CoxOy−manganese carbonate (X%)(CoxOy−MnCO3 catalysts (X = 1−7)) were synthesized via a straightforward co-precipitation strategy followed by calcination at 300 °C. Upon calcination at 500 °C, these were transformed to CoxOy−dimanganese trioxide i.e., (X%)CoxOy−Mn2O3. A relative catalytic evaluation was conducted to compare the catalytic efficiency of the two prepared catalysts for aerial oxidation of benzyl alcohol (BzOH) to benzaldehyde (BzH) using O2 molecule as a clean oxidant without utilizing any additives or alkalis. Amongst the different percentages of doping with CoxOy (0−7% wt./wt.) on MnCO3 support, the (1%)CoxOy−MnCO3 catalyst exhibited the highest catalytic activity. The influence of catalyst loading, calcination temperature, reaction time, and temperature and catalyst dosage was thoroughly assessed to find the optimum conditions of oxidation of benzyl alcohol (BzOH) for getting the highest catalytic efficiency. The (1%)CoxOy−MnCO3 catalyst which calcined at 300 °C displaye... [more]

This paper deals with the scale-up of equipment for the mixing of suspensions. The measurement of just-suspended agitator speeds was carried out with standard, pitched, four-blade turbines and folded, four-blade turbines in three vessels (290 mm, 600 mm, and 800 mm in diameter) for several particle sizes and concentrations. The results of measurements confirmed that scale-up based on dimensionless Froude number dependence, on the relative particle size and concentration, can be used. On the basis of the results, a scale-up rule for agitator speeds in a given suspension and equipment geometry was recommended, and various conclusions reported by different investigators were discussed.

In this study, we describe the development of an automated immunomagnetic separation device combined with real-time polymerase chain reaction (PCR) for detecting foodborne bacteria. Immunomagnetic separation (IMS) is a well-known method for the separation and concentration of target bacteria from a large volume of food samples. Magnetic beads functionalized with an antibody provide selectivity for target bacteria such as Escherichia coli O157:H7. Moreover, compared to conventional methods, real-time PCR enables high-sensitivity detection of target bacteria. The method proposed in this study involves three steps: (1) pre-enrichment, (2) automated IMS and concentration of target bacteria, and (3) detection of target bacteria by real-time PCR. Using food samples with a working sample volume as large as 250 mL, the whole process only requires 3 h. As a result, target bacteria in the range of 101−102 colony-forming units per mg or g of sample can be detected in food samples, such as milk, g... [more]

Gantry-type computer numerical control (CNC) machines are widely used in the manufacturing industry. A novel structure with moveable gantry is proposed to improve the traditional gantry-type machine structure’s disadvantage of taking up too much space. Geometric errors have direct impacts on the actual position of the tool, which significantly reduces the accuracy of machines. Errors of different components are always coupled and have uncertain effects on the total geometric error. Thus, it is essential to find an effective way to identify the dominant errors and do targeted compensation. First, a novel identification method using value leaded global sensitivity analysis (VLGSA) is proposed to find the dominant errors. In VLGSA, weighting factors which show the influence of the error range are used to modify the multi-body system (MBS) error model. Results show that the dominant errors in three directions respectively contribute 80%, 86% and 85% of the total error in their directions.... [more]

The spanwise distribution of impeller exit circulation (SDIEC) has a significant effect on the impeller performance, therefore, there is a need for its consideration in the optimization design of mixed-flow pumps. In this study, a combination optimization system, including a 3D inverse design method (IDM), computational fluid dynamics (CFD), Latin hypercube sampling (LHS) method, response surface model (RSM), and non-dominated sorting genetic algorithm (NSGA-Ⅱ) was used to improve the performance of the mixed-flow pump after considering the effect of SDIEC on the performance of the impeller. The CFD results confirm the accuracy and credibility of the optimization results because of the good agreement the CFD results established with the experimental measurements. Compared with the original impeller, the pump efficiency of the preferred impeller at 0.8Qdes, 1.0Qdes, and 1.2Qdes improved by 0.63%, 3.39%, and 3.77% respectively. The low-pressure region on the blade surface reduced by 96.9... [more]

