for those ML models without an embedded feature selection process. The results show that the regression models perform significantly better than classification models for the prediction of electricity demand a... [more]
4639. LAPSE:2023.21556
Aerodynamic Analysis of a Two-Bladed Vertical-Axis Wind Turbine Using a Coupled Unsteady RANS and Actuator Line Model
March 22, 2023 (v1)
Subject: Energy Systems
Keywords: actuator line method, OpenFOAM, torque control, URANS, vertical-axis turbine, wind energy
Close-packed contra-rotating vertical-axis turbines have potential advantages in wind and hydrokinetic power generation. This paper describes the development of a numerical model of a vertical axis turbine with a torque-controlled system using an actuator line model (ALM). The developed model, coupled with the open-source OpenFOAM computational fluid dynamics (CFD) code, is used to examine the characteristics of turbulent flow behind a single two-bladed vertical-axis turbine (VAT). The flow field containing the turbine is simulated by solving the unsteady Reynolds-averaged Navier-Stokes (URANS) equations with a k - ω shear stress transport (SST) turbulence model. The numerical model is validated against experimental measurements from a two-bladed H-type wind turbine. Turbine loading is predicted, and the vorticity distribution is investigated in the vicinity of the turbine. Satisfactory overall agreement is obtained between numerical predictions and measured data on thrust co... [more]
4640. LAPSE:2023.21555
Evaluation and Improvement of the Sound Quality of a Diesel Engine Based on Tests and Simulations
March 22, 2023 (v1)
Subject: Energy Systems
Keywords: diesel engine, Moore–Glasberg loudness, sharpness, sound evaluation, sound improvement
Traditional acoustic evaluation of a diesel engine generally uses the A-weighted sound pressure level (AWSPL) and radiated sound power to assess the noise of an engine prototype present in an experiment. However, this cannot accurately and comprehensively reflect the auditory senses of human subjects during the simulation stage. To overcome such shortage, the Moore−Glasberg loudness and sharpness approach is applied to evaluate and improve the sound quality (SQ) of a 16 V-type marine diesel engine, and synthesizing noise audio files. Through finite element (FE) simulations, the modes of the engine’s block and the average vibrational velocity of the entire engine surface were calculated and compared with the test results. By further applying an automatically matched layer (AML) approach, the engine-radiated sound pressure level (SPL) and sound power contributions of all engine parts were obtained. By analyzing the Moore−Glasberg loudness and sharpness characteristics of three critical s... [more]
4641. LAPSE:2023.21554
Dual Fuel Reaction Mechanism 2.0 including NOx Formation and Laminar Flame Speed Calculations Using Methane/Propane/n-Heptane Fuel Blends
March 22, 2023 (v1)
Subject: Energy Systems
Keywords: Arrhenius parameter, dual fuel combustion, ignition delay time, laminar flame speed, methane–propane–n-heptane mixtures, NOx, reaction kinetics, reaction rate coefficient, sensitivity analysis
This study presents the further development of the TU Wien dual fuel mechanism, which was optimized for simulating ignition and combustion in a rapid compression expansion machine (RCEM) in dual fuel mode using diesel and natural gas at pressures higher than 60 bar at the start of injection. The mechanism is based on the Complete San Diego mechanism with n-heptane extension and was attuned to the RCEM measurements to achieve high agreement between experiments and simulation. This resulted in a specific application area. To obtain a mechanism for a wider parameter range, the Arrhenius parameter changes performed were analyzed and updated. Furthermore, the San Diego nitrogen sub-mechanism was added to consider NOx formation. The ignition delay time-reducing effect of propane addition to methane was closely examined and improved. To investigate the propagation of the flame front, the laminar flame speed of methane−air mixtures was simulated and compared with measured values from literatur... [more]
4642. LAPSE:2023.21553
Multi-Disciplinary Optimization Design of Axial-Flow Pump Impellers Based on the Approximation Model
March 22, 2023 (v1)
Subject: Optimization
Keywords: approximation model, axial-flow pump, impeller, multi-disciplinary, optimization design
This study adopts a multi-disciplinary optimization design method based on an approximation model to improve the comprehensive performance of axial-flow pump impellers and fully consider the interaction and mutual influences of the hydraulic and structural designs. The lightweight research on axial-flow pump impellers takes the blade mass and efficiency of the design condition as the objective functions and the head, efficiency, maximum stress value, and maximum deformation value under small flow condition as constraints. In the optimization process, the head of the design condition remains unchanged or varies in a small range. Results show that the mass of a single blade was reduced from 0.947 to 0.848 kg, reaching a decrease of 10.47%, and the efficiency of the design condition increased from 93.91% to 94.49%, with an increase rate of 0.61%. Accordingly, the optimization effect was evident. In addition, the error between the approximate model results and calculation results of each r... [more]
