In this paper, the inhibitory effects of added hydrogen in reactor headspace on fermentative hydrogen production from acidogenesis of glucose by a bacterium, Clostridium acetobutylicum, was investigated experimentally in a batch reactor. It was observed that hydrogen itself became an acute inhibitor of hydrogen production if it accumulated excessively in the reactor headspace. A mathematical model to simulate and predict biological hydrogen production process was developed. The Monod model, which is a simple growth model, was modified to take inhibition kinetics on microbial growth into account. The modified model was then used to investigate the effect of hydrogen concentration on microbial growth and production rate of hydrogen. The inhibition was moderate as hydrogen concentration increased from 10% to 30% (v/v). However, a strong inhibition in microbial growth and hydrogen production rate was observed as the addition of H2 increased from 30% to 40% (v/v). Practically, an extended l... [more]

Renewable energy has become very popular in recent years. The amount of renewable generation has increased in both grid-connected and stand-alone systems. This is because it can provide clean energy in a cost-effective and environmentally friendly fashion. Among all varieties, photovoltaic (PV) is the ultimate rising star. Integration of other technologies with solar is enhancing the efficiency and reliability of the system. In this paper a fuel cell−solar photovoltaic (FC-PV)-based hybrid energy system has been proposed to meet the electrical load demand of a small community center in India. The system is developed with PV panels, fuel cell, an electrolyzer and hydrogen storage tank. Detailed mathematical modeling of this system as well as its operation algorithm have been presented. Furthermore, cost optimization has been performed to determine ratings of PV and Hydrogen system components. The objective is to minimize the levelized cost of electricity (LCOE) of this standalone system... [more]

The presented work is focused on biomass thermochemical conversion with integrated CO2 capture. The main aim of this study was the in-depth investigation of the impact of pyrolysis temperature (500, 600 and 700 °C) and CaO sorbent addition on the chemical and physical properties of obtained char and syngas. Under the effect of the pyrolysis temperature, the properties of biomass chars were gradually changed, and this was confirmed by examination using thermal analysis, scanning electron microscopy, X-ray diffraction, and porosimetry methods. The chars were characterised by a noticeable carbon content (two times at 700 °C) resulting in a lower O/C ratio. The calculated combustion indexes indicated the better combustible properties of chars. In addition, structural morphology changes were observed. However, the increasing pyrolysis temperature resulted in changes of solid products; the differences of char properties were not significant in the range of 500 to 700 °C. Syngas was analysed... [more]

The Future Fuels project combines research in several institutes of the German Aerospace Center (DLR) on the production and use of synthetic fuels for space, energy, transportation, and aviation. This article gives an overview of the research questions considered and results achieved so far and also provides insight into the multidimensional and interdisciplinary project approach. Various methods and models were used which are embedded in the research context and based on established approaches. The prospects for large-scale fuel production using renewable electricity and solar radiation played a key role in the project. Empirical and model-based investigations of the technological and cost-related aspects were supplemented by modelling of the integration into a future electricity system. The composition, properties, and the related performance and emissions of synthetic fuels play an important role both for potential oxygenated drop-in fuels in road transport and for the design and ce... [more]

This paper explores the alternative roles hydrogen can play in the future European Union (EU) energy system, within the transition towards a carbon-neutral EU economy by 2050, following the latest policy developments after the COP21 agreement in Paris in 2015. Hydrogen could serve as an end-use fuel, a feedstock to produce carbon-neutral hydrocarbons and a carrier of chemical storage of electricity. We apply a model-based energy system analysis to assess the advantages and drawbacks of these three roles of hydrogen in a decarbonized energy system. To this end, the paper quantifies projections of the energy system using an enhanced version of the PRIMES energy system model, up to 2050, to explore the best elements of each role under various assumptions about deployment and maturity of hydrogen-related technologies. Hydrogen is an enabler of sectoral integration of supply and demand of energy, and hence an important pillar in the carbon-neutral energy system. The results show that the en... [more]

