Forests are the main sources of wood chips delivered to the end customers by road or railway. This research analysed the impact of the quarter of the year: Q1 (January−March), Q2 (April−June), Q3 (July−September), Q4 (October−December) when wood chips were obtained over two consecutive years (2019−2020) and the type of transport used (railway and road) on the thermophysical properties of wood chips and the cost of their delivery. The mean moisture content in the wood chips was 38.28% and it was the highest (45.55%) in Q1, while in Q2 and Q3, this parameter was 8 and 17 percentage points (p.p.) lower. The mean lower heating value (LHV) of the chips was 10.46 GJ Mg−1. The chips delivered by road transport had a 4% higher LHV compared to those shipped by railway transport. The wood chips contained 3.42% d.m. of ash. The road transport at a distance of 200 km was found to be approximately 10% cheaper compared to the transport by rail for most of the study period, both with respect to 1 Mg... [more]

Photovoltaic (PV) panels must be equipped with a cooling system to increase their electrical output generation. Despite numerous publications on the fabrication of form-stable phase change material (FSPCM) for thermal energy storage application, studies on the usage of FSPCM for PV cooling are incredibly limited. In this work, the cooling performance of myristic acid FSPCM encapsulated with cross-linked nitrile rubber (NBR) was investigated. A fin heat sink (FHS) was employed to hold the FSPCM. The thermal performance of the FHS embedded with FSPCM (FHS-FSPCM) was preliminarily tested in an indoor setup. Results show that the FHS-FSPCM has a lower temperature distribution curve than the bare FHS, highlighting the increase in cooling capability of fabricated FSPCM. Field-testing of PV panels integrated with an FHS-FSPCM displayed that FSPCM manages to reduce the operating temperature of the panel by 4 to 15 °C and increase power output generation by 38.61%.

We examined the oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) of Pt-based Pt3M/Pt nanoalloy catalysts (where M represents a 3d transition metal) for bifunctional electrocatalysts using spin-polarized density functional theory calculations. First, the stability of the Pt3M/Pt catalyst was investigated by calculating the bulk formation energy and surface separation energy. Using the calculated adsorption energies for the OER/ORR intermediates in the modeled catalysts, we predicted the OER/ORR overpotentials and potential limiting steps for each catalyst. The origins of the enhanced catalytic reactivity in Pt3M/Pt catalysts caused by strain and ligand effects are explained separately. In addition, compared to Pt(111), the OER and ORR activities in a Pt3Ni/Ptskin catalyst with a Pt skin layer were increased by 13.7% and 18.4%, respectively, due to the strain and ligand effects. It was confirmed that compressive strain and ligand effects are key factors in improving th... [more]

The efficiency of thermochemical heat storage is crucially determined by the performance of the sorbent used, which includes a high sorption capacity and a low regeneration temperature. The thermochemical salt hydrate− γ-alumina composite sorbents are promising materials for this application but lack systematic study of the influence of γ-alumina structural properties on the final storage performance. In this study, mesoporous γ-Al2O3 supports were prepared by solvothermal and hydrothermal synthesis containing a block copolymer (F-127) surfactant to design thermochemical CaCl2 and LiCl composite water sorbents. Altering the solvent in the synthesis has a significant effect on the structural properties of the γ-Al2O3 mesostructure, which was monitored by powder XRD, nitrogen physisorption, and SEM. Solvothermal synthesis led to a formation of mesoporous γ-Al2O3 with higher specific surface area (213 m2/g) and pore volume (0.542 g/cm3) than hydrothermal synthesis (147 m2/g; 0.414 g/cm3).... [more]

