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Records with Type: Published Article
3961. LAPSE:2023.35176
Gas-Driven Endoscopic Robot for Visual Inspection of Corrosion Defects Inside Gas Pipelines
April 28, 2023 (v1)
Subject: Energy Systems
Keywords: corrosion detection, endoscopic robot, gas-driven robot, pipelines
The internal inspection of corrosion in large natural gas pipelines is a fundamental task for the prevention of possible failures. Photos and videos provide direct proof of internal corrosion defects. However, the implementation of this technique is limited by fast robot motion and poor lighting conditions, with high-quality images being key to its success. In this work, we developed a natural gas-driven pipeline endoscopic robot (GDPER) for the visual inspection of the inner wall surfaces of pipelines. GDPER consists of driving, odometer, and vision modules connected by universal joints. It is designed to work in a 154 mm gas-pressurized pipeline up to a maximum of 6 MPa, allowing it to smoothly pass through bends and cross-ring welds at a maximum speed of 3 m/s using gas pressure driving. Test results have shown that HD MP4 video files can be obtained, and the location of defects on the pipelines can be detected by intelligent video image post-processing. The gas-driven function enab... [more]
3962. LAPSE:2023.35175
Experimental and Simulation Study on the Direct Contact Condensation of Saturated Steam on Moving Droplets at Sub-Atmospheric Pressure
April 28, 2023 (v1)
Subject: Modelling and Simulations
Keywords: direct contact condensation, droplets, heat transfer coefficient, numerical simulation, saturated steam
The recovery of low-temperature steam is of great significance to the effective utilization of energy. Direct contact condensation (DCC) technology is an effective heat recovery method with a low initial investment. An evaluation of the direct contact condensation heat transfer technology of water droplets and low-temperature saturated steam (at an absolute pressure of 7.3−19.9 kPa) was performed using both experimental and computational approaches. In the experiment, an experimental device based on the weighing method was set up, and the direct contact heat transfer process between droplets with a normalized diameter of less than 21.7 and saturated pure steam at 40−60 °C was experimentally investigated. The transient condensation efficiency and heat transfer coefficient were calculated by the real-time mass variation. The rapid condensation stage was classified to discuss the effects of initial droplet diameter, pressure, temperature, and mass flow rate on the heat transfer process. A... [more]
3963. LAPSE:2023.35174
Short Review of Self-Powered Nitrogen Removal via Abiotic Electrochemical Catalysis
April 28, 2023 (v1)
Subject: Materials
Keywords: abiotic electrocatalysts, Fuel Cells, nitrogen removal, self-power
Microbial nitrification and denitrification are efficient technologies for the treatment of nitrogen-containing wastewater. However, these biotic technologies are inapplicable for the treatment of toxic substances such as heavy metals, polyaromatic hydrocarbons, adsorbable organic halogens, and polychlorinated biphenyls, which have an inhibitory effect on microbial metabolism. It is therefore necessary to develop abiotic nitrogen removal technology with comparable cost efficiency. Nitrogen contaminants are promising indirect fuel sources. The integration of electrocatalysis energy conversion with nitrogen contaminants could drive an entire electrochemical system to obtain nitrogen removal in a self-powered fashion. Research advances in the development of fuel cells have corroborated their promising application for nitrogen removal. This work aims to review the most recent advances in the utilization of ammonia and nitrate as fuels for self-powered nitrogen removal and demonstrate how c... [more]
3964. LAPSE:2023.35173
Mixed Seeds of Oat and Vetch Based on DEM-Fluent Coupling Motion Simulation in a Venturi Tube
April 28, 2023 (v1)
Subject: Modelling and Simulations
Keywords: DEM-CFD coupling approach, gas–solid two-phase flow, mixed seeding metering device, seed motion, venturi tube
The gas−solid flow of mixed seeds of oat and vetch in the air-blowing venturi tube was simulated numerically by means of a coupling approach of the discrete element method (DEM) and computational fluid dynamics (CFD). In the gas−solid coupling model, EDEM software was used to depict the discrete particle phase, and ANSYS Fluent software was used to describe the continuous gas phase. The effects of the seed entry angle and inlet air velocity on the uniformity of mixed seed supply were studied and analyzed from the angle of airflow field variation and mixed seeds movement characteristics. The simulation results showed that the seeding angle has a great influence on the seed movement in the tube and affects the pressure and velocity gradient of the airflow field. If the seed insertion angle is too large, the number of collisions between the seed and the tube wall will increase, and the phenomenon of seeds retention and disordered jumping will occur. The inlet air velocity mainly affects t... [more]
