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Records with Subject: Energy Systems
8369. LAPSE:2023.7493
Proposal of a System to Identify Failures and Evaluate the Efficiency of Internal Combustion Engines of Thermal Power Plants
February 24, 2023 (v1)
Subject: Energy Systems
Keywords: internal combustion engine, monitoring, thermal efficiency
Thermoelectric plants are one of the main forms of energy generation in the world, being the second main source of generation in Brazil. However, with rising fuel costs and greater concern for the environment, controlling the efficiency levels of these plants has become critical. This work presents a system to identify failures and evaluate the efficiency of internal combustion engines used in thermal power plants. To assess efficiency, the developed system monitors subsystem losses (such as cooling, lubrication, turbocharger, etc.). In addition, sensors for cylinder pressure and instantaneous speed were installed and comprise an online monitoring system for the pressure condition of each cylinder of the engines. All this is combined into a supervisory system that presents the Sankey diagram of the engine as its main information online and remotely. To validate the system, experiments were carried out in a controlled configuration (where faults were purposely inserted) and in a Brazili... [more]
8370. LAPSE:2023.7487
Occurrence and Migration Mechanisms of Methane in Marine Shale Reservoirs
February 24, 2023 (v1)
Subject: Energy Systems
Keywords: low-temperature nitrogen adsorption, marine shale, methane, migration, nuclear magnetic resonance, occurrence
The occurrence mechanism of methane is very important as evaluating the gas-bearing properties of marine shale reservoirs, and the evaluation of the development effect of shale gas wells need to focus on the migration mechanism of methane. In this study, LTNA technology and NMR technology were used to analyze the pores and methane of shale. The results show that inorganic pores have better connectivity, larger pore size, and micro−nano cracks between pores compared to organic pores. Most of the pores in shale are micropores and mesopores, which provide most of the specific surface area, but the contribution of macropores to pore volume cannot be ignored. Adsorbed gas volume depends on the pore surface area and gas pressure, while free gas volume depends on pore volume and gas pressure. The pore structure of micropores and mesopores is complex, and the specific surface area is large. The dispersion force between pore surface molecules and methane molecules is firm, which makes the pore... [more]
8371. LAPSE:2023.7486
Experimental Assessment of the Performance and Fine Particulate Matter Emissions of a LPG-Diesel Dual-Fuel Compression Ignition Engine
February 24, 2023 (v1)
Subject: Energy Systems
Keywords: combustion engines, Diesel, dual fuel, knock detection, LPG
The present work is focused on the assessment of the performance and fine particulate matter emissions (PM2.5) of a turbocharged four-cylinder direct injection diesel engine operating under dual-fuel mode with Liquefied Petroleum Gas (LPG). For load levels of 30%, 60% and 100%, measurements were taken, keeping the engine speed constant at 2200, 2500 and 3200 rpm, while the engine knock detonation was detected through a non-invasive internal system. According to experimental measurements, the abnormal knock combustion occurred at full load operation with a maximum LPG energy fraction of ~60%. The brake fuel conversion efficiency increased by 2.6% with an LPG energy fraction of 10%, where a fuel saving of 11.9% was achieved with respect to the diesel-only operation. The reduction of diesel consumption was around 50% with respect to 100% diesel operation at full load operations, where the highest brake fuel conversion efficiency was achieved. The brake fuel conversion efficiency decreased... [more]
8372. LAPSE:2023.7485
Time-Average Heat Transfer Coefficient for Steam-Air Condensation during the Dropping of Containment Pressure
February 24, 2023 (v1)
Subject: Energy Systems
Keywords: passive containment cooling system, self-sustaining stability, time-average condensation heat transfer coefficient, transient-state heat transfer
The passive containment cooling system (PCCS) has been applied in the new generation nuclear power plant. Previous studies mainly focused on steady-state heat transfer, but the actual heat transfer of PCCS is the transient process. Thus, investigating the transient heat transfer during the containment pressure dropping is necessary. The present study proposes a time-average condensation heat transfer coefficient (time-average condensation HTC) to characterize the intensity of transient condensation heat transfer. The time-average condensation HTC is defined as the heat absorbed per unit heat transfer area and per unit wall subcooling in a unit time. Experiments were performed to research the effect of initial gas-mixture pressure and air mass fraction on transient HTC. The result showed that the more significant gas-mixture pressure and lower air mass fraction could promote the transient-state heat transfer, especially the low air mass fraction. Based on the experimental result, a deta... [more]
8373. LAPSE:2023.7480
Energy Sector Derived Combustion Products Utilization—Current Advances in Carbon Dioxide Mineralization
February 24, 2023 (v1)
Subject: Energy Systems
Keywords: Carbon Dioxide, carbon dioxide utilization, carbonation, CCU, combustion products, fluidized bed fly ash, mineralization
