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Records with Type: Published Article
3986. LAPSE:2023.35151
Influence of Varying Amounts of Alumina (Al2O3) on the Wear Behavior of ZnO, SiO2 and TiO2 Compounds
April 28, 2023 (v1)
Subject: Materials
Keywords: Al2O3, hot pressing, powder metallurgy, sol–gel, wear
This study aimed to exploit the superior properties of TiO2, ZnO, SiO2 and Al2O3 inorganic materials to combine them under pressure and investigate their mechanical properties. The hot pressing technique was used to produce new materials. Varying amounts of alumina such as 0, 5, 10, 20 and 30 wt% in compounds was considered. The produced materials were characterized by SEM, EDS and XRD analyses. The microhardness properties of the materials were studied, and their tribological properties under different wear loads, i.e., 10 N, 20 N and 30 N, were investigated for every specimen. In XRD analysis, it was observed that no significant new peaks were formed regarding increasing alumina content. The SEM and EDS characterization analyses showed that the materials had a two-phase structure with complex boundaries, and no clear grain boundaries were formed. Moreover, the elements in the EDS analyses and the compounds in the XRD analyses were found to be in line with each other. In wear tests, i... [more]
3987. LAPSE:2023.35150
Enhanced Cyber Attack Detection Process for Internet of Health Things (IoHT) Devices Using Deep Neural Network
April 28, 2023 (v1)
Subject: Numerical Methods and Statistics
Keywords: cyber-attack, deep learning, IoHT
Internet of Health Things plays a vital role in day-to-day life by providing electronic healthcare services and has the capacity to increase the quality of patient care. Internet of Health Things (IoHT) devices and applications have been growing rapidly in recent years, becoming extensively vulnerable to cyber-attacks since the devices are small and heterogeneous. In addition, it is doubly significant when IoHT involves devices used in healthcare domain. Consequently, it is essential to develop a resilient cyber-attack detection system in the Internet of Health Things environment for mitigating the security risks and preventing Internet of Health Things devices from becoming exposed to cyber-attacks. Artificial intelligence plays a primary role in anomaly detection. In this paper, a deep neural network-based cyber-attack detection system is built by employing artificial intelligence on latest ECU-IoHT dataset to uncover cyber-attacks in Internet of Health Things environment. The propos... [more]
3988. LAPSE:2023.35149
Quality Monitoring of Biodiesel and Diesel/Biodiesel Blends: A Comparison between Benchtop FT-NIR versus a Portable Miniaturized NIR Spectroscopic Analysis
April 28, 2023 (v1)
Subject: Energy Systems
Keywords: adulteration, biodiesel, contaminants, diesel/biodiesel blends, portable NIR spectrometer
A methodology such as near-infrared (NIR) spectroscopy, which enables in situ and in real-time analysis, is crucial to perform quality control of biodiesel, since it is blended into diesel fuel and the presence of contaminants can hinder its performance. This work aimed to compare the performance of a benchtop Fourier Transform (FT) NIR spectrometer with a prototype of a portable, miniaturized near-infrared spectrometer (miniNIR) to detect and quantify contaminants in biodiesel and biodiesel in diesel. In general, good models based on principal component analysis-linear discriminant analysis (PCA-LDA) of FT-NIR spectra were obtained, predicting with high accuracies biodiesel contaminants and biodiesel in diesel (between 75% to 95%), as well as good partial least square (PLS) regression models to predict contaminants concentration in biodiesel and biodiesel concentration in diesel/biodiesel blends, with high coefficients of determination (between 0.83 and 0.99) and low prediction errors... [more]
3989. LAPSE:2023.35148
Preparation and Emulsifying Properties of Carbon-Based Pickering Emulsifier
April 28, 2023 (v1)
Subject: Materials
Keywords: graphene oxide, interfacial catalysis, Pickering emulsion
