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Records with Subject: Process Design
Showing records 58 to 82 of 2098. [First] Page: 1 2 3 4 5 6 7 8 Last
An Ultra Compact Microstrip Branch Line Coupler with Wide Stopband Using LCL Filter and Meandered Stubs for Microwave Applications
Muhammad Akmal Chaudhary, Saeed Roshani, Sobhan Roshani
June 9, 2023 (v1)
Keywords: communication systems, harmonic suppression, lumped component, microstrip coupler
A branch line coupler (BLC) with ultra-compact size and harmonic suppression ability using an LCL filter and meandered stubs is proposed in this paper. There are some important factors in microstrip coupler design, including size reduction, harmonic suppression, and low insertion loss. Thus, improving each of these factors will contribute to a more efficient design. In the proposed circuit, for the first time, LCL filters, including four T-shaped circuits and four meandered line open-ended stubs, were used together to reduce the circuit size and suppress unwanted harmonics. The proposed LCL filters, incorporated in the BLC branches, resulted in superior size reduction and harmonic suppression for the presented BLC. The proposed BLC correctly worked at 900 MHz with 300 MHz operating bandwidth, which showed 33% fractional bandwidth (FBW). Additionally, a wide suppression band from 1.4 GHz to 8.8 GHz, with more than 20 dB attenuation level was obtained, which suppressed the second to nint... [more]
Techno-Economic Evaluation of the Thermochemical Energy Valorization of Construction Waste and Algae Biomass: A Case Study for a Biomass Treatment Plant in Northern Greece
Georgios Manthos, Dimitris Zagklis, Sameh S. Ali, Constantina Zafiri, Michael Kornaros
June 9, 2023 (v1)
Keywords: biomass treatment, combustion, gasification, pyrolysis, techno−economic analysis, thermochemical treatment
Biomass treatment for energy production is a promising way for achieving fossil fuel replacement and environmental relief. Thermochemical processes are a common way of processing biomass, but their potential economic benefits are not always clear to investors. In this work, three basic thermochemical processes (combustion, gasification, and pyrolysis) are examined in terms of their theoretical yields and their products, as well as their economic viability. The goal of this analysis was to look into the total amount of available biomass streams and compare business plans in terms of sustainability from a technical and economic perspective. The estimation of the fixed capital investment was based on ready−made solutions that are already available on the market. The analysis showed that the gasification unit has the optimum sustainability results since the total amount of gross income was EUR 0.13/kg of biomass while the treatment cost was estimated at EUR 0.09/kg of biomass. The internal... [more]
Dynamic Process and Damage Evaluation Subject to Explosion Consequences Resulting from a LPG Tank Trailer Accident
Kan Wang, Yang Liu, Hao Wang, Xiaolei Liu, Yu Jiao, Yujian Wu
June 7, 2023 (v1)
Keywords: explosion consequence, heat flux, process safety, propagation trajectory, shock wave
The involvement of liquefied petroleum gas (LPG), which is highly combustible and explosive, greatly increases risk in road transport. A 3D numerical model was conducted in FLACS, which depicts the dynamic process and variation of combined effects along the multi-directions of LPG explosion under an actual case. With the simulation of scenarios, power-law explosion and fireball models were used to reproduce the results, and the dynamic evolution of specific parameters during the LPG explosion process was analyzed. The results reveal that the LPG explosion’s expansion around the expressway moved along the spaces between obstacles, while conditions at the site of the accident had an enhancement effect on LPG/air mixture accumulation. The propagation trajectory of the shock wave in the horizontal direction presented a regular circle within 623.73 ms, and the overpressure was enough to lead to extensive damage to surrounding structures. Further, shock wave-driven overpressure brought hazar... [more]
NiCoAl-Based Monolithic Catalysts for the N2O Intensified Decomposition: A New Path towards the Microwave-Assisted Catalysis
Olga Muccioli, Eugenio Meloni, Simona Renda, Marco Martino, Federico Brandani, Pluton Pullumbi, Vincenzo Palma
June 7, 2023 (v1)