Carbon dioxide and combustion products are among the main waste streams deriving from the energy sector. Efficient and cost-effective methods of solid waste valorization and carbon capture, storage and utilization are needed in the transition period towards carbon neutrality in light of the recent scenarios forecasting energy demand and energy supply mix under dynamic social, economic and political circumstances. Within this paper, the current advances in carbon dioxide mineralization, combining carbon dioxide utilization and combustion products valorization, are presented in terms of the recognized methodological options of carbonation methods, process efficiency and effects on the process product properties. Special attention is given to the studies on the valorization of fluidized bed boilers fly ash, differing in a range of parameters from the conventional boilers fly ash, as well as the effects of the carbonation process on the stabilization and improvement of its properties and t... [more]
8374. LAPSE:2023.7479
Enhanced Biodiesel Synthesis via a Homogenizer-Assisted Two-Stage Conversion Process Using Waste Edible Oil as Feedstock
February 24, 2023 (v1)
Subject: Energy Systems
Keywords: biodiesel, esterification, homogenize, transesterification, waste edible oil
In this study, a homogenizer in conjunction with a two-stage process was utilized to facilitate biodiesel production from waste edible oil (WEO). This paper contributes to the improvement of the yield and the shortening of the reaction time for biodiesel synthesis. Sulfuric acid was used in the first stage which was the esterification of the free fatty acids (FFA) of the WEO; then the transesterification reaction of triglycerides took place in the second stage with an alkaline catalysis. The present investigation aimed to explore the parameters affecting the reactions, including homogenizer speed, alcohol/oil molar ratio, catalyst dosage, reaction temperature, and reaction time. Under the operating conditions of the first stage (the reaction temperature was 65 °C, the homogenizer speed was 8000 rpm, the methanol/oil molar ratio was 15:1, and the amount of sulfuric acid was 4 wt%), the acid value fell to below 2 mg KOH/g after 10 min. The best base-catalyzed conditions in the second sta... [more]
8375. LAPSE:2023.7474
Multi-Criteria Analysis of the Selection of Vehicles with Electric, Hybrid, and Conventional Drive for Car-Sharing Services from the Perspective of Polish Occasional System Users
February 24, 2023 (v1)
Subject: Energy Systems
Keywords: car-sharing systems, civil engineering and transport, e-car-sharing, electric car-sharing systems, electric mobility, electromobility, mobility management, multi-criteria data analysis, shared mobility, sustainable transport systems, transportation engineering
Car-sharing systems, i.e., short-term car rentals, are one of the solutions that can be an alternative to individual motorization in cities. However, these services must adapt well to customers’ needs to develop appropriately. Currently, there have been attempts in scientific research to make numerous optimizations of car-sharing systems, but little emphasis was placed on the type of car fleet used in the systems, which is particularly important at the stage of transformation of the automotive industry towards electric mobility. In response to this research gap, this article was dedicated to the selection of vehicles for car-sharing systems. The work focuses on users of Polish car-sharing systems who use the services of short-term vehicle rental occasionally, i.e., up to five times a year. The research made it possible to determine the types of vehicles (cars with electric, hybrid and internal combustion engines) that the users are interested in and to indicate the specific features th... [more]
8376. LAPSE:2023.7473
Review of the Chosen Methods of Producing Front Contacts to Transparent Conductive Oxides Layers in Photovoltaic Structures
February 24, 2023 (v1)
Subject: Energy Systems
Keywords: atomic layer deposition (ALD), solar cells, transparent conductive oxides (TCO)
It is well known that PV thin films can be deposited by an extensive range of more or less expensive and complicated techniques (such as sputtering, chemical vapor deposition (CVD), physical vapor deposition (PVD), pulsed laser deposition, atomic layer deposition (ALD)). The present paper focuses on TCO layers applied by chosen techniques, including mainly the ALD and CVD methods. Thin layers of transparent conductive oxides constitute a well-known group of materials with unique properties. Oxides such as ZnO, SnO2, and In2O3 are the most significant materials of this type; some of them are discussed in the paper. From the application point of view in the photovoltaic industry, the goal is to apply a method that will provide the highest value of electric charge conductivity while maintaining the minimum value of absorption in the layer and a reduced value of the reflection coefficient. The implementation of significant achievements in the coming decade is for developing guidelines for... [more]
8377. LAPSE:2023.7472
An Enhanced Second-Order Cone Programming-Based Evaluation Method on Maximum Hosting Capacity of Solar Energy in Distribution Systems with Integrated Energy
February 24, 2023 (v1)
Subject: Energy Systems
Keywords: enhanced second-order cone programming, integrated energy distribution system, maximum hosting capacity, solar energy
