This study examines the potential of applying computational intelligence modelling to describe the drying kinetics of persimmon fruit slices during vacuum drying (VD) and hot-air-drying (HAD) under different drying temperatures of 50 °C, 60 °C and 70 °C and samples thicknesses of 5 mm and 8 mm. Kinetic models were developed using selected thin layer models and computational intelligence methods including multi-layer feed-forward artificial neural network (ANN), support vector machine (SVM) and k-nearest neighbors (kNN). The statistical indicators of the coefficient of determination (R2) and root mean square error (RMSE) were used to evaluate the suitability of the models. The effective moisture diffusivity and activation energy varied between 1.417 × 10−9 m2/s and 1.925 × 10−8 m2/s and 34.1560 kJ/mol to 64.2895 kJ/mol, respectively. The thin-layer models illustrated that page and logarithmic model can adequately describe the drying kinetics of persimmon sliced samples with R2 values (>... [more]

Steam stripping is commonly used to remove free fatty acids from crude palm oil. An alternative deacidification method, solvent extraction performed at a much lower temperature, would preserve the natural antioxidants in the refined palm oil. In this work, palmitic acid was extracted using betaine monohydrate-propionic acid and betaine monohydrate-acetic acid deep eutectic solvents (DESs). The effect of temperature (40 °C to 80 °C), mass ratio of palm oil to solvent (2:1 to 1:2), and palmitic acid content in the palm oil feed (2% to 8% mass) on the distribution coefficient values of palmitic acid (0.44−0.93) was investigated. For the first time, a facile recovery of DESs could be accomplished by a cooling process where up to 98% of the palmitic acid separates as solid. A solvent extraction process for palm oil deacidification, employing a DES with a distribution coefficient value much higher than unity, will provide advantages over the steam stripping process.

This research aimed to investigate the chemical composition of seed oils extracted from three Vietnamese Dalbergia species (D. tonkinensis, D. mammosa, and D. entadoides). The fatty acid profiles and contents of tocopherols and sterols of the seed oils, and total phenolic compounds extracted from the fresh seeds were characterized using different methods. Among the examined samples, D. tonkinensis seed oils showed high contents of linoleic acid (64.7%), whereas in D. mammosa, oleic acid (51.2%) was predominant. In addition, α- and γ-tocopherol and β-sitosterol were major ingredients in the seed oils, whereas ferulic acid and rosmarinic acid are usually predominant in the seeds of these species. Regarding sterol composition, the D. entadoides seed oil figured for remarkably high content of Δ5,23-stigmastadienol (1735 mg/kg) and Δ7-stigmastenol (1298 mg/kg). In addition, extracts with methanol/water (80:20, v/v) of seeds displayed significant in vitro antioxidant activity which was deter... [more]

Food demand is increasing every year and, usually animal-derived products are generated far from consumer-places. New technologies are being developed to preserve quality characteristics during processing and transportation. One of them is electrolyzed water (EW) that helps to avoid or decrease the development of foodborne pathogens, or losses by related bacteria. Initially, EW was used in ready-to-eat foods such as spinach, lettuce, strawberries, among others; however, its application in other products is under study. Every product has unique characteristics that require an optimized application of EW. Different sanitizers have been developed; unfortunately, they could have undesirable effects like deterioration of quality or alterations in sensory properties. Therefore, EW is gaining popularity in the food industry due to its characteristics: easy application and storage, no corrosion of work surfaces, absence of mucosal membrane irritation in workers handling food, and it is conside... [more]

Exhausted olive pomace (EOP) is the main residue generated in olive oil industries, after the extraction of the residual oil from olive pomace with hexane. This work studies the ethanol production from hemicellulosic sugars of EOP. The fermentability of the sugar solution, resulting from the acid pretreatment of EOP, was evaluated using Escherichia coli SL100, although a detoxification step was required before fermentation. Overliming and activated charcoal detoxification were tested to minimize the presence of inhibitory compounds in the hydrolysate and to achieve a fermentable medium. E. coli assimilated all sugars in both detoxified hydrolysates and achieved ethanol yields of about 90% of the theoretical one. However, the fermentation time was much shorter when the hydrolysate had been detoxified with activated charcoal (20 h versus 120 h).

