The building sector is known to have a significant environmental impact, considering that it is the largest contributor to global greenhouse gas emissions of around 36% and is also responsible for about 40% of global energy consumption. Of this, about 50% takes place during the building operational phase, while around 10−20% is consumed in materials manufacturing, transport and building construction, maintenance, and demolition. Increasing the necessity of reducing the environmental impact of buildings has led to enhancing not only the thermal performances of building materials, but also the environmental sustainability of their production chains and waste prevention. As a consequence, novel thermo-insulating building materials or products have been developed by using both locally produced natural and waste/recycled materials that are able to provide good thermal performances while also having a lower environmental impact. In this context, the aim of this work is to provide a detailed... [more]

A theoretical analysis of the influence of temperature and nanoparticle concentration on free convection heat transfer from a horizontal tube immersed in an unbounded nanofluid was presented. The Nusselt (Nu) number and heat transfer coefficient were parameters of the intensity of the convective heat transfer. For free convection, the Nu number was a function of the Rayleigh (Ra) number and Prandtl (Pr) number. The Rayleigh (Ra) number and Prandtl (Pr) number were functions of the thermophysical properties of nanofluids. The thermophysical properties of nanofluids varied with temperature and nanoparticle concentration. Therefore, an analysis was conducted to evaluate the effects on the performance of nanofluids due to variations of thermal conductivity, viscosity, thermal expansion, density, and specific heat, which are functions of nanoparticle concentration and temperature. Water- and ethylene glycol (EG)-based nanofluids with dispersed alumina (Al2O3) nanoparticles at mass concentra... [more]

High temperature and overheating of photovoltaic panels lead to efficiency losses and eventual degradation. For solar PV systems, this is a significant impediment for achieving economic viability. In this study, a novel Window-Integrated Concentrated Photovoltaic (WICPV) system is proposed for window integration. This offers high (50%) transparency and is fabricated and characterised indoors at an irradiance of 1000 Wm−2. Its electrical performance is tested (a) without applied cooling (i.e., under natural ventilation) and (b) with a heat sink to accommodate passive cooling media. The results are compared to study the effects of reduction in operating temperature on system performances. The effectiveness of a sensible cooling medium (water) and two latent heat removal media, phase change materials (or PCMs, RT50 and RT28HC), is investigated. This paper reports the passive temperature regulation of this WICPV at ambient testing conditions. The results demonstrate an increase in electric... [more]

The generation and use of energy are significant contributors to CO2 emissions. Globally, approximately 30% to 40% of all energy consumption can be directly or indirectly linked to buildings. Nearly half of energy usage in buildings is linked to maintaining the thermal comfort of the inhabitants. Therefore, finding solutions that are not only technically but also economically feasible is of utmost importance. Though much research has been conducted to address this issue, most solutions are still costly for developing countries to implement practically. This study endeavors to find a less expensive yet straightforward methodology to achieve thermal comfort while conserving energy. This study takes a broader view of multiple habitat-related CO2 emission issues in developing regions and describes a hybrid solution to address them. New technologies and innovative concepts are being globally examined to benefit from the considerable potential of PCMs and their role in thermal energy storage... [more]

The paper presents an innovative method for smoothing fluctuations of heat flux, using the thermal energy storage unit (TES Unit) with phase change material and Artificial Neural Networks (ANN) control. The research was carried out on a pilot large-scale installation, of which the main component was the TES Unit with a heat capacity of 500 MJ. The main challenge was to smooth the heat flux fluctuations, resulting from variable heat source operation. For this purpose, a molten salt phase change material was used, for which melting occurs at nearly constant temperature. To enhance the smoothing effect, a classical control system based on PID controllers was supported by ANN. The TES Unit was supplied with steam at a constant temperature and variable mass flow rate, while a discharging side was cooled with water at constant mass flow rate. It was indicated that the operation of the TES Unit in the phase change temperature range allows to smooth the heat flux fluctuations by 56%. The tests... [more]