In order to adjust to the change of the large-scale deployment of photovoltaic (PV) power generation and fully exploit the potentialities of an integrated energy distribution system (IEDS) in solar energy accommodation, an evaluation method on maximum hosting capacity of solar energy in IEDS based on convex relaxation optimization algorithm is proposed in this paper. Firstly, an evaluation model of maximum hosting capacity of solar energy for IEDS considering the electrical-thermal comprehensive utilization of solar energy is proposed, in which the maximization of PV capacity and solar collector (SC) capacity are fully considered. Secondly, IEDS’s potential in electricity, heat, and gas energy coordinated optimization is fully exploited to enhance the hosting capacity of solar energy in which the electric distribution network, heating network, and natural gas network constraints are fully modeled. Then, an enhanced second-order cone programming (SOCP)-based method is employed to solve... [more]
8378. LAPSE:2023.7470
Mitigating Adverse Impacts of Increased Electric Vehicle Charging on Distribution Transformers
February 24, 2023 (v1)
Subject: Energy Systems
Keywords: distribution transformer, electric vehicles, reactive power compensation, transformer aging, V2G
As the world is transitioning to electric vehicles (EVs), the existing power grids are facing several challenges. In particular, the additional charging power demand may repeatedly overload the traditionally-sized distribution transformers and adversely impact their operational life. To address this challenge, this paper proposes an EV-based reactive power compensation strategy for transformer overloading mitigation. Specifically, a low-bandwidth centralized recursive controller is proposed to determine a set point for the EV’s onboard charger’s reactive power. Importantly, the proposed strategy is practically implementable in existing distribution grids as it does not rely on smart grid infrastructure and is stable under potential communication delays and partial failures. This paper discusses the controller’s structure, design, and stability in detail. The proposed solution is tested with a realistic secondary distribution system considering four different EV charging scenarios with... [more]
8379. LAPSE:2023.7466
Study of Rotation Effect on Nanofluid Natural Convection and Heat Transfer by the Immersed Boundary-Lattice Boltzmann Method
February 24, 2023 (v1)
Subject: Energy Systems
Keywords: heat transfer, IB-LBM, nanofluid, rotation effect
Aiming to investigate the rotation effect on the natural convection and heat transfer of nanofluid, which has an important application in the control of heat transfer, the velocity field and temperature distribution inside the square cylinder with the rotating heat source in the center were numerically studied and presented in detail at different Hartman numbers and aspect ratios using the immersed boundary-lattice Boltzmann method. Then, the average Nusselt number on the surface of the heat source was calculated to compare the heat transfer rate in different cases. The results showed that the rotation would reduce the effect of gravity on the flow and suppress the heat transfer between the rotating heat source and nanofluid, while the external magnetic field would reduce the rotation effect on the flow and suppress or promote the heat transfer depending on the rotational speed and aspect ratio. Moreover, the smaller aspect ratio of the heat source to the square cylinder would enhance... [more]
8380. LAPSE:2023.7464
Computing Day-Ahead Dispatch Plans for Active Distribution Grids Using a Reinforcement Learning Based Algorithm
February 24, 2023 (v1)
Subject: Energy Systems
Keywords: active distribution grids, battery control, dispatch plan, reinforcement learning
The worldwide aspiration for a sustainable energy future has led to an increasing deployment of variable and intermittent renewable energy sources (RESs). As a result, predicting and planning the operation of power grids has become more complex. Batteries can play a critical role to this problem as they can absorb the uncertainties introduced by RESs. In this paper, we solve the problem of computing a dispatch plan for a distribution grid with RESs and batteries with a novel approach based on Reinforcement Learning (RL). Although RL is not inherently suited for planning problems that require open loop policies, we have developed an iterative algorithm that calls a trained RL agent at each iteration to compute the dispatch plan. Since the feedback given to the RL agent cannot be directly observed because the dispatch plan is computed ahead of operation, it is estimated. Compared to the conventional approach of scenario-based optimization, our RL-based approach can exploit significantly... [more]
8381. LAPSE:2023.7461
Assessing Wind Energy Projects Potential in Pakistan: Challenges and Way Forward
February 24, 2023 (v1)
Subject: Energy Systems
Keywords: Pakistan, Renewable and Sustainable Energy, Sustainability, wind energy potential
