Photocatalysis is a classical solution to energy conversion and environmental pollution control problems. In photocatalysis, the development and exploration of new visible light catalysts and their synthesis and modification strategies are crucial. It is also essential to understand the mechanism of these reactions in the various reaction media. Recently, bismuth and graphene’s unique geometrical and electronic properties have attracted considerable attention in photocatalysis. This review summarizes bismuth-graphene nanohybrids’ synthetic processes with various design considerations, fundamental mechanisms of action, heterogeneous photocatalysis, benefits, and challenges. Some key applications in energy conversion and environmental pollution control are discussed, such as CO2 reduction, water splitting, pollutant degradation, disinfection, and organic transformations. The detailed perspective of bismuth-graphene nanohybrids’ applications in various research fields presented herein sho... [more]

Since the introduction of Perovskite Solar Cells, their photovoltaic efficiencies have grown impressively, reaching over 25%. Besides the exceptional efficiencies, those solar cells need to be improved to overcome some concerns, such as their intrinsic instability when exposed to humidity. In this respect, the development of new and stable Hole Transporting Materials (HTMs) rose as a new hot topic. Since the doping agents for common HTM are hygroscopic, they bring water in contact with the perovskite layer, thus deteriorating it. In the last years, the research focused on “dopant-free” HTMs, which are inherently conductive without any addition of dopants. Dopant-free HTMs, being small molecules or polymers, have still been a relatively small set of compounds until now. This review collects almost all the relevant organic dopant-free small-molecule HTMs known so far. A general classification of HTMs is proposed, and structure analysis is used to identify structure−property relationships... [more]

In this paper, a hybrid electric power supply system for an electric vehicle (EV) is investigated. The study aims to reduce electric stress on the main energy source (fuel cell) and boost energetic performances using energy sources with high specific power (supercapacitors, batteries) for rapid traction chain solicitations such as accelerations, decelerations, and braking operations. The multisource EV power supply system contains a fuel cell stack, a lithium batteries module, and a supercapacitors (Sc) pack. In order to emulate the EV energy demand (wheels, weight, external forces, etc.), a bidirectional load based on a reversible current DC-DC converter was used. Fuel cell (Fc) stack was interfaced by an interleaved boost converter. Batteries and the Sc pack were coupled to the DC point of coupling via buck/boost converters. Paper contribution was firstly concentrated on the distribution of energy and power between onboard energy sources in consonance with their dynamic characteristi... [more]

Latent heat storage systems are a promising technology for storing and providing thermal energy with low volume, mass and cost requirements, especially when operated at high temperatures. Metallic phase change materials are particularly advantageous for high thermal input and output, which is especially important for mobile applications. When designing a storage system, it is essential to have precise knowledge about the potential storage capacity. However, the system’s storage capacity is typically calculated from material properties determined at lab scale, although systemic boundary conditions can have a considerable influence. Systemic influences can result from thermal and reactive interfaces or from the storage design. In order to consider these influences, we propose three calorimetric procedures to thermally analyse high-temperature metallic latent energy storage systems at an application scale. We examined the procedures in a transient simulation environment, monitoring the st... [more]

The characterization of materials, stress and fatigue state monitoring based on the acoustoelastic principle are gaining widespread attention in recent years, mainly due to their advantages such as high sensitivity and non-destructive character. This article presents the application of a non-destructive acoustic method to test the degree of degradation of materials with which the heating boiler is coated. The combustion chamber is covered in materials when the temperature of the process itself increases, and has a very positive effect on fuel combustion. Unfortunately, with the passage of time, such materials undergo gradation. This article describes an innovative measuring system that has been successfully applied to monitor changes in resonance frequency under uniaxial compression in refractory grade material, which by definition is characterized by a high level of heterogeneity with a network of pre-existing cracks. The paper indicates that both stress and elasticity coefficients ha... [more]