Keywords: alternative heating, electrification, microwave heating, N2O decomposition, Process Intensification, silicon carbide monoliths, structured catalysts
Nitrous oxide (N2O) is considered the primary source of NOx in the atmosphere, and among several abatement processes, catalytic decomposition is the most promising. The thermal energy necessary for this reaction is generally provided from the external side of the reactor by burning fossil fuels. In the present work, in order to overcome the limits related to greenhouse gas emissions, high heat transfer resistance, and energy losses, a microwave-assisted N2O decomposition was studied, taking advantages of the microwave’s (MW) properties of assuring direct and selective heating. To this end, two microwave-susceptible silicon carbide (SiC) monoliths were layered with different nickel−cobalt−aluminum mixed oxides. Based on the results of several characterization analyses (SEM/EDX, BET, ultrasound washcoat adherence tests, Hg penetration technique, and TPR), the sample showing the most suitable characteristics for this process was reproduced in the appropriate size to perform specific MW-as... [more]
Effect of Aging Methods and Ultrasonication Treatment on the Sensory Profile of Beef Longissimus lumborum Muscle
Ivan A. Garcia-Galicia, Raheel Suleman, Ujala Hussain, Mariana Huerta-Jimenez, Luis M. Carrillo-Lopez, Alma D. Alarcon-Rojo
June 7, 2023 (v1)
Keywords: aging, beef muscle, consumer acceptability, sensory traits, ultrasound
Tenderness is one of the most appreciated quality characteristics in beef by consumers. Meat aging is the most recognized natural methodology to improve tenderness in beef. The current study was designed to evaluate if ultrasonication was able to simulate (ultrasonication alone) or to grant an additional effect (aging plus ultrasonication) to two different aging methods (dry and wet) on the sensory profile of the beef Longissimus lumborum muscle. The two aging methods (dry and wet), or ultrasonication for 40 min (US), had no effect (p > 0.05) in overall consumer acceptability. However, in terms of sensory attribute liking, the highest values (p < 0.05) were observed in the ultrasonicated and wet-aged meat for 10 d and the dry-aged meat for 10 d, without difference between them (p > 0.05). It is concluded that ultrasound offers the possibility to obtain tender meat without the cost and contamination risks implicated in the dry-aging method.
A Risk-Data-Based Human Reliability Analysis for Chemical Experiments with Hazardous Processes
Renyou Zhang, Jun Ge, Jinchao Zhang, Huanhuan Cui, Qinhao Zhang, Zexing Zhang
June 7, 2023 (v1)
Keywords: chemical experiments, fuzzy CREAM, GRA, hazardous processes, human reliability, risk data
In recent years, chemical experiment accidents have frequently occurred, resulting in injuries and fatalities among researchers. It is crucial to address this issue to improve laboratory safety. Based on many publications, it is clear that human error makes a major contribution to many laboratory accidents which contain hazardous processes. However, there is limited research focusing on human error in laboratory safety, and there is also a lack of effective measures to assess Human Error Probability (HEP) for experimental process safety. Therefore, we propose an improved Cognitive Reliability and Error Analysis Method (CREAM) which is based on risk data to assess the HEP during hazardous processes in chemical experiments. The proposed method adjusts nine Common Performance Conditions (CPCs) in conventional CREAM to make them suitable to describe chemical experiments. Then, in contrast to the traditional approach, this study uses the definition of risk as the support to collect CPC data... [more]
Dissolving Activated Carbon Pellets for Ibuprofen Removal at Point-of-Entry
Michelle Finn, Noelle Yackel, Gabrielle Giampietro, David Mazyck
June 7, 2023 (v1)
Keywords: activated carbon, carbon pellet, ibuprofen, water treatment