Energy is the driver of the socioeconomic growth and development of a country. In the pursuit of available and affordable sources of energy, nations around the world have forgotten the sustainability angle and are facing an energy crisis. The developing world has initiated development plans in an unsustainable way, causing a demand−supply gap and leading to very high energy prices. Renewable energy gives us a solution to this circular crisis. The recent world has seen significant investment in renewables, particularly in the wind energy sector. The investment was initiated as a government spending program, but is now taken up by the private sector. The current study presents a thorough analysis of the prospects for wind energy and the means and measures required to fully capacitate the sector in Pakistan. In Pakistan’s three largest provinces, there is tremendous potential for wind energy, which requires proper utilization and exploration for sustained socioeconomic development. This s... [more]
8382. LAPSE:2023.7458
Site-Adaptation for Correcting Satellite-Derived Solar Irradiance: Performance Comparison between Various Regressive and Distribution Mapping Techniques for Application in Daejeon, South Korea
February 24, 2023 (v1)
Subject: Energy Systems
Keywords: DNI, GHI, satellite-derived solar irradiance, site-adaptation, solar energy resource assessment, UASIBS-KIER model
Satellite-derived solar irradiance is advantageous in solar resource assessment due to its high spatiotemporal availability, but its discrepancies to ground-observed values remain an issue for reliability. Site adaptation can be employed to correct these errors by using short-term high-quality ground-observed values. Recent studies have highlighted the benefits of the sequential procedure of a regressive and a distribution-mapping technique in comparison to their individual counterparts. In this paper, we attempted to improve the sequential procedure by using various distribution mapping techniques in addition to the previously proposed quantile mapping. We applied these site-adaptation techniques on the global horizontal irradiance (GHI) and direct normal irradiance (DNI) obtained from the UASIBS-KIER model in Daejeon, South Korea. The best technique, determined by a ranking methodology, can reduce the mean bias from −5.04% and 13.51% to −0.45% and −2.02% for GHI and DNI, respectively... [more]
8383. LAPSE:2023.7455
Thermal Perturbations at Crystal Nucleation in Glass-Forming Liquids
February 24, 2023 (v1)
Subject: Energy Systems
Keywords: crystallization, dynamic heat capacity, glass-forming liquids, nonequilibrium heat transfer, phase transitions
Understanding the processes occurring during the nanocrystallization of glass-forming liquids is important for creating artificial nanostructures for various applications. In this article, local thermal perturbations in supercooled glass-forming liquids and polymers during the nucleation of a crystalline phase are studied. To describe the thermal response of supercooled glass-forming liquids, an integro-differential heat equation with dynamic heat capacity is used. We have found that the effect of the dynamic heat capacity is significant for fast local thermal perturbations that arise in the early stages of crystal nucleation in glass-forming liquids and polymers. It has been established that local temperature perturbations during the nucleation of crystals in silicate glasses and polymers can change the nucleation rate by 2−5 orders of magnitude. The knowledge gained can be useful for the technology of artificial microstructures and advanced materials.
8384. LAPSE:2023.7452
Status of Micro-Hydrokinetic River Technology Turbines Application for Rural Electrification in Africa
February 24, 2023 (v1)
Subject: Energy Systems
Keywords: Africa, capacity building, energy accessibility, hydrokinetic river turbine, Sustainability
Energy accessibility, reliability and availability are key components of improved quality of life and human development in all spheres. As the United Nations’ SDG 7 calls for access to electricity for all by 2030, Africa still has a wide gap to fill as the statistics show that 85% of the population that will not have access to electricity is in Africa. As the world tries to wean itself off non-renewable energy and transition to green through use of renewable energy sources, hydropower energy remains at the heart of Africa for this venture. With majority of the rural population in Africa lacking electricity, there is need for a low-tech system that utilizes river flow to generate just enough energy for normal operation in these regions. Micro-hydrokinetic river turbine technology (µ-HRT), which offers less intermittency, can potentially contribute to sustainably electrifying Africa rural areas. The technology has been adopted by few countries worldwide, with limited comprehensive study... [more]
8385. LAPSE:2023.7449
Investigation of the OA-300M Electrolysis Cell Temperature Field of Metallurgical Production
February 24, 2023 (v1)
Subject: Energy Systems
Keywords: aluminum, analysis, computer modeling, diagnostics, mathematical model, monitoring
In this study, the authors explored the issues of the Soderbergh electrolysis cell’s increase in economic efficiency. This result was achieved by analyzing the temperature fields of the electrolysis cell in order to determine the overheating points. As a result, it led to the determination of the points of the hearth bottom’s subsequent breakdown, causing the failure of the electrolysis cell. In this paper, the mathematical modeling of the temperature fields using a spatially distributed mathematical model and conducted experimental studies were carried out. The mathematical model also provides the opportunity to measure the temperature field in the hearth bottom (at the bottom) of the OA-300M electrolysis cell. The results of the given research can be used to solve the experimental determination of the hearth bottom internal defect problem.
