The developments in the field of nano-additives have increased in the recent years due to the desire to reduce the level of exhaust emissions in diesel engines. The soot characteristics of particulate matter (PM) and nitrogen oxides (NOX) were experimentally investigated using two concentrations of titanium dioxide (TiO2) as nano-additives (25 ppm and 40 ppm) blended with C20D (composed of 20% castor oil methyl ester and 80% diesel fuel) and 30% exhaust gas recirculation (EGR). The combustion of C20D + TiO2 increases brake thermal efficiency (BTE) by 2.8% in comparison with neat C20D, while a significant reduction was obtained in BSFC 6.5% and NOX emissions were maintained at a level parallel with diesel. The results indicated that the technique involving a high EGR rate and the addition of 25 ppm and 40 ppm of TiO2 nanoparticles to the C20D exhibits better reductions in NOX emissions by 17.34% and 21.83%, respectively, compared to the technique comprising the use of C20D + TiO2 and C2... [more]

Nowadays, the main challenge for industrial and municipal enterprises is related to the tightening regulations and recommendations regarding environmental protection, which have been included in the circular economy (CE) package. Enterprises from all sectors, including water and sewage management, are obliged to actively participate in the CE transition. Modern wastewater treatment plants (WWTPs) should include actions aimed at a more sustainable use of available resources (water, energy, raw materials) to contribute to the protection of natural resources. In this way, they can be treated as resource facilities. This paper proposes a conceptual framework for a ‘Wastewater Treatment Plant of the Future’ that includes several technological solutions that take into account circular management of waste streams generated in WWTPs, such as wastewater (WW), sewage sludge (SS) and sewage sludge ash (SSA). Many actions have been already taken to modernize and build WWTPs that can respond to cur... [more]

There are several models for magnetic hysteresis. Their key purposes are to model magnetization curves with a history dependence to achieve hysteresis cycles without a frequency dependence. There are different approaches to handling history dependence. The two main categories are Duhem-type models and Preisach-type models. Duhem models handle it via a simple directional dependence on the flux rate, without a proper memory. While the Preisach type model handles it via memory of the point where the direction of the flux rate is changed. The most common Duhem model is the phenomenological Jiles−Atherton model, with examples of other models including the Coleman−Hodgdon model and the Tellinen model. Examples of Preisach type models are the classical Preisach model and the Prandtl−Ishlinskii model, although there are also many other models with adoptions of a similar history dependence. Hysteresis is by definition rate-independent, and thereby not dependent on the speed of the alternating f... [more]

A composite container for an electric vehicle (EV) battery module filled with a phase-change material (PCM) was experimentally tested at various discharge rates. The average cell temperatures at 1 C, 2 C, and 4 C discharge rates, respectively, might reach 38 °C, 50 °C, and 70 °C in the absence of any heat-absorbing material. The temperature was noticeably lower with PCM present than with a conventional battery module. For instance, at 4 C discharge rates, none of the battery cells inside the PCM-filled module were able to reach 70 °C. Unfortunately, the PCM addition also degraded the composite’s tensile qualities. Further investigations used Paraffin-20 and Caprylone since PCMs provide a notably different thermal performance due to their distinctive latent heat profiles. It was observed that a high melting temperature of the paraffin mixture, despite its slightly lower latent heat capacity compared to Caprylone, could lead to a more uniform temperature. Overall, both PCMs can be used a... [more]

The automotive and aerospace industries increasingly use lightweight materials to improve performance while reducing fuel consumption. Lightweight materials are frequently used in electric vehicles (EVs). However, using these materials can increase airborne and structure-borne noise. Furthermore, EV noise occurs at high frequencies, and conventional materials have small damping. Thus, there is an increasing need for procedures that help design new materials and coatings to reduce the transferred and radiated noise at desired frequencies. This study pioneered new techniques for microstructure modeling of coated and uncoated materials with improved noise, vibration, and harshness (NVH) performance. This work uses the microstructure of materials to study their vibration-damping capacity. Images from an environmental scanning electron microscope (ESEM) show the microstructure of a sample polymer and its coating. Tensile tests and experimental modal analysis were used to obtain the material... [more]

