Nickel catalysts supported on zirconium oxide and modified by various amounts of lanthanum with 10, 15, and 20 wt.% were synthesized for CO2 reforming of methane. The effect of La2O3 as a promoter on the stability of the catalyst, the amount of carbon formed, and the ratio of H2 to CO were investigated. In this study, we observed that promoting the catalyst with La2O3 enhanced catalyst activities. The conversions of the feed, i.e., methane and carbon dioxide, were in the order 10La2O3 > 15La2O3 > 20La2O3 > 0La2O3, with the highest conversions being about 60% and 70% for both CH4 and CO2 respectively. Brunauer−Emmett−Teller (BET) analysis showed that the surface area of the catalysts decreased slightly with increasing La2O3 doping. We observed that 10% La2O3 doping had the highest specific surface area (21.6 m2/g) and the least for the un-promoted sample. The higher surface areas of the promoted samples relative to the reference catalyst is an indication of the concentration of the meta... [more]

In this paper, ZnCo2O4 nanowire arrays with a uniform carbon coating were introduced when polyvinyl alcohol (PVA) served as the carbon source. The coating process was completed by a facile bath method in PVA aqueous solution and subsequent pyrolyzation. The PVA-derived carbon-coated ZnCo2O4 nanowire array composites can be used directly as the binder-free and self-supported anode materials for lithium-ion batteries. In the carbon-coated ZnCo2O4 composites, the carbon layer carbonized from PVA can accelerate the electron transfer and accommodate the volume swing during the cycling process. The lithium storage properties of the carbon-coated ZnCo2O4 composites are investigated. It is believed that the novel carbon-coating method is universal and can be applied to other nanoarray materials.

Dried blood spot (DBS) technology has become a promising utility for the transportation and storage of biological fluids aimed for the subsequent clinical analysis. The basis of the DBS method is the adsorption of the components of a biological sample onto the surface of a membrane carrier, followed by drying. After drying, the molecular components of the biosample (nucleic acids, proteins, and metabolites) can be analyzed using modern omics, immunological, or genomic methods. In this work, we investigated the safety of proteins on a membrane carrier by tryptic components over time and at different temperatures (+4, 0, 25 °C) and storage (0, 7, 14, and 35 days). It was shown that the choice of a protocol for preliminary sample preparation for subsequent analytical molecular measurements affects the quality of the experimental results. The protocol for preliminary preparation of a biosample directly in a membrane carrier is preferable compared to the protocol with an additional stage of... [more]

This paper presents results of investigation of co-combustion process of biodiesel with gasoline, in form of mixture and using dual fuel technology. The main objective of this work was to show differences in both combustion systems of the engine powered by fuels of different reactivity. This paper presents parameters of the engine and the assessment of combustion stability. It turns out that combustion process of biodiesel was characterized by lower ignition delay compared to diesel fuel combustion. For 0.54 of gasoline energetic fraction, the ignition delay increased by 25% compared to the combustion of the pure biodiesel, but for dual fuel technology for 0.95 of gasoline fraction it was decreased by 85%. For dual fuel technology with the increase in gasoline fraction, the specific fuel consumption (SFC) was decreased for all analyzed fractions of gasoline. In the case of blend combustion, the SFC was increased in comparison to dual fuel technology. An analysis of spread of ignition d... [more]

Microscale combustion has potential application in a micro power generator. This paper studied the ignition and combustion behavior of individual graphite microparticles in a micro-combustor to explore the utilization of carbon-based fuels at the microscale system. The individual graphite microparticles inside the micro-combustor were ignited by a highly focused laser in an air flow with natural convection at atmospheric temperature and pressure. The results show that the ignition of graphite microparticles was heterogeneous. The particle diameter had a small weak effect on ignition delay time and threshold ignition energy. The micro-combustor wall heat losses had significant effects on the ignition and combustion. During combustion, flame instability, photophoresis, repetitive extinction and reignition were identified. The flame structure was asymmetric, and the fluctuation of flame front and radiation intensity showed combustion instability. Photophoretic force pushed the graphite aw... [more]

