The achievement of a carbon-free emissions economy is one of the main goals to reduce climate change and its negative effects. Scientists and technological improvements have followed this trend, improving efficiency, and reducing carbon and other compounds that foment climate change. Since the main contributor of these emissions is transportation, detaching this sector from fossil fuels is a necessary step towards an environmentally friendly future. Therefore, an evaluation of alternative fuels will be needed to find a suitable replacement for traditional fossil-based fuels. In this scenario, hydrogen appears as a possible solution. However, the existence of the drawbacks associated with the application of H2-ICE redirects the solution to dual-fuel strategies, which consist of mixing different fuels, to reduce negative aspects of their separate use while enhancing the benefits. In this work, a new combustion modelling approach based on machine learning (ML) modeling is proposed for pre... [more]

In recent years, several researchers have studied the potential use of ammonia (NH3) as an energy vector, focused on the techno-economic advantages and challenges for full global deployment. The use of ammonia as fuel is seen as a strategy to support decarbonization; however, to confirm the sustainability of the shift to ammonia as fuel in thermal engines, a study of the environmental profile is needed. This paper aims to assess the environmental life cycle impacts of ammonia-based electricity generated in a combined heat and power cycle for different ammonia production pathways. A cradle-to-gate assessment was developed for both ammonia production and ammonia-based electricity generation. The results show that electrolysis-based ammonia from renewable and nuclear energy have a better profile in terms of global warming potential (0.09−0.70 t CO2-eq/t NH3), fossil depletion potential (3.62−213.56 kg oil-eq/t NH3), and ozone depletion potential (0.001−0.082 g CFC-11-eq/t NH3). In additio... [more]

The effects of climate change and global warming are arising a new awareness on the impact of our daily life. Power generation for transportation and mobility as well as in industry is the main responsible for the greenhouse gas emissions. Indeed, currently, 80% of the energy is still produced by combustion of fossil fuels; thus, great efforts need to be spent to make combustion greener and safer than in the past. For this reason, a review of the most recent gas turbines combustion strategy with a focus on fuels, combustion techniques, and burners is presented here. A new generation of fuels for gas turbines are currently under investigation by the academic community, with a specific concern about production and storage. Among them, biofuels represent a trustworthy and valuable solution in the next decades during the transition to zero carbon fuels (e.g., hydrogen and ammonia). Promising combustion techniques explored in the past, and then abandoned due to their technological complexit... [more]

Recent studies have demonstrated that ammonia is an emerging energy vector for the distribution of hydrogen from stranded sources. However, there are still many unknown parameters that need to be understood before ammonia can be a substantial substitute in fuelling current power generation systems. Therefore, current attempts have mainly utilised ammonia as a substitute for natural gas (mainly composed of methane) to mitigate the carbon footprint of the latter. Co-firing of ammonia/methane is likely to occur in the transition of replacing carbonaceous fuels with zero-carbo options. Hence, a better understanding of the combustion performance, flame features, and radical formation of ammonia/methane blends is required to address the challenges that these fuel combinations will bring. This study involves an experimental approach in combination with numerical modelling to elucidate the changes in radical formation across ammonia/methane flames at various concentrations. Radicals such as OH... [more]

Biological methanation as a method of sector coupling between electric and gas grids is expected to be an integral part of the green energy change. Wastewater treatment plants (WWTPs) involving anaerobic digestion (AD) allow existing infrastructure to operate as energy conversion plants, to close carbon cycles and to generate long-term storable energy in the form of biomethane. Therefore, municipal raw sludge and additional organic residuals (co-substrates) are converted into biogas. Hydrogen is added to convert the carbon dioxide in the biogas into methane via biological methanation (BM). In this study, the energy amount that is convertible via BM in municipal digesters in Austria was calculated. The amount of energy, which can be transformed from electric surplus energy into biomethane, was assessed. Operational data from lab-scale digesters were combined with data from 28 Austrian full-scale wastewater treatment plants with AD. They represent 9.2 Mio population equivalents (PE), or... [more]