A diamond’s color grading is a dominant property that determines its market value. Its color quality is dependent on the light transmittance through the diamond and is largely influenced by nitrogen contamination, which induces a yellow/brown tint within the diamond, as well as by structural defects in the crystal (in rare cases boron contamination results in a blue tint). Generally, spectroscopic instrumentation (in the infrared or UV−visible spectral range) is used in industry to measure polished and rough diamonds, but the results are not accurate enough for precise determination of color grade. Thus, new methods should be developed to determine the color grade of diamonds at longer wavelengths, such as microwave (MV). No difference exists between rough and polished diamonds regarding stray light when the MW frequency is used. Thus, several waveguides that cover a frequency range of 3.95−26.5 GHz, as well as suitable resonator mirrors, have been developed using transmission/reflecti... [more]

In view of potential uses in short-term thermochemical heat storage by sorption of water vapor, the capacity to release a sufficient heat amount at the appropriate rate of a Prussian blue analogue (PBA) containing hexacyanocobaltate vacancies has been compared with those of 13X type zeolites possessing Na+, Ce3+, Ce4+, or Tb3+ extra-framework compensating cations. The extended structural and surface characterization demonstrated good reproducibility of the preparation procedures performed on a 10-g scale. The adsorbents were tested under dynamic conditions of gas flow with the aid of either a gas flow calorimeter (120 mL h−1 helium flow) to measure the amount and rate of the integral heat release or a laboratory-scale test rig (15,000 to 22,800 mL h−1 nitrogen flow) to monitor the outlet temperature of nitrogen heated by adsorption. For a regeneration temperature of 353 K and a partial H2O pressure of 2.8 kPa in helium, the PBA sample yielded an integral heat ranging between 900 and 10... [more]

Degradation of electrode microstructure is one of the key factors affecting long term performance of Solid Oxide Fuel Cell systems. Evolution of a multiphase system can be described quantitatively by the change in its interfacial energy. In this paper, we discuss free energy of a microstructure to showcase the anisotropy of its evolution during a long-term performance experiment involving an SOFC stack. Ginzburg Landau type functional is used to compute the free energy, using diffuse phase distributions based on Focused Ion Beam Scanning Electron Microscopy images of samples taken from nine different sites within the stack. It is shown that the rate of microstructure evolution differs depending on the position within the stack, similar to phase anisotropy. However, the computed spatial relation does not correlate with the observed distribution of temperature.

A special element of road safety research is accidents at the interface of the road and rail system. Due to their low share in the total number of incidents, they are not a popular subject of analyses but rather an element of collective studies, whereas the specificity of the road−rail accidents requires a separate characteristic, allowing, on the one hand, to categorize these types of incidents, and on the other, to specify the factors that affect them, along with an assessment of the strength of this impact. It is important to include in such analyses all potential predictors, both qualitative and quantitative. Moreover, the literature considers most often a number of accidents while, according to the authors, it does not fully reflect the scale of the danger. A better evaluation would be the victim’s degree of injury. Therefore, the purpose of this article is to assess the likelihood of occurrence of various effects of road−rail accidents in the aspect of selected factors. Due to th... [more]

The refurbishment of the building stock is a key strategy towards the achievement of the climate and energy goals of the European Union. This study aims at evaluating the energy and environmental impacts associated with retrofitting a residential apartment to improve its vertical envelope thermal insulation. Two insulation materials, stone wool and cellulose fibers, are compared. The life cycle assessment methodology is applied assuming 1 m2 of retrofitted vertical envelope as functional unit. Moreover, to estimate the net energy and environmental benefits achievable in the retrofitted scenario compared with the non-retrofitted one, a second analysis is performed in which the system boundaries are expanded to include the building operational phase, and 1 m2 of walkable floor per year is assumed as reference. The results show that the use of cellulose fibers involve lower impacts in most of the assessed categories compared to stone wool, except for abiotic resource depletion. In detail,... [more]