Natural populations of Ruta graveolens L. and Artemisia abrotanum L. in northern Saudi Arabia may be a rich source of natural polyphenols with potential biological activities. Therefore, tentative high-performance liquid chromatography−diode array detection was used to analyze the polyphenol contents of leaf extracts. R. graveolens mainly contained the phenolic acids chlorogenic acid and p-coumaric acid and the flavonoids rutoside and quercetin, whereas those of A. abrotanum mainly contained the phenolic acids isochlorogenic acid and rosmarinic acid and the flavonoid quercetin. Leaf extracts of both species showed antioxidant activities due to the presence of quercetin, chlorogenic acid, and p-coumaric acid as well as antiproliferative and cytotoxic activities against cancer cells, which may be attributed to necrotic cell accumulation during the early and late apoptotic periods. Both species also exhibited antibacterial activity, although the activity was higher in R. graveolens due to... [more]

Wastewater treatment is crucial to ensure a sustainable supply of clean water, especially for human use. Natural flocculants can overcome the disadvantages of chemical flocculants in wastewater treatment. This study proposes a new natural-based flocculant from the Tacca leontopetaloides plant for leachate treatment. The plant tuber was processed through gelatinization to produce Tacca leontopetaloides biopolymer flocculant (TBPF). The characterization of TBPF for flocculant properties was investigated, and the performance of TBPF on leachate treatment using a standard jar test procedure was examined at different pH values of leachate and TBPF dosages. The characteristics of TBPF in terms of amylose/amylopectin fraction, viscosity, and zeta potential were 26:74, 0.037−0.04 Pa·s, and −13.14 mV, respectively. The presence of −COOH and −OH structure in TBPF indicates the flocculant properties. TBPF reduced the turbidity, total suspended solids (TSS), and color from 218 NTU, 214 mg/L, 14201... [more]

The purpose of this review is to reveal the lipid and protein contents in black soldier fly larvae (BSFL) for the sustainable production of protein and energy sources. It has been observed from studies in the literature that the larval lipid and protein contents vary with the rearing conditions as well as the downstream processing employed. The homogenous, heterogenous and microbial-treated substrates via fermentation are used to rear BSFL and are compared in this review for the simultaneous production of larval protein and biodiesel. Moreover, the best moisture content and the aeration rate of larval feeding substrates are also reported in this review to enhance the growth of BSFL. As the downstream process after harvesting starts with larval inactivation, various related methods have also been reviewed in relation to its impact on the quality/quantity of larval protein and lipids. Subsequently, the other downstream processes, namely, extraction and transesterification to biodiesel, a... [more]

Olive oil industry is one of the most important industries in the world. Currently, the land devoted to olive-tree cultivation around the world is ca. 11 × 106 ha, which produces more than 20 × 106 t olives per year. Most of these olives are destined to the production of olive oils. The main by-products of the olive oil industry are olive-pruning debris, olive stones and different pomaces. In cultures with traditional and intensive typologies, one single ha of olive grove annually generates more than 5 t of these by-products. The disposal of these by-products in the field can led to environmental problems. Notwithstanding, these by-products (biomasses) have a huge potential as source of energy. The objective of this paper is to comprehensively review the latest advances focused on energy production from olive-pruning debris, olive stones and pomaces, including processes such as combustion, gasification and pyrolysis, and the production of biofuels such as bioethanol and biodiesel. Futu... [more]

The aim of the study was to determine the effect of the method and temperature of the sublimation, vacuum and convective drying process on the kinetics of dehydration of the Moldovan dragonhead leaves, as well as on the physical and chemical properties, such as color coordinates, total content of phenolic compounds, antioxidant capacity, total monomeric anthocyanins content, total flavonoids content and content of essential oils. It was shown that the kinetics of the sublimation and vacuum drying process are best described by the logarithmic and Page models. Sublimation and vacuum drying were characterized by comparable process times. An increase in drying temperature caused a decrease in the content of phenolic compounds and antioxidant activity of the dried material and a significant change in the composition of essential oils. The lowest brightness of the dried material and the lowest color saturation was found after sublimation drying at 20 °C. The highest dried material quality wa... [more]

