Browse
Records Added in 2023
Records added in 2023
Filter by month: January | February | March | April | May | June | July | August | September | October | November | December
36263. LAPSE:2023.0103
Parameter Optimization and Testing of a Conveying and Soil-Removing Device for Tiger Nut (Cyperus esculentus) Mechanical Harvesting
February 17, 2023 (v1)
Subject: Optimization
Keywords: conveying and soil-removing, harvesting, parameter optimization, tiger nut
Aimed at solving the large power consumption and high operating cost problems associated with the process of harvesting tiger nuts, the use of a conveying and soil-removing device which removes sandy soil while conveying tiger nuts was proposed. The device was numerically simulated with and without vibration using EDEM software. The results showed that the vibrating force was more conducive to the complete removal of sandy soil and the effective conveyance of tiger nuts. The simulation testing was carried out using spiral speed, vibration amplitude, and vibration frequency as the independent variables and conveyance efficiency, sandy soil removal rate, etc., as the dependent variables. The test results showed that the optimal parameter combination was a spiral speed of 107 r/min, a vibration amplitude of 8.5 mm, and a vibration frequency of 10.7 Hz, under which the theoretical value of conveyance efficiency was 80.39%, the sandy soil removal rate was 84.61%, and the variation coefficie... [more]
36264. LAPSE:2023.0102
Real-World Pipe-Out Emissions from Gasoline Direct Injection Passenger Cars
February 17, 2023 (v1)
Subject: Process Control
Keywords: Carbon Dioxide, driving behavior, GDI vehicles, nitrogen oxides, particulate number, real-world emissions
The analysis of real-world emissions is necessary to reduce the emissions of vehicles during on-road driving. In this paper, the matrix of gasoline direct injection passenger cars is applied to analyze the real-world emissions. The results show that high acceleration and high speed conditions are major conditions for the particulate number emissions, and the particulate number emissions are positively correlated with torque and throttle opening. The catalyst temperature and saturation are important factors that affect nitrogen oxide emission. The nitrogen oxide emissions of low speed and low torque conditions cannot be ignored in real-world driving. The carbon dioxide emissions are positively correlated with acceleration, torque and throttle opening. Once the vehicles are in the acceleration condition, the carbon dioxide emissions increase rapidly. The vehicles with higher average emission factors are more susceptible to driving behaviors, and the differences in the emission factors ar... [more]
36265. LAPSE:2023.0101
Designing Dispatching Rules via Novel Genetic Programming with Feature Selection in Dynamic Job-Shop Scheduling
February 17, 2023 (v1)
Subject: Planning & Scheduling
Keywords: dispatching rules, dynamic job shop scheduling (DJSS), feature selection, genetic programming (GP)
Genetic Programming (GP) has been widely employed to create dispatching rules intelligently for production scheduling. The success of GP depends on a suitable terminal set of selected features. Specifically, techniques that consider feature selection in GP to enhance rule understandability for dynamic job shop scheduling (DJSS) have been successful. However, existing feature selection algorithms in GP focus more emphasis on obtaining more compact rules with fewer features than on improving effectiveness. This paper is an attempt at combining a novel GP method, GP via dynamic diversity management, with feature selection to design effective and interpretable dispatching rules for DJSS. The idea of the novel GP method is to achieve a progressive transition from exploration to exploitation by relating the level of population diversity to the stopping criteria and elapsed duration. We hypothesize that diverse and promising individuals obtained from the novel GP method can guide the feature... [more]
36266. LAPSE:2023.0100
Design and Development of a High-Speed Precision Internal Grinding Machine and the Associated Grinding Processes
February 17, 2023 (v1)
Subject: Process Design
Keywords: high-speed grinding, hydrostatic bearings, internal grinding machine, machining dynamics, precision machine design
In order to meet the P2-grade bearing grinding requirements, we designed a high-speed internal grinding machine to be used for grinding bearing raceways and inner circles. The machine has a T-type layout and a four-axis numerical control linkage. It is supported by hydrostatic pressure and driven directly by a torque motor. In addition, it is equipped with a high-speed hydrostatic grinding wheel spindle. Our design includes a hydrostatic workpiece shaft and hydrostatic turntable, and the process has a good engineering application value. Finally, the designed precision grinding machine was used to grind a P2-grade bearing raceway.
