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2004. LAPSE:2023.34908
Small Modular Reactor Deployment and Obstacles to Be Overcome
April 28, 2023 (v1)
Subject: Planning & Scheduling
Keywords: financing, licensing, public acceptance, small modular reactor deployment, Supply Chain.
To meet climate policy goals, it will be necessary to deploy a series of low-carbon energy technologies, including nuclear power. The small modular reactor (SMR) can potentially support climate change mitigation and energy security issues. Small modular reactors (SMRs) are gaining popularity; however, one crucial debate is whether SMRs can compete economically with conventional nuclear reactors or not. From a commercial point of view, SMRs will be able to provide process heat in various industrial applications, replace older nuclear, natural gas, and coal power facilities, and serve smaller energy markets with less established infrastructure. Realizing these advantages would rely heavily on the near-term quick up-scaling of SMRs; this paper, then, examines and identifies some of the most hindering constraints and barriers for the quick deployment of SMR such as the technology choice, licensing, economy of scale and financing, public acceptance, supply chain, and proliferation. A clear... [more]
2005. LAPSE:2023.34907
Advances in Reduction Technologies of Gas Emissions (CO2, NOx, and SO2) in Combustion-Related Applications
April 28, 2023 (v1)
Subject: Energy Systems
Global energy production and consumption have increased continuously over the past few decades [...]
2006. LAPSE:2023.34906
Advanced Exergoeconomic Assessment of CO2 Emissions, Geo-Fluid and Electricity in Dual Loop Geothermal Power Plant
April 28, 2023 (v1)
Subject: Energy Systems
Keywords: advanced exergoeconomic analysis, CO2 emission cost, electricity generation cost, geothermal power plant, performance indicators.
Binary geothermal power plants (GPPs) are mostly encountered in geothermal fields with medium and low temperatures. The design and operation of dual binary GPPs can be difficult due to the geothermal fluid properties. This affects their performance and feasibility. Thermoeconomics are essential elements for the design and operation of the GPPs. In this study, advanced exergoeconomic analysis is applied to a true dual binary GPP (as a case study) to further evaluate it from performance and economic perspectives. In analysis, the specific exergy cost (SPECO) method is used. Then, some specific indicators are presented to evaluate the performance and economics of the GPP. Thus, technical and economic solutions have been developed in the design and operation stages through the analysis. The results of the study indicated that the total operating cost of 1218 USD/h could be reduced to 186 USD/h by improving the operating conditions. This corresponds to an 85% decrease. The cost per electric... [more]
2007. LAPSE:2023.34905
Research on Solidity of Horizontal-Axis Tidal Current Turbine
April 28, 2023 (v1)
Subject: Energy Systems
Keywords: Matlab, solidity of blade, tidal current capture device.
In this paper, the blade solidity of the tidal current turbine was investigated. Based on the blade element momentum theory, different design flow velocities were selected to design two blade types with different solidities. The geometric parameters of the blade were calculated using MATLAB programming, and the performance of two blades was compared in terms of the start-up flow rate, power generation and thrust by test experiment, which showed that the blade with higher solidity has better start-up performance and higher energy capture efficiency at low flow rates. The performance is better than that of the blade with low solidity, but due to the high solidity, the thrust is also high, which should be taken into account when installing the turbine.
2008. LAPSE:2023.34904
Internet of Things: A Comprehensive Overview on Protocols, Architectures, Technologies, Simulation Tools, and Future Directions
April 28, 2023 (v1)
Subject: Information Management
Keywords: application layer protocols, communication protocols, hybrid IoT protocols, Internet of Things, IoT challenges, IoT comparison, IoT hardware, network simulation tools.
The Internet of Things (IoT) is a global network of interconnected computing, sensing, and networking devices that can exchange data and information via various network protocols. It can connect numerous smart devices thanks to recent advances in wired, wireless, and hybrid technologies. Lightweight IoT protocols can compensate for IoT devices with restricted hardware characteristics in terms of storage, Central Processing Unit (CPU), energy, etc. Hence, it is critical to identify the optimal communication protocol for system architects. This necessitates an evaluation of next-generation networks with improved characteristics for connectivity. This paper highlights significant wireless and wired IoT technologies and their applications, offering a new categorization for conventional IoT network protocols. It provides an in-depth analysis of IoT communication protocols with detailed technical information about their stacks, limitations, and applications. The study further compares indust... [more]
2009. LAPSE:2023.34903
A New Design for the Peer-to-Peer Electricity and Gas Markets Based on Robust Probabilistic Programming
April 28, 2023 (v1)
Subject: Optimization
Keywords: alternating direction method of multipliers, decentralized robust optimization, energy hub, fuzzy robust optimization, peer-to-peer electricity and gas transactions.