Greenhouses with efficient controlled environment offer a promising solution for food security against the impacts of increasing global temperatures and growing water scarcity. However, current technologies used to achieve this controlled environment consume a significant amount of energy, which impacts on operational costs and CO2 emissions. Using advanced metal organic framework materials (MOFs) with superior water adsorption characteristics, this work investigates the development of a new technology for a greenhouse-controlled environment. The system consists of MOF coated heat exchanger, air to air heat exchanger, and evaporative cooler. A three-dimensional computational fluid dynamics (CFD) model was developed using COMSOL software and experimentally validated for the MOF-801/Graphene coated heat exchanger (DCHE) to determine the best cycle time and power input. It was found that using desorption time of 16 min and power input of 1.26 W, the maximum water removal rate was obtained... [more]

The primary purpose of this article is to use the laws of thermodynamics, mainly the second and fourth laws, to evaluate three energy technologies of the future: fusion, solar, and fission. Among the criteria used to evaluate them, the most important are the amount of matter needed to sustain the technology itself and the environmental impact. Much emphasis is placed here on the fourth law of thermodynamics, which introduces the concept of material entropy. Zemansky−Georgescu-Roegen’s Law of Inevitable Dissipation of Useful Concentrated Matter states that, in the economic process, some matter is inevitably degraded and becomes unavailable matter. This has tremendous implications for humanity as a whole since the Earth is thermodynamically a closed system, meaning that it cannot exchange matter with space but is open to the flow of solar energy. This results in the need to conserve matter and natural resources. This law can be used as an important criterion for the selection of energy t... [more]

Gas turbines produce a large amount of NOx and CO due to high temperatures and insufficient combustion. Through the selective catalytic reduction of NO with CO (CO-SCR) in a gas turbine, the activities of the Mn-Fe-Ce/FA catalyst using fly ash (FA) as a carrier under different atmospheres were studied. The catalysts prepared by calcining different active materials under different atmospheres were used to analyze their denitrification abilities and resistance to water vapor. The denitrification performance of the catalyst prepared under reducing atmosphere is about 30 percent higher than that of the catalyst prepared under air atmosphere, and the decarburization performance is about 40 percent higher. In the presence of oxygen, the denitrification rate and decarburization rate of the 1:1 ratio of the Mn-Ce catalyst reach 67.16% and 59.57%, respectively. In an oxygen-containing atmosphere, the catalyst prepared by replacing Ce with Fe shows better denitrification and decarburization perf... [more]

Additive manufacturing (AM) or 3D printing has opened up new opportunities for researchers in the field of electrical machines, as it allows for more flexibility in design and faster prototyping, which can lead to more efficient and cost-effective production. An overview of the primary AM techniques utilized for designing electrical machines is presented in this paper. AM enables the creation of complex and intricate designs that are difficult or impossible to achieve using traditional methods. Topology Optimization (TO) can be used to optimize the design of parts for various purposes such as weight, thermal, material usage and structural performance. This paper primarily concentrates on the most recent studies of the AM and TO of the reluctance machines. The integration of AM with TO can enhance the design and fabrication process of magnetic components in electrical machines by overcoming current manufacturing limitations and enabling the exploration of new design possibilities. The t... [more]

Paraffin phase change materials (PCMs) exhibit great potential in battery thermal management (BTM); nevertheless, their application has been hampered by the handicap of low thermal conductivity, leakage, and volume expansion during phase transition. In this work, ternary composite PCMs formed of paraffin, expanded graphite (EG), and low-density polyethylene (LDPE) were developed for application in BTM. The structure and properties of the composite PCMs were characterized via X-ray diffraction, scanning electron microscopy, differential scanning calorimetry, and thermal constant analysis. The result shows that EG can form a large-size graphite frame as heat conduction paths to improve the thermal conductivity of the composite PCM, and LDPE can form an interpenetrating network within the composite PCM to resist the internal stress of paraffin expansion and prevent deformation. The latent heat and thermal conductivity of the composite PCMs loaded with 10 wt% EG and 4 wt% LDPE can reach 17... [more]