3965. LAPSE:2023.35172
An Investigation into the Metabolic Differences between Conventional and High Seeding Density Fed-Batch Cell Cultures by Applying a Segmented Modeling Approach
April 28, 2023 (v1)
Subject: Modelling and Simulations
Keywords: feeding optimization, intensified fed-batch, segmented modeling
The conventional fed-batch process characterized by a low titer currently challenges pharmaceutical development. Process optimization by applying a perfusion process in the pre-stage and subsequent production phase at a high seeding density (HSD) can meet this challenge. In this study, we employed a simplified approach based on measured experiments, namely segmented modeling, to systematically analyze an HSD fed-batch process compared to a standard process. A comparison indicated that the metabolic phases of HSD processes are not only shifted in time, but metabolite trends show an altered metabolism. In an extended study, we integrated the intracellular fluxes determined by a metabolic flux analysis into the segmented modeling approach. Compared to using only extracellular rates, similar phases are identified, and this highlights the reliability of phase identification modeling using extracellular rates only. Furthermore, the segmented linear regression approach is used to create a mod... [more]
3966. LAPSE:2023.35171
A Novel Ultra Local Based-Fuzzy PIDF Controller for Frequency Regulation of a Hybrid Microgrid System with High Renewable Energy Penetration and Storage Devices
April 28, 2023 (v1)
Subject: Energy Systems
Keywords: fuzzy control, load frequency control, marine predator algorithm, PID, Renewable and Sustainable Energy, ultra-local control
A new ultra-local control (ULC) model and two marine predator algorithm (MPA)-based controllers; MPA-based proportional-integral-derivative with filter (PIDF) and MPA-based Fuzzy PIDF (FPIDF) controllers; are combined to enhance the frequency response of a hybrid microgrid system. The input scaling factors, boundaries of membership functions, and gains of the FPIDF con-troller are all optimized using the MPA. In order to further enhance the frequency response, the alpha parameter of the proposed ULC model is optimized using MPA. The performance of the pro-posed controller is evaluated in the microgrid system with different renewable energy sources and energy storage devices. Furthermore, a comparison of the proposed MPA-based ULC-PIDF and ULC-FPIDF controllers against the previously designed controllers is presented. Moreover, a vari-ety of scenarios are studied to determine the proposed controller’s sensitivity and robustness to changes in wind speed, step loads, solar irradiance, and... [more]
3967. LAPSE:2023.35170
Effect of Drying Pretreatment on Cellulolytic Enzymatic Hydrolysis of Lignin from Napier Grass
April 28, 2023 (v1)
Subject: Numerical Methods and Statistics
Keywords: cellulase, enzymatic hydrolysis, lignin, Napier grass, pretreatment
Biomass can be a viable supplement and alternative to non-renewable sources of fuel and chemicals. Lignin is an important part of biomass sources which can be used in various chemical and fuel industries. This study explores the pretreatment of lignin from Napier grass using thermal and physical means, as well as extraction of lignin via cellulolytic enzymatic hydrolysis to determine the optimum condition for feedstock pretreatment. Napier grass parts under various drying conditions and particle sizes were treated with enzymes. Moisture analysis, FTIR spectroscopy, UV−Vis analysis, and Klason lignin were carried out to analyze the moisture, functional group, and yield of lignin. Moisture content of the samples were inversely proportional to the drying conditions. The FTIR result showed lower peak intensity for higher drying conditions, while ball-milling showed less reduction in peak intensity. More Klason lignin was extracted under higher drying conditions. The yield of cellulolytic e... [more]
3968. LAPSE:2023.35169
The Influences of Emulsification Variables on Emulsion Characteristics Prepared through the Phase Inversion Temperature Method as Engine Fuel
April 28, 2023 (v1)
Subject: Energy Systems
Keywords: electrical conductance, emulsification stability, emulsification variables, nonionic surfactant, phase inversion temperature