Biofuels are still too costly to compete in the energy market and it has been suggested that low-value feedstocks could provide an opportunity for the production of low-cost biofuels; however, the lower quality of these feedstocks requires the introduction of a conditioning step in the biorefinery process. The aim of this study was to evaluate whether feedstock savings cover the cost of conditioning in the case of animal bedding. The BioSTEAM software was used to simulate a wheat straw biorefinery and an animal bedding biorefinery, whose economic performance was compared. The wheat straw biorefinery could deliver ethanol at a minimum selling price of USD 0.61 per liter, which is similar to prices in the literature. The cost of producing ethanol in the animal bedding biorefinery without water recycling was almost 40% higher, increasing the minimum selling price to USD 1.1 per liter of ethanol. After introducing water recycling in the conditioning step, the animal bedding biorefinery cou... [more]

To more clearly understand the changes in flow characteristics around two square cylinders with different spacing ratios, the main mode of the flow field was extracted by using the Proper Orthogonal Decomposition (POD) and Dynamic Mode Decomposition (DMD) methods. The changes in the main mode of the flow field at different spacing ratios and the difference of the time series were analyzed and compared. This processing can separate the mixed information in the flow field and obtain the dominant modes in the flow field. These main modes can clearly reflect the dominant flow characteristics in the flow field. The analysis results show that when L/D = 2, the flow field structure is consistent with the flow field around a single square cylinder. When L/D = 2.5−3.5, the vortex shedding from upstream cylinders combines with the vortex near the downstream cylinders. This mutual coupling causes a significant change in the drag coefficient value of the downstream cylinder. When L/D = 4, the main... [more]

The present study focused on the development of a new method to determine the lag phase of Lactobacillus in breast milk which was attained during the 1st, 3rd, and 6th month (M1, M3, and M6). The colonies’ phylogenetic analysis, derived from the 16S rRNA gene sequences, was evaluated with genus Lactobacillus pentosus and achieved a similarity value of 99%. Raman spectroscopy in optical densities of 600 nm (OD600) were used for six consecutive days to observe the changes of the cell growth rate. The values of OD600 were well fitted with the regression model. From this work, M1 was found to be the longest lag phase in 18 h, and it was 17% to 27% longer compared to M3 and M6, respectively. However, the samples of M3 and M6 showed the shortest duration in reaching 0.5 of OD600 nm (16 h) which was enhanced by 80% and 96% compared to M1, respectively. These studies will be of significance when applied in determining the bacteria growth curve and in assessing the growth behavior for the strai... [more]

Currently over 845 million people are believed to be living under severe water scarcity, and an estimated 2.8 billion people across the globe are projected to come under serious water scarcity by the year 2025, according to a United Nations (UN) report. Seawater desalination has gained more traction as the solution with the most potential for increasing global freshwater supplies amongst other solutions. However, the economic and energy costs associated with the major desalination technologies are considered intrinsically prohibitive largely due to their humongous energy requirements alongside the requirements of complex equipment and their maintenance in most cases. Whilst forward osmosis (FO) is being touted as a potentially more energy efficient and cost-effective alternative desalination technique, its efficiency is challenged by draw solutes and the draw solutes recovery step in FO applications alongside other challenges. This paper looks at the present situation of global water s... [more]

This study investigated influences of the open/close states of pores and porosity distribution of activated coke on the mechanical strength of common activated coke for the purification of coal-fired flue gas by analyzing pore structure, abrasive resistance, and compression strengths of 9 types of desulfurization and denitration activated cokes. Research conclusions are conducive to disclosing the influences of porosity characteristics of activated coke for the purification of coal-fired flue gas on mechanical strength, decreasing the physical consumption of activated coke in the recycling of flue gas purification systems, and lowering the purification cost of coal-fired flue gas. According to research results, pores in the ranges of 0−2 nm and 2−500 nm of activated coke are further developed after recycling using the coal-fired flue gas purification system, and the average compression strength of activated coke is about 70% of the added fresh activated coke. However, the abrasive resi... [more]