36267. LAPSE:2023.0099
Gas Pipeline Flow Prediction Model Based on LSTM with Grid Search Parameter Optimization
February 17, 2023 (v1)
Subject: Energy Systems
Keywords: flow prediction, grid search algorithm, LSTM, natural gas pipeline, parameter optimization
Due to the abundant operation data (e.g., pressure, flow rate, and temperature) for natural gas (NG) gathering pipelines provided by the supervisory control and data acquisition (SCADA) system, the machine-learning-based real-time flow prediction has become a critical solution to enable the identification of the abnormality of pipelines, further to guarantee the safe operation of the pipelines. However, traditional machine-learning-based methods cannot always function well due to the temporal characteristics of the SCADA data often being ignored, resulting from a lack of time memory capability. Therefore, this paper proposes a method to automatically perform the feature mining of flow time series by considering the correlation of flow data at both ends of the pipeline, combined with the long short-term memory (LSTM) network. The current and historical data at both pipeline ends are used as input vectors of the LSTM network to predict the terminal output flow at the next moment. Further... [more]
36268. LAPSE:2023.0098
Enhance the Injection Molding Quality Prediction with Artificial Intelligence to Reach Zero-Defect Manufacturing
February 17, 2023 (v1)
Subject: Materials
Keywords: Artificial Intelligence, Data Augmentation, Human-in-the-Loop labeling, injection molding, OEE, predictive quality
With the spread of the Industry 4.0 concept, implementing Artificial Intelligence approaches on the shop floor that allow companies to increase their competitiveness in the market is starting to be prioritized. Due to the complexity of the processes used in the industry, the inclusion of a real-time Quality Prediction methodology avoids a considerable number of costs to companies. This paper exposes the whole process of introducing Artificial Intelligence in plastic injection molding processes in a company in Portugal. All the implementations and methodologies used are presented, from data collection to real-time classification, such as Data Augmentation and Human-in-the-Loop labeling, among others. This approach also allows predicting and alerting with regard to process quality loss. This leads to a reduction in the production of non-compliant parts, which increases productivity and reduces costs and environmental footprint. In order to understand the applicability of this system, it... [more]
36269. LAPSE:2023.0097
Coarse X-ray Lumbar Vertebrae Pose Localization and Registration Using Triangulation Correspondence
February 17, 2023 (v1)
Subject: Biosystems
Keywords: Delaunay triangulation, SURF features, vertebrae pose localization, X-ray
Plain film X-ray scanners are indispensable for medical diagnostics and clinical procedures. This type of device typically produces two radiographic images of the human spine, including the anteroposterior and lateral views. However, these two photographs presented perspectives that were distinct. The proposed procedure consists of three fundamental steps. For automated cropping, the grayscale lumbar input image was initially projected vertically using its vertical pattern. Then, Delaunay triangulation was performed with the SURF features serving as the triangle nodes. The posture area of the vertebrae was calculated by utilizing the edge density of each node. The proposed method provided an automated estimation of the position of the human lumbar vertebrae, thereby decreasing the radiologist’s workload, computing time, and complexity in a variety of bone-clinical applications. Numerous applications can be supported by the results of the proposed method, including the segmentation of l... [more]
36270. LAPSE:2023.0096