A nanofluid is composed of a base fluid with a suspension of nanoparticles that improve the base fluid’s thermophysical properties. In this work, the authors have conducted experimental tests on an alumina-based nanofluid (Al2O3/H2O) moving inside a 3D-printed lattice channel. The unit cell’s lattice shape can be considered a double X or a double pyramidal truss with a common vertex. The test channel is 80 mm long and has a cross-sectional area, without an internal lattice with that has the dimensions H × W, with H = 5 mm and W = 15 mm. A nanofluid and a lattice duct can represent a good compound technique for enhancing heat transfer. The channel is heated by an electrical resistance wound onto its outer surface. The heat transfer rate absorbed by the nanofluid, the convective heat transfer coefficients, and the pressure drops are evaluated. The experimental tests are carried out at various volumetric contents of nanoparticles (φ = 1.00%, φ = 1.50% and φ = 2.05%) and at various volumet... [more]

One of the challenges posed by renewable energies is the stabilization of parameters related to the quality of electrical energy. This study demonstrates the existence of a relationship between input blocks of hydropower and the variation of the fundamental frequency of the electricity grid. By mapping production data provided by the Spanish Electric Network with frequency measured in the laboratory, it is shown that gradients of hydropower are correlated with frequency fluctuations for certain characteristic times. Considering hourly instances of energy input, the study compares two methods for calculating hydropower gradients (linear regression and pseudo-linear regression) and two methods for calculating local frequency extrema (the “specular inertia” method and analysis by comparison with the moving average) in order to corroborate the results.

Porous carbon materials (PCs) were prepared via hydrothermal carbonization from calcium lignosulfonate (CL) based on enzymatic hydrolysis and alkali activation. The effects of enzymatic hydrolysis and different KOH feeding ratios on the structure and electrochemical properties of enzymatic hydrolysis CL (EHCL)-derived PCs were evaluated in detail. The results showed that the EHCL-derived PCs showed a higher SSA than that of CL. When the mass ratio of KOH/EHCL was 3/2, the PCs exhibited a honeycomb-like microscopic morphology with a specific surface area of up to 1771 m2/g and a 3D hierarchical porous structure composed of abundant micropores, mesopores, and macropores. As an electrode in a supercapacitor, the highest specific capacitance was 147 F/g at a current density of 0.25 A/g, and it maintained 78% of the initial value at a high current density of 10 A/g. The excellent electrochemical cycle and structural stability were confirmed on the condition of a higher capacitance retention... [more]

Analyzing and mastering the fractal features of coal-measure sedimentary rocks is crucial for accurately describing the pore structure of coalbed methane resources. In this work, mercury intrusion porosimetry (MIP) and nuclear magnetic resonance (NMR) are performed on coal-measure sedimentary rocks (i.e., shale, mudstone, and sandstone) to analyze their pore structure. Pore size distributions (PSDs) and the multifractal dimensions of the investigated samples are discussed. Moreover, multivariable linear regression models of multifractal dimensions are established through a comprehensive analysis of multifractal characteristics. The results show that sandstone (SS-1) and clay rocks are dominated by nanopores of 0.01 to 1 μm, while sandstone (SS-2) is mostly mesopores and macropores in the range of 1 to 10 μm. The fractal characteristics of the investigated rock samples show a prominent multifractal characteristic, in which DA reflects the surface structure of micropores, while DS repres... [more]

As the essential component of shale, clay minerals have a vital influence on the pore structure and the gas content of reservoirs. To investigate the compositional characteristics of coal-measure shale and its effects on pore structure, a total of thirteen Taiyuan formation shale samples were collected from the Qinshui Basin and were analyzed using a combination of X-ray diffraction analysis, X-ray fluorescence spectrometry, Fourier transform infrared spectroscopy (FE-SEM), polarized optical microscopy, and field emission scanning electron microscopy. The results show that the principal minerals of the samples are quartz, kaolinite, and illite. Most of the kaolinite was an original terrigenous detrital material with low crystallinity and a low degree of ordering, whereas the illite was mainly composed of 1Md resulting from diagenesis. Clay minerals developed slits, irregularly-shaped or multisized pores during diagenesis, which can be classed into interlayered pores, intergranular pore... [more]