The effects of emulsification variables, such as surfactant type and heating/cooling emulsion processes, on the emulsification characteristics of silicone oil’s emulsions prepared by the phase inversion temperature method were investigated in this study. The water-in-oil (W/O) emulsions have been widely applied to enhance burning efficiency and reduce both pollutant emissions and fuel consumption. The silicone oil was emulsified with de-ionized water with the assistance of nonionic surfactants to form oil-in-water (O/W) emulsions. The hydrophilic−lipophilic balance (HLB) value of the Span 80 and Tween 20 surfactant mixture was set equal to 10 based on their weight proportions and the respective HLB values of the two surfactants. The experimental results show that the emulsions with the Span 80/Tween 20 surfactant mixture appeared to have a higher phase inversion temperature and a larger electrical conductance. On the other hand, it has a lower emulsification stability and a narrower ra... [more]
3969. LAPSE:2023.35168
Stability Analysis Method for Initial Support Structure of Tunnel in Swelling Loess
April 28, 2023 (v1)
Subject: Energy Systems
Keywords: initial support structure, softening, stability, swelling force, swelling loess
The stability of tunnel is greatly affected by the changes in volume and strength of swelling loess caused by humidification. Quantitative reflection of the influence of humidification on stability in mechanical model has important engineering significance for the design of support structures. Based on the fact that parameters related to swelling and strength are functions of water content, the water content was introduced into the classical surrounding rock−support model, and a safety factor was employed as the index of stability. Thus, a stability analysis framework of swelling loess tunnel was established by considering the swelling and softening of swelling loess. In an engineering case, the theoretical models presented in this paper were introduced to investigate the change rules of surrounding rock deformation and tunnel safety factor, as well as the sensitivity of the safety factor of tunneling in swelling loess. Analysis results showed that the change rules of surrounding rock... [more]
3970. LAPSE:2023.35167
A Square Wave Alternating Current Preheating with High Applicability and Effectiveness of Preventing Lithium Plating
April 28, 2023 (v1)
Subject: Energy Systems
Keywords: alternating current preheating, lithium-plating, square wave, temperature-adaptive
Alternating current preheating (ACP) of lithium-ion batteries has the advantage of a high heating rate while inhibiting lithium plating. Two strategies based on terminal voltage control and full battery impedance control were proposed to simplify the ACP implementation. However, such strategies either severely compromise the preheating rate or induce non-negligible lithium plating. To maximize the preheating rate while ensuring no lithium plating, an ACP method based on anode potential control is developed using a square wave alternating current. The operation boundaries of lithium plating prevention, in terms of frequency and maximum permissible current amplitude, are determined using the anode potential and impedance. Their effectiveness in preventing lithium plating is validated by repeating 800 cycles of preheating. By applying the operation boundaries, a temperature-adaptive preheating is found to be able to speed up the preheating rate with higher frequency, smaller temperature i... [more]
3971. LAPSE:2023.35166
Effect of Rosehip Powder Addition on Dough Extensographic, Amylographic and Rheofermentographic Properties and Sensory Attributes of Bread
April 28, 2023 (v1)
Subject: Food & Agricultural Processes
Keywords: amylograph, ascorbic acid, bread, dough, extensograph, rheofermentometer, rosehip powder, sensory attributes, wheat flour
One of the improvers used in breadmaking is ascorbic acid (AA), a chemical compound that strengthens the dough and extends the shelf life of bread. This work investigates the suitability of replacing the synthetic AA with rosehip powder (Rp) rich in this bioactive compound. Thus, a comprehensive study of wheat flour (WF) replaced with 0.5−2.5% w/w Rp regarding the extensographic, amylographic and rheofermentographic properties of dough and sensory attributes of bread was performed. WF without RP or AA addition of 2 mg/100 g was used as a control. A sample with an AA addition of 2 mg/100 g was also used. The Rp addition positively influenced the extensographic, amylographic and rheofermentographic properties of the dough. The dough resistance to extension, R, in Brabender Units (BU), increased from 330 ± 1.41 BU (control) to 995 ± 1.41 BU (2.5% w/w Rp) for a resting time of 90 min. The gelatinization temperature of the dough increased from 61.0 °C (control) to 62.9 °C (2.5% w/w Rp). The... [more]
3972. LAPSE:2023.35165
A Novel High-Voltage Gain Step-Up DC−DC Converter with Maximum Power Point Tracker for Solar Photovoltaic Systems