Water is increasingly being used as a solvent in place of organic solvent in order to meet the demand for green chemical synthesis. Nevertheless, many of the reaction substrates are organic matter, which have low water solubility, resulting in a low reaction interface and limiting the development of organic-water biphasic systems. A surfactant is typically added to the two-phase system to form an emulsion to increase the contact area between the organic phase and the water. Compared to ordinary emulsion stabilized with the surfactant, Pickering emulsion offers better adhesion resistance, biocompatibility, and environmental friendliness. It possesses unrivaled benefits as an emulsifier and catalyst in a two-phase interfacial catalysis system (PIC). In this study, the amine group (NNDB) was employed to alter the surface of graphene oxide (GO). A stable Pickering emulsion was created by adsorbing GO-NNDB on the toluene−water interface. It was determined that the emulsion system had good s... [more]
3990. LAPSE:2023.35147
Fabrication of Ni−MOF−74@PA−PEI for Radon Removal under Ambient Conditions
April 28, 2023 (v1)
Subject: Materials
Keywords: adsorption coefficient, composite material, metal–organic framework, Ni−MOF−74, polyacrylate, radon
Radon is one of the 19 carcinogenic substances identified by the World Health Organization, posing a significant threat to human health and the environment. Properly removing radon under ambient conditions remains challenging. Compared with traditional radon−adsorbent materials such as activated carbon and zeolite, metal−organic framework (MOF) materials provide a high specific surface area, rich structure, and designability. However, MOF material powders demonstrate complications regarding practical use, such as easy accumulation, deactivation, and difficult recovery. Ni−MOF−74 was in situ grown on a porous polyacrylic acid (PA) spherical substrate via stepwise negative pressure impregnation. Ni−MOF−74 was structured as one−dimensional rod−shaped crystals (200−300 nm) in large−pore PA microspheres, whose porous structure increased the diffusion of radon gas. The radon adsorption coefficient of a Ni−MOF−74@PA−polyethyleneimine composite material was 0.49 L/g (293 K, relative humidity o... [more]
3991. LAPSE:2023.35146
The Non-Uniformity Control Strategy of a Marine High-Speed Diesel Engine Based on Each Cylinder’s Exhaust Temperature
April 28, 2023 (v1)
Subject: Energy Systems
Keywords: closed-loop control, exhaust temperature, multi-cylinder marine diesel engine, non-uniformity control strategy
To improve the non-uniformity of a multi-cylinder marine diesel engine caused by manufacturing assembly errors and performance degradation of the fuel injection system, with the instantaneous speed applied as the control target, the feedback variable of each cylinder’s exhaust temperature was used to obtain the non-uniformity information and the injection quantity of each cylinder was applied as the control variable; the inhomogeneity control was accomplished by modifying the injection pulse spectrum. The model of AVL Cruise M was established and validated by bench test data. The non-uniformity control strategy based on the instantaneous speed and the exhaust temperature of each cylinder was developed in SIMULINK, and the control effect was compared with the closed-loop control of cylinder pressure by software in-loop simulation. The results showed that the non-uniformity control strategy based on exhaust temperature could significantly improve the uniformity of each cylinder; although... [more]
3992. LAPSE:2023.35145
Shredding Roller Effect on the Cannabis sativa L. Residues and Environment
April 28, 2023 (v1)
Subject: Environment
Keywords: fibrous cannabis, plant residues, roller, soil, sustainable agriculture
Fiber cannabis has been grown in Lithuania for a long time, but its cultivation technologies have not been widely studied. However, the growing population and consumption forces us to look to alternatives and to make efforts and find solutions to facilitate the cultivation of fiber cannabis because the use of fiber cannabis can be for many different types of products. The aim of the study was to evaluate the impact of the interaction of fibrous cannabis (Cannabis sativa L.) residue and soil on the mechanical properties of the residue and the environment in cultivation technology using a shredding roller. The study determined the effect of the shredding roller on the moisture content of cannabis residues, lignin content, visual changes, and mechanical characteristics of breaking and cutting. Examining cannabis residues according to the dominant different diameters of 5-, 8-, and 10-mm organic cannabis residues, it was found that the highest efficiency of the shredding roller is when rol... [more]