This paper reports on the optimum conditions for simultaneous hydrogen and butyric acid production from microalgae (Chlorella sp.) using enriched anaerobic mixed cultures as inoculum. The fermentation was objectively carried out under acidogenic conditions to achieve butyric acid for further ABE fermentation in solventogenesis stage. The main effects of initial pH (5 and 7), temperature (35 °C and 55 °C), and substrate concentration (40, 60, 80, and 100 g-VS/L) for hydrogen and butyric acid production were evaluated by using batch fermentation experiment. The major effects on hydrogen and butyric acid production are pH and temperature. The highest production of hydrogen and butyric acid was observed at pH 7 and temperature 35 °C. Using initial Chlorella sp. concentration of 80 g-VS/L or 100 g-VS/L at pH 7 and temperature 35 °C could produce hydrogen with an average yield of 22 mL-H2/g-VS along with high butyric acid production yield of 0.05 g/g-VS, suggesting that microalgae (Chlorella... [more]

The co-pyrolysis of various biomasses mixed with two types of plastic waste was investigated in this study. Mixture M1 consisted of 30% m/m styrene−butadiene rubber (SBR), 40% m/m polyethylene terephthalate (PET), and 30% m/m polypropylene (PP). M2 consisted of 40% m/m PET, 30% m/m PP, and 30% m/m acrylonitrile−butadiene−styrene copolymer (ABS). The SBR, ABS, and PP used in this study were from the automotive industry, while the PET originated from scrap bottles. Co-pyrolysis was performed using wood biomass, agricultural biomass, and furniture trash. Thermal treatment was performed on samples from room temperature to 400 or 600 °C at a heating rate of 10 °C/min under N2 at a flow rate of 3 dm3/min. Based on the findings of the experiments, an acceptable temperature was found for the fixed-bed pyrolysis of biomass−plastic mixtures with varying ratios, and the raw materials were pyrolyzed under the same conditions. The composition of the derived gaseous fraction was investigated. The co... [more]

Diesel engines play a very significant role in the automotive industry, but the total emissions of diesel engines are more than 1.8 times that of petrol engines. It is therefore important for diesel engines to control emissions. Theoretically, the Miller cycle can be used to achieve NOx reductions by changing the effective compression ratio, while it has become increasingly popular in recent years with the increasing maturity of current turbocharging technology. Based on Ricardo WAVE software, this paper analyses the NOx emissions and engine performance of diesel engines by modelling and simulating their operation under different loads with two types of Miller cycles (EIVC and LIVC) at different degrees. Simulation of engines operating under different loads allows a more comprehensive study of the effects of the Miller cycle on the engine, and a specific analysis in the context of the actual engine operating environment. The result is that both versions of the Miller cycle are most eff... [more]

Biomass gasification is a relevant option to produce a gaseous fuel, it faces, however, several barriers regarding its quality for energetic applications. Therefore, in this study, air-steam and O2-enriched air mixtures were used as gasification agents during the gasification of residual biomass from eucalyptus to improve the producer gas quality. The steam addition promoted an increase in CO2 and H2 concentrations, whilst decreasing the CO and CH4 concentrations. The steam addition had no evident impact on the lower heating value of the dry producer gas and a positive effect on gas yield and the H2:CO molar ratio, attaining the later values up to 1.6 molH2∙mol−1CO. The increase in O2 concentration in the gasification agent (φ) promoted an increase in all combustible species and CO2 concentrations. The lower heating value of the dry producer gas underwent an increase of 57%, reaching a value of 7.5 MJ∙Nm−3dry gas, when the φ increased from 20 to 40 %vol.O2, dry GA. The gas yield had a... [more]