This paper presents a fully-decentralized peer-to-peer (P2P) electricity and gas market for retailers and prosumers with coupled energy units, considering the uncertainties of wholesale electricity market price and prosumers’ demand. The goal is to improve the overall economy of the proposed market while increasing its flexibility. In this market, the retailers are equipped with self-generation and energy storage units and can bilaterally negotiate for electricity and gas transactions with prosumers to maximize their profit. Furthermore, they can sell power to the upstream market in addition to prosumers. The prosumers have access to several retailers to supply their required electricity and gas and can freely provide their energy needs from every retailer, contributing to dynamicity in the proposed market. Given that they have an energy hub consisting of boiler units, combined heat and electricity (CHP) units, and electric pumps, they can switch their energy supply source from electri... [more]
2010. LAPSE:2023.34902
Thermoelectric Field Analysis of Trapezoidal Thermoelectric Generator Based on the Explicit Analytical Solution of Annular Thermoelectric Generator
April 28, 2023 (v1)
Subject: Materials
Keywords: annular thermoelectric generator, explicit analytical solution, output power, trapezoidal thermoelectric generator, varied cross section.
The geometrical configuration is one of the main factors that affect the thermoelectric performance of a device. Research on the trapezoidal thermoelectric generator (TTEG) with varied cross section is mainly based on finite element simulation and experiment. In this paper, an explicit analytical solution of the maximum output power of annular thermoelectric generators (ATEG) is proposed, which has been proved to have high accuracy. Then, the maximum output power between ATEG and TTEG is compared. Results show that, for the appropriate geometric parameter δ, the relative error of maximum output power between explicit analytical ATEG and the simulated solution of TTEG can reach the order of 10−3. When the hot end is at the a side, the high temperature and θ is 510 K and 10°, respectively. For Bi2Te3 material and PbTe material, the relative error of maximum output power between the explicit analytical and simulated solution is 0.0261% and 0.074%, respectively. Under suitable working cond... [more]
2011. LAPSE:2023.34901
An Application of Machine Learning Algorithms by Synergetic Use of SAR and Optical Data for Monitoring Historic Clusters in Cypriot Cities
April 28, 2023 (v1)
Subject: Modelling and Simulations
Keywords: change detection, historic architecture clusters, land cover classification, Machine Learning, remote sensing, Sentinel-1, Sentinel-2, SNAP, urban heritage.
In an era of rapid technological improvements, state-of-the-art methodologies and tools dedicated to protecting and promoting our cultural heritage should be developed and extensively employed in the contemporary built environment and lifestyle. At the same time, sustainability principles underline the importance of the continuous use of historic or vernacular buildings as part of the building stock of our society. Adopting a holistic, integrated, multi-disciplinary strategy can link technological innovation with the conservation and restoration of heritage buildings. This paper presents the ongoing research and results of the application of Machine Learning methods for the remote monitoring of the built environment of the historic cluster in Cypriot cities. This study is part of an integrated, multi-scale, and multi-disciplinary study of heritage buildings, with the end goal of creating an online HBIM platform for urban monitoring.
2012. LAPSE:2023.34900
Pyrolysis of Oils from Unconventional Resources
April 28, 2023 (v1)
Subject: Energy Systems
Keywords: enhanced oil recovery, Oil Sands, oil shale, pyrolysis, superheat steam, unconventional oil resource.
In this study, oils from various sources were subjected to pyrolysis conditions; that is, without oxidizer, as the samples were heated to 500 °C, and held at that temperature. The oils studied included: (1) heavy oil from Grassy Creek, Missouri; (2) oil from tar sands of Asphalt Ridge in Utah; (3) mid-continent oil shales of three formations (two of Chattanooga formation, Pennsylvanian (age) formation, and Woodford formation); and (4) a Colorado Piceance Basin shale. Differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) with either gas chromatography (GC) or mass spectrometry (MS) were used to quantify the produced gases evolved in the tests. Purge gases of helium, argon, and humid carbon dioxide were utilized. Larger scale pyrolysis tests were conducted in a tube furnace coupled to a MS and a GC. The results consistently showed that pyrolysis occurred between 300 °C and 500 °C, with the majority of gases being mainly hydrogen and light alkanes. This behavior was... [more]
2013. LAPSE:2023.34899
Investigation of Optimal Temperature for Thermal Catalytic Conversion of Marine Biomass for Recovery of Higher-Added-Value Energy Products
April 28, 2023 (v1)
Subject: Energy Systems
Keywords: bio-gas, bio-oil, macroalgae, slow-pyrolysis, waste-to-energy.