A novel auto-aspirated sparger is examined experimentally in a closed-loop reactor (CLR) at lab scale using particle image velocimetry, high-speed camera and oxygen mass transfer rate measurements. State-of-the-art 3D printing technology was utilized to develop the sparger design in stainless steel. An insignificant change in the bubble size distribution was observed along the aerated flow, proving the existence of a low coalescence rate in the constraint domain of the CLR pipeline. The studied sparger created macrobubbles evenly dispersed in space. In pure water, the produced bubble size distribution from 190 to 2500 μm is controlled by liquid flow rate. The bubble size dynamics exhibited a power-law function of water flow rate approaching a stable minimum bubble size, which was attributed to the ratio of the fast-growing energy of the bubble surface tension over the kinetic energy of the stream. Potentially, the stream energy can efficiently disperse higher gas flow rates. The oxygen... [more]

One popular method for optimizing systems, referred to as ANN-PSO, uses an artificial neural network (ANN) to approximate the system and an optimization method like particle swarm optimization (PSO) to select inputs. However, with reinforcement learning developments, it is important to compare ANN-PSO to newer algorithms, like Proximal Policy Optimization (PPO). To investigate ANN-PSO’s and PPO’s performance and applicability, we compare their methodologies, apply them on steady-state economic optimization of a chemical process, and compare their results to a conventional first principles modeling with nonlinear programming (FP-NLP). Our results show that ANN-PSO and PPO achieve profits nearly as high as FP-NLP, but PPO achieves slightly higher profits compared to ANN-PSO. We also find PPO has the fastest computational times, 10 and 10,000 times faster than FP-NLP and ANN-PSO, respectively. However, PPO requires more training data than ANN-PSO to converge to an optimal policy. This cas... [more]

Optimal steam process drive sizing is crucial for efficient and sustainable operation of energy-intense industries. Recent years have brought several methods assessing this problem, which differ in complexity and user-friendliness. In this paper, a novel complex method was developed and presented and its superiority over other approaches was documented on an industrial case study. Both the process-side and steam-side characteristics were analyzed to obtain correct model input data: Driven equipment performance and efficiency maps were considered, off-design and seasonal operation was studied, and steam network topology was included. Operational data processing and sizing calculations were performed in a linked MATLAB®−Aspen Plus® environment, exploiting the strong sides of both software tools. The case study aimed to replace a condensing steam turbine by a backpressure one, revealing that: 1. Simpler methods neglecting frictional pressure losses and off-design turbine operation efficie... [more]

This study evaluated the leakage characteristics of a stepped labyrinth seal. Experiments and computational fluid dynamics (CFD) analysis were conducted for a wide range of pressure ratios and clearance sizes, and the effect of the clearance on the leakage characteristics was analyzed by determining the performance of the seal using a dimensionless parameter. It was observed from the analysis that the performance parameter of the seal decreases as the clearance size increases, but it tends to increase when the clearance size exceeds a certain value. In other words, it was revealed that there exists a specific clearance size (Smin) which minimizes the performance parameter of the seal. To identify the cause of this tendency change, a flow analysis was conducted using CFD. It was confirmed that the leakage characteristics of the stepped seal are affected by the size of the cavity, which is the space between the teeth. Therefore, a parametric study was conducted on the design parameters r... [more]

Sustainable Development Goals establish the main challenges humankind is called to tackle to assure equal comfort of living worldwide. Among these, the access to affordable renewable energy and clean water are overriding, especially in the context of developing economies. Reversible Solid Oxide Cells (rSOC) are a pivotal technology for their sector-coupling potential. This paper aims at studying the implementation of such a technology in new concept PV-hybrid energy storage mini-grids with close access to seawater. In such assets, rSOCs have a double useful effect: charge/discharge of the bulk energy storage combined with seawater desalination. Based on the outcomes of an experimental proof-of-concept on a single cell operated with salty water, the operation of the novel mini-grid is simulated throughout a solar year. Simulation results identify the fittest mini-grid configuration in order to achieve energy and environmental optimization, hence scoring a renewable penetration of more t... [more]