Supercapacitors (SCs) have received much interest due to their enhanced electrochemical performance, superior cycling life, excellent specific power, and fast charging−discharging rate. The energy density of SCs is comparable to batteries; however, their power density and cyclability are higher by several orders of magnitude relative to batteries, making them a flexible and compromising energy storage alternative, provided a proper design and efficient materials are used. This review emphasizes various types of SCs, such as electrochemical double-layer capacitors, hybrid supercapacitors, and pseudo-supercapacitors. Furthermore, various synthesis strategies, including sol-gel, electro-polymerization, hydrothermal, co-precipitation, chemical vapor deposition, direct coating, vacuum filtration, de-alloying, microwave auxiliary, in situ polymerization, electro-spinning, silar, carbonization, dipping, and drying methods, are discussed. Furthermore, various functionalizations of SC electrode... [more]

Engaging firms to generate and adopt energy efficient innovation is crucial for balancing energy needs for sustainable development. In addition, a reduction in energy consumption can address environmental problems and lower production costs by reducing materials and/or energy costs and costs related to compliance with regulations. Considering the lack of systematic reviews focused on the determinants of energy efficient innovation, we address this gap and set forth to enhance the body of knowledge in the field of energy efficient innovation. To achieve the research aim, a systematic literature review and qualitative content analysis were conducted. This study offers two contributions. First, the study distinguishes the determinants of energy efficient innovation in three levels: micro-level, meso-level, and macro-level. According to the findings, the following determinants of energy efficient innovation are highlighted at the micro-level: (1) cost savings; (2) previous experience; (3)... [more]

Enclosed airspaces to reduce heat flow have been recognized for well over 100 years. Airspaces with one or more reflective surfaces define reflective insulation (RI) assemblies, a product type used in walls, roofs, windows with multiple panes, curtain walls and skylights. The thermal resistance (R value) of airspaces depends on the emittance of all surfaces, airspace dimensions and orientation, heat flow direction and surfaces temperatures. The modeling of RI now includes CFD coupled with radiation to quantify the total heat transfer. This study compares a validated model for airspace R values with existing methods such as ISO 6946 and hot-box results that provide the R values in the ASHRAE Handbook of Fundamentals. The existing methods do not include an airspace aspect ratio. This study showed that the aspect ratio can impact the R value by a factor of two. The impact of aspect ratio was calculated for double airspaces variation such as that for single airspaces. The present calculati... [more]

Benefitting from the characteristics of a high latent heat capacity and stable phase change behavior, phase change materials have widely received concerns in the field of thermodynamic management. Ba(OH)2·8H2O is an ideal phase change material (PCM) in the mid-to-low temperature range, but its large-scale application is still limited by severe supercooling during the nucleation process. In this paper, the experimental analysis and comparison are performed via an Edisonian approach, where Ba(OH)2·8H2O is adopted as an original substrate; BaCO3, CaCl2, NaCl, KH2PO4, and NaOH are selected as nucleating agents; and graphite is used as a heat-conducting agent. The results show that Ba(OH)2·8H2O containing 1.2% BaCO3 and 0.2% graphite powder has the best performance. Compared with pure Ba(OH)2·8H2O, the supercooling degree is reduced to less than 1 °C, the phase change latent heat duration is extended, and the thermal conductivity is significantly improved. Therefore, this study not only pro... [more]

Hydrogen derived from biomass feedstock (biohydrogen) can play a significant role in Germany’s hydrogen economy. However, the bioenergy potential and environmental benefits of biohydrogen production are still largely unknown. Additionally, there are no uniform evaluation methods present for these emerging technologies. Therefore, this paper presents a methodological approach for the evaluation of bioenergy potentials and the attainable environmental impacts of these processes in terms of their carbon footprints. A procedure for determining bioenergy potentials is presented, which provides information on the amount of usable energy after conversion when applied. Therefore, it elaborates a four-step methodical conduct, dealing with available waste materials, uncertainties of early-stage processes, and calculation aspects. The bioenergy to be generated can result in carbon emission savings by substituting fossil energy carriers as well as in negative emissions by applying biohydrogen prod... [more]