8386. LAPSE:2023.7448
Research Progress of SPH Simulations for Complex Multiphase Flows in Ocean Engineering
February 24, 2023 (v1)
Subject: Energy Systems
Keywords: granular multiphase flows, high-pressure multiphase flows, multiphase flows, multiphase flows under atmospheric pressure, phase-change multiphase flows, SPH method
Complex multiphase flow problems in ocean engineering have long been challenging topics. Problems such as large deformations at interfaces, multi-media interfaces, and multiple physical processes are difficult to simulate. Mesh-based algorithms could have limitations in dealing with multiphase interface capture and large interface deformations. On the contrary, the Smoothed Particle Hydrodynamics (SPH) method, as a Lagrangian meshless particle method, has some merit and flexibility in capturing multiphase interfaces and dealing with large boundary deformations. In recent years, with the improvement of SPH theory and numerical models, the SPH method has made significant advances and breakthroughs in terms of theoretical completeness and computational stability, which starts to be widely used in ocean engineering problems, including multiphase flows under atmospheric pressure, high-pressure multiphase flows, phase-change multiphase flows, granular multiphase flows and so on. In this pape... [more]
8387. LAPSE:2023.7447
A Survey of the Quasi-3D Modeling of Wind Turbine Icing
February 24, 2023 (v1)
Subject: Energy Systems
Keywords: annual power production, icing conditions, power curve generation, Quasi-3D modeling, wind turbine
Wind turbine icing has been the subject of intensive research over the past two decades, primarily focusing on applying computational fluid dynamics (CFD) to 2D airfoil simulations for parametric analysis. As a result of blades’ airfoils deformation caused by icing, wind turbines experience a considerable decrease in aerodynamic performance resulting in a substantial loss of productivity. Due to the phenomenon’s complexity and high computational costs, a fully 3D simulation of the entire iced-up rotating turbine becomes infeasible, especially when dealing with several scenarios under various operating and weather conditions. The Quasi-3D steady-state simulation is a practical alternative method to assess power loss resulting from ice accretion on wind turbine blades. To some extent, this approach has been employed in several published studies showing a capability to estimate performance degradation throughout the generation of power curves for both clean and iced wind turbines. In this... [more]
8388. LAPSE:2023.7439
A Review of Recent Investigations on Flow and Heat Transfer Enhancement in Cooling Channels Embedded with Triply Periodic Minimal Surfaces (TPMS)
February 24, 2023 (v1)
Subject: Energy Systems
Keywords: heat transfer, internal cooling, pressure loss, thermal performance, triply periodic minimal surfaces
Triply periodic minimal surfaces (TPMS) have shown better mechanical performance, mass transfer, and thermal conductivity than conventional and strut-based structures, which have been employed in different disciplines. Most of the literature investigates different TPMS topologies in cooling channels to enhance thermal performance due to the smooth curvature and large surface area. However, a deeper investigation of the effects of TPMS design variables and the thermal performance advantages of cooling channels is required. This review details the effects of TPMS design variables, i.e., porosity, wall thickness, and unit cell size, on flow and heat transfer enhancement. It is found that varying the design variables significantly changes the flow and heat transfer characteristics. Also, by comparing TPMS and conventional cooling structures, it is found that most TPMS structures show better thermal performance than other strategies. Moreover, different fabrication methods for TPMS-based co... [more]
8389. LAPSE:2023.7437
How Dependent Are European Power Systems and Economies on Natural Gas?—A Macroeconomic Optimization for Security of Electricity Supply
February 24, 2023 (v1)
Subject: Energy Systems
Keywords: economic optimization, European power system, Natural Gas, security of electricity supply
How dependent are European power systems and economies on natural gas? To answer this pressing question, we coupled a simulation model for assessing security of electricity supply and an economic optimization model. With this, we were able to analyze different reduction scenarios of the amount of gas utilized in the power sector. Our results show that reducing the amount of natural gas in the European power sector by up to 30% has a relatively moderate impact on the security of electricity supply. Restrictions of 40% or more result in substantially higher reductions in electricity demand shortfall and are associated with economic costs of more than EUR 77 billion. Furthermore, we demonstrate that a close coordination of gas distribution on a European level would be instrumental in mitigating negative economic consequences. Finally, it can be deduced that a coordinated delay of planned power plant shutdowns could effectively compensate for reduced gas volumes in the electricity sector.