April 28, 2023 (v1)
Subject: Energy Systems
Keywords: high-voltage gain step-up DC–DC converter, hill climbing algorithm, maximum power point tracker, non-isolated topology
In order to generate electricity from solar PV modules, this study proposed a novel high-voltage gain step-up (HVGSU) DC−DC converter for solar photovoltaic system operation with a maximum power point (MPP) tracker. The PV array can supply power to the load via a DC−DC converter, increasing the output voltage. Due to the stochastic nature of solar energy, PV arrays must use the MPPT control approach to function at the MPP. This study suggests a novel HVGSU converter that uses the primary boost conversion cell and combines switched capacitors and voltage multiplier cells. The proposed topology is upgradeable for high-voltage gain step-up and can be incorporated as well. A clamp circuit reuses the energy that leaks out so that the switch voltage stress and power loss are kept to a minimum. One thing that makes it stand out is that the voltage stress on the diodes and switch stays low and constant even as the duty cycle changes. Additionally, the inductor greatly reduces the diodes’ rever... [more]
3973. LAPSE:2023.35164
A Laborer’s Mask-Wearing Behavior Detection Approach in the Manufacturing Field
April 28, 2023 (v1)
Subject: Modelling and Simulations
Keywords: anomaly detection, cloud computing, deep learning, image data analytics
Industry 4.0 has considerably advanced multiple manufacturing fields through digitalization and intelligentization. Many technologies, such as supervisory control, data acquisition, and data analytics, have been used widely in manufacturing sites to enhance production efficiency. Therefore, this created a cloud-based anomaly detection module for epidemic prevention at the manufacturing site. Image process technologies, deep learning algorithms, and cloud computing were employed in the proposed module to automatically identify labor anomaly behavior in the manufacturing site and prevent the epidemic. This study used image processing technologies and deep learning to recognize and train the manufacturing site image. Accordingly, the analyzed result could be incorporated into the cloud system using the Message Queuing Telemetry Transport (MQTT) protocol. Therefore, the administrators and laborers can be notified regarding the anomaly behavior. The author used the image data obtained from... [more]
3974. LAPSE:2023.35163
Instant Controlled Pressure Drop (DIC) Processing to Reduce 3-Monochloropropane-1,2-diol Concentration in Palm Oil
April 28, 2023 (v1)
Subject: Process Control
Keywords: 3-MCPD, DIC, oil refined, palm oil, quality preservation, RSM
Deodorization of vegetable oils may introduce potentially carcinogenic, as well as genotoxic contaminants, generating health risks for consumers. However, the deodorization step of the refining process leads to the formation of 3-monochloro-1,2-propanediol (3-MCPD). 3-MCPD has been classified as potentially carcinogenic to humans by the World Health Organization (WHO). The purpose of this study was to optimize recently updated oil treatment techniques using Instant Controlled Pressure Drop (DIC) to improve 3-MCPD elimination in edible palm oil. Based on the central composite (CCD-DoE), response surface methodology (RSM) was developed to find the best combination of two variables at five levels to remove 3-MCPD from the palm oil. Samples of palm oil were split into two groups. The first group was treated only by the traditional method, including refining, degumming, deacidification, decolorization, deodorization, dehydration, filtration, and dewaxing processes. The second group was firs... [more]
3975. LAPSE:2023.35162
Optimization of Flow and Mixing in a Venturi Tube Mixer with a Two-Step Method Using Numerical Simulation
April 28, 2023 (v1)
Subject: Modelling and Simulations
Keywords: flow, Mixing, numerical simulation, Venturi tube mixer
To achieve efficient mixing in a Venturi tube mixer (VTM), an optimization with a two-step method for this mixing device based on a Venturi tube (VT) was carried out using numerical simulation. Firstly, the effects of the structural parameters on the flow in VT were revealed, and the optimized configuration was determined for the following VTM. Subsequently, by introducing a jetting tube, the suction capacity, energy consumption and mixing quality were used to evaluate the performance of VTM under various configurations and operating conditions. According to the effects of the structural parameters on the mixing quality of VTM, an empirical formula for mixing quality with structural parameters was proposed. Finally, an optimized VTM was proposed. This work can provide a valid suggestion for the design and optimization of such a mixing device.
