Allotropes of carbon are responsible for discovering the three significant carbon-based compounds, fullerene, carbon nanotubes, and graphene. Over the last few decades, groundbreaking graphene with the finest two-dimensional atomic structure has emerged as the driving force behind new research and development because of its remarkable mechanical, electrical, thermal, and optical functionalities with high surface area. Synthesis of graphene oxide (GO) and reduced graphene oxide (rGO) has resulted in numerous applications that previously had not been possible, incorporating sensing and adsorbent properties. Our study covers the most prevalent synthetic methods for making these graphene derivatives and how these methods impact the material’s main features. In particular, it emphasizes the application to water purification, CO2 capture, biomedical, potential energy storage, and conversion applications. Finally, we look at the future of sustainable utilization, its applications, and the cha... [more]

The ferrocyanide-based organic redox flow battery (ferrocyanide-based ORFB), based on electrochemistry, has become a potential energy storage technology due to its low price, eco-friendliness, safety, and convenience. However, its low efficiency and poor mass transfer performance hinder the application of the ORFB. The influence of the electrode shape (trapezoid, sector, and rectangle) on the mass transfer and battery performance are studied based on a numerical model, which is verified by the experiments. The results show that battery performance of the trapezoid electrode is better than that of the sector and rectangle electrode. The discharge voltage of the rectangle battery is the lowest, and the discharge voltage of the trapezoid battery is the highest. The discharge voltage of the rectangle battery is 4.47% lower than that of the trapezoid battery. The uniformity factor value of the trapezoid battery is 26.9% higher than that of the rectangle battery. The trapezoid shape is the b... [more]

Lithium-ion batteries (LIBs) have circumvented the energy storage landscape for decades. However, safety concerns about liquid−electrolyte-based LIBs have challenged their mobilization. Lithium polymer (LiPo) batteries have gained rising interest due to their high thermal stability. Despite an array of commercially available LiPo batteries, limited studies have ventured into modeling. Numerical simulations allow low-cost optimization of existing battery designs through parameter analysis and material configuration, leading to safer and more energy-efficient batteries. This work examined the electrochemical, thermal, and thermal runaway behavior of a lithium cobalt oxide cathode, graphite anode, and poly(vinylidene fluoride-hexafluoropropylene) electrolyte pouch-type LiPo battery using COMSOL Multiphysics®, and validated results with experimental data. The simulated potential curve exhibited strong agreement with experiment data, while the temperature profile during discharge displayed... [more]

This paper presents a mathematical programming approach for the strategic planning of hydrogen production from renewable energies and its use in electric power generation in conventional technologies. The proposed approach aims to determine the optimal selection of the different types of technologies, electrolyzers and storage units (energy and hydrogen). The approach considers the implementation of an optimization methodology to select a representative data set that characterizes the total annual demand. The economic objective aims to determine the minimum cost, which is composed of the capital costs in the acquisition of units, operating costs of such units, costs of production and transmission of energy, as well as the cost associated with the emissions generated, which is related to an environmental tax. A specific case study is presented in the Mexican peninsula and the results show that it is possible to produce hydrogen at a minimum sale price of 4200 $/tonH2, with a total cost... [more]

The calcium looping (CaL) process, which exploits the reversible calcination of calcium carbonate, has been proposed as a solution to the challenges facing deployment of concentrated solar power (CSP). As an extension of the work undertaken to date, this project proposes a novel configuration of the CSP-CaL process which may offer advantages over other proposed configurations, including a reduction in process equipment requirements, elimination of pressure differentials between vessels, and a reduction in compression duty during the energy discharge period. The results obtained through process simulation indicate that the proposed process can achieve round-trip efficiencies in the range of 32−46% and energy storage densities in the range of 0.3−1.0 GJ/m3. These parameters are strongly dependent on the residual conversion of the CaO sorbent as well as the efficiency of the power cycles used to remove heat on the carbonator side of the process.

There is increased talk about using second-life batteries in applications. In first-life applications, the batteries start from new, and a range of life cycle estimation techniques are applied. However, it is not clear how second-life batteries should be monitored compared to first life batteries. This paper investigated different algorithms from first-life applications for estimating and forecasting battery cell state of health in conjunction with capacity calculations using second life cells under long term durability testing. The paper looks at how close these models predict capacity fade based on a set of second-life batteries that have been undertaking sweat testing over six different applications. The paper concludes that there are two methods that could be suitable candidates for predicting lifespan. One of these needed to be modified from the original.