3993. LAPSE:2023.35144
Statistical Investigation of Rotary Fluidized Bed Agglomeration Process with Tangential Spray and In-Line Particle Size Measurement for PAT Process Control
April 28, 2023 (v1)
Subject: Numerical Methods and Statistics
Keywords: agglomeration, design of experiments, in-line particle size measurement, process analytical technology, rotary fluidized bed, tangential spray process
A statistical design of experiments for a rotary fluidized bed agglomeration process is performed to improve both the knowledge of the process and the influence of the process parameters. Agglomerates of a pharmaceutical formulation are manufactured in a laboratory fluidized bed rotor apparatus with a tangential spray nozzle. Particle size is measured in-line over the entire agglomeration process with a spatial filter velocimetry probe installed directly in the process chamber and off-line with dynamic image analysis for comparison. The influence of the process parameters spray rate, spray pressure, rotor speed, and process air temperature on the fluidized bed is investigated using a central composite design. In-line measurement of particle size is possible over the entire rotor process. Spray pressure, spray rate, square of process air temperature, and some interactions proved to be statistically significant. Particle size measured with spatial filter velocimetry and dynamic image ana... [more]
3994. LAPSE:2023.35143
Application of Wearable Gloves for Assisted Learning of Sign Language Using Artificial Neural Networks
April 28, 2023 (v1)
Subject: Numerical Methods and Statistics
Keywords: Artificial Intelligence, internet of things, LSTM, neural network, RNN, wearable
This study proposes the design and application of wearable gloves that can recognize sign language expressions from input images via long short-term memory (LSTM) network models and can learn sign language through finger movement generation and vibration motor feedback. It is difficult for nondisabled people who do not know sign language to express sign language accurately. Therefore, we suggest the use of wearable gloves for sign language education to help nondisabled people learn and accurately express sign language. The wearable glove consists of a direct current motor, a link (finger exoskeleton) that can generate finger movements, and a flexible sensor that recognizes the degree of finger bending. When the coordinates of the hand move in the input image, the sign language motion is fed back through the vibration motor attached to the wrist. The proposed wearable glove can learn 20 Korean sign language words, and the data used for learning are configured to represent the joint coor... [more]
3995. LAPSE:2023.35142
Study on Estimation Method of Enthalpy of Evaporation Based on Elements and Chemical Bonds
April 28, 2023 (v1)
Subject: Optimization
Keywords: chemical bonds, elements, evaporation enthalpy, group contribution method, Optimization
A new Group Contribution Method based on elements and chemical bonds was proposed to predict the enthalpy of evaporation of organic compounds at their normal boiling points. A prediction model was built using 1266 experimental data points, and the accuracy of the model estimations was evaluated using 16 experimental data points. The new method has only 42 groups, a simple way of group splitting, and a wide range of predictions with an average relative error of 5.84%. Furthermore, the inclusion of silicon elements and their chemical bonds in the group library enables the effective prediction of silicon-containing compounds with an average relative error of 2.71%. By analyzing and comparing the other three commonly used methods, it can be concluded that the new method provides accurate and reliable estimation results and has a more comprehensive application range.