Magnesium is an attractive hydrogen storage candidate due to its high gravimetric and volumetric storage capacities (7.6 wt.% and 110 gH2/l, respectively). Unfortunately, its use as a storage material for hydrogen is hampered by the high stability of its hydride, its high dissociation temperature of 573−673 K and its slow reaction kinetics. In order to overcome those drawbacks, an important advancement toward controlling the enthalpy and desorption temperatures of nano-structured MgH2 thin films via stress/strain and size effects is presented in this paper, as the effect of the nano-structuring of the bulk added to a biaxial strain on the hydrogen storage properties has not been previously investigated. Our results show that the formation heat and decomposition temperature correlate with the thin film’s thickness and strain/stress effects. The instability created by decreasing the thickness of MgH2 thin films combined with the stress/strain effects induce a significant enhancement in t... [more]

Chalcopyrite Cu(In,Ga)Se2 (CIGS) solar cells prepared via metal-organic chemical vapor deposition (MOCVD) are one of the candidates for highly advanced photovoltaic devices. This is because of their effectiveness and potential for reducing production costs through large-scale production. However, research on MOCVD-prepared solar cells is progressing slower than that on other types of solar cells, primarily because the preparation of CuInSe2 (CIS)-based films via MOCVD is relatively more sophisticated. In this study, we analyzed CIS solar cells prepared via three-stage MOCVD and processed with relatively simple precursors and techniques. We achieved an energy-conversion efficiency of 7.39% without applying a buffer layer. Instead, we applied a Cu-deficient layer to create a buried pn junction. Ultimately, we demonstrated that the fabrication of fully-MOCVD-processed CIS photovoltaic devices is feasible.

Climate change and energy dependence are nowadays critical issues that the world is facing, requiring effective and urgent actions to properly address them in a timely fashion [...]

Recently, nanomaterial-based scintillators are newly emerging technologies for many research fields, including medical imaging, nuclear security, nuclear decommissioning, and astronomical applications, among others. To date, scintillators have played pivotal roles in the development of modern science and technology. Among them, plastic scintillators have a low atomic number and are mainly used for beta-ray measurements owing to their low density, but these types of scintillators can be manufactured not in large sizes but also in various forms with distinct properties and characteristics. However, the plastic scintillator is mainly composed of C, H, O and N, implying that the probability of a photoelectric effect is low. In a gamma-ray nuclide analysis, they are used for time-related measurements given their short luminescence decay times. Generally, inorganic scintillators have relatively good scintillation efficiency rates and resolutions. And there are thus widely used in gamma-ray s... [more]

Natural gas continues to be one of the basic energy sources used as fuel in the power sector, in industries and in households. The potential and attractiveness of this fuel is gaining special significance in the current energy transitions from coal-based power engineering to power generation based on renewable energy sources. Natural gas is supplied to consumers mainly through a network of pipelines, which ensures a relatively high reliability of the supply. Still, failures occur due to the corrosion of pipeline walls, material defects or human errors, which can result in uncontrolled release of gas. The released gas can trigger dangerous phenomena, such as fires and explosions. This paper presents an analysis of the causes and effects of damage to a medium-pressure pipeline caused by earthworks carried out within an area where a pipeline is located. Holes in the pipeline due to the impact of an excavator bucket are analysed. The impact of the excavator bucket may cause a rupture equal... [more]

Coking coal has been on the European list of critical raw materials since 2014 due to its high economic importance and high supply risk. In 2017, coking coal narrowly missed passing the threshold of economic importance. However, out of caution, it remained on the list of critical raw materials, as the steel industry still needs it. It is likely to be phased out of the list below when it does not fully meet the required criteria. As there are no significant alternatives for this energy intensive industry and neither electrification nor material or energy efficiency improvements are yet available at a sufficient level of technological readiness, the European Union remains dependent on coking coal imports. Therefore, any coking coal mining project in Europe is of great importance and an important alternative to solving the problems of providing this raw material. In this study, the Dębieńsko coking coal project in Poland is analyzed using a scientifically proven methodology based on world... [more]