Germany’s energy transition, known as ‘Energiewende’, was always very progressive. However, it came technically to a halt at the question of large-scale, seasonal energy storage for wind and solar, which was not available. At the end of the 2000s, we combined our knowledge of both electrical and process engineering, imitated nature by copying photosynthesis and developed Power-to-Gas by combining water electrolysis with CO2-methanation to convert water and CO2 together with wind and solar power to synthetic natural gas. Storing green energy by coupling the electricity with the gas sector using its vast TWh-scale storage facility was the solution for the biggest energy problem of our time. This was the first concept that created the term ‘sector coupling’ or ‘sectoral integration’. We first implemented demo sites, presented our work in research, industry and ministries, and applied it in many macroeconomic studies. It was an initial idea that inspired others to rethink electricity as we... [more]

This paper provides a comprehensive review and critical analysis of the latest research results in addition to an overview of the future challenges and opportunities regarding the use of hydrogen to power internal combustion engines (ICEs). The experiences and opinions of various international research centers on the technical possibilities of using hydrogen as a fuel in ICE are summarized. The advantages and disadvantages of the use of hydrogen as a solution are described. Attention is drawn to the specific physical, chemical, and operational properties of hydrogen for ICEs. A critical review of hydrogen combustion concepts is provided, drawing on previous research results and experiences described in a number of research papers. Much space is devoted to discussing the challenges and opportunities associated with port and direct hydrogen injection technology. A comparison of different fuel injection and ignition strategies and the benefits of using the synergies of selected solutions... [more]

The energy security landscape that we envisage in 2050 will be different from that of today. Meeting the future energy needs of the armed forces will be a key challenge, not least for military security. The World Energy Council’s World Energy Scenarios forecast that the world’s population will rise to 10 billion by 2050, which will also necessitate an increase in the size of the armed forces. In this context, energy extraction, distribution, and storage become essential to stabilizing the imbalance between production and demand. Among the available solutions, Power to Hydrogen (P2H) is one of the most appealing options. However, despite the potential, many obstacles currently hinder the development of the P2H market. This article aims to identify and analyse existing barriers to the introduction of P2H technologies that use hydrogen. The holistic approach used, which was based on a literature survey, identified obstacles and possible strategies for overcoming them. The research conduct... [more]

The effects of doping manganese ions into a cerium oxide lattice for a thermochemical two-step water-splitting cycle to produce oxygen and hydrogen and new synthesis methods were experimentally investigated. In order to comparison of oxygen/hydrogen producing performance, pristine CeO2, a coprecipitation method for Mn-CeO2, and a direct depositing method for Mn-CeO2 with different particle sizes (50~75, 100−212, over 212 μm) and doping extents (0, 5, 15 mol%) were tested in the context of synthesis and fabrication processes of reactive metal oxide coated ceramic foam devices. Sample powders were coated onto zirconia (magnesium partially stabilized zirconia oxide, MPSZ) porous foam at 30 weight percent using spin coating or a direct depositing method, tested using a solar reactor at 1400 °C as a thermal reduction step and at 1200 °C as a water decomposition step for five repeated cycles. The sample foam devices were irradiated using a 3-kWth sun-simulator, and all reactive foam devices... [more]

Hydrogen derived from biomass feedstock (biohydrogen) can play a significant role in Germany’s hydrogen economy. However, the bioenergy potential and environmental benefits of biohydrogen production are still largely unknown. Additionally, there are no uniform evaluation methods present for these emerging technologies. Therefore, this paper presents a methodological approach for the evaluation of bioenergy potentials and the attainable environmental impacts of these processes in terms of their carbon footprints. A procedure for determining bioenergy potentials is presented, which provides information on the amount of usable energy after conversion when applied. Therefore, it elaborates a four-step methodical conduct, dealing with available waste materials, uncertainties of early-stage processes, and calculation aspects. The bioenergy to be generated can result in carbon emission savings by substituting fossil energy carriers as well as in negative emissions by applying biohydrogen prod... [more]