Magnesium Spinel Ferrites Development for FDM 3D-Printing Material for Microwave Absorption
February 17, 2023 (v1)
Subject: Materials
Keywords: composites, electrical conductivity, electromagnetic microwave properties, FDM 3D-printing, magnesium nanoferrite, microstructure
The magnesium nanosized ferrite powder with formula MgFe2O4 was synthesized via a pyrochemical sol−gel glycine−nitrate method and annealed consistently at temperatures of up to 1300 °C. The MgFe2O4 ferrite samples’ microstructure was studied by SEM and XRD methods. According to the results of the studies, the increase in MgFe2O4 nanoparticles size from about 15 nm to micron-sized particles was observed when increasing annealing temperatures. The DC electrical conductivity of MgFe2O4 also clearly shows the change in conduction behavior of samples with increased calcination temperatures. The electromagnetic microwave properties of micron-sized particles of MgFe2O4 ferrite powder for a 1200 °C annealing temperature were studied for composites in paraffin matrix with produced magnetic filler mass concentration at 40% and 50%. The filament composites of polymer polylactic acid with MgFe2O4 ferrite powder samples were prepared by the FDM 3D-printing process and their microwave-absorbing prop... [more]
36271. LAPSE:2023.0095
Influence of the Machining Process on the Thrust Force and Mechanical Characteristics for the Direct Drive System
February 17, 2023 (v1)
Subject: Other
Keywords: cutting force, direct drive feed system, electromechanical coupling, machining process, thrust force
This paper investigates the effects of the machining process on the thrust force and mechanical characteristics for the direct drive feed system driven by the flat permanent magnet synchronous linear motor (PMSLM) in machine tools considering the electromechanical couplings. Firstly, the cutting force in the machining process is researched. Then, the analytical model of the direct drive feed system is established and analyzed. The electromechanical couplings between the mechanical system and servo system in the direct drive feed system are studied. Furthermore, the influences of the cutting force on different couplings are analyzed, and the thrust force characteristic is analytically represented. Finally, the validity of the theoretical analysis is verified by the experiments, and the effects of the machining process on the dynamic precision of the feed system are discussed. The results show that the electromechanical couplings in the direct drive system will aggravate the effects of t... [more]
36272. LAPSE:2023.0094
Weibull Reliability and Mechanical Properties of Chemical Strengthening Lightweight Glass Containers Using Spray Coating
February 17, 2023 (v1)
Subject: Materials
Keywords: accelerated life test, chemical strengthening, lightweight glass bottle, reliability, Weibull modulus
In this study, the effects of heat-treatment temperature and hot-end coating (HEC) by spray coating on the mechanical properties and reliability of lightweight glass bottles were investigated. When the chemical strengthening occurred at Tg, the hardness and impact strength increased by 163% and 198%, respectively. All specimens exhibited improved mechanical properties with chemical strengthening, regardless of the HEC. The strengthening effect was relatively large in the absence of HEC. However, the distribution of the impact strength was smaller when HEC was applied. Compared to non-HEC bottles, HEC glass bottles had higher Weibull modulus values after chemical strengthening, which increased their reliability. Therefore, it is possible to chemically strengthen a lightweight glass bottle by spray-coating. Chemically strengthened lightweight glass bottles with excellent mechanical properties and high reliability can be produced when both HEC and chemical strengthening are applied.