Pine tree biochar produced by flame-curtain pyrolysis, an inexpensive and simple pyrolysis methodology, was used as the starting material for KOH-activated carbon. Flame-curtain pyrolysis is a simple, low-technology methodology that can be performed by non-specialized personnel. The elemental analysis of the biochars highlighted the high reproducibility of the process. The N2 adsorption isotherms indicated that KOH activation was effective for the preparation of high-surface-area activated carbons from the biochar. The BET specific surface area increased with the quantity of KOH added in the activation process, achieving a maximum value of 3014 m2 g−1 at 85.7 wt.% of KOH addition. The adsorption isotherms of all samples were IUPAC type I, establishing their microporous nature. Results from the Mikhail−Brunauer (MP) method and αs plot indicated that the pore size distribution became wider and the pore volume increased as the KOH content increased. The measured capacitance values followe... [more]

Hybridization of CSP plants with alternative energy sources (fuels) represents a means to improve flexibility of operation, power dispatchability and utilization factor of the plant. New generation CSP plants make use of molten salts as Heat Transfer Fluid (HTF) besides Thermal Energy Storage (TES) medium. Therefore, proper interfaces should be developed to effectively transfer the heat from the back-up source to the molten salt. This paper presents the results obtained in the experimental validation of an innovative gas-fueled Molten Salt Heater (MSH) prototype. The objective of this research is to validate the MSH design, where the specific properties of molten salts (compared to other HTFs, e.g., thermal oils) have to be taken into account. The developed reduced-scale MSH (90 kW thermal) consists of a heat exchanger with the molten salt flowing inside finned tubes cross-flowed with the hot flue gas generated in an upstream combustion chamber. LPG or a biogas-like mixture has been us... [more]

The development of supercapacitors with high volumetric capacitance and high-rate performance has been an important research topic. Activated carbon (AC), which is a widely used material for supercapacitor electrodes, has different surface structures, porosities, and electrochemical properties. However, the low conductivity of the electrode material is a major problem for the efficient use of AC in supercapacitors. To tackle this challenge, we prepared conductive, additive-free electrodes for supercapacitors by a simple one-pot treatment of AC with melamine (nitrogen source), pitch, and sucrose (both carbon source). Nitrogen-doped and carbon-coated AC was successfully generated after high-temperature heat treatment. The AC was doped with approximately 0.5 at.% nitrogen, and coated with carbon leading to a decreased oxygen content. Thin carbon layers (~10 nm) were coated onto the outer surface of the AC, as shown in TEM images. The modification of the AC surface with a sucrose source is... [more]

Joint roughness determination is a fundamental issue in many areas of rock engineering, because joint roughness has significant influences on mechanical properties and deformation behavior of rock masses. Available models suggested in the literature neglected combined effects of shear direction, scale of rock discontinuities, inclination angle, and amplitude of asperities during the roughness calculations. The main goals of this paper are to establish a comprehensive parameter that considers the characteristics of the size effect, anisotropy, and point spacing effect of the discontinuity roughness, and to investigate the correlation between the proposed comprehensive parameter and joint roughness coefficients. In this work, the Barton ten standard profiles are digitally represented, then the morphological characteristics of the discontinuity profiles are extracted. A comprehensive parameter that considers the characteristics of the size effect, anisotropy, and point spacing effect of t... [more]

Concerns associated with global warming and the depleting reserves of fossil fuels have highlighted the importance of high−performance energy storage systems (ESSs) for efficient energy usage. ESSs such as supercapacitors can contribute to improved power quality of an energy generation system, which is characterized by a slow load response. Composite materials are primarily used as supercapacitor electrodes because they can compensate for the disadvantages of carbon or metal oxide electrode materials. In this study, a composite of oxide nanoparticles loaded on a carbon nanofiber support was used as an electrode material for a hybrid supercapacitor. The addition of a small amount of hydrophilic FeN@GnP (Fe− and N−doped graphene nanoplates) modified the surface properties of carbon nanofibers prepared by electrospinning. Accordingly, the effects of the hydrophobic/hydrophilic surface properties of the nanofiber support on the morphology of Co3O4 nanoparticles loaded on the nanofiber, as... [more]

