The aim of the study was to assess the effect of anode materials, namely a carbon nanotube (CNT)-buckypaper and a commercial carbon paper (CP) on the performance of a two-chamber microbial electrolysis cell (MEC), in terms of hydrogen production and main electrochemical characteristics. The experiments were performed using both acetate-based synthetic wastewater and real wastewater, specifically the effluent of a dark fermentative hydrogenogenic reactor (fermentation effluent), using cheese whey (CW) as substrate. The results showed that CP led to higher hydrogen production efficiency and current density compared to the CNT-buckypaper anode, which was attributed to the better colonization of the CP electrode with electroactive microorganisms, due to the negative effects of CNT-based materials on the bacteria metabolism. By using the fermentation effluent as substrate, a two-stage process is developed, where dark fermentation (DF) of CW for hydrogen production occurs in the first step,... [more]

Our study evaluated the specific methane yield (SMY) of selected wetland species subjected to wet and dry anaerobic digestion: Carex elata All. (CE), a mixture (~50/50) of Carex elata All. and Carex acutiformis L. (CA), Phragmites australis (Cav.) Trin. ex Steud. (PA), Typha latifolia L. (TL) and Phalaris arundinacea L. (PAr). Plants were harvested in late September, and therefore, the study material was characterised by high lignin content. The highest lignin content (36.40 ± 1.04% TS) was observed in TL, while the lowest (16.03 ± 1.54% TS) was found in CA. PAr was characterised by the highest hemicellulose content (37.55 ± 1.04% TS), while the lowest (19.22 ± 1.22% TS) was observed in TL. Cellulose content was comparable in almost all plant species studied and ranged from 25.32 ± 1.48% TS to 29.37 ± 0.87% TS, except in PAr (16.90 ± 1.29% TS). The methane production potential differed significantly among species and anaerobic digestion (AD) technologies. The lowest SMY was observed fo... [more]

We demonstrated the efficient coupling of BiFeO3 (BFO) ferroelectric material within the carbon−sulfur (C-S) composite cathode, where polysulfides are trapped in BFO mesh, reducing the polysulfide shuttle impact, and thus resulting in an improved cyclic performance and an increase in capacity in Li-S batteries. Here, the built-in internal field due to BFO enhances polysulfide trapping. The observation of a difference in the diffusion behavior of polysulfides in BFO-coupled composites suggests more efficient trapping in BFO-modified C-S electrodes compared to pristine C-S composite cathodes. The X-ray diffraction results of BFO−C-S composite cathodes show an orthorhombic structure, while Raman spectra substantiate efficient coupling of BFO in C-S composites, in agreement with SEM images, showing the interconnected network of submicron-size sulfur composites. Two plateaus were observed at 1.75 V and 2.1 V in the charge/discharge characteristics of BFO−C-S composite cathodes. The observed... [more]

Induction heating (IH) is a process of heating the electrically conducting materials especially ferromagnetic materials with the help of electromagnetic induction through generating heat in an object by eddy currents. A well-entrenched way of IH is to design a heating system pertaining to the usage of ferromagnetic materials such as stainless steel, iron, etc., which restricts the end user’s choice of using utensils made of ferromagnetic only. This research article proposes a new scheme of induction heating that is equally effective for heating ferromagnetic and non-ferromagnetic materials such as aluminium and copper. This is achieved by having a competent IH system that embodies a series resonant inverter and controller where a competent flexible load modulation (FLM) is deployed. FLM facilitates change in operating frequency in accordance with the type of material chosen for heating. The recent attempts by researchers on all metal IH have not addressed much on the variable shapes an... [more]

This work illustrates the application of the nth-order comprehensive adjoint sensitivity analysis methodology for response-coupled forward/adjoint linear systems (abbreviated as “nth-CASAM-L”) to a paradigm model that describes the transmission of particles (neutrons and/or photons) through homogenized materials, as encountered in radiation protection and shielding. The first-, second-, and third-order sensitivities of responses that depend on both the forward and adjoint particle fluxes are obtained exactly, in closed-form, underscoring the principles and methodology underlying the nth-CASAM-L. The results presented in this work underscore the fundamentally important role of the nth-CASAM-L in the quest to overcome the “curse of dimensionality” in sensitivity analysis, uncertainty quantification and predictive modeling.