36273. LAPSE:2023.0091
A Simultaneous Design and Optimization Framework for the Reaction and Distillation Sections of Methanol to Olefins Process
February 17, 2023 (v1)
Subject: Process Design
The reaction and separation sections are the keys to the methanol-to-olefins (MTO) chemical processes, and they should be optimized to reduce the cost of production. This work develops a framework for the simultaneous design and optimization of the reaction and distillation sections. An optimization model with shortcut and rigorous methods combined is established for distillation columns to improve accuracy and efficiency. With the auxiliary devices and the selection of utilities considered, the reaction and distillation sections are integrated to maximize profits. The genetic algorithm targets the optimal parameters, including the catalyst’s coke content and reaction temperature, each column’s operating pressure, and the allocation of utilities and auxiliary devices. For the studied MTO process, the optimal reaction temperature and catalyst’s coke content were identified to be 496 °C and 7.8%, respectively. The maximum profit is 15.3% greater than that identified with only the separat... [more]
36274. LAPSE:2023.0090
Investigations of Lithium-Ion Battery Thermal Management System with Hybrid PCM/Liquid Cooling Plate
February 17, 2023 (v1)
Subject: Materials
Keywords: battery thermal management, hybrid cooling system, liquid cold plate, local optimization, phase change material
To improve the operating performance of the large-capacity battery pack of electric vehicles during continuous charging and discharging and to avoid its thermal runaway, in this paper we propose a new hybrid thermal management system that couples the PCM with the liquid cooling plate with microchannels. The flow direction of the microchannel structure in the bottom plate is designed according to the characteristics of the large axial thermal conductivity of the battery, and the cooling performance of the whole system under continuous charge/discharge cycles is numerically simulated. The results show that the hybrid PCM/liquid cooling plate can maintain good cooling performance under the discharge process of a large-capacity battery pack. After each cycle the temperature of the battery pack can be reduced to less than 30°, and the maximum temperature change rate of multiple cycles is controlled within 0.8%. With the application of the hybrid PCM/liquid-cooled plate battery cooling syste... [more]
36275. LAPSE:2023.0089
Modern Technologies of Hydrogen Production
February 17, 2023 (v1)
Subject: Energy Systems
Keywords: biohydrogen, Biomass, hydrogen production, hydrogen storage, membrane catalysis, Steam Reforming, water electrolysis
Transitioning to energy-saving and renewable energy sources is impossible without accelerated development of hydrogen energy and hydrogen technologies. This review summarizes the state-of-the-art and recent advances of various hydrogen production processes, including but not limited to thermochemical and electrolytic processes. Their opportunities and limitations, operating conditions, and catalysts are discussed. Nowadays, most hydrogen is still produced by steam reforming of methane, its partial oxidation, or coal gasification. Considerable attention is also paid to natural gas pyrolysis. However, hydrogen produced using these technologies has a lot of impurities and needs additional purification. A series of technologies for hydrogen purification, including its filtration through palladium alloy membranes, and membrane catalysis, allowing hydrogen production and purification in one stage, are discussed. The main way to produce carbon-free hydrogen is water electrolysis using low-cos... [more]
36276. LAPSE:2023.0088
Influence of Tip Clearance on Cavitation Characteristics of an Inducer of Turbopump: CFD Study
February 17, 2023 (v1)
Subject: Modelling and Simulations
Keywords: blade loading, inducer, radial force, rotating cavitation, tip clearance, tip leakage
The tip clearance, a compact gap between the inducer blade tip and casing wall, is critical to both the liquid leakage and cavitation-induced forces of a turbopump. In this study, we numerically investigate the effect of tip clearance on the cavitation characteristics of an inducer. Six different tip clearances, 0.1, 0.3, 0.5, 1.0, 1.5, and 2 mm, namely Models A−F, were designed to evaluate the cavitation performance, cavity structure, blade loading, radial force, etc. Model D (1.0 mm) had the relatively highest head coefficient and smallest cavity area on each blade as compared to all other models. The pressure coefficient distribution and blade loading further confirmed that Model D can maintain a higher pressure head and better suppress the cavitation onset than the other models. The radial force signals in the time and frequency domains show that Model D has an intermediate force magnitude with slightly higher noises at the rotating frequency and its harmonic frequencies. Model D a... [more]