Rocks’ physical, mechanical, and mineralogical properties are essential in the design process of underground applications. To understand changes in these rocks’ properties at high temperatures, numerous studies have been conducted on several rock types, with little being known about microschist rock. This paper presents experimental study on the physical (e.g., density and P-wave velocity), mechanical (uniaxial compressive strength (UCS)), and microstructural behavior of microschist rock at room temperature (22 °C) and at high temperatures, i.e., 400, 600, and 800 °C. The results indicated that as the temperature increases, the microschist’s color changed, and dry density decreased by 0.97% at 800 °C. Additionally, the average P-wave velocity of microschist decreased by 4.14, 7.07, and 34.23%, at 400, 600, and 800 °C, respectively. Similarly, at these temperatures, the UCS of the microschist decreased by 34.4, 56.9, and 80.1%, respectively. Further findings from microscopic studies rev... [more]

This paper presents the testing campaign of the two First Wall mock-ups in the HELOKA facility, one mock-up having a 3 mm thick Oxide Dispersion Strengthened (ODS) steel layer on its surface and the other featuring a tungsten functionally graded cover. Special consideration is given to the diagnostics used for these tests, in particular, the measurement of the surface temperature of the tungsten functionally graded layer with an infrared camera. Additionally, the paper looks into the uncertainty associated with the calorimetric evaluation of the applied heating power for these experiments.

Rotary kiln incineration technology has the advantages of strong material adaptability and a simple treatment process and has been widely used in hazardous waste treatment. However, the actual incineration process has caused problems such as ring formation in the treatment system due to the lack of research on the slagging mechanisms. In this paper, slagging phenomena occurring in the second half of the rotary kiln, the exit flue of the secondary combustion chamber, and the wall of the quench tower are analyzed and discussed in detail through characterization methods. The results indicate that the adhesion of low-melting alkali metal salts on the refractory surface in the second half of the rotary kiln is the key factor in forming the initial slagging layer. In the growth process of the slagging ring, the formed liquid phase can bond incineration residues of different sizes together and form a dense embryo body through liquid phase sintering. The deposition and solidification of molten... [more]

In building construction, it is very important to reduce energy consumption and provide thermal comfort. In this regard, defects in insulating panels can compromise the capability of these panels of reducing the heat flow by conduction with the surroundings. In recent years, both experimental techniques and numerical methods have been used for investigating the effect of defects on the thermal behavior of building panels. The main novelty of this work regards the application of both numerical and experimental approaches based on infrared thermography techniques for studying the effects of defects such as debonding on the insulation properties of cork panels. In particular, the effects of defects were investigated by using the Long Pulse Thermography technique and then by analyzing the thermal behavior of the panel during the cooling phase. Results show the capability of the proposed approaches in describing the effects of defects in cork panels such as detachments and the benefit effec... [more]

Imbibition is an important mechanism of recovery during waterflooding and low flow-back during fracking in shale reservoirs. Experiments were carried out to study the development of imbibition in shale samples. The effects of clay minerals, especially the illite and IS, were mainly investigated and discussed. The imbibition under different pressures was conducted and compared. The influence of clay minerals on imbibition in shale is significant and complex. It is shown that the low content of illite and IS and small capillary force lead to small imbibition mass and speed. Formation of new micro fractures due to the swelling of clay minerals can cause the permeability to increase and the imbibition to be speeded up. The pore structure, the content of IS, and the capillary force affect the imbibition process significantly. The external pressure obviously affects the imbibition speed and the final imbibition mass. The content of clay minerals is more important to the formation of new micr... [more]