For the first time, the present work assesses the feasibility of using Korean red ginseng root extract, a non-ionic surfactant, for the purposes of enhanced oil recovery (EOR). The surfactant is characterized by Fourier-transform infrared spectroscopy (FT-IR) analysis. Pendant drop and sessile drop techniques are employed to study the oil−water interfacial tension (IFT) and wettability nature of the sandstone rock, respectively. In addition, oil recovery enhancement is investigated using micromodel and core floods. In the salt-free system, IFT measurements indicate that the surfactant carries a critical micelle concentration of 5 g/L. In a saline medium (up to 50 g/L), the addition of a surfactant with different concentrations leads to an IFT reduction of 47.28−84.21%. In a constant surfactant concentration, a contact angle reduction is observed in the range of 5.61−9.30°, depending on salinity rate, revealing a wettability alteration toward more water-wet. Surfactant flooding in the g... [more]

Due to the high availability of lignocellulosic biomass, which can be obtained from terrestrial plants, agricultural waste biomass, and the agro-food, paper or wood industries, its use for energy production by methane fermentation is economically and environmentally justified. However, due to their complex structures, lignocellulosic substrates have a low conversion factor to biogas. Therefore, scientists are still working on the development of new methods of the pre-treatment of lignocellulosic materials that will increase the biogas productivity from lignocellulosic biomass. The presented research focuses on the use of a pulsed electric field (PEF) to disintegrate rapeseed straw prior to the methane fermentation process. Scanning electron microscopy observation showed that, in the disintegrated sample, the extent of damage to the plant tissue was more severe than in the control sample. In the sample disintegrated for 7 min, the chemical oxygen demand increased from 4146 ± 75 mg/L to... [more]

In fusion devices, such as European Demonstration Fusion Power Reactor (EU DEMO), primary neutrons can cause material activation due to the interaction between the source particles and the targeting material. Subsequently, the reactor’s inner components become activated. For safety and safe performance purposes, it is necessary to evaluate neutron-induced activities. Activities results from divertor reflector and liner plates are presented in this work. The purpose of liner shielding plates is to protect the vacuum vessel and magnet coils from neutrons. As for reflector plates, the function is to shield the cooling components under plasma-facing components from alpha particles, thermal effects, and impurities. Plates are made of Eurofer with a 3 mm layer of tungsten, while the water is used for cooling purposes. The calculations were performed using two EU DEMO MCNP (Monte Carlo N-Particles) models with different breeding blanket configurations: helium-cooled pebble bed (HCPB) and wate... [more]

The increase in cement production as a result of growing demand in the construction sector means an increase in energy consumption and CO2 emissions. These emissions are estimated at 7% of the global production of CO2. Ultra-high-performance concrete (UHPC) has excellent mechanical and durability characteristics. Nevertheless, it is costly and affects the environment due to its high amount of cement, which may reach 800−1000 kg/m3. In order to reduce the cement content, silica fume (SF) was utilized as a partial alternative to cement in the production of UHPC. Nevertheless, SF is very expensive. Therefore, the researchers investigated the use of supplementary cementitious materials cheaper than SF. Very limited review investigates addressed the impact of such materials on different properties of UHPC in comparison to that of SF. Thus, this study aims to summarize the effectiveness of using some common supplementary cementitious materials, including fly ashes (FA), ground granulated bla... [more]

Development of efficient and affordable photocatalysts is of great significance for energy production and environmental sustainability. Transition metal chalcogenides (TMCs) with particle sizes in the 1−100 nm have been used for various applications such as photocatalysis, photovoltaic, and energy storage due to their quantum confinement effect, optoelectronic behavior, and their stability. In particular, TMCs and their heterostructures have great potential as an emerging inexpensive and sustainable alternative to metal-based catalysts for hydrogen evolution. Herein, the methods used for the fabrication of TMCs, characterization techniques employed, and the different methods of solar hydrogen production by using different TMCs as photocatalyst are reviewed. This review provides a summary of TMC photocatalysts for hydrogen production.