3996. LAPSE:2023.35141
Modelling and Scaling-Up of a Supercritical Fluid Extraction of Emulsions Process
April 28, 2023 (v1)
Subject: Modelling and Simulations
Keywords: continuous process, counter-current packed column, scale-up, supercritical carbon dioxide, supercritical fractionation
Supercritical CO2 (scCO2) is utilized in the supercritical fluid extraction of emulsions (SFEE) to swiftly extract the organic phase (O) from an O/W emulsion. The dissolved substances in the organic phase precipitate into small particles and remain suspended in the water (W) with the aid of a surfactant. The process can be continuously conducted using a packed column in a counter-current flow of the emulsion and scCO2, at moderate pressure (8−10 MPa) and temperature (37−40 °C). To ensure the commercial viability of this technique, the organic solvent must be separated from the CO2 to facilitate the recirculation of both streams within the process while minimizing environmental impact. Thus, the aim of this work was to design a plant to produce submicron materials using SFEE, integrating the recovery of both solvents. First, experimental equilibrium data of the ternary system involved (CO2/ethyl acetate/water) were fitted with a proper thermodynamic model. Then, simulations of the whole... [more]
3997. LAPSE:2023.35140
Modelling and Analysis of Hospital Inventory Policies during COVID-19 Pandemic
April 28, 2023 (v1)
Subject: Modelling and Simulations
Keywords: COVID-19, healthcare supplies, inventory, mathematical modeling, pandemic, SEIR model
The global coronavirus pandemic (COVID-19) started in 2020 and is still ongoing today. Among the numerous insights the community has learned from the COVID-19 pandemic is the value of robust healthcare inventory management. The main cause of many casualties around the world is the lack of medical resources for those who need them. To inhibit the spread of COVID-19, it is therefore imperative to simulate the demand for desirable medical goods at the proper time. The estimation of the incidence of infections using the right epidemiological criteria has a significant impact on the number of medical supplies required. Modeling susceptibility, exposure, infection, hospitalization, isolation, and recovery in relation to the COVID-19 pandemic is indeed crucial for the management of healthcare inventories. The goal of this research is to examine the various inventory policies such as reorder point, periodic order, and just-in-time in order to minimize the inventory management cost for medical... [more]
3998. LAPSE:2023.35139
Experimental Investigation and Thermodynamic Assessment of the Ternary Al−Ni−Er System
April 28, 2023 (v1)
Subject: Modelling and Simulations
Keywords: Al–Ni–Er system, CALPHAD, equilibrated alloys, isothermal sections, vertical section
Al−Ni−Er is an essential system in heat-resistant Al alloys. However, the aluminum-rich corner of this system, which has the most practical application significance, has not been fully studied. In this work, the phase equilibria of the Al−Ni−Er system are investigated via experiments and thermodynamic modeling. The isothermal sections of the Al-rich corner of this ternary system at 600 and 700 °C were determined through equilibrated alloys combined with scanning electron microscopy (SEM), electron probe microanalysis (EPMA) and X-ray diffractometry (XRD). In addition, the vertical sections of the Al−Ni−Er system at Al0.7Ni0.3−Al0.7Er0.3 and Al0.8Ni0.2−Al0.8Er0.2 were measured via differential scanning calorimetry (DSC) analysis. A new ternary compound, τ14-Al12Ni2Er3, was discovered. On the basis of the experimental results of this and previous studies, the ternary Al−Ni−Er system was optimized with the calculation of phase diagrams (CALPHAD) method. The calculated isothermal and verti... [more]
3999. LAPSE:2023.35138
Ontology-Based Semantic Modeling of Coal Mine Roof Caving Accidents
April 28, 2023 (v1)
Subject: Modelling and Simulations
Keywords: data fusion, knowledge representation, ontology, reasoning mechanisms, roof-caving accidents, semantic rules
The frequency of roof-caving accidents ranks first among all coal mine accidents. However, the scattered knowledge system in this field and the lack of standardization exacerbate the difficulty of analyzing roof fall accidents. This study proposes an ontology-based semantic modeling method for roof fall accidents to share and reuse roof fall knowledge for intelligent decision-making. The crucial concepts of roof fall accidents and the correlations between concepts are summarized by analyzing the roof fall knowledge, providing a standard framework to represent the prior knowledge in this field. Besides, the ontology modeling tool Protégé is used to construct the ontology. As for ontology-based deep information mining and semantic reasoning, semantic rules based on expert experience and data fusion technology are proposed to evaluate mines’ potential risks comprehensively. In addition, the roof-falling rules are formalized based on the Jena syntax to make the ontology uniformly expressed... [more]