The presence of different pollutants in recycled plastics is reviewed in this article. The desirable circular economy of plastics should be linked to the availability of clean recycled plastics with a non-significant and small to nil amount of substances of concern. Different researchers found polycyclic aromatic hydrocarbons (PAHs) and Persistent Organic Pollutants (POPs), such as brominated flame retardants (BFRs), pesticides, dioxins and furans (PCDD/Fs and PBDD/Fs) in plastic recyclates. This represents an added difficulty to the effective recycling process of plastics that reduces the demand for energy and materials, in addition to posing a great environmental danger since they represent a vector of accumulation of the contaminants that will finally appear in the most unexpected products. Life Cycle Analysis of the plastic wastes recycling process indicates a great saving of energy, water and CO2 emissions.

The research project Fraunhofer Cluster of Excellence “Programmable Materials” aims to develop new materials that can change their properties according to defined boundaries. This article describes the development and use of a novel programmable phase change material (PCM) for latent heat storage applications. At the moment, these PCMs have a programmable trigger mechanism incorporated that activates the crystallization of the material as a reaction to a defined stimulus so that the stored heat is released. In future development stages, programmability is to be integrated on the material level. The latent heat storage that is based on PCMs can be recharged by using the energy of the sun. As an example, for a possible application of such a material, the use of a novel programmable PCM in greenhouses to support heating energy reduction or to reduce the risk of frost is explained. Using the hygrothermal simulation tool WUFI® Plus, the effects in greenhouse constructions without and with c... [more]

The article investigated the possibility of reusing heat resistant glass cullet to improve the mechanical properties of high-temperature composites. This is an excellent recycled aggregate that may be used as a substitute for alumina cement, and for fine natural aggregate in the production of concrete based on hydraulic binder. The experimental programme comprised of strength testing conducted on 40 × 40 × 160 mm cuboidal samples. The model mixture was modified by filler that comprised glass recyclate, amounting to 5%, 10%, and 15% of the mass of gravel and cement. Given the degree of glass grounding, use was made of two fractions, 0/4 and 0/0.125 mm. Six modified mixtures were produced. Tests were then carried out on their selected physical and mechanical properties as well as the impact of temperature, topography, and chemical composition exerted on the composite. Next, the progress and development of compressive strength and flexural strength after 14 and 28 days of curing were stud... [more]

Signs of wetness in housing are a significant obstacle to the renovation and energy rehabilitation of old and energy-intensive heritage buildings, especially in cold climates. Thus, in order to avoid the numerous possibilities of degradation caused by the moisture transfer phenomena in the building envelope, the a disruptive aeraulic process, which focuses on the ventilation of an air gap between the thermal insulation and the wet wall, has been designed and its assessed. This system avoids the presence of liquid water at the wall surface by maintaining the hygrothermal balance within the wet wall. This enables the mechanical durability of the supporting structure, the absence of biological activity and/or frost and, hence, the durability of the thermal insulation. These issues are investigated through a case study based on a real site. Over a year of measurements, the wet wall was constantly maintained in hygroscopic balance, around 90% RH, guaranteeing the preservation of its mechani... [more]

This paper presents the comprehensive analysis of the sub-microwave, radio frequency band resonant metastructures’ electromagnetic properties with a particular emphasis on the possibility of their application in energy harvesting systems. Selected structures based on representative topologies of metamaterials have been implemented in the simulation environment. The models have been analyzed and their substitute average electromagnetic parameters (absorption, reflection, transmission and homogenized permeability coefficients) have been determined. On the basis of simulation research, prototypes of electromagnetic field two-dimensional absorbers have been manufactured and verified experimentally in the proposed test system. The absorber has been implemented as a component of the low-cost energy harvesting system with a high-frequency rectifier and a voltage multiplier, obtaining usable DC energy from the electromagnetic field in certain frequency bands. The energy efficiency of the syste... [more]