Characteristics of microjet hydrogen diffusion flames stabilized near extinction are investigated numerically. Two-dimensional simulations are carried out using a detailed reaction mechanism. The effect of burner wall material, thickness, and thermal radiation on flame characteristics such as flame height and maximum flame temperature are studied. Results show that the flame stabilizes at lower fuel jet velocities for quartz burner than steel or aluminum. Higher flame temperatures are observed for low conductive burners, whereas the flame length increases with an increase in thermal conductivity of the burner. Even though thermal radiation has a minor effect on flame characteristics like flame temperature and flame height, it significantly influences the flame structure for low conductive burner materials. The burner tip and its vicinity are substantially heated for low conductive burners. The effect of burner wall thickness on flame height is significant, whereas it has a more negligi... [more]

A thin Pd-based H2-permeable membrane is required to produce high-purity H2 with high efficiency. In this study, a porous Ni-supported Pd60Cu40 composite H2-permeable membrane was developed using a reverse build-up method to produce economical H2 purification. The thickness of the Pd60Cu40 alloy layer produced by the improved membrane production process reached 1.0 μm; it was thinner than the layer obtained in a previous study (3.7 μm). The membrane was characterized by scanning electron microscope, inductively coupled plasma optical emission spectrometer, H2 permeation test, and Auger microprobe analysis. The permeation tests were performed at 300−320 °C and 50−100 kPa with H2 introduced from the primary side. The H2 permeation flux was stable up to ~320 °C. The n-value was determined to be 1.0. The H2 permeance of the membrane was 2.70 × 10−6 mol m−2 s−1 Pa−1.0 at 320 °C, after 30 h, similar to those of other 2.2-µm-thick and 3.7-µm-thick Pd60Cu40 composite membranes, suggesting that... [more]

Successive flashover would result in carbonized tracking on insulator surface and cause deterioration to the insulation. Thus, investigation of the tracking can be beneficial in understanding flashover characteristics during long-term operation. In this paper, DC flashover was operated on the insulator, and the image of tracking after successive discharge were captured. Improved differential box-counting method (IDBM) was applied to analyze these images based on fractal theory. Weighted item was suggested during the counting procedure for rectangle image with margin covered by cut-size box. Fractal dimension of the tracking was calculated according to the suggested method. It is claimed that the suggested method could estimate the discharge propagation property and deterioration characteristics on the insulator surface. Moreover, IDBM showed advantages in image pre-processing and deterioration property revealed compared to traditional box-counting method attributing to the consideratio... [more]

Increasing the field development efficiency of fractured reservoirs is a contemporary issue. This paper presents fundamental and exploratory research results in this field using modern high-tech experimental equipment from the “Arctic” Scientific Centre at the Saint Petersburg Mining University. Oil reserves in fractured reservoirs are enormous; however, they are classified as hard-to-recover. The before-mentioned reservoirs require a specific approach when selecting technologies to improve the efficiency of their development. In this paper, as a solution to the problem under discussion, we propose the use of a physicochemical method of developing fractured reservoirs based on the injection of a water shut-off agent to exclude highly permeable water-conducting fractures from the drainage process. This technology makes it possible to effectively include and develop previously undrained reservoir areas by directly controlling their filtration properties with the use of new highly efficie... [more]

When the electromagnetic transients occur in a power transformer, an inrush current is generated in its winding. The inrush current not only affects the performance of the transformer windings, but also affects the lifetime of the transformer. Many factors affect the inrush current, the most influential ones among which are the closing phase angle and the residual flux. In this paper, a dry-type transformer simulation model is built to analyze the influence of the inrush current on the performance of transformer windings during no-load reclosing conditions. Firstly, the inrush current was generated in the transformer windings during the no-load reclosing operation under different residual fluxes. Secondly, the field-circuit coupling 3d finite element method is used to analyze the electromagnetic force at different locations of the transformer windings under the influence of different inrush currents. The results of winding structural parameter variations are obtained through electromag... [more]