The structure and performance of promoted Ni/Al2O3 with Cu via thermocatalytic decomposition (TCD) of CH4 mixture (2% CH3OH) were studied. Mesoporous Cat-1 and Cat-2 were synthesized by the impregnation method. The corresponding peaks of nickel oxide and copper oxide in the XRD showed the presence of nickel and copper oxides as a mixed alloy in the calcined catalyst. Temperature program reduction (TPR) showed that Cu enhanced the reducibility of the catalyst as the peak of nickel oxide shifted toward a lower temperature due to the interaction strength of the metal particles and support. The impregnation of 10% Cu on Cat-1 drastically improved the catalytic performance and exhibited 68% CH4 conversion, and endured its activity for 6 h compared with Cat-1, which deactivated after 4 h. The investigation of the spent carbon showed that various forms of carbon were obtained as a by-product of TCD, including graphene fiber (GF), carbon nanofiber (CNF), and multi-wall carbon nanofibers (MWCNF... [more]

Mobilizing industry and transforming industrial sectors to a circular economy (CE) is one of the key areas of activities in the European Green Deal (EGD)—the newest strategy of economic growth in European Union (EU). In the CE, the raw materials that can be recovered from various waste streams play a key role, therefore, recommendations for their management were developed, both at the European and national level. In Poland, the raw material recovery sector is one of the strategic sectors (key industries) described in several documents determining the further directions of economic growth in the country. This paper presents the revision of these documents and guidelines for the implementation of the CE in the raw material recovery sector. The scope of the paper also includes a description of the current state of the raw materials recovery sector and its return, supported by the analysis of drivers and barriers in its further development. In previous years, a dynamic development of the r... [more]

Fractures and micropores have varying contributions to the gas permeability of fractured reservoirs. The quantification of the contribution of fractures and micropores that form a dual-porosity system for gas permeability is critical when attempting to accurately evaluate gas production. However, due to insufficient knowledge of fracture−matrix flow partitioning in such dual-porosity systems, it is challenging for previous models to quantitatively characterize the fracture heterogeneity and accurately evaluate the gas flow and permeability in fractured rocks. In this study, we propose a dual-porosity percolation model to quantitatively investigate the contributions of fractures and matrix micropores towards the gas permeability of fractured rocks. Using percolation theory, we establish fracture networks with complex heterogeneity, which are characterized by various fracture densities and percolation probabilities within a porous matrix with various fracture/matrix permeability ratios.... [more]

Chemical hydrogen storage stands as a promising option to conventional storage methods. There are numerous hydrogen carrier molecules that afford satisfactory hydrogen capacity. Among them, ammonia borane has attracted great interest due to its high hydrogen capacity. Great efforts have been devoted to design and develop suitable catalysts to boost the production of hydrogen from ammonia borane, which is preferably attained by Ru catalysts. The present review summarizes some of the recent Ru-based heterogeneous catalysts applied in the hydrolytic dehydrogenation of ammonia borane, paying particular attention to those supported on carbon materials and oxides.

The research presented by the authors in this paper focused on understanding the behavior of mercury during coal combustion and flue gas purification operations. The goal was to determine the flue gas temperature on the mercury emissions limits for the combustion of lignites in the energy sector. The authors examined the process of sorption of mercury from flue gases using fine-grained organic materials. The main objectives of this study were to recommend a low-cost organic adsorbent such as coke dust (CD), corn straw char (CS-400), brominated corn straw char (CS-400-Br), rubber char (RC-600) or granulated rubber char (GRC-600) to efficiently substitute expensive dust-sized activated carbon. The study covered combustion of lignite from a Polish field. The experiment was conducted at temperatures reflecting conditions inside a flue gas purification installation. One of the tested sorbents—tire-derived rubber char that was obtained by pyrolysis—exhibited good potential for Hg0 into Hg2+... [more]

Copper sinter paste has been recently established as a robust die-attach material for high -power electronic packaging. This paper proposes and studies the implementation of copper sinter paste materials to create top-side interconnects, which can substitute wire bonds in power packages. Here, copper sinter paste was exploited as a fully printed interconnect and, additionally, as a copper clip-attach. The electrical and thermal performances of the copper-sinter paste interconnections (“sinterconnects”) were compared to a system with wire bonds. The results indicate comparable characteristics of the sinterconnect structures to the wire-bonded ones. Moreover, the performance of copper sinterconnects in a power module was further quantified at higher load currents via finite element analysis. It was identified that the full-area thermal and electrical contact facilitated by the planar sinterconnects can reduce ohmic losses and enhance the thermal management of the power packages.