4643. LAPSE:2023.21552
Linear-Gompertz Model-Based Regression of Photovoltaic Power Generation by Satellite Imagery-Based Solar Irradiance
March 22, 2023 (v1)
Subject: Energy Systems
Keywords: Gompertz model, numerical analysis, photovoltaic system performance, power output prediction, satellite-derived global horizontal irradiance
A simple yet accurate photovoltaic (PV) performance curve as a function of satellite-based solar irradiation is necessary to develop a PV power forecasting model that can cover all of South Korea, where more than 35,000 PV power plants are currently in operation. In order to express the nonlinear power output of the PV module with respect to the hourly global horizontal irradiance derived from satellite images, this study employed the Gompertz model, which is composed of three parameters and the sigmoid equation. The nonphysical behavior of the Gompertz model within the low solar irradiation range was corrected by combining a linear equation with the same gradient at the conjoint point. The overall fitness of Linear-Gompertz regression to the 242 PV power plants representing the country was R2 = 0.85 and nRMSE = 0.09. The Gompertz model coefficients showed normal distributions and equivariance of standard deviations of less than 15% by year and by season. Therefore, it can be conjectur... [more]
4644. LAPSE:2023.21551
Low-Carbon Impact of Urban Rail Transit Based on Passenger Demand Forecast in Baoji
March 22, 2023 (v1)
Subject: Environment
Keywords: carbon emission reduction, four-stage model, passenger demand, residents’ trip survey, urban rail transit
There are increasing traffic pollution issues in the process of urbanization in many countries; urban rail transit is low-carbon and widely regarded as an effective way to solve such problems. The passenger flow proportion of different transportation types is changing along with the adjustment of the urban traffic structure and a growing demand from passengers. The reduction of carbon emissions brought about by rail transit lacks specific quantitative research. Based on a travel survey of urban residents, this paper constructed a method of estimating carbon emissions from two different scenarios where rail transit is and is not available. This study uses the traditional four-stage model to forecast passenger volume demand at the city level and then obtains the basic target parameters for constructing the carbon emission reduction model, including the trip origin-destination (OD), mode, and corresponding distance range of different modes on the urban road network. This model was applied... [more]
4645. LAPSE:2023.21550
A Cloud-Based In-Field Fleet Coordination System for Multiple Operations
March 22, 2023 (v1)
Subject: Food & Agricultural Processes
Keywords: agricultural machinery, auto-steering system, collaborative operating system, field experiment, fleet management, flow-shop, Simulation
In large-scale arable farming, multiple sequential operations involving multiple machines must be carried out simultaneously due to restrictions of short time windows. However, the coordination and planning of multiple sequential operations is a nontrivial task for farmers, since each operation may have its own set of operational features, e.g., operating width and turning radius. Taking the two sequential operations—hoeing cultivation and seeding—as an example, the seeder has double the width of the hoeing cultivator, and the seeder must remain idle while waiting for the hoeing cultivator to finish two rows before it can commence its seeding operation. A flow-shop working mode can coordinate multiple machines in multiple operations within a field when different operations have different implement widths. To this end, an auto-steering-based collaborative operating system for fleet management (FMCOS) was developed to realize an in-field flow-shop working mode, which is often adopted by... [more]
4646. LAPSE:2023.21549
Modular Battery Charger for Light Electric Vehicles
March 22, 2023 (v1)
Subject: Energy Systems
Keywords: AC-DC power converters, interleaved control, land vehicles, lithium-ion batteries battery chargers, power factor correction, single-ended primary-inductor converter (SEPIC)
Rapid developments in energy storage and conversion technologies have led to the proliferation of low- and medium-power electric vehicles. Their regular operation typically requires an on-board battery charger that features small dimensions, high efficiency and power quality. This paper analyses an interleaved step-down single-ended primary-inductor converter (SEPIC) operating in the discontinuous conduction mode (DCM) for charging of battery-powered light electric vehicles such as an electric wheelchair. The required characteristics are achieved thanks to favourable arrangement of the inductors in the circuit: the input inductor is used for power factor correction (PFC) without additional elements, while the other inductor is used to provide galvanic isolation and required voltage conversion ratio. A modular interleaved structure of the converter helps to implement low-profile converter design with standard components, distribute the power losses and improve the performance. An optima... [more]
4647. LAPSE:2023.21548