There is a significant energy transition in progress globally. This is mainly driven by the insertion of variable sources of energy, such as wind and solar power. To guarantee that the supply of energy meets its demand, energy storage technologies will play an important role in integrating these intermittent energy sources. Daily energy storage can be provided by batteries. However, there is still no technology that can provide weekly, monthly and seasonal energy storage services where pumped hydro storage is not a viable solution. Herein, we introduce an innovative energy storage proposal based on isothermal air compression/decompression and storage of the compressed air in the deep sea. Isothermal deep ocean compressed air energy storage (IDO-CAES) is estimated to cost from 1500 to 3000 USD/kW for installed capacity and 1 to 10 USD/kWh for energy storage. IDO-CAES should complement batteries, providing weekly, monthly and seasonal energy storage cycles in future sustainable energy gr... [more]

Under a two-part tariff, the user-side installation of photovoltaic and energy storage systems can simultaneously lower the electricity charge and demand charge. How to plan the energy storage capacity and location against the backdrop of a fully installed photovoltaic system is a critical element in determining the economic benefits of users. In view of this, we propose an optimal configuration of user-side energy storage for a multi-transformer-integrated industrial park microgrid. First, the objective function of user-side energy storage planning is built with the income and cost of energy storage in the whole life cycle as the core elements. This is conducted by taking into consideration the time-of-use electricity price, demand price, on-grid electricity price, and energy storage operation and maintenance costs. Then, considering the load characteristics and bidirectional energy interaction of different nodes, a user-side decentralized energy storage configuration model is develop... [more]

Renewable energy sources are nowadays a viable choice to satisfy the rising energy consumption and promote the advancement of sustainable development. These systems are integrated into microgrids using a variety of technological solutions to ensure customer communication and distributed generation facilities in an optimal way. Energy management in microgrids refers to the information and control system that provides the necessary functionality to guarantee that the generating and distribution systems produce energy at the lowest expenses. This study analyzes the various optimization objectives, constraints, problem-solving techniques, and simulation tools used for connected and freestanding microgrids. It reviews the literature on energy control in microgrids powered by sustainable energy. Energy storage technology is also viewed as an intriguing alternative to managing the intermittent nature of renewable energy because of its advanced techniques, increased energy efficiency, and capa... [more]

In this paper, we address the problem of high greenhouse gas emissions from oil and gas platforms in Norway. We look at the potential of integrating an energy system composed of wind turbines and battery systems to unload the electrical power generated by gas turbines being the main source of emissions today. We propose a simulation model of the energy system, the power demand, the available wind speed, and different control strategies. By putting the models together, we evaluate the performance of various compositions of the system and determine their impact on emissions and battery lifetime. The numerical results show that changing today’s practices has great potential to reduce greenhouse gases, with amounts varying between 30% and 80% compared with today’s level.

Renewable integration into the electricity system of Great Britain (GB) is causing considerable demand for additional flexibility from plants. In particular, a considerable share of this flexibility may be dispatched to secure post-fault transient frequency dynamics. Pursuant to the unprecedented changes to the traditional portfolio of generation sources, this work presents a detailed analysis of the potential system-level value of unlocking flexibility from nuclear electricity production. A rigorous enhanced mixed integer linear programming (MILP) unit commitment formulation is adopted to simulate several generation-demand scenarios where different layers of flexibility are associated to the operation of nuclear power plants. Moreover, the proposed optimisation model is able to assess the benefit of the large contribution to the system inertial response provided by nuclear power plants. This is made possible by considering a set of linearised inertia-dependent and multi-speed constrai... [more]

The scientific and technical issues related to energy harvesting and conversion are inseparably bound to the issues of environmental protection. Energy conversion systems and devices that are applied for converting the chemical energy contained in different fuels into heat, electricity, and cold in industry and housing are sources of different gases and solid particle emissions. Thus, the development of different technologies for energy conversion and environmental protection that can be jointly applied to cover growing energy needs has become a crucial challenge for scientists and engineers around the world. Progress in the precise description, modeling, and optimization of physical and chemical phenomena related to these energy conversion systems is a key research and development field for the economy. Legal and social issues that are affecting key aspects and problems related to the energy conversion and power sector are also significant and worth investigating. The aim of Energy Pr... [more]

An optimal power flow algorithm for unbalanced three-phase distribution grids is presented in this paper as a new tool for grid planning on low voltage level. As additional equipment like electric vehicles, heat pumps or solar power systems can sometimes cause unbalanced power flows, existing algorithms have to be adapted. In comparison to algorithms considering balanced power flows, the presented algorithm uses a complete model of a three-phase four-wire low voltage grid. Additionally, a constraint for the voltage unbalance in the grid is introduced. The algorithm can be used to optimize the operation of energy storage systems in unbalanced systems. The used grid model, constraints, objective function and solver are explained in detail. A validation of the algorithm using a commercial tool is done. Additionally, three exemplary optimizations are performed to show possible applications for this tool.