4000. LAPSE:2023.35137
Dual Role of Sugarcane Waste in Benthic Microbial Fuel to Produce Energy with Degradation of Metals and Chemical Oxygen Demand
April 28, 2023 (v1)
Subject: Biosystems
Keywords: benthic microbial fuel cell, chemical oxygen demand, Energy, organic substrate, sugarcane waste
One of the most advanced systems of microbial fuel cells is the benthic microbial fuel cell (BMFC). Despite several developments, this strategy still has a number of significant flaws, such as instable organic substrate. Waste material (sugarcane) is used as a substrate in this work to address the organic substrate instability. The process was operated continuously for 70 days. A level of 300 mV was achieved after 33 days of operation, while the degradation efficiencies of Pb (II), Cd (II), and Cr (III) were more than 90%. More than 90% of the removed chemical oxygen demand (COD) was also recorded. The measured power density was 3.571 mW/m2 at 1000 external resistance with 458 internal resistance. This demonstrates that electrons are effectively transported throughout the operation. The Bacillus strains are the most dominant bacterial community on the surface of the anode. This research’s mechanism, which involves metal ion degradation, is also explained. Finally, parameter optimizatio... [more]
4001. LAPSE:2023.35136
Investigating the Effect of Bi2MoO6/g-C3N4 Ratio on Photocatalytic Degradation of Sulfadiazine under Visible Light
April 28, 2023 (v1)
Subject: Materials
Keywords: Bi2MoO6/g-C3N4, photocatalysis, sulfadiazine, visible light
In this study, a series of Bi2MoO6/g-C3N4 composites were prepared through a wet-impregnation method, and their photocatalytic properties were investigated for the degradation of sulfadiazine (SDZ) under visible light irradiation. Physical and chemical characterizations were carried out using X-ray diffraction (XRD), scanning electron microscope (SEM), Fourier transform infrared spectroscopy (FT-IR), photoluminescence spectroscopy (PL), UV-vis diffuse reflectance spectra (UV-vis), and electrochemical impedance spectra (EIS). Compared to pure g-C3N4, the introduction of Bi2MoO6 significantly enhanced the visible light responsive photocatalytic activity, with the 1:32 Bi2MoO6/g-C3N4 composite exhibiting the highest photodegradation efficiency towards SDZ under visible light irradiation with a photocatalytic efficiency of 93.88% after 120 min of visible light irradiation. The improved photocatalytic activity can be attributed to the formation of a heterojunction between Bi2MoO6 and g-C3N4... [more]
4002. LAPSE:2023.35135
Optimization of Destressing Parameters of Water Jet Slits in Rock Burst Coal Seams for Deep Mining
April 28, 2023 (v1)
Subject: Materials
Keywords: deep mining, numerical simulation, parameter optimization, rock burst, water jet slotting
Mining in deep coal seams is characterized by high ground stress, often accompanied by coal and rock dynamic disasters such as rock bursts. High-pressure water jet slotting technology can relieve pressure and reduce the stress concentration on the coal seam, which is one of the effective pressure relief measures in rock burst coal seams for deep mining. Reasonable pressure relief parameters are an important influence on the effectiveness of pressure relief achieved by a high-pressure water jet. This paper uses theoretical analysis and numerical simulation to analyze the principle of high-pressure water jet pressure relief and rock burst prevention, and a theoretical calculation model of six key pressure relief parameters is constructed. The optimal values of each pressure relief parameter are obtained, and good pressure relief effect is achieved in a certain rock burst risk area. The research results showed that (1) parameters such as drilling spacing−slit radius, drilling depth−slit l... [more]
4003. LAPSE:2023.35134
Experimental Study on the Forcible Imbibition Law of Water in Shale Gas Reservoirs
April 28, 2023 (v1)
Subject: Energy Systems
Keywords: forcible imbibition, imbibition capacity, induced microfractures, shale, shut-in time