This study concerns the numerical simulation and the experimental implementation of a low-scale Phase Change Material-based (PCM-based) condenser, to be included in a PCM-based portable cooling systems. In this category of cooling systems, the PCM can be integrated either in the condenser or in the evaporator. In the present study, the PCM is integrated in the condenser of the vapor compression cycle to absorb the heat power released from the refrigerant fluid (R134a) during condensation, thus eliminating the need to transfer heat to the external environment. The main objective of the present study is to realize and validate a numerical model capable of simulating both the refrigerant fluid and the PCM thermofluid dynamics. For this purpose, a commercial solver was used for the implementation of the developed numerical model, and experimental tests were performed to validate the numerical simulations results. The paper reports the details and test results of both the numerical model an... [more]

Electrospray ionization (ESI) coupled with high-resolution mass spectrometry (HRMS) is rapidly developing into a powerful tool for the molecular characterization of petroleum fractions. However, the occurrence of ion−molecule aggregates seriously affects the interpretation of the mass spectrometry results. Ion−molecule aggregates are not inherent compounds in petroleum but they are produced during the analysis of petroleum samples by high-resolution mass spectrometry. Also, the classes of aggregates are the same as many compounds in petroleum. Therefore, the removal of these species is crucial, and their analysis from methods of dissociation and mechanism points of view is essential for this purpose. In this study, aggregates of a vacuum gas oil fraction were analyzed and the types were defined. The compositions of the aggregates were characterized by changing operating conditions. Several factors affecting the aggregates were evaluated by a parameter of dissociation efficiency. By est... [more]

Submicron-structured films of thermoelectric materials, exhibiting an improved thermoelectric figure of merit, are reviewed, including methods of fabrication and characterization. The review emphasizes the beneficial role of the grain boundaries in polycrystalline films. The enhanced Seebeck coefficient of lead chalcogenide films is attributed to a potential relief that is built along the grain boundaries. It scatters charge carriers with low energy and does not affect carriers with higher energy. The model that accounts for the thermoelectric properties of the films is described and assessed experimentally. The application of a flexible thermoelectric device (module) based on the nanocrystalline film thermoelectric semiconductors as high sensitivity radiation detectors is suggested.

Experimental data associated with the thermophysical properties (TPPs) of various nanofluids (NFs) are essential for their diverse applications in energy storage and conversion, as well as thermal management. This study experimentally investigated important TPPs such as thermal conductivity (TC), thermal diffusivity, density and viscosity, as well as the electrical conductivity of two new types of NFs, namely silica (SiC) and boron nitride (BN) nanofluids. The NFs are prepared at five low concentrations of nanoparticles from 0.01 to 0.05 vol.% dispersed into a mixture of ethylene glycol (EG) and distilled water (DW). The TPPs are measured, and their enhancements are evaluated in comparison with their base fluids. The results show a good increase in TC and thermal diffusivity for both types of nanofluids with increasing concentrations until reaching the maximum enhancement of about 4.4% for the SiC nanofluid and about 7.0% for the BN nanofluid at the same concentration (0.05 vol.%). On... [more]

Li metal has been considered an ideal anode in lithium batteries due to its high theoretical capacity of 3860 mAh·g−1 and lowest negative reduction potential of −3.040 V among the standard hydrogen electrodes. However, lithium dendrites can easily grow on the surface of the negative electrode during charging, which results in a short circuit of the battery and reduces its efficiency. This paper investigated dendrite growth and inhibition mechanisms in lithium metal batteries to improve battery life. The impacts of the initial nucleation spacing, surface energy anisotropy strength, and interfacial electrochemical driving force on lithium dendrite growth were analyzed with electrochemical experiments and mathematical models. The results showed that the smaller nucleation spacing inhibits the growth of dendrite side branches and reduces the roughness of lithium metal deposition on the negative electrode. A lower interfacial energy anisotropy strength can slow down the growth of dendrite t... [more]