(1) Plants, due to their phytochemicals, have long been known for their pharmacological potential and medicinal value. Verjuice, the acidic juice of unripe green grape, is still poorly characterized in terms of its chemical composition and biological activities. (2) In this study, we characterized the chemical composition, antioxidant and antitumor potential of verjuice extract. Folin−Ciocalteu and aluminum chloride reagents were used to identify the total phenol and total flavonoid composition. Various conventional methods were used to quantify the alkaloids and tannins. DPPH (2,2-diphenyl-1-picrylhydrazyl) free radical scavenging assay and Neutral Red assay were used to assess the antioxidant and antitumor activities, respectively. (3) We showed that the verjuice extract contains alkaloids, tannins, and a high quantity of total flavonoids and total phenols. Besides its antioxidant activity, verjuice significantly repressed human pulmonary adenocarcinoma (A549) cells’ viability in bot... [more]

Batch ozonation was performed to assess its efficacy as a pretreatment for reverse osmosis (RO) membranes for treating leachate with high concentrations of recalcitrant organic compounds. Leachate samples from two different landfills were collected and characterized. The modified fouling index (MFI) was used to estimate the fouling potential of raw and ozonized leachates. A response surface experimental design was applied to optimize operational pH and ozone dose. The results demonstrate that the best operational conditions are 1.5 g/L of O3 at pH 12.0 and 1.5 g/L of O3 at pH 9.0 for Landfills 1 and 2, which reduce MFI by 96.22% and 94.08%, respectively. Additionally, they show toxicity factor decays of 98.44% for Landfill 1 and 93.75% for Landfill 2. These results, along with the similar behavior shown by leachate samples from distinct landfills, suggest that ozonation is a promising technology to fit this kind of wastewater into the requirements of RO membranes, enabling their use in... [more]

This study proposes an innovative installation concept for the sustainable utilization of sewage sludge. The aim of the study is to prove that existing devices and technologies allow construction of such an installation by integration of a dryer, torrefaction reactor and gasifier with engine, thus maximizing recovery of the waste heat by the installation. This study also presents the results of drying tests, performed at a commercial scale paddle dryer as well as detailed analysis of the torrefaction process of dried sewage sludge. Both tests aim to identify potential problems that could occur during the operation. The scarce literature studies published so far on the torrefaction of sewage sludge presents results from batch reactors, thus giving very limited data of the composition of the torgas. This study aims to cover that gap by presenting results from the torrefaction of sewage sludge in a continuously working, laboratory scale, isothermal rotary reactor. The study confirmed the... [more]

Coffee, one of the most popular food commodities and beverage ingredients worldwide, is considered as a potential source for food industry and second-generation biofuel due to its various by-products, including mucilage, husk, skin (pericarp), parchment, silver-skin, and pulp, which can be produced during the manufacturing process. A number of research studies have mainly investigated the valuable properties of brewed coffee (namely, beverage), functionalities, and its beneficial effects on cognitive and physical performances; however, other residual by-products of coffee, such as its mucilage, have rarely been studied. In this manuscript, the production of bioethanol from mucilage was performed both in shake flasks and 5 L bio-reactors. The use of coffee mucilage provided adequate fermentable sugars, primarily glucose with additional nutrient components, and it was directly fermented into ethanol using a Saccharomyces cerevisiae strain. The initial tests at the lab scale were evaluate... [more]

This research quantified the unit and bulk density of several biomass crops across a variety of harvest and processing methods, as well as the energy and fuel requirements for these operations. A load density of approximately 240 kg·m−3 is needed to reach the legal weight limit of most transporters. Of the three types of balers studied, only the high density (HD) large square baler achieved this target density. However, the specific energy and fuel requirements increased exponentially with bale density, and at the maximum densities for corn stover and switchgrass, the dry basis energy and fuel requirements ranged from 4.0 to 5.0 kW·h·Mg−1 and 1.2 to 1.4 L·Mg−1, respectively. Throughputs of tub grinders when grinding bales was less than any other harvesting or processing methods investigated, so specific energy and fuel requirements were high and ranged from 13 to 32 kW·h·Mg−1 and 5.0 to 11.3 L·Mg−1, respectively. Gross size-reduction by pre-cutting at baling increased bale density by l... [more]