The eutrophication process, caused by the uncollected seaweed and macroalgae, is a relevant and ongoing ecological issue. In case this biomass is collected from the seashores, it could be used as a potential feedstock for recovery of higher-added-value energy products. This paper aims to investigate the seaweed perspective of uses as a potential feedstock in the slow-pyrolysis process, using microthermal analysis combined with Fourier transform infrared spectrometry and experiments at the laboratory scale at different temperatures with two different types of zeolite catalysts. The primary investigation was performed using a micro-thermal analyser, and the results revealed that seaweed thermally decomposes in two stages, at 250 and 700 °C, while the catalyst slightly decreased the activation energy required for the process, lowering the temperatures of decomposition. Experiments on a laboratory scale showed that the most common compounds in the gaseous phase are CnHm, H2, CO, and CO2. N... [more]
2014. LAPSE:2023.34898
Impact of the Short-Circuit Current Value on the Operation of Overhead Connections in High-Voltage Power Stations
April 28, 2023 (v1)
Subject: Electricity & Electrical Devices
Keywords: analysis, electrodynamic forces, mechanical effects, power substations, short circuit calculations, short circuit current, thermal effects.
This paper focuses on determining the effects of short-circuit current values on the operation of high-voltage substations. The analyses performed focused on the dynamic and thermal effects on the short-circuit current for different input data configurations. The analyses of the dynamic effects of short-circuit current were performed in two ways. First, calculations were executed using the procedures contained in “IEC 60865-1:2012 Short-circuit currents, calculations of the effects of short-circuit currents. Part 1: Definitions and calculation methods”. Analytic calculations were accomplished for different values of the initial three-phase short-circuit current, the type of short circuit, the static tension force of the conductors, the stiffness of the structure and the methods of attaching the lashing chains. Secondly, the same analysis was performed using PRIMTECH 3D software. The connections were modeled in computer software, for which the calculations were implemented according to... [more]
2015. LAPSE:2023.34897
Interpretation of Sand Body Architecture in Complex Fault Block Area of Craton Basin: Case Study of TIII in Sangtamu Area, Tarim Basin
April 28, 2023 (v1)
Subject: Food & Agricultural Processes
Keywords: architecture, braided river delta front, complex fault block oilfield, Tarim Basin, triassic.
The complex fault block oilfields in the craton basin contain vast reserves of oil and gas resources. During the development of an oilfield, the flow of oil, gas, and water, is controlled by faults and configuration boundaries. The distribution of remaining oil and gas depends on the interpretation of the reservoir’s architecture. However, recognizing the faults and the architecture boundary remains a challenge, hindering the efficient development of these resources. This study proposes a new idea for interpreting the configuration of thick sand bodies. This study was conducted in order to interpret the fine architecture of thick sand bodies in the Sangtamu area, using core samples, well logging, and production data, guided by sedimentation patterns from ancient to modern times. Results indicate that the Sangtamu area is a braided river delta front sedimentary system, dominated by the backbone underwater distributary channel and branch-type underwater distributary channels. The backbon... [more]
2016. LAPSE:2023.34896
Cracking Analysis of a Brass Clamp Mounted on the Main Transformer in the Power Grid System
April 28, 2023 (v1)
Subject: Energy Systems
Keywords: brass clamp, failure, fracture, stress corrosion cracking.
Cracking of conductive brass accessories in substations causes overheating or an open circuit, seriously affecting the safe and stable operation of the power grid system. A deep understanding of failure mechanisms could provide more safety, as well as lower down costs and save time for the power grid system, which have been seldomly involved in the literature. This paper presents a cracking analysis of a brass clamp in service for seven years that is mounted on the main transformer. The fracture morphology, chemical composition, and metallographic structure of the brass clamp were systematically analyzed, and the stress conditions were obtained by finite element simulation. The clamp exhibits transgranular brittle fracture with high oxygen content in the fracture, containing a crack propagation along the Pb particle connecting pathways, and the stress concentration was confirmed at the crack position. It is concluded that the failure was a result of the stress corrosion cracking and ex... [more]
2017. LAPSE:2023.34895
Optical and Numerical Investigations on Combustion and OH Radical Behavior Inside an Optical Engine Operating in LTC Combustion Mode
April 28, 2023 (v1)
Subject: Energy Systems
Keywords: IEM model, internal combustion engine, LTC combustion, OH radical, optical diagnostics, turbulence model.