The fine particulate matter (PM) emitted from jet aircraft poses a serious threat to the environment and human health which can be mitigated by using biofuels. This paper aims to quantify PM emissions from a small turbofan fueled with the alcohol to jet (ATJ) synthetic kerosene and its various blends (5%, 20%, and 30% of ATJ) with Jet A-1 fuel. Emissions from a turbofan engine (DGEN 380) with a high bypass ratio, applicable in small private jets, were studied. Among the four fuels tested, the PM-number emission index (EIN) was the lowest for the ATJ 30% blend. EIN for ATJ 30% dropped from 1.1 × 1017 to 4.7 × 1016 particles/kg of fuel. Burning alternative fuel blends reduced the particle mass emissions over the entire range of fuel flow by at least 117 mg/kg of fuel. The particles formed in the nucleation mechanism dominate PM emission, which is characteristic of jet engines. Thus, number-based particle size distributions (PSDs) exhibit a single mode log-normal distribution. The highest... [more]

The hydrodynamic conditions resulting from the permeability of porous materials are based not only on the assessment of the gas flow through these materials, but also the losses related to the pressure energy in this flow. Flow resistance is a direct measure of this loss. The aim of this experimental research was to evaluate the flow resistance of the porous material in relation to the gas flow. The research was carried out on a material with a slit-porous structure. The tests were carried out on a system for measuring gas permeability under the conditions of gas bubbling through the char. The issue of the total pressure drop process in the porous bed was considered in the Reynolds number category. The coefficient of flow resistance for the char was determined and the value of this coefficient was compared with the gas stream, and an experimental evaluation of the total pressure drop on the porous bed was made. The novelty of this article is the determination of the tortuosity and the... [more]

As a part of our research in the field of thermochemical energy storage, this study aims to investigate the potential of three fly ash samples derived from the fluidized bed reactors of three different pulp and paper plants in Austria for their use as thermochemical energy (TCES) and CO2 storage materials. The selected samples were analyzed by different physical and chemical analytical techniques such as X-ray fluorescence spectroscopy (XRF), X-ray diffraction (XRD), particle size distribution (PSD), scanning electron microscopy (SEM), inductively coupled plasma atomic emission spectroscopy (ICP-OES), and simultaneous thermal analysis (STA) under different atmospheres (N2, CO2, and H2O/CO2). To evaluate the environmental impact, leaching tests were also performed. The amount of CaO as a promising candidate for TCES was verified by XRF analysis, which was in the range of 25−63% (w/w). XRD results indicate that the CaO lies as free lime (3−32%), calcite (21−29%), and silicate in all fly... [more]

Sustainable fuel-range hydrocarbons can be produced via the catalytic decarboxylation of biomass-derived carboxylic acids without the need for hydrogen addition. In this present study, 5 wt% platinum on carbon (Pt/C) has been found to be an effective catalyst for hydrothermally decarboxylating butyric acid in order to produce mainly propane and carbon dioxide. However, optimisation of the reaction conditions is required to minimise secondary reactions and increase hydrocarbon selectivity towards propane. To do this, reactions using the catalyst with varying parameters such as reaction temperatures, residence times, feedstock loading and bulk catalyst loading were carried out in a batch reactor. The highest yield of propane obtained was 47 wt% (close to the theoretical decarboxylation yield of 50 wt% on butyric acid basis), corresponding to a 96% hydrocarbon selectivity towards propane. The results showed that the optimum parameters to produce the highest yield of propane, from the rang... [more]

This work examines the effects of the known boundary conditions on the accuracy of the solution in one-dimensional inverse heat conduction problems. The failures in many applications of these problems are attributed to inaccuracy of the specified constants and boundary conditions. Since the boundary conditions and material properties in most thermal problems are imposed with uncertainty, the effects of their inaccuracy should be understood prior to the inverse analyses. The deviation from the exact solution has been examined for each case according to the errors in material properties, boundary location, and known boundary conditions. The results show that the effects of such errors are dramatic. Based on these results, the applicability and limitations of the inverse heat conduction analyses have been evaluated and discussed.