Due to the increasing share of renewable energy sources in the electrical network, the focus on decarbonization has extended into other energy sectors. The gas sector is of special interest because it can offer seasonal storage capacity and additional flexibility to the electricity sector. In this paper, we present a new simulation method designed for hydrogen-enriched natural gas network simulation. It can handle different gas compositions and is thus able to accurately analyze the impact of hydrogen injections into natural gas pipelines. After describing the newly defined simulation method, we demonstrate how the simulation tool can be used to analyze a hydrogen-enriched gas pipeline network. An exemplary co-simulation of coupled power and gas networks shows that hydrogen injections are severely constrained by the gas pipeline network, highlighting the importance and necessity of considering different gas compositions in the simulation.

Nowadays, many aircraft manufacturers are working on new airplanes to reduce the environmental footprint and therefore meet greenhouse gas reduction targets. The concept of more electric aircraft is one of the solutions to achieve this goal. For this aircraft architecture, several electrical devices are used in order to supply propulsive and non-propulsive functions. This paper focuses on the sizing of a direct hybridization system to supply a non-propulsive function in an aircraft. It is composed of a High-Temperature Proton Exchange Membrane Fuel Cell (HT-PEMFC) and a lithium-ion (Li-ion) battery. This sizing is based on a static model of each storage device. The accuracy of these models is compared with dynamic models during a simulation for an aeronautical mission. Static models are implemented in a genetic algorithm to achieve two goals: on the one hand, satisfy the mission profile, and on the other hand, minimize the mass of the system. Other criteria, such as battery and fuel ce... [more]

The flammable hydrogen-blended methane−air and natural gas−air mixtures raise specific safety and environmental issues in the industry and transportation; therefore, their explosion characteristics such as the explosion limits, explosion pressures, and rates of pressure rise have significant importance from a safety point of view. At the same time, the laminar burning velocities are the most useful parameters for practical applications and in basic studies for the validation of reaction mechanisms and modeling turbulent combustion. In the present study, an experimental and numerical study of the effect of hydrogen addition on the laminar burning velocity (LBV) of methane−air and natural gas−air mixtures was conducted, using mixtures with equivalence ratios within 0.90 and 1.30 and various hydrogen fractions rH within 0.0 and 0.5. The experiments were performed in a 14 L spherical vessel with central ignition at ambient initial conditions. The LBVs were calculated from p(t) data, determ... [more]

Blending hydrogen into the natural gas infrastructure is becoming a very promising practice to increase the exploitation of renewable energy sources which can be used to produce “green” hydrogen. Several research projects and field experiments are currently aimed at evaluating the risks associated with utilization of the gas blend in end-use devices such as the gas meters. In this paper, the authors present the results of experiments aimed at assessing the effect of hydrogen injection in terms of the durability of domestic gas meters. To this end, 105 gas meters of different measurement capabilities and manufacturers, both brand-new and withdrawn from service, were investigated in terms of accuracy drift after durability cycles of 5000 and 10,000 h with H2NG mixtures and H2 concentrations of 10% and 15%. The obtained results show that there is no metrologically significant or statistically significant influence of hydrogen content on changes in gas meter indication errors after subject... [more]

Hydrogen as carbon-free fuel is a very promising candidate for climate-neutral internal combustion engine operation. In comparison to other renewable fuels, hydrogen does obviously not produce CO2 emissions. In this work, two concepts of hydrogen internal combustion engines (H2-ICEs) are investigated experimentally. One approach is the modification of a state-of-the-art gasoline passenger car engine using hydrogen direct injection. It targets gasoline-like specific power output by mixture enrichment down to stoichiometric operation. Another approach is to use a heavy-duty diesel engine equipped with spark ignition and hydrogen port fuel injection. Here, a diesel-like indicated efficiency is targeted through constant lean-burn operation. The measurement results show that both approaches are applicable. For the gasoline engine-based concept, stoichiometric operation requires a three-way catalyst or a three-way NOX storage catalyst as the primary exhaust gas aftertreatment system. For the... [more]