36277. LAPSE:2023.0087
Effect of Annular Gas−Liquid Two-Phase Flow on Lateral Vibration of Drill String in Horizontal Drilling for Natural Gas Hydrate
February 17, 2023 (v1)
Subject: Energy Systems
Keywords: drill string, drilling, fluid–structure interaction, gas–liquid two-phase flow, NGH
NGH (natural gas hydrate) is a sort of green energy with huge reserves. When drilling and exploiting NGH, the complex drilling environment will aggravate the vibration of the drill string, which will destroy the stability of the NGH reservoir and make it decompose to produce a large amount of gas. Gas flows into the annular with the drilling fluid, filling the annular with a gas−liquid two-phase flow with a complex variation in the characteristic parameters of the pipe flow. The mixed gas−liquid annular flow will make the drill string vibration more complex and intense. In this study, the nonlinear mathematical model of the drill string lateral vibration is established by considering the influence of the internal and external fluids, gravity, and the bottom axial force on the lateral vibration of the drill string. The effect of the annular fluid velocity and gas content on the lateral vibration of the drill string was studied through experiments and numerical simulations. This study fo... [more]
36278. LAPSE:2023.0086
Cellulose Acetate Film Containing Bonechar for Removal of Metribuzin from Contaminated Drinking Water
February 17, 2023 (v1)
Subject: Materials
Keywords: carbonaceous material, environmental remediation, herbicide, natural polymer
Bonechar presents high sorption capacity for mobile herbicides retained in soil and water. However, its use in a granulated and/or powder form makes it difficult to remove water. The objective of this study was to produce a cellulose acetate film with bonechar as a viable alternative to remove metribuzin from water. The treatments were composed of 2 and 3 g of bonechar fixed on a cellulose acetate film, pure bonechar, and a control (no bonechar). The sorption and desorption study was carried out in the equilibrium batch mode with five concentrations of metribuzin (0.25, 0.33, 0.5, 1, and 2 mg L−1). The water used in the experiment was potable water. Herbicide analysis was performed by High-Performance Liquid Chromatography (HPLC). The addition of 2 and 3 g of the bonechar fixed on the acetate film sorbed 40% and 60%, respectively, of the metribuzin at the lowest concentrations (0.25, 0.33, and 0.5 mg L−1). For both additions, desorption was low, being 7% and 2.5% at 24 and 120 h, respe... [more]
36279. LAPSE:2023.0085
Oxygenated and Nitrated Polycyclic Aromatic Hydrocarbons: Sources, Quantification, Incidence, Toxicity, and Fate in Soil—A Review Study
February 17, 2023 (v1)
Subject: Environment
Keywords: fate and behavior, NPAH, OPAH, PAH, soil, toxicity
The genotoxicity, mutagenesis, and carcinogenic effects of polycyclic aromatic hydrocarbon (PAH) derivatives may exceed the parent PAHs. However, their influence on the soil environment has not been explored to a large extent. Oxygenated polycyclic aromatic hydrocarbons (OPAHs) and nitrated polycyclic aromatic hydrocarbons (NPAHs) are typical polar substituted compounds. We offer a review of the literature on the sources, quantification, incidence, toxicity, and transport of these compounds in soil. Although their environmental concentrations are lower than those of their parent compounds, they exert higher toxicity. Both types of substances are basically related to carcinogenesis. OPAHs are not enzymatically activated and can generate reactive oxygen species in biological cells, while NPAHs have been shown to be mutagenic, genotoxic, and cytotoxic. These compounds are largely derived from the transformation of PAHs, but they behave differently in soil because of their higher molecular... [more]
36280. LAPSE:2023.0084
Evaluation of the Performance of a Heat Pipe for Pre-Frozen Soil around a Solar Support by a Numerical Method
February 17, 2023 (v1)
Subject: Numerical Methods and Statistics
Keywords: frozen soil, heat pipe, heat transfer, porous media
The base of solar collector systems is usually installed in soil that contains moisture. In cold regions, due to the low ambient temperature, the moisture in the soil freezes, creating a risk of frost heave. This study analyzed the frost heave mechanism of power transmission and transformation foundation, clarified the factors affecting soil frost heave and the way to solve soil layer frost heave, and proposed the use of heat transfer elements to pre-frozen soil layers to prevent the foundation of the solar collector system from freezing. A numerical model of the ground heat exchange pipes in soil was established. The effects of different soil types, soil moisture content, and the effective radius and operating time on the heat transfer performance of the system were investigated by the verified numerical model. The results show that the heat pipe pre-freezing technology can reduce the drop in soil temperature, thereby increasing the temperature difference between the ground heat excha... [more]