Low Temperature Combustion (LTC) is a relevant process for internal combustion engines (ICE). This combustion mode is based on premixed fuel/air and fuel lean in-cylinder mixture allowing reduction in NOx and PM emissions while maintaining higher thermal efficiency. In order to investigate the effect of engine operating conditions on the behavior of LTC mode, including OH radical evolution, optical measurements and numerical simulations were performed on a transparent CR diesel engine. The homogeneity of the engine charge was obtained by using very early injection timings. In this study, varying injection strategies were investigated for different engine speeds. In parallel to the experimentation, simulations of LTC mode for the same experimental operations were carried out. The model used in this study is based on a stochastic reactor model. This model includes a turbulence (k-ε) model based on a zero-dimensional energy cascade to calculate the turbulent time scale during the cycle. O... [more]
2018. LAPSE:2023.34894
A Review of Research on Advanced Control Methods for Underground Coal Gasification Processes
April 28, 2023 (v1)
Subject: Energy Systems
Keywords: advanced control, automation, control algorithm, control methods, Modelling, Optimization, review, UCG.
Underground coal gasification (UCG) is a clean coal mining technology without significant environmental impacts. This technology can also be used in deep, hard-to-reach seams or deposits affected by tectonic disturbances, where conventional mining is impossible. Several techniques and methods have been investigated worldwide to support the process control of UCG. Global research focuses on the control of UCG operating parameters to stabilize or to optimize the performance of the underground reactor during energy conversion. This paper studies recent research in the field of UCG control and compares individual control techniques and possibilities for practical application. The paper focuses on advanced control methods that can be implemented in an in situ control system (e.g., adaptive control, extremum seeking control, and robust control). The study investigates control methods that ensure desired syngas calorific value or maximization. The review showed that robust control techniques... [more]
2019. LAPSE:2023.34893
Simulation and Experimental Study on the Use of Ventilation Air for Space Heating of a Room in a Low-Energy Building
April 28, 2023 (v1)
Subject: Modelling and Simulations
Keywords: 5R1C, air heating system, heat recovery, indoor air temperature, thermal network model.
In thermally modernised buildings, sharing of ventilation heat loss becomes more significant. In the case of the application of ventilation with heat recovery, especially during transitional periods, there arises a question of whether an air system makes it possible to maintain the required indoor air temperature without the necessity of using a basic hydronic heating system. This paper presents the application of a simple thermal network model of a building zone to simulate indoor air temperature in a single room of a multi-storey building with a mechanical ventilation system with heat recovery. Ventilation air was supposed to be the only heat source and its ability to maintain the required indoor air temperature was checked in simulations and then compared with measurements. The 5R1C thermal network model of a building zone was used for simulations. Comparison with measurements showed the Mean Absolute Error (MAE) and Root Mean Square Error (RMSE) of indoor air calculation to be 2.37... [more]
2020. LAPSE:2023.34892
Study and Analysis of Dynamics and Energy Efficiency of Arc Steelmaking Furnace Electrical Mode with a Fuzzy Control Algorithm
April 28, 2023 (v1)
Subject: Process Control
Keywords: arc steelmaking, automatic control, fuzzy systems, regulators.
A review of the control laws (models) of alternating current arc steelmaking furnaces’ (ASF) electric modes (EM) is carried out. A phase-symmetric three-component additive fuzzy model of electrode movement control signal formation is proposed. A synthesis of fuzzy inference systems based on the Sugeno model for the implementation of the proposed additive three-component fuzzy law of arc length control is performed. A structural computer Simulink model of the EM control system in a high-power arc steelmaking furnace of the DSP-200 type with an ARDM-T-12 arcs power regulator is created. Computer research into control dynamics indicators under the influence of deterministic perturbations and also integral indicators of energy efficiency when handling stationary random arc lengths fluctuations (corresponding to various technological stages of melting) are carried out. A comparative analysis of dynamics indicators, energy efficiency, and electromagnetic compatibility of the proposed fuzzy a... [more]
2021. LAPSE:2023.34891
Physical Simulation Test of Underground Coal Gasification Cavity Evolution in the Horizontal Segment of U-Shaped Well
April 28, 2023 (v1)
Subject: Energy Systems
Keywords: cavity evolution, gasification cavity, physical simulation, temperature field, underground coal gasification.