An opportunity to decarbonise the offshore oil and gas sector lies in the integration of renewable energy sources with energy storage in a hybrid energy system (HES). Such concept enables maximising the exploitation of carbon-free renewable power, while minimising the emissions associated with conventional power generation systems such as gas turbines. Offshore plants, in addition to electrical and mechanical power, also require process heat for their operation. Solutions that provide low-emission heat in parallel to power are necessary to reach a very high degree of decarbonisation. This paper investigates different options to supply process heat in offshore HES, while the electric power is mostly covered by a wind turbine. All HES configurations include energy storage in the form of hydrogen tied to proton exchange membrane (PEM) electrolysers and fuel cells stacks. As a basis for comparison, a standard configuration relying solely on a gas turbine and a waste heat recovery unit is c... [more]

Hydrogen is fast becoming a new international “super fuel” to accelerate global climate change ambitions. This paper has two inter-weaving themes. Contextually, it focuses on the potential impact of the EU’s new Carbon Border Adjustment Mechanism (CBAM) on fossil fuel-generated as opposed to green hydrogen imports. The CBAM, as a transnational carbon adjustment mechanism, has the potential to impact international trade in energy. It seeks both a level playing field between imports and EU internal markets (subject to ambitious EU climate change policies), and to encourage emissions reduction laggards through its “carbon diplomacy”. Countries without a price on carbon will be charged for embodied carbon in their supply chains when they export to the EU. Empirically, we focus on two hydrogen export/import case studies: Australia as a non-EU state with ambitions to export hydrogen, and Germany as an EU Member State reliant on energy imports. Energy security is central to energy trade debat... [more]

An uninterrupted chain of energy supplies is the core of every activity, without exception for the operations of the North Atlantic Treaty Organization. A robust and efficient energy supply is fundamental for the success of missions and a guarantee of soldier safety. However, organizing a battlefield energy supply chain is particularly challenging because the risks and threats are particularly high. Moreover, the energy supply chain is expected to be flexible according to mission needs and able to be moved quickly if necessary. In line with ongoing technological changes, the growing popularity of hydrogen is undeniable and has been noticed by NATO as well. Hydrogen is characterised by a much higher energy density per unit mass than other fuels, which means that hydrogen fuel can increase the range of military vehicles. Consequently, hydrogen could eliminate the need for risky refuelling stops during missions as well as the number of fatalities associated with fuel delivery in combat ar... [more]

In recent years, the growing concern for air quality has led to the development of sustainable vehicles to replace conventional internal combustion engine (ICE) vehicles. Currently, the most widespread technology in Europe and Portugal is that of Battery Electric Vehicles (BEV) or plug-in HEV (PHEV) electric cars, but hydrogen-based transport has also shown significant growth in the commercialization of Fuel Cell Electric Vehicles (FCEV) and in the development of new infrastructural schemes. In the current panorama of EV, particular attention should be paid to hydrogen technology, i.e., FCEVs, which is potentially a valid alternative to BEVs and can also be hybrid (FCHEV) and plug-in hybrid (FCPHEV). Several sources cited show a positive trend of hydrogen in the transport sector, identifying a growing trend in the expansion of hydrogen infrastructure, although at this time, it is still at an early stage of development. At the moment, the cost of building the infrastructure is still hig... [more]

As an energy-intensive industry sector, the glass industry is strongly affected by the increasingly stringent climate protection targets. [d=Rev2] As However, asestablished combustion-based production systems ensure high process stability and glass quality, an immediate switch to low greenhouse gas emission processes is [d=Rev2] difficulthighly challenging. To approach these challenges, this work investigates a step-by-step integration of a Power-to-Hydrogen concept into established oxyfuel glass melting processes using a simulation approach. This is complemented by a case study for economic analysis on a selected German glass industry site by simulating the power production of a nearby renewable energy park and subsequent optimization of the power-to-hydrogen plant performance and capacities. The results of this study [d=Rev2] indicateshow, that the proposed system can reduce specific carbon dioxide emissions by up to 60%, while increasing specific energy demand by a maximum of 25%. I... [more]