36281. LAPSE:2023.0083
Numerical Study of the Purge Flow’s Effect on the Loss Mechanism of the Blocking and Shear Effects
February 17, 2023 (v1)
Subject: Numerical Methods and Statistics
Keywords: blocking effect, purge flow, seal structure, sealing efficiency, shear loss, tangential velocity, tangential velocity gradient
The loss mechanism of shear and upstream blockage caused by the interaction of the purged flow and ingested gas needs to be systematically studied to optimize the flow near the rim. In order to study the causes and influence factors of blocking and shearing effects and quantify their losses reasonably, the three-dimensional unsteady numerical method validated by the experiment data was adopted to study the turbine with three kinds of sealing structures. The block and shear loss are quantified by integrating the dissipation coefficient in the volume where the specific aerodynamic loss occurs. The result indicated that there was a larger radial velocity and smaller tangential velocity of the purged flow relative to the main flow caused the blocking effect. Therefore, its loss is affected by the seal flow and seal structure. The shear effect is mainly affected by the tangential velocity gradient and the axial velocity gradient near the cavity exit. The contribution of the tangential veloc... [more]
36282. LAPSE:2023.0082
Solving Tea Blending Problems Using Interactive Fuzzy Multi-Objective Linear Programming
February 17, 2023 (v1)
Subject: Materials
Keywords: blending problem, fuzzy-efficient solution, interactive fuzzy programming, multi-objective decision making, tea industry
Blending is a classical and well-known optimization problem that has been applied in the food, steel, and composite material industries. However, tea blending is more complicated than general problems due to the variety of products, processes, and sources of raw materials and semi-products. So, in this research, a fuzzy multi-objective model for the tea blending problem was proposed to minimize the total production cost and the deviation of quality target score; it provides a more robust and flexible method than existing models for complex real-world problems. Existing research works of a blending problem consider only raw material cost, but semi-product cost and processing cost are included in the proposed model that matches the actual case. Losses that occur during production are also incorporated. The selection of appropriate raw materials and semi-product sources can be obtained with the preferred levels of cost and quality by the proposed algorithm. The interactive fuzzy multi-obj... [more]
36283. LAPSE:2023.0081
Behavioral Model Deployment for the Transportation Projects within a Smart City Ecosystem: Cases of Germany and South Korea
February 17, 2023 (v1)
Subject: Planning & Scheduling
Keywords: behavioral model, Germany, key variables, project, smart city ecosystem, South Korea, transportation industry
This research focused on a behavioral model as a significant tangible enabler for smart city plans and initiatives across Asian and EU regions as per transportation projects. This study aimed to create a behavioral model to serve as a planning tool for policymakers, planners, and implementers of transportation initiatives in smart cities. The paper discusses the validity of the proposed model framework for fostering the diffusion of a successful smart city project transformation in a general smart city ecosystem and particularly within the transportation industry. The framework was verified using three different methods: literature review to give a speculative understanding of current smart city approaches; case studies from Germany and South Korea smart city ecosystems that were selected and applied against the behavioral model; and finally, desktop research (behavioral model) performed for smart city project development. As a result, the authors recognized key variables for deriving... [more]
36284. LAPSE:2023.0080
Numerical Simulations of Particle Motions at Continuous Rotational Speed Changes in Horizontal Rotating Drums
February 17, 2023 (v1)
Subject: Modelling and Simulations
Keywords: discrete element method, number of contacts, numerical simulations, particle segregation, rotating drums