Nanofluids have great potential to improve the heat transfer properties of liquids, as demonstrated by recent studies. This paper presents a novel idea of utilizing nanofluid. It analyzes the performance of a HVAC (Heating Ventilation Air Conditioning) system using a high-performance heat transfer fluid (water-glycol nanofluid with nanoparticles of Al2O3), in the university campus of Lecce, Italy. The work describes the dynamic model of the building and its heating and cooling system, realized through the simulation software TRNSYS 17. The use of heat transfer fluid inseminated by nanoparticles in a real HVAC system is an innovative application that is difficult to find in the scientific literature so far. This work focuses on comparing the efficiency of the system working with a traditional water-glycol mixture with the same system that uses Al2O3-nanofluid. The results obtained by means of the dynamic simulations have confirmed what theoretically assumed, indicating the working condi... [more]

To design a residential or commercial building with high energy performance that would be economical at the same time, an analysis was performed that relates these two aspects of the problem. The first aspect is focused on evaluation of the thermal performance of a multi-layered wall in order to achieve the lowest energy consumption for heating and cooling. The second aspect of the analysis covered the choice of materials (type, thickness and price) so that the building has the lowest possible construction costs, but the best achieved thermal comfort. The three types of external walls with the same structure were analyzed in this paper. The lowest and highest values of the layer thickness offered by the manufacturer were chosen and their dynamic characteristics for the heat transfer were calculated. The following step was to perform optimization of the objective function, which was defined by the unit price of the material per mass of the material, that is, the economical aspect was pr... [more]

In this work, Ni0.5Zn0.5Fe2O4 is synthesized as binder-based (NZF) and binder-free electrodes (NZF@NF). The binder-free electrode is directly synthesized on nickel foam via facile hydrothermal techniques. The crystalline phase of both of these electrodes is examined through X-ray diffraction. Their morphology is investigated by scanning electron microscopy (SEM) and high-resolution transmission electron microscopy (TEM), which revealed the well-defined nanostructure with the shape like thin hexagonal platelets. The chemical composition is verified by energy dispersive spectroscopy (EDS). Their electrochemical properties are analyzed by cyclic voltammetry (CV), galvanostatic charge−discharge (GCD), and electrochemical impedance spectroscopy (EIS). The NZF@NF electrode has outperformed the binder-based NZF electrode in terms of electrochemical performance owing to the 3D interconnected structure of the nickel foam. The NZF@NF electrode has delivered a high specific capacity of 504 F g−1... [more]

Additive manufacturing of ferromagnetic materials for electrical machine applications is maturing. In this work, a full E-type transformer core is printed, characterized, and compared in terms of performance with a conventional Goss textured core. For facilitating a modular winding and eddy current loss reduction, the 3D printed core is assembled from four novel interlocking components, which structurally imitate the E-type core laminations. Both cores are compared at approximately their respective optimal working conditions, at identical magnetizing currents. Due to the superior magnetic properties of the Goss sheet conventional transformer core, 10% reduced efficiency (from 80.5% to 70.1%) and 34% lower power density (from 59 VA/kg to 39 VA/kg) of the printed transformer are identified at operating temperature. The first prototype transformer core demonstrates the state of the art and initial optimization step for further development of additively manufactured soft ferromagnetic comp... [more]

Battery degradation is a fundamental concern in battery research, with the biggest challenge being to maintain performance and safety upon usage. From the microstructure of the materials to the design of the cell connectors in modules and their assembly in packs, it is impossible to achieve perfect reproducibility. Small manufacturing or environmental variations will compound big repercussions on pack performance and reliability. This review covers the origins of cell-to-cell variations and inhomogeneities on a multiscale level, their impact on electrochemical performance, as well as their characterization and tracking methods, ranging from the use of large-scale equipment to in operando studies.