Essential oils are derived from not-fatty parts of plants and are mostly used in aromatherapy, as well as cosmetics and perfume production. The essential oils market is growing rapidly due to their claimed health benefits. However, because only therapeutic grade oil is required in the medicinal sector, there is a substantial low-value waste stream of essential oils that can be used in the transportation and agricultural sectors. This study investigated the influence of orange, eucalyptus, and tea tree oil on engine performance and combustion characteristics of a multi-cylinder compression ignition engine. Orange, eucalyptus, and tea tree oil were blended with diesel at 10% by volume. For benchmarking, neat diesel and 10% waste cooking biodiesel-diesel blend were also tested. The selected fuels were used to conduct engine test runs with a constant engine speed (1500 RPM (revolutions per minute)) at four loads. As the load increased, frictional power losses decreased for all of the fuel... [more]

Despite the huge amounts of grape marc generated in Tunisia from the wine industry, very few efforts have been exerted to manage this harmful waste. Therefore, thermal processes may contribute to an environmental friendly management and also help winemakers to create new economic profitable circuits in an increasingly competitive context. Among the various thermochemical conversion process, pyrolysis is suitable for the recovery of food processing residues, due to their high minerals content and ability to create high added values of the derived products (biochar, bio-oil and syngas). In this context, the aim of this work is to optimize the pyrolysis process in order to benefit from the grape marc potential for achieving highest product yields. Therefore, physico-chemical and energy characteristics of grape marc issued from a Tunisian wine cooperative were determined according to international standards. Thermogravimetric analyzes were also performed to predict the grape marc behavior... [more]

We evaluated the thermogravimetric and devolatilization rates of hemicellulose and cellulose, and the calorimetric behavior of the torrefied biomass, of five tropical woody species (Cupressus lusitanica, Dipteryx panamensis, Gmelina arborea, Tectona grandis and Vochysia ferruginea), at three temperatures (TT) and three torrefaction times (tT) using a thermogravimetric analyzer. Through a multivariate analysis of principal components (MAPC), the most appropriate torrefaction conditions for the different types of woody biomass were identified. The thermogravimetric analysis-derivative thermogravimetry (TGA-DTG) analysis showed that a higher percentage of the hemicellulose component of the biomass degrades, followed by cellulose, so that the hemicellulose energy of activation (Ea) was less than that of cellulose. With an increase in TT and tT, the Ea for hemicellulose decreased but increased for cellulose. The calorimetric analyses showed that hemicellulose is the least stable component i... [more]

Astaxanthin is a valuable carotenoid, which has been approved as a food coloring by the US Food and Drug Administration and is considered as a food dye by the European Union (European Commission). This work aimed to attain Rhodosporidium toruloides mutants for enhanced astaxanthin accumulation using ultraviolet (UV) and gamma irradiation mutagenesis. Gamma irradiation was shown to be more efficient than UV for producing astaxanthin-overproducer. Among the screened mutants, G17, a gamma-induced mutant, exhibited the highest astaxanthin production, which was significantly higher than that of the wild strain. Response surface methodology was then applied to optimize the medium compositions for maximizing astaxanthin production by the mutant G17. The optimal medium compositions for the cultivation of G17 were determined as a peptone concentration of 19.75 g/L, malt extract concentration of 13.56 g/L, and glucose concentration of 19.92 g/L, with the maximum astaxanthin yield of 3021.34 µg/L... [more]

Whiskey distillery waste streams consisting of pot ale (liquid residue) and spent grain (solid residue) are high strength organic wastes and suitable feedstock for anaerobic digestion (AD) from both economic and environmental stand points. Anaerobic digestion of pot ale and pot ale/spent grain mixtures (with mixing ratios of 1:1, 1:3, and 1:5 by wet weight) was performed after implementation of a novel hybrid pre-treatment (combined chemical and mechanical) in order to modify lignocellulosic structure and ultimately enhance digestion yield. Lignin, hemicellulose, and cellulose fractions were determined before and after chemical pre-treatment. Effects of different inoculum rates (10−30−50% on wet basis) and beating times (0−7.5−15 min) on anaerobic digestion of pot ale alone and of pot ale/spent grain mixtures were investigated in lab scale batch mode with a major focus of optimising biogas yield by using response surface methodology (RSM) in Design Expert Software. The highest biogas y... [more]