A key point in the underground coal gasification process is the cavity evolution in the horizontal segment. The morphological evolution law of the gasification cavity has not been clarified, which is the bottleneck restricting the analysis of its controllability. In this paper, a physical simulation system for cavity generation was developed, and the cavity evolution in a targeted coal seam with overburden pressure was duplicated in the laboratory. A set of temperature field synchronous monitoring devices was developed to realize temperature sampling within a cavity and the surrounding rock. By analyzing the relationship between the overall temperature distribution pattern and the gasification agent injection condition, the morphological propagation law of the cavity is verified to be water drop-shaped, and influencing factors including the injection flow rate and the gasification agent component ratio are investigated. The axial length and volume of the cavity increase with an increas... [more]
2022. LAPSE:2023.34890
New Sustainable Banana Value Chain: Waste Valuation toward a Circular Bioeconomy
April 28, 2023 (v1)
Subject: Food & Agricultural Processes
Keywords: agricultural residue, anaerobic digestion, circular economy, closed loop supply chain, mathematical model.
According to the needs of sustainability, a new sustainable banana chip value chain, which is a combination of the traditional banana chip value chain and the banana waste value chain, was designed. Scenarios were created assuming that an anaerobic digester would be implemented to produce biogas—which can act as a substitute for liquefied petroleum gas (LPG) used in banana processing—from banana wastes. The values of banana residues throughout the value chain were determined depending on farm gate tree price, transportation cost, and the final value of LPG substitution. The value chain was optimized using two objective functions: total chain profit maximization and factory profit maximization. The tree price at the farm gate was determined and assumed to be between USD 0.067 and USD 0.093 per tree, and the transportation cost of tree transportation was assumed to be between USD 0.31 and USD 0.39 per km. Different tree prices and transportation costs affected the profits of all stakehol... [more]
2023. LAPSE:2023.34889
A Review of Reinforcement Learning-Based Powertrain Controllers: Effects of Agent Selection for Mixed-Continuity Control and Reward Formulation
April 28, 2023 (v1)
Subject: Process Control
Keywords: powertrain control, reinforcement learning, review.
One major cost of improving the automotive fuel economy while simultaneously reducing tailpipe emissions is increased powertrain complexity. This complexity has consequently increased the resources (both time and money) needed to develop such powertrains. Powertrain performance is heavily influenced by the quality of the controller/calibration. Since traditional control development processes are becoming resource-intensive, better alternate methods are worth pursuing. Recently, reinforcement learning (RL), a machine learning technique, has proven capable of creating optimal controllers for complex systems. The model-free nature of RL has the potential to streamline the control development process, possibly reducing the time and money required. This article reviews the impact of choices in two areas on the performance of RL-based powertrain controllers to provide a better awareness of their benefits and consequences. First, we examine how RL algorithm action continuities and control−act... [more]
2024. LAPSE:2023.34888
Determination of Heat and Mass Transport Correlations for Hollow Membrane Distillation Modules
April 28, 2023 (v1)
Subject: Modelling and Simulations
Keywords: membrane distillation, Modelling, Nusselt number, thermal conductivity, tortuosity factor.
Development and optimization of the membrane distillation (MD) process are strongly associated with better understanding of heat and mass transport across the membrane. The current state-of-the-art on heat and mass transport in MD greatly relies upon the use of various empirical correlations for the Nusselt number (Nu), tortuosity factor (τ), and thermal conductivity (κm) of the membrane. However, the current literature lacks investigations about finding the most representative combination of these three parameters for modeling transport phenomena in MD. In this study, we investigated 189 combinations of Nu, κm, and τ to assess their capability to predict the experimental flux and outlet temperatures of feed and permeate streams for hollow fiber MD modules. It was concluded that 31 out of 189 tested combinations could predict the experimental flux with reasonable accuracy (R2 > 0.95). Most of the combinations capable of predicting the flux reasonably well could predict the feed outlet... [more]
2025. LAPSE:2023.34887
Experimental Evaluation of a Photovoltaic/Thermal Air Heater with Metal Mesh-Integrated Thermal Energy Storage System
April 28, 2023 (v1)
Subject: Energy Systems
Keywords: metal meshes, photovoltaic/thermal, solar air heater, thermal energy storage.