Green hydrogen, produced using renewable energy, is nowadays one of the most promising alternatives to fossil fuels for reducing pollutant emissions and in turn global warming. In particular, the use of hydrogen as fuel for internal combustion engines has been widely analyzed over the past few years. In this paper, the authors show the results of some experimental tests performed on a hydrogen-fueled CFR (Cooperative Fuel Research) engine, with particular reference to the combustion. Both the air/fuel (A/F) ratio and the engine compression ratio (CR) were varied in order to evaluate the influence of the two parameters on the combustion process. The combustion duration was divided in two parts: the flame front development (characterized by laminar flame speed) and the rapid combustion phase (characterized by turbulent flame speed). The results of the hydrogen-fueled engine have been compared with results obtained with gasoline in a reference operating condition. The increase in engine C... [more]

Empty fruit bunch, a significant by-product of the palm oil industry, represents a tremendous and hitherto neglected renewable energy resource for many countries in South East Asia and Sub-Saharan Africa. The design and simulation of a plant producing pure hydrogen through autothermal reforming (ATR) of palm empty fruit bunch (PEFB) was carried out based on successful laboratory experiments of the core process. The bio-oil feed to the ATR stage was represented in the experiments and in the simulation by a surrogate bio-oil mixture of 11 organic compounds shown to be main constituents of PEFB oil from previous work, and whose combined elemental composition and volatility was determined to be as close as possible to that of the real PEFB bio-oil. The experiments confirmed that H2 yields close to equilibrium predictions were achievable using an in-house synthetised Rh-Al2O3 catalyst in a packed bed reactor. Initial sensitivity analysis on the plant revealed that feed molar steam to carbon... [more]

The study investigated co-digestion batch experiments using kitchen waste (KW) and garden waste (GW) collected from individual households. Grass and leaves were first subjected to a 3-day hyperthermophilic pretreatment at 70 °C and 80 °C and then co-digested with kitchen waste at 35 °C and 55 °C. The hyperthermophilic pretreatment resulted in the solubilization of organic material with the release of fatty acids, whereas the biogas yield was negligible. In the second stage, the greatest methane yield of 387 NmL/gVS was achieved for the mono-digestion of leaves, whereas the co-digestion of grass with 50% KW gave the highest hydrogen production of 88 NmL/gVS. Considering the overall process performance, the best operating conditions were established using a 3-day hyperthermophilic pretreatment at 70 °C, followed by co-digestion at 55 °C in the second stage for the mixture of 25% garden waste with 75% KW.

The main part of mankind’s ecological footprint is the carbon footprint, a measure of the environmental impact of humanity’s energy release from fossil fuels. The use of fossil fuels will have to change in the forthcoming decades to a largely climate-neutral use of solar energy enabled by dramatic cost reductions for PV and wind energy systems. The impact of this trend on world society has been discussed in a previous paper. In connection with these important technical developments, the role of electricity, its transport and storage will alter in the coming decades, allowing the design and use of larger and larger electricity grids and a parallel use of hydrogen for both storage and energy transport. This will further change the energy landscape of the world. All these developments and their relationship to global sustainable development are elaborated in this cross-disciplinary paper by specifically analyzing whether the Sustainable Development Goals by the United Nations are an effec... [more]

Several carbon sequestration technologies have been proposed to utilize carbon dioxide (CO2) to produce energy and chemical compounds. However, feasible technologies have not been adopted due to the low efficiency conversion rate and high-energy requirements. Process intensification increases the process productivity and efficiency by combining chemical reactions and separation operations. In this work, we present a model of a chemical-electrochemical cyclical process that can capture carbon dioxide as a bicarbonate salt. The proposed process also produces hydrogen and electrical energy. Carbon capture is enhanced by the reaction at the cathode that displaces the equilibrium into bicarbonate production. Literature data show that the cyclic process can produce stable operation for long times by preserving ionic balance using a suitable ionic membrane that regulates ionic flows between the two half-cells. Numerical simulations have validated the proof of concept. The proposed process cou... [more]