Protein glycation and oxidative stress lead to severe health complications in various diseases including diabetes mellitus. The intake of flavonoid-rich foods has been confirmed previously to have a positive effect on human health. Ginger is an important source of flavonoids and is one of the most widely used traditional medicines in many Asian countries. The aim of this study was to verify the therapeutic potential of methanolic extract from ginger against glycation and other oxidative stress-induced complications using in vitro study. In this study, quantitative estimations of antioxidant components such as total phenolic and flavonoids were determined by UV−visible spectrophotometry. The anti-inflammatory action of the ginger extract was checked by determining its protective action against the denaturation of proteins, anti-proteinase activity and its membrane stabilization effect. The anti-inflammatory action of ginger extract was found to be comparable with reference standard drug... [more]

In this work, the transformation of urine into nutrients using electrolytic oxidation in a single-compartment electrochemical cell in galvanostatic mode was investigated. The electrolytic oxidation was performed using thin film anode materials: boron-doped diamond (BDD) and dimensionally stable anodes (DSA). The transformation of urine into nutrients was confirmed by the release of nitrate (NO3−) and ammonium (NH4+) ions during electrolytic treatment of synthetic urine aqueous solutions. The removal of chemical oxygen demand (COD) and total organic carbon (TOC) during electrolytic treatment confirmed the conversion of organic pollutants into biocompatible substances. Higher amounts of NO3− and NH4+ were released by electrolytic oxidation using BDD compared to DSA anodes. The removal of COD and TOC was faster using BDD anodes at different current densities. Active chlorine and chloramines were formed during electrolytic treatment, which is advantageous to deactivate any pathogenic micro... [more]

Due to climate change problems caused by greenhouse gas emissions generated by fossil fuels and from waste disposition, fuel alternatives for power generation are being extensively researched. Currently, in Brazil and in many countries, wood waste is disposed in landfills. However, due to lignin, one of the major constituents of biomass, which prevents wood waste from suffering microbial degradation, there is no significant mass degradation, even over decades, when landfilled. Hence, landfilling is not a solution to discard wood waste. Hence, one of the solutions to get rid of the great amount of wood waste is to use it as feedstock in waste-to-electricity (WTE) projects. WTE projects are in high demand in the world, as they can replace fossil fuels and they reduce two major environmental problems (greenhouse gas emissions due to the use of fossil fuels and the accumulation of waste in landfills), while generating biofuels and/or electricity. One of the residues that can be used in WTE... [more]

In this study, we evaluate potato pulp waste as a potential raw material for obtaining yeast biomass. A portion of the carbohydrates in the potato pulp waste can thereby be converted into more valuable protein. The potato pulp waste was analyzed in terms of protein and ash content, dry mass, simple sugars, and starch content. Two kinds of hydrolysis were performed (thermo-acidic and enzymatic) to produce media for cultivating Candida guilliermondii and Pichia stipitis. The hydrolysates and post-cultivation leachates were analyzed by High Performance Liquid Chromatography (HPLC). The highest biomass yield after 48 h (39.3%) was noted for Candida guilliermondii yeast grown on enzymatic hydrolysate-based medium. Our results prove that potato waste pulp is a promising raw material for the production of yeast single-cell protein (SCP).

The aim of the study was to compare the physical and sensory properties of gluten-free bread with the addition of whole and ground flax seeds. The grinding process of flax seeds was carried out using a knife grinder and ball mill. After short-knife grinding (20 s) (GM-200, Retsch), the seeds were divided into whole (average particle size 0.634 mm), coarse (769 mm) and fine (0.328 mm) flour, and these flours were additionally ground with ball milling (60 s) (Pulverisette 6, Fritsh). The grinding energy of seeds was evaluated. Baking of gluten-free bread was performed with 10% addition of different forms of whole and ground flaxseeds. The colour, volume, texture and sensory parameters of bread were evaluated. In addition, the crumbling index of bread was developed and defined as the percentage share of crumbed pieces of the bread slice in relation to the mass of the entire crumb sample cut out together with crumbs. Specific grinding energy of flaxseeds during short (20 s) knife grinding... [more]