This paper presents a numerical study that aims at investigating the effects of different parameters on the dynamic performance of single and multi-layer encapsulated phase material (PCM) thermocline tanks. A transient, one-dimensional, two-phase, concentric-dispersion model is formulated to evaluate such performance. Encapsulated paraffin waxes having different melting-points are used as PCMs, with water as heat transfer fluid. Comprehensive comparisons between single-PCM and multiple-PCMs systems are numerically analyzed first. Second, the effects of the PCM volume fraction (VF) and the inverse Stefan number have been discussed. The results show that among the various cases the single-PCM70 system has the highest performance in terms of charging and discharging efficiency, followed by a multiple-PCMs system with average performance. Compared with the PCM40 case, the PCM70 case has a 29% increase in the output energy from the system. The VF of PCMs influences the system output, both i... [more]

Non-ideal explosives with differing contents of silicon dioxide (silica or dioxosilane) added in the form of powder and gel were tested. Measurements of structure, crystallinity and morphology were performed by means of infrared spectroscopy (IR), X-ray diffraction (XRD) and scanning electron microscopy (SEM). IR and XRD analysis revealed a lack of SiO2 influence on the non-ideal explosive structure. SEM analysis indicated that all the surface deformations of ammonium nitrate(V) prill were filled by a thin fuel film layer on which SiO2 was present. The additional calculations of selected theoretical properties of non-ideal compositions were made using ZMWCyw software. Based on this, it was established that the optimum semimetal content was 1.0 wt.%. Blasting tests confirmed that the addition of 1.0 wt.% SiO2 to the Ammonium Nitrate Fuel Oil (ANFO) resulted in the lowest volume of post-blast fumes. Moreover, it was established that finer SiO2 powder cannot be used as the oxide component... [more]

Extraction of hydrogen from hydrocarbons is a logical intermediate-term solution for the escalating worldwide demand for hydrogen. This work explores the possibility of using a single membrane to accomplish both the catalytic dehydrogenation and physical separation of hydrogen gas as a possible way to improve the efficiency of hydrogen production from hydrocarbon sources. The present analysis shows that regions of pressure/temperature space exist for which the overall process is thermodynamically spontaneous (ΔG < 0). Each step in the process is based on known physics. The rate of hydrogen production is likely to be controlled by the barrier to hydrogen abstraction, with the density of H-binding sites also playing a role. A critical materials issue will be the strength of the oxide/metal interface.

Determining gas compositions from live well fluids on a drilling rig is critical for real time formation evaluation. Development and utilization of a reliable mass spectrometric method to accurately characterize these live well fluids are always challenging due to lack of a robust and effectively selective instrument and procedure. The methods currently utilized need better calibration for the characterization of light hydrocarbons (C1−C6) at lower concentrations. The primary goal of this research is to develop and optimize a powerful and reliable analytical method to characterize live well fluid using a quadruple mass spectrometer (MS). The mass spectrometers currently being used in the field have issues with detection, spectra deconvolution, and quantification of analytes at lower concentrations (10−500 ppm), particularly for the lighter (<30 m/z) hydrocarbons. The objectives of the present study are thus to identify the detection issues, develop and optimize a better method, cali... [more]

Novel core-shell structure hard carbon/Si-carbon composites are prepared, and their electrochemical performances as an anode material for lithium-ion batteries are reported. Three different types of shell coating are applied using Si-carbon, Si-carbon black-carbon and Si-carbon black-carbon/graphite nanosheets. It appears that the use of n-Si/carbon black/carbon composite particles in place of n-Si for the shell coating is of great importance to achieve enhanced electrochemical performances from the core-shell composite samples, and additional wrapping with graphite nanosheets leads to a more stable cycle performance of the core-shell composites.