This paper covers the hydrogen technologies regarding the role of hydrogen as an energy carrier and the possibilities of its production and use. It is initially presented the modalities and the efficiency of the current technologies of obtaining hydrogen, detailing its obtaining by the electrolysis of the water, the electrochemical efficiency and the specific consumption of electricity as well as the thermodynamics of the electrochemical processes. The following paragraph addresses hydrogen conversion possibilities. This paragraph details the thermodynamic analysis of the fuel cell, the external characteristic of the fuel cell and the types of fuel cell. The last paragraph addresses the possibilities of using the fuel cells for electrical vehicles and cogeneration systems for buildings.In this context, the traditional transport and distribution grid will have to adapt to the new realities as they will need to actively participate in the internal energy market by the transformation of t... [more]

In both the private and public sectors, green hydrogen is treated as a promising alternative to fossil energy commodities. However, building up production capacities involves significant carbon production, especially when considering secondary infrastructure, e.g., renewable power sources. The amount of required capacity as well as the carbon production involved is calculated in this article. Using Germany as an example we show that the switch to purely green hydrogen involves significant bow waves in terms of carbon production as well as financial and resource demand. An economic model for an optimal decision is derived and—based on empirical estimates—calibrated. It shows that, even if green hydrogen is a competitive technology in the future, using alternatives like turquoise hydrogen or carbon capture and storage is necessary to significantly reduce or even avoid the mentioned bow waves.

In December 2019, the European Commission unveiled an ambitious project, the European Green Deal, which aims to lead the European Union to climate neutrality by 2050. This is a significant challenge for all EU countries, and especially for Poland. The role of hydrogen in the processes of decarbonization of the economy and transport is being discussed in many countries around the world to find rational solutions to this difficult and complex problem. There is an ongoing discussion about the hydrogen economy, which covers the production of hydrogen, its storage, transport, and conversion to the desired forms of energy, primarily electricity, mechanical energy, and new fuels. The development of the hydrogen economy can significantly support the achievement of climate neutrality. The belief that hydrogen plays an important role in the transformation of the energy sector is widespread. There are many technical and economic challenges, as well as legal and logistical barriers to deal with in... [more]

With the global warming of the planet, new forms of energy are being sought as an alternative to fossil fuels. Currently, hydrogen (H2) is seen as a strong alternative for fueling vehicles. However, the major challenge in the use of H2 arises from its physical properties. An earlier study was conducted on the storage of H2, used as fuel in road vehicles powered by spark ignition engines or stacks of fuel cells stored under high pressure inside small spheres randomly packed in an envelope tank. Additionally, the study evaluated the performance of this new storage system and compared it with other storage systems already applied by automakers in their vehicles. The current study aims to evaluate the H2 leaks from the same storage system, when inserted in any road vehicle parked in conventional garages, and to show the compliance of these leaks with European Standards, provided that an appropriate choice of materials is made. The system’s compliance with safety standards was proved. Regar... [more]

Lignocellulose and starch-based raw materials are often applied in the investigations regarding biohydrogen generation using dark fermentation. Management of the arising post-fermentation broth becomes a problem. The Authors proposed sequential processes, to improve the efficiency of both hydrogen generation and by-products management carried under model conditions. During the proposed procedure, the simple sugars remaining in broth are converted into organic acids, and when these products are used as substrates for the photo fermentation process. To enhance the broth management also conditions promoting Deep Eutectic Solvents (DES) precursors synthesis are simultaneously applied. Application of Box-Behnken design allows defining of the optimal conditions for conversion to DESs precursors. During the procedure hydrogen was obtained, the concentration of hydrogen in the photo fermentation reached up to 819 mL H2/L medium/7 d, depending on the broth type, i.e., when the broth was optimiz... [more]

This paper aims at addressing the exploitation of solid-state carriers for hydrogen storage, with attention paid both to the technical aspects, through a wide review of the available integrated systems, and to the social aspects, through a preliminary overview of the connected impacts from a gender perspective. As for the technical perspective, carriers to be used for solid-state hydrogen storage for various applications can be classified into two classes: metal and complex hydrides. Related crystal structures and corresponding hydrogen sorption properties are reviewed and discussed. Fundamentals of thermodynamics of hydrogen sorption evidence the key role of the enthalpy of reaction, which determines the operating conditions (i.e., temperatures and pressures). In addition, it rules the heat to be removed from the tank during hydrogen absorption and to be delivered to the tank during hydrogen desorption. Suitable values for the enthalpy of hydrogen sorption reaction for operating condi... [more]