3976. LAPSE:2023.35161
Asssessing the Green Technology Innovation Efficiency in Yangtze River Delta Region under Dual Carbon Background
April 28, 2023 (v1)
Subject: Energy Policy
Keywords: dual carbon, green technology innovation efficiency, high-tech manufacturing, SBM-DEA, Yangtze River Delta region
With the promotion of the dual carbon policy and the process of transforming and upgrading manufacturing, vigorously developing high-tech manufacturing with high-technology content and significant added value has become a powerful driving force to improve the development of the regional economy. In this regard, this research employs the two-stage network SBM-DEA method with undesirable outputs and multi-stage activities involved in the green production process. We examine the green technology innovation efficiency of high-tech manufacturing in the Yangtze River Delta (YRD) region from 2010 to 2020. We divide the activities of the high-tech manufacturing industry into two sub-stages, namely, the research and development (R&D) stage and the result transformation stage. The results are as follows: (1) The efficiency level of green technology innovation in Shanghai is at an outstanding level, having the most significant performance both in the R&D stage at 0.833 as well as in the result tr... [more]
3977. LAPSE:2023.35160
Physical and Mechanical Behaviors of Compacted Soils under Hydraulic Loading of Wetting−Drying Cycles
April 28, 2023 (v1)
Subject: Environment
Keywords: degree of saturation, matric suction, shear modulus, void ratio, wetting–drying cycles
Exposed geo−infrastructures filled with compacted soils experience cyclic wetting−drying effects due to environment and underground water fluctuations. Soil physical and mechanical behaviors are prone to deterioration to a great extent, e.g., swelling, collapse, or even slope failure, resulting in huge losses to human life, safety, and engineering construction. In this paper, hydraulic loading tests of wetting−drying cycles were carried out on compacted fine soil via a one−dimensional pressure plate apparatus equipped with bender elements. The influences of wetting−drying paths on the soil characteristics of moisture content, void ratio and shear modulus were obtained and analyzed. Results showed that cyclic wetting−drying effects weakened the soil’s water retention capacity. It was observed that it was harder for pore water to approach saturation at a lower matric suction level and to be expelled at a higher matric suction level. Typical swelling and shrinkage deformations occurred du... [more]
3978. LAPSE:2023.35159
Treatment of Motor Oil-Contaminated Soil with Green Surfactant Using a Mobile Remediation System
April 28, 2023 (v1)
Subject: Environment
Keywords: 3D printing, biobased surfactants, biosurfactants, green surfactants, Petroleum, response surface methodology, soil remediation, soil washing
Leak of fuels and lubricants occurring during exploration, distribution, refining and storage operations is the major cause of environmental pollution due to petroderivatives dispersion. The quick use of a series of physicochemical and biological techniques is needed to drastically reduce the magnitude of damage provoked by these pollutants. Among them, soil washing proved to be an effective alternative to the remediation of hydrocarbon-polluted sites, mainly if combined with surfactant utilization. However, the direct use of surfactants can lead to problems related to the toxicity and dispersion of the resulting by-products, as the majority of marketed surfactants are produced from oil derivatives. In this context, green surfactants appear as a promising alternative to their synthetic counterpart. In the present study, two green surfactants, i.e., a chemically synthesized biobased surfactant and a Starmerella bombicola biosurfactant, were applied in soil decontamination tests using a... [more]
3979. LAPSE:2023.35158
RNN-LSTM-Based Model Predictive Control for a Corn-to-Sugar Process
April 28, 2023 (v1)
Subject: Process Control
Keywords: corn-to-sugar process, data-driven method, Model Predictive Control, RNN-LSTM