A piezoelectric sensor is a typical self-powered sensor. With the advantages of a high sensitivity, high frequency band, high signal-to-noise ratio, simple structure, light weight, and reliable operation, it has gradually been applied to the field of smart wearable devices. Here, we first report a flexible piezoelectric sensor (FPS) based on tungsten disulfide (WS2) monolayers that generate electricity when subjected to human movement. The generator maximum voltage was 2.26 V, and the produced energy was 55.45 μJ of the electrical charge on the capacitor (capacity: 220 μF) when applying periodic pressing by 13 kg. The generator demonstrated here can meet the requirements of human motion energy because it generates an average voltage of 7.74 V (a knee), 8.7 V (a sole), and 4.58 V (an elbow) when used on a running human (weight: 75 kg). Output voltages embody distinct patterns for different human parts, the movement-recognition capability of the cellphone application. This generator is q... [more]

Nonlinear optical properties of aqueous dispersions of single-wall carbon nanohorns (SWCNH) are investigated by a simple and original technique, relating nonlinear transmittance measurements with semi-empirical model fitting and allowing to identify the dominant nonlinear mechanism. The nanofluids shown a particularly strong optical limiting under irradiation by nanosecond laser pulses at 355, 532 and 1064 nm, much stronger than that previously reported in SWCNHs with smaller aggregate size. The effect is more relevant at 355 nm, where a nearly ideal optical limiting behavior with output energy practically independent on the input one is obtained, and it is attributed to the massive production of bubbles under the effect of light irradiation. This result opens interesting perspectives for the use of SWNCH-based suspensions for smart materials applications and green energy.

The electrochromic property of nickel doped vanadium pentoxide (V2O5) deposited by a co-sputtering system is investigated. The structural analysis of the thin film was done by an X-ray diffraction (XRD) analyzer. The surface morphology of the film was studied by a field emission scanning electron microscopy (FE-SEM). The composition of the film was detected by an Auger analysis. The electrochromic properties of the device were measured by cyclic voltammetry. For the undoped V2O5 thin film, the charge storage capacity increases with the thickness and is 42.58 mC/cm2 at the thickness of 192.4 nm after 2 h deposition. For the Ni-doped V2O5, the Ni-V-O film shows V2O5 structural dominate with cathode coloration in the lower Ni deposition power region and the charge storage capacity decreases with the increases of the power, while the Ni-V-O film transfers to NiO structural dominate with anodic coloration at the realm of higher Ni doping. The charge storage capacity increases with the incre... [more]

In 2016, a law was introduced in Poland that required management bodies of energy companies owned by the state and a municipality to adopt management goals. The remuneration of the board members of these companies depended on the extent to which these goals were implemented. The challenge was that profit became an end in itself. The purpose of this article is to describe the process used to set up strategic goals on the basis of balancing capital within energy companies, which demonstrates a positive impact on the effectiveness of these companies. The solution proposed in this article is an alternative to using profit as the sole measure. The article consists of three parts. The first part is a review of the literature on management goals and how they relate to various economic measures—the main conclusions of this literature review were that, despite many attempts, we were not able to (1) clearly define the purpose of a company and (2) find an indisputable measure of the degree to whi... [more]