Hydrogen used as an energy carrier can provide an important route to the decarbonization of energy supplies, but realizing this opportunity will require both significantly increased production and transportation capacity. One route to increased transportation capacity is the shipping of liquid hydrogen, but this requires an energy-intensive liquefaction step. Recent study work has shown that the energy required in this process can be reduced through the implementation of new and improved process designs, but since all low-temperature processes are affected by the available heat-sink temperature, local ambient conditions will also have an impact. The objective of this work is to identify how the energy consumption associated with hydrogen liquefaction varies with heat-sink temperature through the optimization of design parameters for a next-generation mixed refrigerant based hydrogen liquefaction process. The results show that energy consumption increases by around 20% across the coolin... [more]

The world of energy is on the cusp of profound transformation. Hydrogen or hydrogen-containing fuel mixtures in the form of synthesis gas, as carriers of clean energy, will be in the short term among the most efficient solutions to pressing environmental problems, reducing the amount of greenhouse gases as well as pollution of cities and dependence on oil-based fuels. Carbon dioxide conversion of methane is the most promising method for the production of synthesis gas due to the simultaneous consumption of two greenhouse gases and, accordingly, a successful solution to environmental problems. Ni/Mn-based catalysts have been prepared by self-propagating high-temperature synthesis (SHS) for this process. The samples were characterized by X-ray diffraction, scanning electron microscopy, and nitrogen porosimetry. The effects of the catalysts’ composition on activity, selectivity, and product yield were investigated. The influence of the content of Ni, Mn on the behavior of catalysts has be... [more]

Hydrogen is an environmentally friendly biofuel which, if widely used, could reduce atmospheric carbon dioxide emissions. The main barrier to the widespread use of hydrogen for power generation is the lack of technologically feasible and—more importantly—cost-effective methods of production and storage. So far, hydrogen has been produced using thermochemical methods (such as gasification, pyrolysis or water electrolysis) and biological methods (most of which involve anaerobic digestion and photofermentation), with conventional fuels, waste or dedicated crop biomass used as a feedstock. Microalgae possess very high photosynthetic efficiency, can rapidly build biomass, and possess other beneficial properties, which is why they are considered to be one of the strongest contenders among biohydrogen production technologies. This review gives an account of present knowledge on microalgal hydrogen production and compares it with the other available biofuel production technologies.

Energy storage, both short- and long-term, will play a vital role in the energy system of the future. One storage technology that provides high power and capacity and that can be operated without carbon emissions is compressed air energy storage (CAES). However, it is widely assumed that CAES plants are not economically feasible. In this context, a mixed-integer linear programming (MILP) model of the Huntorf CAES plant was developed for revenue maximization when participating in the day-ahead market and the minute-reserve market in Germany. The plant model included various plant variations (increased power and storage capacity, recuperation) and a water electrolyzer to produce hydrogen to be used in the combustion chamber of the CAES plant. The MILP model was applied to four use cases that represent a market-orientated operation of the plant. The objective was the maximization of revenue with regard to price spreads and operating costs. To simulate forecast uncertainties of the market... [more]

The Energy System lab at the University of Trieste has carried out a study to investigate the reduction in performance of high temperature polymer electrolyte membrane (HTPEM) fuel cell membrane electrode assemblies (MEAs) when subjected to different ageing tests. In this study, start and stop cycles, load cycles, open circuit voltage (OCV) permanence and constant load profile were considered. Polarization curves (PC) together with electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV) data were recorded during the ageing tests to assess the fuel cell performance. In this paper, experimental data are presented to confirm the test methodology previously proposed by the authors and to quantitatively correlate the performance degradation to the operational profiles. It was demonstrated that OCV condition, start and stop and load cycling increase degradation of the MEAs with respect to constant load operation. As expected, the OCV is the operational condition that influen... [more]