Transitioning to a renewable energy economy requires the widespread integration of solar and wind power, which are intermittent, into the electricity grid. To this goal, it is paramount to develop cost-competitive, reliable, location-independence, and large-scale energy storage technologies. The hydrogen bromine flow battery (HBFB) is a promising technology given the abundant material availability and its high power density. Here, the aim is to perform a comprehensive techno-economic analysis of a 500 kW nominal power/5 MWh HBFB storage system, based on the levelized cost of storage approach. Then, we systematically analyze stack and system components costs for both the current base and a future scenario (2030). We find that, for the base case, HBFB capital investments are competitive to Li-ion battery technology, highlighting the potential of large-scale HBFB market introduction. Improving the stack performance and reducing the stack and system costs are expected to result in ~62% red... [more]

In the tight sandstone oil production stage, the migration of particles will not only block the oil path and throat, but also block the wellbore and damage the equipment. Based on the theory of non-Newtonian fluid, hydrodynamics, the extended Derjaguin Landau Verwey Overbeek (DLVO) theory and the JKR (the model of Johnson−Kendall−Roberts) contact theory, the mathematical model and quantitative analysis of the critical condition of the particle separation from the surface due to the influence of oil flow in the fracture environment are presented in this paper. A theoretical model with pressure gradient as the core parameter and particle size, crack size and various contact forces as variables is established. By adding the formula of non-Newtonian fluid and taking the consistency coefficient and fluidity index as the contrast relation, the change rule of particle migration under the influence of non-Newtonian fluid is obtained. Effective prevention and control measures for the purpose of... [more]

Foam materials have been widely used in various industrial applications, where higher and higher heat and mass transfer performances are pursued. However, the mechanism of many factors on the heat transfer performances is still unclear. The main purpose of this article is to investigate how the porous properties, porosity, cell size and the sample thickness affect the volumetric convective heat transfer. In this study, the single-blow method is used to determine the volumetric heat transfer coefficient of ceramics foam in the temperature range from 283 K to 323 K. In particular, sensitivity analysis of the foam porosity, cell size, velocity and the sample thickness on the volumetric heat transfer coefficient within the ceramics foam were all conducted. The results indicate that the sample thickness has a significant effect on the volumetric heat transfer coefficient which decreases with the sample thickness. In addition, the local thermal equilibrium phenomenon is verified and its infl... [more]

The application of the Discrete Element Method (DEM) allows simulating the movement of a particle of any shape in a conveyor. The DEM method uses the assumptions of the Lagrange calculation model, in which each particle in the domain is tracked individually. It makes it possible to conduct a thorough examination of the behavior of the entire bulk material bed consisting of a set of elements with characteristic physicochemical properties. Therefore, the deposit is not considered according to averages and constants, e.g., strength values, but as a set of elements that can be described individually. The article presents the results of a simulation, with the use of the Discrete Elements Method (DEM), of the process of soft fruit transport in the food industry. The results of the research and exemplary simulations of blueberry fruit transport are presented. The influence of the type of a transport device on the values of normal and tangential forces occurring between the blueberry fruit and... [more]

The design and synthesis of new multifunctional organic porous polymers has attracted significant attention over the years due to their favorable properties, which make them suitable for carbon dioxide storage. In this study, 2-, 3-, and 4-hydroxybenzaldehyde reacted with phenyltrichlorosilane in the presence of a base, affording the corresponding organosilicons 1−3, which further reacted with benzidine in the presence of glacial acetic acid, yielding the organic polymers 4−6. The synthesized polymers exhibited microporous structures with a surface area of 8.174−18.012 m2 g−1, while their pore volume and total average pore diameter ranged from 0.015−0.035 cm3 g−1 and 1.947−1.952 nm, respectively. In addition, among the synthesized organic polymers, the one with the meta-arrangement structure 5 showed the highest carbon dioxide adsorption capacity at 323 K and 40 bar due to its relatively high surface area and pore volume.