Development of Scenarios for a Multi-Model System Analysis Based on the Example of a Cellular Energy System
March 22, 2023 (v1)
Subject: Modelling and Simulations
Keywords: cellular energy systems, energy system modelling, multi-model analysis, scenario development
Scenario analysis combined with system and market modelling is a well-established method to evaluate technological and societal developments and their impacts on future energy pathways. This paper presents a process-oriented method for developing consistent energy scenarios using multiple energy system models. Its added value is that the developed energy scenarios are consistent in a multi-model environment and practicable for a broader target group from scientists to practitioners. The scenarios consist of comprehensive storylines and systematically defined quantitative parameters. Following a step-by-step process, a condensed set of overlapping descriptors is generated and used to define the scenarios in a consistent parameter matrix. The set of descriptors allow consistent and comparable outputs independent of model-specific characteristics. The corresponding quantitative parameters can be used by diverse energy system tools. Using multiple models, a team of researchers can explore... [more]
4648. LAPSE:2023.21547
A Case Study on the Optimal Design of the Horizontal Wellbore Trajectory for Hydraulic Fracturing in Nong’an Oil Shale
March 22, 2023 (v1)
Subject: Energy Systems
Keywords: bedding planes, fracture initiation, horizontal wellbore trajectory, hydraulic fracturing, oil shale
A horizontal well with hydraulic fractures is key to forming a fracture network in oil shale for the generated hydrocarbon flows. By considering the influence of anisotropic strength, a prediction model is proposed for fracture initiation by studying different fracture initiation modes (FIMs) in oil shale: failure of the intact rock matrix and of the bedding planes. Through a case study on Nong’an oil shale, the influences of wellbore trajectory and bedding planes on the fracture initiation pressure (FIP), location (FIL), and FIM were analyzed and the induced changes in wellbore trajectory design were concluded. The preferred angle between the wellbore axis and the minimum horizontal principal stress was the same of 90° or 270°, when the lowest required FIP corresponded to the failure of the intact rock matrix. However, when the angle corresponded to the failure of the bedding planes, the preferred direction of the wellbore axis was away from the fixed direction and not corresponding t... [more]
4649. LAPSE:2023.21546
Catalytic Hydrotreatment of the Pyrolytic Sugar and Pyrolytic Lignin Fractions of Fast Pyrolysis Liquids Using Nickel Based Catalysts
March 22, 2023 (v1)
Subject: Energy Systems
Keywords: catalytic hydrotreatment, nickel-based catalysts, pyrolysis liquids, pyrolytic lignin, pyrolytic sugars
Catalytic hydrotreatment is recognized as an efficient method to improve the properties of pyrolysis liquids (PO) to allow co-feeding with fossil fuels in conventional refinery units. The promising catalyst recipes identified so far are catalysts with high nickel contents (38 to 57 wt.%), promoted by Cu, Pd, Mo and/or a combination, and supported by SiO2, SiO2-ZrO2, SiO2-ZrO2-La2O3 or SiO2-Al2O3. To gain insights into the reactivity of the pyrolytic sugar (PS) and pyrolytic lignin (PL) fraction of PO, hydrotreatment studies (350 °C, 120 bar H2 pressure (RT) for 4 h) were performed in a batch autoclave. Catalyst performance was evaluated by considering the product properties (H/C ratio, the charring tendency (TGA) and molecular weight distribution (GPC)) and the results were compared with a benchmark Ru/C catalyst. All Ni based catalysts gave products oils with a higher H/C compared to Ru/C. The Mo promoted catalyst performed best, giving a product with the highest H/C ratio (1.54) and... [more]
4650. LAPSE:2023.21545
Analysis of Gas Composition and Nitrogen Sources of Shale Gas Reservoir under Strong Tectonic Events: Evidence from the Complex Tectonic Area in the Yangtze Plate
March 22, 2023 (v1)
Subject: Energy Systems
Keywords: atmospheric source, deep crust-upper mantle source, deep fault, detachment layers, nitrogen isotope, stratification planes, thermal evolution of organic matter, volcanic activity
Strong tectonic movement brings great risk to exploration of shale gas in southern China, especially in Lower Cambrian shale with complex tectonic backgrounds, which has good hydrocarbon-generation matter but low or no gas content. In this paper, the Lower Cambrian shale from the southeast Chongqing region, located in the Upper Yangtze Platform, and the Xiuwu Basin, located in the Lower Yangtze Platform, were selected as the research objects. First, the gas components in shale gas samples were measured, then analysis of nitrogen isotopic was used to reveal the nitrogen sources. Using regional geological backgrounds, core description, and seismic interpretation, combined with the perpendicular and parallel permeability test and focused ion beam−helium ion microscopy (FIB−HIM) observation, the reasons for high content of nitrogen in the Lower Cambrian shale from the Xiuwu Basin and the Southeast Chongqing region were clarified. The results indicate that the main sources of nitrogen in th... [more]
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