As renewable energy source integration increases, P2G technology that can store surplus renewable power as methane is expected to expand. The development of a CO2 methanation catalyst, one of the core processes of the P2G concept, is being actively conducted. In this work, low-rank coal (LRC) was used as a catalyst support for CO2 methanation, as it can potentially enhance the diffusion and adsorption behavior by easily controlling the pore structure and composition. It can also improve the process efficiency owing to its simplicity (no pre-reduction step) and high thermal conductivity, compared to conventional metal oxide-supported catalysts. A screening of single metals (Ni, Co, Ru, Rh, and Pd) on LRC was performed, which showed that Ni was the most active. When Ni on the LRC catalyst was doped with a promoter (Ce and Mg), the CO2 conversion percentage increased by >10% compared to that of the single Ni catalyst. When the CO2 methanation activity was compared at 250−500 °C, the Ce-do... [more]

Solid Oxide Fuel Cells are a promising technology for Solid Oxide Fuel Cells (SOFC) are a promising technology For high-efficiency electrochemical conversion of a vast range of fuel gas mixtures, thigh operating temperature conditions (650−900 °C) represent a challenge both at system level and at laboratory testing level, in terms of material properties and performance dynamics. In this work a detailed procedural analysis is presented for an innovative all-ceramic compact SOFC test rig and first experimental testing results are reported in terms of polarization curves obtained under parametric variation of operating conditions (H2 content, air ratio λ and temperature) and short-term voltage stability test under load (140 h at 0.3 A/cm2). The electrochemical characterization results confirm the validity of the used all-ceramic cell holder, showing excellent cell performances in terms of polarization. H2 content has the most impact on SOFC performance, followed by temperature and finally... [more]

This study conducted a radial flow experiment to investigate the existence of non-Darcy flow and calculate the non-Darcy “inertia” coefficient; the experiment was performed on seven cylindrical perforated artificial porous media samples. Two hundred thirty-one runs were performed, and the pressure drop was reported. The non-Darcy coefficient β was calculated and compared with available in the literature. The results showed that the non-Darcy coefficient decreased nonlinearly and converged on a value within a specific range as the permeability increased. Nonetheless, it was found that the non-Darcy flow exists even in the very low flow rate deployed in this study. In addition, it has been found that the non-Darcy effect is not due to turbulence but also the inertial effect. The existence of a non-Darcy flow was confirmed for all the investigated samples. The Forchheimer numbers for airflow at varied flow rates are determined using experimentally measured superficial velocity, permeabili... [more]

The inhibition effect of calcined lime (CaO) and limestone (CaCO3) on the formation of dioxins during iron ore co-sintering with fly ash was investigated in a sinter pot in the present work. Experimental results indicated that international total toxicity equivalent concentration of dioxins decreased from 1.4335 to 0.2922, 0.1048, 0.4562, and 0.3098 ng I-TEQ Nm−3 under four different experimental conditions. It can be concluded that 5 wt.% calcined lime with 3 wt.% limestone is the optimal addition to reduce the concentration of dioxins in flue gas, with 92.70% inhibition efficiency. Effects on dioxin distribution was also analyzed. The distribution proportion of low-chlorinated dioxins was found to increase, while that of high-chlorinated dioxins decreased, except for octachlorianted dibenzo-p-dioxins (OCDD). The reason is that the consumption of HCl not only inhibits the de novo synthesis, but also dramatically promotes the condensation and dechlorination to produce more tetrachloria... [more]

Generally, impregnation of solid insulation is performed to increase the dielectric strength and reduce the dielectric losses of solid insulants. This increase in dielectric strength depends on the oil’s diffusion and dielectric properties. This paper investigates the diffusion behavior of mineral oil and ester fluids (synthetic, natural, and mixed) to understand the influence of oil diffusion on paper breakdown voltage. To better understand this phenomenal influence, cellulose insulation paper of different thicknesses has been considered. Wetting characteristics of various oil-paper insulation systems were investigated with and without thermal stressing. Thermal aging was carried out as per modified ASTM D1934 at 110 °C, 140 °C, 160 °C, and 185 °C respectively for 2 weeks. The wetting characteristics and influence of different oils on paper breakdown voltage were explicitly reported. It is inferred that paper wetting characteristics are attributable to the type of oil, the thickness o... [more]