Mineral base oils are used to produce commercial lubricants and are obtained from refining vacuum residue. Lubricants are used to reduce friction in industry devices, so their viscosity is a key characteristic that needs to be optimized throughout the process. The purpose of this study is to show how global chemical characterization of samples from the base oil production chain can facilitate a better understanding of the molecular impacts of processing and their effect on macroscopic properties like viscosity. Eight different samples were characterized by different analytical techniques, including liquid chromatography and mass spectrometry techniques, to understand their chemical evolution through the different process units at the molecular level. Furthermore, a statistical treatment allowed for the identification of parameters that influence viscosity, mainly sulfur and polyaromatics content. This study demonstrates the importance and effectiveness of cross-checking results from di... [more]

Production of medium chain carboxylic acids (MCCA) as renewable feedstock bio-chemicals, from food waste (FW), requires complicated reactor configurations and supplementation of chemicals to achieve product selectivity. This study evaluated the manipulation of organic loading rate in an un-supplemented, single stage stirred tank reactor to steer an anaerobic digestion (AD) microbiome towards acidogenic fermentation (AF), and thence to chain elongation. Increasing substrate availability by switching to a FW feedstock with a higher COD stimulated chain elongation. The MCCA species n-caproic (10.1 ± 1.7 g L−1) and n-caprylic (2.9 ± 0.8 g L−1) acid were produced at concentrations comparable to more complex reactor set-ups. As a result, of the adjusted operating strategy, a more specialised microbiome developed containing several MCCA-producing bacteria, lactic acid-producing Olsenella spp. and hydrogenotrophic methanogens. By contrast, in an AD reactor that was operated in parallel to prod... [more]

Sweet sorghum is a unique bioenergy crop that produces stalks with fermentable free sugars. The purpose of this study was to evaluate how the production of hemicellulosic saccharides and bioethanol from sweet sorghum stalks (SSS) can be influenced by a dilute sulfuric acid (H2SO4) pretreatment under different isothermal conditions. The bioethanol production from untreated SSS and pretreated solid phases was achieved through the Simultaneous Saccharification and Fermentation (SSF) process. A good SSS fractionation and an extensive hemicellulose hydrolysis into soluble saccharides were obtained, the most abundant hemicellulose-derived compounds present in the pretreated liquid phase being monosaccharides, with up to 17.22 g/L of glucose and 16.64 g/L of xylose in the pretreatments performed with 3% and 1% H2SO4 for 30 min at 134 °C, respectively. The SSF process of untreated SSS allowed a maximum bioethanol concentration of 9.78 g/L, corresponding to a maximum glucan conversion into etha... [more]

This study investigated the use of brewing wastewater (BW) as the primary carbon source in the Postgate medium for the optimisation of sulphate reduction in acid mine drainage (AMD). The results showed that the sulphate-reducing bacteria (SRB) consortium was able to utilise BW for sulphate reduction. The response surface methodology (RSM)/Box−Behnken design optimum conditions found for sulphate reduction were a pH of 6.99, COD/SO42− of 2.87, and BW concentration of 200.24 mg/L with predicted sulphate reduction of 91.58%. Furthermore, by using an artificial neural network (ANN), a multilayer full feedforward (MFFF) connection with an incremental backpropagation network and hyperbolic tangent as the transfer function gave the best predictive model for sulphate reduction. The ANN optimum conditions were a pH of 6.99, COD/SO42− of 0.50, and BW concentration of 200.31 mg/L with predicted sulphate reduction of 89.56%. The coefficient of determination (R2) and absolute average deviation (AAD)... [more]

A novel carbonaceous adsorbent was prepared from sulfur-impregnated heavy oil ash via pyrolysis using potassium sulfide (K2S) solution, and its ability to remove lead (Pb2+) from aqueous solutions was examined. It was compared with an adsorbent synthesized by conventional pyrolysis using potassium hydroxide (KOH) solution. Specifically, the raw ash was immersed in 1 M K2S solution or 1 M KOH solution for 1 day and subsequently heated at 100−1000 °C in a nitrogen (N2) atmosphere. After heating for 1 h, the solid was naturally cooled in N2 atmosphere, and subsequently washed and dried to yield the product. Regardless of the pyrolysis temperature, the product generated using K2S (Product-K2S) has a higher sulfur content than that obtained using KOH (Product-KOH). Moreover, Product-K2S has a higher lead removal ability than Product-KOH, whereas the specific surface area of the former is smaller than that of the latter. Product-K2S obtained at 300 °C (Product-K2S-300) achieves the highest l... [more]