In this article, the most important publications on the subject are compiled to highlight the progress in biodiesel production from tropical cultivars, including energy and environmental potential, raw materials, and the advantages and disadvantages of this biofuel. A critical and objective review of biodiesel production as an alternative fuel for power generation systems and its importance in the energy matrix was conducted. A survey of real applications, new computational and experimental trends, and proposals in internal combustion engines employing organic biofuel was performed. The main findings were as follows: (i) there is the possibility of integration and support in the energy matrix of different countries, as well as the competing with and complementing, energetically, other renewable energy sources, such as solar and wind; (ii) Jatropha curcas, sunflowers, soybean, Moringa oleifera, palm, cottonseed, castor, rubber seed, and coconut are tropical cultivars used to obtained oi... [more]

Phase change materials are used in passive solar house construction with light steel structure walls, which can overcome the problems of weak heat storage capacity and poor utilization of solar heat and effectively solve the thermal defects of light steel structure walls. Based on this, on the basis of preliminary experimental research, this study further carried out theoretical analysis and simulation research on the thermal performance of a light steel structure passive solar house (Trombe form) with PCM walls. Through the heat balance analysis of heat transfer in the heat collecting partition wall, the theoretical calculation formula of the phase change temperature of the PCM was obtained, and it verified theoretically that the phase change temperature value should be 1−3 °C higher than the target indoor air temperature. The evaluation index “accumulated daily indoor temperature offset value” was proposed for evaluating the effect of phase change materials on the indoor temperature... [more]

Rods and plates at the connections in composite insulating material towers are commonly fixed to each other by metal bolts, which may cause electrical field distortion at the connections. So, the rod−plate connections are prone to partial discharge under polluted and wet conditions, and the resulting electric field and temperature changes can affect the mechanical and electrical performance of the whole tower. In this paper, an artificial pollution test synchronous observation platform with an infrared and visible light imager, leakage current, and voltage measurement was built to observe the dry band formation and partial discharge at the simplified rod−plate connections in the composite towers. Then, the electric field simulation of the rod−plate connection specimen showed the current density distribution. When combining the test and the simulation, it was concluded that the cause of the partial discharge was the distortion of the current density and, thus, measures to suppress the p... [more]

This work uses a hole-transporting copper cobaltite/copper oxide nanocomposite to fabricate carbon-based MAPbI3 PSCs. The copper cobaltite/copper oxide HTM-based PSC results show the highest power conversion efficiency (PCE = 7.32%) compared with an HTM-free device. The highest photocurrent density (Jsc = 15.17 mA/cm2), open-circuit voltage (Voc = 0.82 V), and fill factor (FF = 0.59) are achieved for the PSC fabricated with hydrothermally synthesized copper cobaltite/copper oxide nanocomposites. Electrochemical impedance spectroscopy is used to analyze the charge transfer resistance (Rs) and the capacitive behavior of copper cobaltite/copper oxide nanocomposite. The maximum electron lifetime of 35.16 μs is witnessed for the PSCs fabricated with 3 mg mL−1 of copper cobaltite/copper oxide (H1). The efficiency of the copper cobaltite/copper oxide-based PSC remains unchanged, showing no further perovskite layer degradation.

Vacuum Insulation Panels (VIPs) provide significant adiabatic performance for heat/cooling systems to reduce energy consumption. The application of fibrous porous material (FPM) as the ideal core of VIPs has gained global attention in recent decades. The microstructure and physical properties of FPMs, filled as novel VIPs’ core material, and holding superior thermal performance, affected effective thermal conductivity (ETC) greatly. Aiming to deeply understand heat transfer mechanisms, a holistic simulation method that combined with a developed 3D FPM structure generation method and a D3Q15-Lattice Boltzmann method (LBM) is proposed to simulate the heat transfer in FPM and to illuminate the influence factors of ETC on the microstructure of FPM in a vacuum. The improved and modified mesoscopic 3D fibrous random micro-structure generation approach involved five structural parameters: generation probability of nucleus growth, fiber length, diameter, coincidence rate, and orientation angle... [more]