A high content of asphaltene and wax in crude oil leads to difficulties in the recovery and transportation of crude oil due to the precipitation of asphaltenes and the deposition of waxes. Comb-like polymers were found to be capable of inhibiting the aggregation of asphaltenes and crystallization of waxes. In this work, comb-like bipolymers of α-olefins/ultra-long chain (C18, C22 and C28) alkyl acrylate were synthesized and characterized by FT-IR and 1H NMR spectra. The results show that, for a model oil containing asphaltene, the initial precipitation point (IPP) of asphaltene was prolonged by UV, and the asphaltene particle size was reduced after adding the biopolymers, as revealed by dynamitic light scattering (DLS). The bipolymer containing the longer alkyl chain had a better asphaltene inhibition effect. However, DSC and rheological results show that the wax appearance temperature (WAT) of the typical high asphaltene and high wax content of crude oil was obviously reduced by addin... [more]

Quantifying frequency converters’ residual phase noise is essential in various applications, including radar systems, high-speed digital communication, or particle accelerators. Multi-input signal source analyzers can perform such measurements out of the box, but the high cost limits their accessibility. Based on an analysis of phase noise transmission theory and the capabilities of popular instrumentation, we propose a technique extending the functionality of single-input devices. The method supplements absolute noise measurements with estimates of the phase noise transfer function (also called the jitter transfer function), allowing the calculation of residual noise. The details of the hardware setup used for the method verification are presented. The injection of single-tone and pseudo-random modulations to the test signal is examined. Optional employment of a spectrum analyzer can reduce the time and number of data needed for characterization. A wideband synthesizer with an integra... [more]

Thermal energy storage based on phase change materials (PCMs) can improve the efficiency of energy utilization by eliminating the mismatch between energy supply and demand. It has become a hot research topic in recent years, especially for cold thermal energy storage (CTES), such as free cooling of buildings, food transportation, electronic cooling, telecommunications cooling, etc. This paper summarizes the latest research progress of the PCMs-based CTES. Firstly, the classification of PCMs for low temperature storage is introduced; the thermal physical properties (e.g., phase change temperature (PCT) and latent heat) of suitable PCM candidates (−97 to 30 °C) for CTES are summarized as well. Secondly, the techniques proposed to enhance the thermal properties of PCMs are presented, including the addition of nanomaterials, the microencapsulation and the shape stabilization. Finally, several representative applications (−97 to 65 °C) of PCMs in different CTES systems are discussed. The pr... [more]

Global energy transition trends are reflected not only in oil and gas market dynamics, but also in the development of related sectors. They influence the demand for various types of metals and minerals. It is well-known that clean technologies require far more metals than their counterparts relying on fossil fuels. Nowadays, rare-earth metals (REMs) have become part and parcel of green technologies as they are widely used in wind turbine generators, motors for electric vehicles, and permanent magnet generators, and there are no materials to substitute them. Consequently, growth in demand for this group of metals can be projected in the near future. The topic discussed is particularly relevant for Russia. On the one hand, current trends associated with the global energy transition affect the country’s economy, which largely depends on hydrocarbon exports. On the other hand, Russia possesses huge REM reserves, which may take the country on a low-carbon development path. However, they are... [more]

Electrochemical impedance spectroscopy is one of the important tools for the performance analysis and diagnosis of proton exchange membrane fuel cells. The equivalent circuit model is an effective method for electrochemical impedance spectroscopy resolution. In this paper, four typical equivalent circuit models are selected to comprehensively compare and analyze the difference in the fitting results of the models for the electrochemical impedance spectroscopy under different working conditions (inlet pressure, stoichiometry, and humidity) from the perspective of the fitting accuracy, change trend of the model parameters, and the goodness of fit. The results show that the fitting accuracy of the model with the Warburg element is the best for all under each working condition. When considering the goodness of fit, the model with constant phase components is the best choice for fitting electrochemical impedance spectroscopy under different inlet pressure and air stoichiometry. However, und... [more]