The objective of this study was to improve the quality attributes of red wines by Saccharomyces cerevisiae (BCRC 21685) mutant CM8 with overexpression of high-mannose mannoproteins, with respective to phenolic compositions, colorimetric parameters, and consumer sensory attributes. The CM8 was mutated by ethyl methane sulfonate and showed the ability of overproducing cell wall mannoproteins selected by killer-9 toxin-containing YPD plates. Kyoho grapes were used as raw materials. It is interesting to find that the cell wall mannoproteins isolated from CM8 mutant possessed a significantly higher mannose content in the polysaccharide fraction (81% w/w) than that did from parent strain (66% w/w). The red wines made of winter grapes and CM8 (CM8-WIN) showed significantly greater total tannins, flavonols, and anthocyanins levels, as well as higher color, higher flavor, and higher consumer preference than those by its SC counterpart (SC-WIN). The characteristics of the red wines studied were... [more]

Do retired professional baseball players become effective coaches? Are Taiwanese coaches up to the job of coaching in the Chinese Professional Baseball League (CPBL)? What are the key coaching factors affecting a CPBL team’s performance in the regular-season? In this study, we examine the key coaching factors affecting the efficiency of CPBL teams from the perspective of efficiency and productivity, using network data envelopment analysis, truncated regression analysis, and bootstrapping methods to provide specific recommendations. We calculated the efficiency of each CPBL team from the 2014 to 2016 regular-seasons. First, the “ex-member” indicator had a significant negative impact on team performance, indicating that a coaching team consisting of coaches with different backgrounds or experience is advantageous to a team’s performance in games; and second, the “ex-professional player” indicator had a significant impact on team performance in the regular season, indicating that the valu... [more]

In 2016, infectious microbes were one of the leading causes of death, especially in developing countries. Puriton® is a mineral mixture consisting of biotite, kaolinite, montmorillonite, serpentine, clinochlore, and vermiculite, and evaluated antimicrobial activity in vitro and safety in vivo. Nine pathogens and opportunistic bacteria, namely Salmonella typhimurium, Escherichia coli, Pseudomonas aeruginosa, Alcaligenes faecalis, Staphylococcus aureus, Enterococcus faecalis, Micrococcus luteus, Mycobacterium smegmatis, and Bacillus subtilis, and the two viruses Zika and Influenza A/Duck/MN/1525/81 were used. A 26-week oral repeated safety study of Puriton® was conducted. Puriton® suppressed the bacterial proliferation, with a minimum proliferative rate of 91.1% in B. subtilis ATCC6633. The virucidal efficacy of Puriton® against Zika virus after 4 h and 18 h of contact time was significant in all groups treated with Puriton®. Twenty-six-week repeated oral administration of Puriton® was c... [more]

The barely satisfactory monitoring situation of the hypertoxic fluorochemical engineering processes requires the application of advanced strategies. In order to deal with the non-linear mechanism of the processes and the highly complicated correlation among variables, a wavelet transform-assisted convolutional neural network (CNN) based multi-model dynamic monitoring method was proposed. A preliminary CNN model was first trained to detect faults and to diagnose part of them with minimum computational burden and time delay. Then, a wavelet assisted secondary CNN model was trained to diagnose the remaining faults with the highest possible accuracy. In this step, benefitting from the scale decomposition capabilities of the wavelet transform function, the inherent noise and redundant information could be filtered out and the useful signal was transformed into a higher compact space. In this space, a well-designed secondary CNN model was trained to further improve the fault diagnosis perfor... [more]

Veterinary antibiotics are widely used worldwide to treat and prevent infectious diseases, as well as (in countries where allowed) to promote growth and improve feeding efficiency of food-producing animals in livestock activities. Among the different antibiotic classes, tetracyclines and sulfonamides are two of the most used for veterinary proposals. Due to the fact that these compounds are poorly absorbed in the gut of animals, a significant proportion (up to ~90%) of them are excreted unchanged, thus reaching the environment mainly through the application of manures and slurries as fertilizers in agricultural fields. Once in the soil, antibiotics are subjected to a series of physicochemical and biological processes, which depend both on the antibiotic nature and soil characteristics. Adsorption/desorption to soil particles and degradation are the main processes that will affect the persistence, bioavailability, and environmental fate of these pollutants, thus determining their potent... [more]