The objective of this study is to improve the performance of a hybrid photovoltaic/thermal (PV/T) air heater incorporating a thermal energy storage system (TESS) that uses paraffin and has metallic mesh layers. In the experimental part of the research, three different pilot-scale PV/Ts have been designed, manufactured, and experimentally investigated. The first system was structured as a conventional PV/T, while the second (PVT/TESS) was modified with a paraffin-based TESS. The efficiency of a hybrid PV/T air heater was improved by integrating a paraffin-based thermal energy storage system (TESS) with metallic mesh layers (PV/T-MTESS). The performance of the modified PV/T-MTESS system was compared to two other PV/T systems under the same weather conditions and air flow rate. The results of the experiment demonstrated that the integration of mesh layers into the TESS led to substantial improvements in the system’s thermal and electrical performance, as well as its overall exergy efficie... [more]
2026. LAPSE:2023.34886
Cracking Behavior of Heavy Petroleum Polar Species in Collision-Induced Dissociation and Thermal Visbreaking
April 28, 2023 (v1)
Subject: Materials
Keywords: bond cleavage, collision-induced dissociation, thermal cracking, vacuum residue.
In thermal cracking and collision-induced dissociation (CID) processes, molecules/ions mainly undergo cleavage reactions. In theory, the cleavage reaction is preferred for weak bonds in both processes. The present study investigates the thermal cracking and CID behavior of polar compounds in vacuum residue. By controlling the thermal reaction temperature and collision energy, different degrees of fragmentation were achieved. The molecular composition before and after the cracking process was analyzed through electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI FT-ICR MS). There was a correlation between the reaction temperature and the collision energy for the average carbon number value. Both desulfurization and decarboxylation were also observed in two processes due to the low C-S bond energy and poor stability of carboxylic acid groups. Nevertheless, the two processes still had some differences in reaction selectivity. Polar species tended to be d... [more]
2027. LAPSE:2023.34885
Pre-Attention Mechanism and Convolutional Neural Network Based Multivariate Load Prediction for Demand Response
April 28, 2023 (v1)
Subject: Numerical Methods and Statistics
Keywords: attention, convolutional neural network, gate recurrent unit, load prediction.
The construction of smart grids has greatly changed the power grid pattern and power supply structure. For the power system, reasonable power planning and demand response is necessary to ensure the stable operation of a society. Accurate load prediction is the basis for realizing demand response for the power system. This paper proposes a Pre-Attention-CNN-GRU model (PreAttCG) which combines a convolutional neural network (CNN) and gate recurrent unit (GRU) and applies the attention mechanism in front of the whole model. The PreAttCG model accepts historical load data and more than nine other factors (including temperature, wind speed, humidity, etc.) as input. The attention layer and CNN layer effectively extract the features and weights of each factor. Load forecasting is then performed by the prediction layer, which consists of a stacked GRU. The model is verified by industrial load data from a German dataset and a Chinese dataset from the real world. The results show that the PreAt... [more]
2028. LAPSE:2023.34884
Improving the Efficiency of Organic Solar Cells via the Molecular Engineering of Simple Fused Non-Fullerene Acceptors
April 28, 2023 (v1)
Subject: Energy Systems
Keywords: crystallinity, organic photovoltaics, push–pull molecules, synthesis of small molecules, thermal properties.
The development of novel non-fullerene small-molecule acceptors (NFAs) with a simple chemical structure for high-performance organic solar cells (OSCs) remains an urgent research challenge to enable their upscaling and commercialization. In this work, we report on the synthesis and comprehensive investigation of two new acceptor molecules (BTPT-OD and BTPT-4F-OD), which have one of the simplest fused structures among the Y series of NFAs, along with the medium energy bandgap (1.85 eV−1.94 eV) and strong absorption in the visible and near-IR spectral range (700−950 nm). The novel NFAs have high thermal stability, good solubility combined with a high degree of crystallinity, and deep-lying levels of the lowest unoccupied molecular orbital (up to −3.94 eV). The BTPT-OD with indan-1-one-3-dicyanvinyl terminal acceptor group is superior to its counterpart BTPT-4F-OD with 5,6-difluorindan-1-one-3-dicyanvinyl group both in the number of synthetic steps and in the photovoltaic performance in O... [more]