The corn-to-sugar process is difficult to control automatically because of the complex physical and chemical phenomena involved. Because the RNN-LSTN model has been shown to handle long-term time dependencies well, this article focused on the design of a model predictive control system based on this machine learning model. Based on the historical data, we first reduced the input variable dimension through data preprocessing, data dimension reduction, sensitivity analysis, etc., and then the RNN-LSTM model, with these identified key sites as inputs, and the dextrose equivalent value as the output, was constructed. Then, through model predictive control using the locally linearized RNN-LSTM as the predictive model, the objective value of the dextrose equivalent was successfully controlled at the target value by our simulation study, in different situations of setpoint changes and disturbances. This showed the potential of applying RNN-LSTM-Based model predictive control in a corn-to-suga... [more]
3980. LAPSE:2023.35157
Effect of Changing Belt Tension on Machining Surface of CNC Lathe Spindle
April 28, 2023 (v1)
Subject: Materials
Keywords: belt tension, CNC lathe, cutting process, surface roughness, vibration
Computer numerical control (CNC) lathes are optimized for machining workpieces into rotating shafts or cylindrical shapes of structures. However, because rotating mechanical parts are used on CNC lathes, vibration from spindles, servomotors, hydraulic pumps, and feed screws occurs. Therefore, periodic preventive maintenance is required to minimize vibrations. Additionally, alignment, balance, and adjustment operations are necessary for parts that perform linear or rotational movements. Thus, this study adjusts the tension of the V-belt that drives the spindle of the CNC lathe, analyzes the primary components and the vibrations occurring at the spindle and servomotor, and measures the surface roughness to identify the cutting quality according to the impact of the belt tension. The experimental results show that the peak value of the vibrating component increases as the cutting speed increases. We demonstrate that the optimal vibration characteristics and excellent surface roughness val... [more]
3981. LAPSE:2023.35156
Experimental Study on Motion Law of the Fragment at Hypersonic Speed
April 28, 2023 (v1)
Subject: Process Control
Keywords: experimental study, hypersonic speed fragments, insensitive munitions, motion law, windward area
As a damage element, high-speed fragments have a significant effect on the ammunition safety. The impact from the fragments are also one of the basic problems of ammunition safety tests. To clarify the reaction characteristics of combustion, explosion, detonation, and so on, when hypersonic fragments hit insensitive munitions, it is necessary to carry out corresponding research on the deceleration law of hypersonic fragment in the air. In this paper, a 30 mm caliber gun with large chamber, small caliber, and large aspect ratio is proposed to drive high-speed fragments. According to STANAG 4496 standard, a near-cylinder steel fragment with Brinell hardness HB ≤ 270 and mass of 18.6 g was designed. The test system was composed of zone interception velocity measurement, chamber pressure sensor, trajectory tracking system, high-speed camera, and other equipment were also established to obtain the pressure variations in the chamber, the velocity of the fragment, and its flight orientation.... [more]
3982. LAPSE:2023.35155
Techno-Economic Modelling of Solar Photovoltaic (PV) Power Transformers in South Africa
April 28, 2023 (v1)
Subject: Process Design
Keywords: economic evaluation, service life, Solar Photovoltaic, total ownership cost, transformer
The increasing demand for electricity in South Africa has led to a rise in the deployment of solar photovoltaic systems. The integration of these systems requires the installation of power transformers to convert the generated DC power into AC power that can be fed into the grid. However, the high cost of these transformers can hinder the widespread adoption of solar PV systems. Consequently, the primary objective of this work is to introduce a novel service-lifetime loss estimation method that acknowledges the unique requirements of transformers facilitating solar photovoltaic applications. In reality, these transformers are required to facilitate a sporadic energy source, which advocates for an appropriate method to assess the cost of their service-lifetime losses and total ownership cost. Thus far, the energy elements of classical coal-power generation are inadequate, and in conformity with operational and financial considerations of solar PVs, a novel method incorporating the outco... [more]