8390. LAPSE:2023.7429
Thin-Film Lithium Cobalt Oxide for Lithium-Ion Batteries
February 24, 2023 (v1)
Subject: Energy Systems
Keywords: bulk doping, lithium cobalt oxide, physical vapor deposition, surface coating, thin film
Lithium cobalt oxide (LCO) cathode has been widely applied in 3C products (computer, communication, and consumer), and LCO films are currently the most promising cathode materials for thin-film lithium batteries (TFBs) due to their high volumetric energy density and favorable durability. Most LCO thin films are fabricated by physical vapor deposition (PVD) techniques, while the influence of preparation on the materials’ properties and electrochemical performance has not been highlighted. In this review, the dominant effects (heating, substrate, power, atmosphere, etc.) on LCO thin films are summarized, and the LCO thin films fabricated by other techniques (spin coating, sol−gel, atomic layer deposition, pulsed laser deposition, etc.) are outlined. Moreover, the modification strategies including bulk doping and surface coating for powder and thin-film LCO electrodes are discussed in detail. This review may pave the way for developing novel, durable, and high-performance LCO thin films b... [more]
8391. LAPSE:2023.7427
Fuel-Water Emulsion as an Alternative Fuel for Gas Turbines in the Context of Combustion Process Properties—A Review
February 24, 2023 (v1)
Subject: Energy Systems
Keywords: Alternative Fuels, CO emission, fuel-water emulsion, gas turbine, NOx emission, smoke emission
Fuel with the addition of water, forming fuel-water emulsions, is a potential way to reduce the emission of pollutants from gas turbines powered by any liquid fuel. This article analyzes the available work on the combustion of fuel-water emulsions in gas turbines. The literature analysis was preceded by a theoretical introduction on fuel-water emulsion, taking into account the factors influencing its micro- and macroscopic properties. The basic features of the agents used to stabilize the emulsion were also discussed and the process of its combustion was described. The analyzed research differed in terms of the test stands on which the experiments were conducted, the fuel constituting the continuous phase of the emulsion, the amount of water contained in the mixture and the method of producing the emulsion. On the basis of the conducted analysis, conclusions were drawn concerning the influence of feeding a gas turbine with a fuel-water emulsion on the emission of nitrogen oxides, carbo... [more]
8392. LAPSE:2023.7424
Advanced Coal, Petroleum, and Natural Gas Exploration Technology
February 24, 2023 (v1)
Subject: Energy Systems
Oil, coal, and natural gas are traditional fossil energy sources and the main components of primary energy consumption globally [...]
8393. LAPSE:2023.7417
Vanadium Oxide−Conducting Polymers Composite Cathodes for Aqueous Zinc-Ion Batteries: Interfacial Design and Enhancement of Electrochemical Performance
February 24, 2023 (v1)
Subject: Energy Systems
Keywords: aqueous zinc-ion battery, composite cathode, electrochemical performance, Energy Storage, poly(3,4-ethylenedioxythiophene), polyaniline, polypyrrole, vanadium(V) oxide
Aqueous zinc-ion batteries (AZIBs) are being intensively developed as potential alternative electrochemical power sources, due to their advantages such as low cost, high safety, abundance of natural zinc resources and appropriate energy density. Among currently investigated prospective cathode materials for AZIBs, vanadium oxide-based composites with intrinsically conducting polymers have shown many advantages, such as high capacity, high power density and long battery life. This review gives a focused view of the design for the boosting of zinc ion storage performance using intrinsically conducting polymers in vanadium oxide-based composites and the mechanism of intercalation processes. The main challenges in interfacial engineering of vanadium oxide-conducting polymers composite structures and the prospects for further development of such cathode materials are summarized and discussed. The review would give rise to a broad interest focusing on the advantageous strategy of the develop... [more]
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