Energy storage system (ESS) has been advocated as one of the key elements for the future energy system by the fast power regulation and energy transfer capabilities. In particular, for distribution networks with high penetration of renewables, ESS plays an important role in bridging the gap between the supply and demand, maximizing the benefits of renewables and providing various types of ancillary services to cope the intermittences and fluctuations, consequently improving the resilience, reliability and flexibility. To solve the voltage fluctuations caused by the high permeability of renewables in distribution networks, an optimal capacity allocation strategy of ESS is proposed in this paper. Taking the life cycle cost, arbitrage income and the benefit of reducing network losses into consideration, a bilevel optimization model of ESS capacity allocation is established, the coordination between active/reactive power of associate power conversion system is considered, and the large sca... [more]

This paper examines the specifications of lithium battery cells, which are considered one of the most vital sources for electrical energy storage units. The specifications have been covered to associate battery performance with its usage for electrically powered motor vehicles. With the motivation of rapid deployment of electric vehicles (EVs) around the world, the key contribution of this study is to provide a comparative investigation of well-known commercially available Li-ion battery cells used as a pack for electric race car. Five lithium cells from different manufacturers were analyzed for start voltage, end voltage, current, and the use of active cooling under different test conditions. Thermal imaging was used to provide more comprehensive analysis of tested battery packs. The outcomes of this experimental investigation are described in the sections below in the order in which the analyses were conducted. The key findings of this study are presented in the conclusion section.

Thermal and mechanical energy storage is pivotal for the effective exploitation of renewable energy sources, thus fostering the transition to a sustainable economy. Hydrogen-based systems are among the most promising solutions for electrical energy storage. However, several technical and economic barriers (e.g., high costs, low energy and power density, advanced material requirements) still hinder the diffusion of such solutions. Similarly, the realization of latent heat storages through phase change materials is particularly attractive because it provides high energy density in addition to allowing for the storage of the heat of fusion at a (nearly) constant temperature. In this paper, we posit the challenge to couple a metal hydride H2 canister with a latent heat storage, in order to improve the overall power density and realize a passive control of the system temperature. A highly flexible numerical solver based on a hybrid Lattice Boltzmann Phase-Field (LB-PF) algorithm is develope... [more]

Modern households usually have independent energy sources such as wind generators, photovoltaic (PV) panels, and similar green energy production equipment. Experts predict that soon, there will be an increasing number of such prosumers who both produce and consume energy. This process alleviates and reduces the load on large national electricity networks and also contributes to overall energy security. In this paper, a simulation model of a household, which employs a wind generator as its independent source of electricity, is developed. It is expected that this approach will be easily replicated for more complex configurations. The other components of the single prosumer microgrid that will be assessed are the non-shiftable electricity consumption equipment, which is used mainly in households and deployed separately for water heater, with a separate battery to meet the needs of these non-shiftable consumers. The 5-min data intervals for the year of simulation have been used. The charac... [more]

To improve access to affordable, reliable and sustainable energy in rural areas of the global south, off-grid systems using renewable generation and energy storage are often proposed. However, solution design is often technology-driven, with insufficient consideration of social and cultural contexts. This leads to a risk of unintended consequences and inappropriate systems that do not meet local needs. To address this problem, this paper describes the application of a capabilities-led approach to understanding a community’s multi-dimensional energy poverty and assessing their needs as they see them, in order to better design suitable technological interventions. Data were collected in Tlamacazapa, Mexico, through site visits and focus groups with men and women. These revealed the ways in which constrained energy services undermined essential capabilities, including relating to health, safety, relationships and earning a living, and highlighted the specific ways in which improved energy... [more]

Many islands around the world present considerable energy supply problems, while their energy mixture is controlled by oil products. Meanwhile, several of these isolated islands enjoy excellent RES potential that support actions to maximize RES integration. In order to ameliorate energy supply security and energy autonomy of the Aegean Archipelagos Greek islands, an integrated solution is deployed based on the exploitation of the existing RES potential in conjunction with the application of an appropriate energy storage scheme, as well as complementary smart-grid elements. The proposed solution has been applied for the Greek Tilos island in the framework of the Tilos-Horizon 2020 program. In this context, the implementation of the integrated Tilos energy solution under the current local legislative frame is a great success story introducing several important innovative characteristics in the European market, like the combined operation of a wind turbine and a PV installation, the appli... [more]