3983. LAPSE:2023.35154
Numerical Estimation of Gas Release and Dispersion from a Submarine Pipeline
April 28, 2023 (v1)
Subject: Numerical Methods and Statistics
Keywords: diffusion-influencing factors, gas release and dispersion, risk assessment, submarine pipelines, VOF
Submarine pipeline gas releases and dispersions can cause safety concerns such as fire and explosion, which can cause serious casualties and property losses. There are many existing studies on the impacts of the horizontal diffusion distances of natural gas leakages from subsea pipelines, but there is a lack of research on the impact of influencing factors on vertical diffusion distances. Therefore, a diffusion model of natural gas leakage from a submarine pipeline is established by using the computational fluid dynamics method (CFD). The influence law and degrees of factors such as water depth at the leakage point, leak orifice size, leak pressure and the ocean current’s velocity on the leakages and vertical diffusion distances of natural gases from submarine pipelines are systematically investigated. The results show that the leaked natural gas jet enters the sea water to form an air mass, which rises continuously under the action of the pressure in the pipe and the buoyancy of the s... [more]
3984. LAPSE:2023.35153
Study on Zinc-Modified Adsorbent for Adsorption of Trace CO2 in Electronic Special Gas BF3
April 28, 2023 (v1)
Subject: Materials
Keywords: 13X molecular sieve, carbonate species, CO2 adsorption
Usually, the ion implantation gases used in semiconductor production are required to be extremely high in purity. Due to the presence of trace CO2 in electronic special gas BF3, the quality of the material is significantly affected, which makes it crucial to impose control on CO2 content. Unlike a series of blank adsorbents reported in other studies, the zinc-loaded adsorbents prepared in this study are intended for the adsorption of CO2 from CO2/BF3. Firstly, the materials were characterized by XRD, BET, SEM-EDS and TG-DSC analysis, etc., and the breakthrough curves of the adsorbents as obtained under different preparation conditions were investigated at 20 °C and 200 kPa. The results show that the adsorption performance reached the optimal level when the activation temperature was 450 °C and a 13X molecular sieve was impregnated by 0.15 mol/L Zn(NO3)2. Moreover, compared with the Zn-13X, the breakthrough time was reduced to 69% and 44% in two adsorption cycles, respectively. Finally,... [more]
3985. LAPSE:2023.35152
Continuous-Flow Hydrogenation of Nitroaromatics in Microreactor with Mesoporous Pd@SBA-15
April 28, 2023 (v1)
Subject: Materials
Keywords: continuous flow, hydrogenation, mesoporous material, nitroaromatics, Pd@SBA-15
The hydrogenation of nitroaromatics to prepare aromatic amines plays a crucial role in the chemical industry. Traditional hydrogenation has the risk of hydrogen leakage from the equipment, and its catalyst has the disadvantage of being easily deactivated and difficult to recover. In this study, we designed an efficient and stable mesoporous catalyst, Pd@SBA-15, which was constructed by impregnating the nanopores of the mesoporous material SBA-15 with palladium nanoparticles. The catalyst was then filled in a micro-packed-bed reactor (MPBR) for continuous flow hydrogenation. The designed continuous flow hydrogenation system has two distinctive features. First, we used mesoporous Pd@SBA-15 instead of the traditional bulk Pd/C as the hydrogenation catalyst, which is more suitable for exposing the active sites of metal Pd and reducing the agglomeration of nanometals. The highly ordered porous structure enhances hydrogen adsorption and thus hydrogenation efficiency. Secondly, the continuous... [more]
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