The motion of binary particles in three horizontal rotating drums with continuous rotational speed changes was studied based on the Discrete Element Method (DEM). Different simulation conditions were compared between two circular drums and an elliptical drum using the same number of physical properties for binary particles and drums, rotating at a speed series from 0.01 to 21.9 rad/s. By varying the rotational speed, four flow regimes were produced in the simulation. Flow regimes, velocity vectors, normal forces, and the number of contacts between 1 mm particles and 3 mm particles were comparatively analyzed, especially the particle velocity at transient changing rotational speeds. The results showed that four flow regimes were found at the same rotational speed for three different rotating drums, and normal forces were weakest for the cataracting regime; moreover, the three layers of particles were damaged when the rotational speed was suddenly decreased and the velocity direction of... [more]
36285. LAPSE:2023.0079
Computational Fluid Dynamics Modeling of Single Isothermal and Non-Isothermal Impinging Jets in a Scaled-Down High-Temperature Gas-Cooled Reactor Facility
February 17, 2023 (v1)
Subject: Modelling and Simulations
Keywords: computational fluid dynamics (CFD), high-temperature gas-cooled reactor (HTGR), isothermal impinging jet, non-isothermal impinging plume, Reynolds numbers (Re), upper plenum
In the current work, the flow characteristics of single isothermal and non-isothermal jets discharging into the upper plenum of a 1/16th scaled-down high-temperature gas-cooled reactor (HTGR) facility were studied. ANSYS Fluent simulations were carried out in the central plane of the jet water flow and the upper plenum for different Reynolds numbers (Re) ranging from 3413 to 12,819. Then, the statistical jet water flow characteristics, such as the mean velocity, root-mean-square fluctuating velocity, Reynolds stress, and the mean temperature in the upper plenum, were computed and presented. The current study’s results showed that the flow maximum velocity occurred far from the jet inlet. Finally, the temperature profiles were plotted, and it was found that the maximum temperature of the flow occurred close to the plume inlet and after that decreased downstream.
36286. LAPSE:2023.0078
Annual Electricity and Energy Consumption Forecasting for the UK Based on Back Propagation Neural Network, Multiple Linear Regression, and Least Square Support Vector Machine
February 17, 2023 (v1)
Subject: Numerical Methods and Statistics
Keywords: back propagation neural network, electricity and energy consumption, forecasting, least square support vector machine, machine learning algorithm, multiple linear regression, UK
The long-term demand forecast for annual national electricity and energy consumption plays a vital role in future strategic planning, power system installation programming, energy investment planning, and next-generation unit construction. Three machine learning algorithms of BP-NN, MLR, and LS-SVM were chosen for training forecasting models, with the data on population, GDP, mean temperature, sunshine, rainfall, and frost days in 1993−2019 serving as the input variables. The total data were divided by 70% into the training set (1993−2011) and 30% into the test set (2012−2019), in chronological order. RMSE, MAPE, and MaxError were adopted as the performance criteria. The statistical results show that the gross population of the UK increases year by year from 1993 to 2020. The GDP generally increases before 2007 but has a decline, and then varies with a large amplitude afterward. The electricity and energy consumption of the UK generally increase from 1993 and reach a peak around 2005.... [more]
36287. LAPSE:2023.0077
Development of a SPE-HPLC-PDA Method for the Quantification of Phthalates in Bottled Water and Their Gene Expression Modulation in a Human Intestinal Cell Model
February 17, 2023 (v1)
Subject: Food & Agricultural Processes
Keywords: Caco-2 cell line, colon disease, gene expression, HPLC, phthalates, pollutions, qRT-PCR
Phthalates are ubiquitous pollutants that are currently classified as endocrine disruptor chemicals causing serious health problems. As contaminants of food and beverages, they come into contact with the epithelium of the intestinal tract. In this work, a SPE-HPLC-PDA method for the determination of phthalates in water from plastic bottles was developed and validated according to the food and drug administration (FDA) guidelines. A chromatographic separation was achieved using a mobile phase consisting of ammonium acetate buffer 10 mM pH 5 (line A) and a mixture of methanol and iso-propanol (50:50 v/v, line B) using gradient elution. Several SPE cartridges and different pH values were investigated for this study, evaluating their performance as a function of recovery. Among these parameters, pH 5 combined with the SPE sep pack C18 cartridge showed the best performance. Finally, the proposed method was applied to the analysis of real samples, which confirmed the presence of phthalates.... [more]