Due to the extreme cost of cargo transportation from Earth to the lunar surface, future lunar base subsystems are required to be rigorously optimized in terms of mass reduction. The purpose of this paper was to identify and evaluate the influence of key parameters of proposed lunar base power systems, as well as of the lunar environment on the total power system mass. Nine different power systems were studied as combinations of two power sources and three energy storage technologies. Power system architecture, total power demand of the base, its power management strategy, solar array structure type, Selenographic latitude and solar illumination conditions were nominated as the primary parameters for this study. Total power system mass calculations were performed for more than 200 combinations of these parameters, including three separate case studies. The total mass calculated for each combination included a power source, an energy storage unit, temperature control and the balance of s... [more]

The paper includes the analysis of the operation of low-voltage prosumer installation consisting of receivers and electricity sources and equipped with a 3-phase energy storage system. The aim of the storage application is the management of active power within the installation to decrease the total power exchanged with the supplying network and thus reduce energy costs borne by the prosumer. A solution for the effective implementation of the storage system is presented. Apart from the active power management performed according to the prosumer’s needs, the storage inverter provides the ancillary service of voltage regulation in the network according to the requirements of the network operator. A control strategy involving algorithms for voltage regulation without prejudice to the prosumer’s interest is described in the paper. Reactive power is used first as a control signal and if the required voltage effect cannot be reached, then the active power in the controlled phase is additional... [more]

For renewable energies to succeed in replacing fossil fuels, large-scale and affordable solutions are needed for short and long-term energy storage. A potentially inexpensive approach of storing large amounts of energy is through the use of a concentration flow cell that is based on cheap and abundant materials. Here, we propose to use aqueous iron chloride as a reacting solvent on carbon electrodes. We suggest to use it in a red-ox concentration flow cell with two compartments separated by a hydrocarbon-based membrane. In both compartments the red-ox couple of iron II and III reacts, oxidation at the anode and reduction at the cathode. When charging, a concentration difference between the two species grows. When discharging, this concentration difference between iron II and iron III is used to drive the reaction. In this respect it is a concentration driven flow cell redox battery using iron chloride in both solutions. Here, we investigate material combinations, power, and concentrati... [more]

The integration of a variety of heterogeneous energy sources and different energy storage systems has led to complex infrastructures and made apparent the urgent need for efficient energy control and management. This work presents a non-linear model predictive controller (NMPC) that aims to coordinate the operation of interconnected multi-node microgrids with energy storage capabilities. This control strategy creates a superstructure of a smart-grid consisting of distributed interconnected microgrids, and has the ability to distribute energy among a pool of energy storage means in an optimal way, formulating a virtual central energy storage platform. The goal of this work is the optimal exploitation of energy produced and stored in multi-node microgrids, and the reduction of auxiliary energy sources. A small-scale multi-node microgrid was used as a basis for the mathematical modelling and real data were used for the model validation. A number of operation scenarios under different weat... [more]

In this study, a novel sizing methodology was developed for centralized and interconnected operating strategies of transactive microgrids and several variables were investigated including starting month, initial charge of battery, load variability, unit cost of solar panels and energy storage, number of systems, climate, and required reliability to determine their effect on total cost. The centralized strategy improved cost by seven to ten percent compared to the isolated strategy in every case. The interconnected strategy saved an incremental amount of money consistently compared to the isolated standard. The number of connected systems was not a strong effect. It was thought that increasing the number of systems would increase the benefit of energy sharing. Climate zones studied (“Cold”; “Hot-Dry/Mixed Dry”; “Mixed Humid”; and “Cold but with lower solar irradiation”) showed a large variation on cost with the Hot-Dry/Mixed Dry being the least expensive and Cold, with lower solar irrad... [more]

This paper presents an innovative approach to the design of a forthcoming, fully electric-powered cargo vessel. This work begins by defining problems that need to be solved when designing vessels of this kind. Using available literature and market research, a solution for the design of a power management system and a battery management system for a cargo vessel of up to 1504 TEU capacity was developed. The proposed solution contains an innovative approach with three parallel energy sources. The solution takes into consideration the possible necessity for zero-emission work with the optional function of operation as an autonomous vessel. Energy storage system based on lithium-ion battery banks with a possibility of expanding the capacity is also described in this work as it is the core part of the proposed solution. It is estimated that the operation range for zero-emission work mode of up to 136 nautical miles can be achieved through the application of all fore-mentioned parts.