Water imbibition is a key factor affecting the flowback regime of shale gas wells after volume fracturing. In this study, a set of experimental apparatus and corresponding test and evaluation methods were developed to analyze the laws of forcible imbibition of water in a shale reservoir, characterize the initiation time of microfractures induced by shale hydration quantitatively, and optimize the shut-in time of shale gas wells; the imbibition depths of different pore types are quantitatively calculated based on the multiple pore imbibition analytical model. The experimental results show that: according to imbibition saturation growth rate, the shale forcible imbibition can be divided into three periods, imbibition diffusion, imbibition transition, and imbibition balance. Among them, the imbibition diffusion period is the main period for imbibition capacity rise. The reason for this phenomenon is that due to the fluid pressure difference effect, the shale fills its large pores and micr... [more]
4004. LAPSE:2023.35133
An Impacting Factors Analysis of Unsafe Acts in Coal Mine Gas Explosion Accidents Based on HFACS-ISM-BN
April 28, 2023 (v1)
Subject: Energy Systems
Keywords: Bayesian network, coal mine gas explosion, HFACS, interpretive structural model, unsafe acts
With the development of intelligent coal mine construction, China’s coal production safety has been greatly improved, but coal mine gas explosion accidents still cannot be completely avoided and the unsafe acts of miners are an important cause of the accidents. Therefore, this study firstly collected 100 coal mine gas explosion cases in China, improved the framework of human factors analysis and classification system (HFACS) and used it to identify the causes of miners’ unsafe acts in detail. A hierarchy of the impacting factors is established. Then, combining with the interpretive structural model (ISM), the correlation between the impacting factors among different levels, especially among non-adjacent levels, is qualitatively analyzed through expert judgment. Then, the correlation among the contributing factors was quantitatively tested by chi-square test and odds ratio (OR) analysis. On this basis, a Bayesian network (BN) is constructed for the impacting factors of miners’ unsafe ac... [more]
4005. LAPSE:2023.35132
Pectin from Three Vietnamese Seagrasses: Isolation, Characterization and Antioxidant Activity
April 28, 2023 (v1)
Subject: Food & Agricultural Processes
Keywords: antioxidant activity, characterization, Enhalus acoroides, Halophila ovalis, isolation, pectin, Thalassia hemprichii, Vietnamese seagrass
This study focused on the isolation and structural characterization of pectin from three distinct species of Vietnamese seagrass including Enhalus acoroides, Thalassia hemprichii, and Halophila ovalis. The pectin yield obtained from Enhalus acoroides was the highest, corresponding to 24.15%, followed by those from Thalassia hemprichii (20.04%) and Halophila ovalis (19.14%). The physicochemical properties of pectin including total carbohydrate content, anhydrouronic acid (AUA) content, equivalent weight (EW), methoxyl content (MeO), and degree of esterification (DE) were determined using various analysis techniques. The pectin obtained from all three species were found to be low-methyl-esterified pectin, with the MeO content and DE for E. acoroides, T. hemprichii, and H. ovalis being 6.15% and 27.18%, 3.26% and 43.31%, and 4.65% and 33.25%, respectively. The average molecular weight (MW) of pectin was analyzed by size-exclusion chromatography. Pectin from T. hemprichii had the highest M... [more]
4006. LAPSE:2023.35131
M-E-AWA: A Novel Task Scheduling Approach Based on Weight Vector Adaptive Updating for Fog Computing
April 28, 2023 (v1)
Subject: Planning & Scheduling
Keywords: fog computing, MOEA/D, multi-objective evolutionary algorithm, task scheduling
Task offloading and real-time scheduling are hot topics in fog computing. This paper aims to address the challenges of complex modeling and solving multi-objective task scheduling in fog computing environments caused by widely distributed resources and strong load uncertainties. Firstly, a task unloading model based on dynamic priority adjustment is proposed. Secondly, a multi-objective optimization model is constructed for task scheduling based on the task unloading model, which optimizes time delay and energy consumption. The experimental results show that M-E-AWA (MOEA/D with adaptive weight adjustment based on external archives) can effectively handle multi-objective optimization problems with complex Pareto fronts and reduce the response time and energy consumption costs of task scheduling.