Hydrogen is a versatile feedstock for various chemical and industrial processes, as well as an energy carrier. Dedicated hydrogen infrastructure is envisioned to conceptualize in hydrogen valleys, which link together the suppliers and consumers of hydrogen, heat, oxygen, and electricity. One potential hydrogen valley is the Bay of Bothnia, located in the northern part of the Baltic Sea between Finland and Sweden. The region is characterized as having excellent wind power potential, a strong forest cluster with numerous pulp and paper mills, and significant iron ore and steel production. The study investigates the hydrogen-related opportunities in the region, focusing on infrastructural requirements, flexibility, and co-operation of different sectors. The study found that local wind power capacity is rapidly increasing and will eventually enable the decarbonization of the steel sector in the area, along with moderate Power-to-X implementation. In such case, the heat obtained as a by-pro... [more]

Decarbonization of the shipping sector is inevitable and can be made by transitioning into low- or zero-carbon marine fuels. This paper reviews 22 potential pathways, including conventional Heavy Fuel Oil (HFO) marine fuel as a reference case, “blue” alternative fuel produced from natural gas, and “green” fuels produced from biomass and solar energy. Carbon capture technology (CCS) is installed for fossil fuels (HFO and liquefied natural gas (LNG)). The pathways are compared in terms of quantifiable parameters including (i) fuel mass, (ii) fuel volume, (iii) life cycle (Well-To-Wake—WTW) energy intensity, (iv) WTW cost, (v) WTW greenhouse gas (GHG) emission, and (vi) non-GHG emissions, estimated from the literature and ASPEN HYSYS modelling. From an energy perspective, renewable electricity with battery technology is the most efficient route, albeit still impractical for long-distance shipping due to the low energy density of today’s batteries. The next best is fossil fuels with CCS (a... [more]

Hydrogen is increasingly receiving a primary role as an energy vector in ensuring the achievement of the European decarbonization goals by 2050. In fact, Hydrogen could be produced also by electrolysis of water using renewable sources, such as photovoltaic and wind power, being able to perform the energy storage function, as well as through injection into natural gas infrastructures. However, hydrogen injection directly impacts thermodynamic properties of the gas itself, such as density, calorific value, Wobbe index, sound speed, etc. Consequently, this practice leads to changes in metrological behavior, especially in terms of volume and gas quality measurements. In this paper, the authors present an overview on the impact of hydrogen injection in natural gas measurements. In particular, the changes in thermodynamic properties of the gas mixtures with different H2 contents have been evaluated and the effects on the accuracy of volume conversion at standard conditions have been investig... [more]

The aim of the study was to assess the effect of anode materials, namely a carbon nanotube (CNT)-buckypaper and a commercial carbon paper (CP) on the performance of a two-chamber microbial electrolysis cell (MEC), in terms of hydrogen production and main electrochemical characteristics. The experiments were performed using both acetate-based synthetic wastewater and real wastewater, specifically the effluent of a dark fermentative hydrogenogenic reactor (fermentation effluent), using cheese whey (CW) as substrate. The results showed that CP led to higher hydrogen production efficiency and current density compared to the CNT-buckypaper anode, which was attributed to the better colonization of the CP electrode with electroactive microorganisms, due to the negative effects of CNT-based materials on the bacteria metabolism. By using the fermentation effluent as substrate, a two-stage process is developed, where dark fermentation (DF) of CW for hydrogen production occurs in the first step,... [more]

This work, dedicated to a mathematical description of energy transition scenarios, consists of three main parts. The first part describes modern trends and problems of the energy sector. A large number of charts reflecting the latest updates in energy are provided. The COVID-2019 pandemic’s impacts on the energy sector are also included. The second part of the paper is dedicated to the analysis of energy consumption and the structure of the world fuel and energy balance. Furthermore, a detailed description of energy-efficient technologies is given. Being important and low-carbon, hydrogen is discussed, including its advantages and disadvantages. The last part of the work describes the mathematical tool developed by the authors. The high availability of statistical data made it possible to identify parameters used in the algorithm with the least squares method and verify the tool. Performing several not complicated steps of the algorithm, the tool allows calculating the deviation of the... [more]