Throughout the world, and especially in the European Union, numerous technologies for the thermal treatment of radioactive waste are available or being developed. These technologies can be applied to a large range of different radioactive waste streams, including non-standard types of waste that present specific waste management challenges. Thermal treatment can result in a significant reduction in volume and hazard, which are beneficial for safe storage and disposal. Thermal treatment also removes organic material that can form complexing agents and increase the mobility of radionuclides in the landfill. In the paper, basic thermal techniques are presented, and some examples of the installations are shown. Common knowledge of these methods may result in an increased public acceptance of nuclear energy in a country just introducing it, as Poland is.

Due to a high risk of power outages, a heat-driven adsorption chillers are gaining the attention. To increase the efficiency of the chiller, new adsorbents must be produced and examined. In this study, four newly developed silica−based porous materials were tested and compared with silica gel, an adsorber commonly paired with water. Extended sorption tests using mercury intrusion porosimetry, gas adsorption, and dynamic vapor sorption were performed. The morphology of the samples was determined using a scanning electron microscope. The thermal properties were defined using simultaneous thermal analysis and a laser flash method. Metal organic silica (MOS) nanocomposites analysed in this study had thermal properties similar to those of commonly used silica gel. MOS samples have a thermal diffusivity coefficient in the range of 0.17−0.25 mm2/s, whereas silica gel of about 0.2 mm2/s. The highest water adsorption capacity was measured for AFSMo-Cu and equal to 33−35%. For narrow porous sili... [more]

Producing chemical fuels from sunlight is a sustainable way to utilize solar energy and reduce carbon emissions. Within the current photovoltaic-electrolysis or photoelectrochemical-based solar fuel generation system, electrochemical CO2 reduction is the key step. Although there has been important progress in developing new materials and devices, scaling up electrochemical CO2 reduction is essential to promote the industrial application of this technology. In this work, we use Ag and In as the representative electrocatalyst for producing gas and liquid products in both small and big electrochemical cells. We find that gas production is blocked more easily than liquid products when scaling up the electrochemical cell. Simulation results show that the generated gas product, CO, forms bubbles on the surface of the electrocatalyst, thus blocking the transport of CO2, while there is no such trouble for producing the liquid product such as formate. This work provides methods for studying the... [more]

Straw is treated as agricultural waste, and it is available in almost every region of Poland. A total of 30 million tons of straw is produced per year, of which there is a surplus of approximately 13.5 million tons of undeveloped straw. For energy purposes, straw from cereals or rapeseed is most often used. When analyzing scientific publications, it was noticed that, in Poland, large amounts of oat straw are produced, and there is no alternative use for it. Hence, we conducted research to determine the energy value of oat straw. Raw material was obtained from an individual farm from 2018 to 2020. Selected energy parameters for straw burned alone (100%) or co-fired with coal were analyzed in the following weight proportions: 70/30, 80/20, and 90/10 coal/oat straw. It was shown that changing weather conditions, in particular years, had a modifying effect on some of the energy parameters of straw. The calorific value of straw was lower than that of coal, but its impact on environmental po... [more]

The necessity of having windows on any building’s façade is not questionable. However, not every window is suitable for any building. The selection of an adequate window must include the analysis of various factors—the most important ones are the type of window (e.g., single or double glazing); filling gas in cavities (e.g., air, argon or some other gas); and placing, i.e., orientation of a window on a façade (facing north, south, or east, etc.). The research presented in this paper is dealing with the calculation of the window thermal loading for the cities of Kragujevac and Bor in Serbia and Žilina in Slovakia. These three cities were selected because they belong to different climate regions, according to the Köppen−Geiger climatic classification. The first two cities in Serbia belong to the same region Cf with difference only in the category of summer—Kragujevac Cfa and Bor Cfb—while the third city—Žilina in Slovakia—belongs to the Dfb region. The calculated thermal loading through... [more]