4007. LAPSE:2023.35130
Reasonable Support Technology of Full-Stress Anchoring Technology of Advance Roadway: A Case Study
April 28, 2023 (v1)
Subject: Energy Systems
Keywords: bolt, full-stress anchoring, roadway, single hydraulic prop, support
Based on the engineering background of providing advance support for the working face of mining roadways, this paper studies the reasonable support technology of advance roadway roofs by combining theoretical analysis, numerical simulation, and field tests. Based on the geological conditions of the 1304 working face of Yineng Coal Mine, the FLAC3D numerical simulation software was used to compare and analyze the effects of the original single hydraulic prop advance support and the bolt-mesh-cable support without the single hydraulic prop. The results show that although the deformation of the surrounding rock is reduced under the support of the single hydraulic prop, the convergence of the roof and floor of the roadway and the left and right sides are still as high as 288 mm and 308 mm, respectively, which does not meet the requirements for safe production. Based on this problem, this study proposes full-stress anchoring technology. FLAC3D numerical simulation software is used to simula... [more]
4008. LAPSE:2023.35129
Green and Cost-Effective Separation of Cadmium from Base Metals in Chloride Medium with Halide-Loaded Anion Exchanger
April 28, 2023 (v1)
Subject: Environment
Keywords: base metals, cadmium separation, chloride medium, halide-loaded anion exchanger
A novel strategy for the separation of cadmium from base metals in chloride medium by anion exchange based on the formation of cadmium halo-complexes is presented in this article. Instead of using excess Br− or I− in the feed solution, the anion exchange resin or fibre was first preloaded with Br− or I− for Cd2+ adsorption from Cl− solution. Thus, the consumption of iodide or bromide was minimized while promising high adsorption stability of Cd2+. The adsorption thermodynamics and kinetics of Cd2+ were studied. The adsorption thermodynamics results were processed with Langmuir and Freundlich models and adsorption kinetics results were treated with Pseudo first order model, Pseudo second order model and intraparticle diffusion model. The adsorption mechanism was studied with the aid of FTIR and elemental analysis. Three strategies were applied for the stripping of Cd2+, including the use of water for disequilibrating its halo-complex formation, the formation of positively charged specie... [more]
4009. LAPSE:2023.35128
Synthesis of CaWO4 as a Photocatalyst for Degradation of Methylene Blue and Carmine under Ultraviolet Light Irradiation
April 28, 2023 (v1)
Subject: Materials
Keywords: calcium tungstate, dye, free radical, mechanism, photocatalysis
Photocatalysis is considered a promising method for wastewater treatment; however, most synthesized photocatalysts have complex structures and are costly. Thus, in this study, a novel CaWO4 sample was synthesized by a co-precipitation method in one step. The characteristic results show that CaWO4 has good dispersibility, a large specific surface area, and good photoresponse under UV light. The synthesized CaWO4 can be used to degrade methylene blue (MB) and carmine (CR) under UV light without the addition of oxidants. The effects of a water matrix, including pH value, solid−liquid ratio, light intensity, and initial concentration of pollutants on photocatalytic degradation were studied. According to the optimization of these factors, the optimal photocatalytic degradation condition was found under the catalyst concentration of 1.0 g/L and ultraviolet light intensity of 80 W. The optimal pH is 8.2 for the MB system and 6.0 for the CR system. The optimal photocatalytic degradation of MB... [more]
4010. LAPSE:2023.35127
Characteristics and Controlling Role in Hydrocarbon Accumulation of Strike-Slip Faults in the Maigaiti Slope
April 28, 2023 (v1)
Subject: Process Control
Keywords: active period, hydrocarbon accumulation, Maigaiti Slope, strike-slip fault, Tarim Basin
The Maigaiti Slope is a significant oil-gas-bearing field in the Tarim Basin. Based on 3D and 2D seismic data, systematic interpretation, stage sorting and genetic analysis of strike-slip faults in the Maigaiti Slope were carried out for the first time. The relationship between strike-slip faults and hydrocarbon accumulation was studied in combination with the fine dissection of hydrocarbon reservoirs. The study suggested that: (1) Staging and segmentation characteristics of strike-slip faults are evidently presented in the Maigaiti Slope. According to active periods, strike-slip faults can be divided into early Caledonian period, late Caledonian period, Hercynian period, and Himalayan period. According to plane distribution characteristics, strike-slip faults can be divided into the west Maigaiti Segment, mid-Maigaiti Segment, Madong Segment, and Bachu Segment. The main active periods and plane distribution of strike-slip faults in different sections are remarkably different. This ana... [more]
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