The increased usage of pharmaceuticals coupled with the desire for greywater reuse to reduce the freshwater demand for potable water requires a user-friendly engineered solution. Activated carbon is a proven technology that is typically used for organic pollutant removal at water treatment plants. Lignite, coconut, and a blend of activated carbon powders were used to develop rapid-dissolving pellets with an inorganic binder. Ibuprofen was the model compound chosen for pharmaceutical adsorption in deionized water and synthetic hydrolyzed and synthetic fresh urine at rapid contact times (0.5 to 30 min) and using various pellet dosages (0.5 to 10 g/L). A cost analysis was performed to determine the feasibility of the engineered solution. With an increase in contact time, the coconut pellets outperformed both the blend and lignite pellets in deionized water at a set pellet dosage. The lignite pellets were the most cost-effective with rapid adsorption in fresh urine and a capacity of 0.089... [more]
Design and Development of Photocatalytic Systems for Reduction of CO2 into Valuable Chemicals and Fuels
Amra Bratovčić, Vesna Tomašić
June 7, 2023 (v1)
Keywords: efficiency, methane, Methanol, MOFs, photocatalytic CO2 reduction, selectivity, semiconductor, TiO2, Z-scheme heterojunction
This review presents the results of research in the field of photocatalytic reduction of carbon dioxide (CO2) to methane and methanol as valuable chemicals and fuels. CO2 reduction is a promising technology, but it is an endothermic process with unfavourable thermodynamics. Other limitations include the inertness of the CO2 molecule, the slow multielectron process, and the lack of understanding of the reaction mechanism, leading to low selectivity and insufficient efficiency. Tailoring reaction parameters such as CO2 adsorption, choice of reducing agent, development of photocatalysts in terms of composition, structural properties and morphology, energy band gap, and the presence of surface functional groups can affect the reaction mechanism and selectivity for the desired product. Therefore, the main challenges in this research area are the development of an active and selective catalyst for the photoreduction of CO2 to useful products with high added value and the optimization and dev... [more]
Study on Flow Characteristics of Flue Gas and Steam Co-Injection for Heavy Oil Recovery
Yanmin Ji, Boliang Li, Zongyuan Han, Jian Wang, Zhaomin Li, Binfei Li
June 7, 2023 (v1)
Keywords: flow characteristic, flue gas, heavy oil, microscopic experiment, steam
Flue gas is composed of N2 and CO2, and is often used as an auxiliary agent for oil displacement, with good results and very promising development prospects for co-injection with steam to develop heavy oil. Although research on the oil displacement mechanism of flue gas has been carried out for many years, the flow characteristics of steam under the action of flue gas have rarely been discussed. In this paper, the flow resistance and heat transfer effect of flue gas/flue gas + steam were evaluated by using a one-dimensional sandpack, a flue gas-assisted steam flooding experiment was carried out using a specially customized microscopic visualization model, and the microscopic flow characteristics in the process of the co-injection of flue gas and steam were observed and analyzed. The results showed that flue gas could improve the heat transfer effect of steam whilst accelerating the flow of steam in porous media and reducing the flow resistance of steam. Compared with pure steam, when t... [more]
Applying a Combination of Cutting-Edge Industry 4.0 Processes towards Fabricating a Customized Component
Antreas Kantaros, Evangelos Soulis, Theodore Ganetsos, Florian Ion Tiberiu Petrescu
June 7, 2023 (v1)
Keywords: 3D printing, 3D scanning, bicycle, customized component, FDM, generative design
3D scanning, 3D printing, and CAD design software are considered important tools in Industry 4.0 product development processes. Each one of them has seen widespread use in a variety of scientific and commercial fields. This work aims to depict the added value of their combined use in a proposed workflow where a customized product needs to be developed. More specifically, the geometry of an existing physical item’s geometry needs to be defined in order to fabricate and seamlessly integrate an additional component. In this instance, a 3D scanning technique was used to digitize an e-bike’s frame geometry. This was essential for creating a peripheral component (in this case, a rear rack) that would be integrated into the frame of the bicycle. In lieu of just developing a tail rack from scratch, a CAD generative design process was chosen in order to produce a design that favored both light weight and optimal mechanical behaviors. FDM 3D printing was utilized to build the final design using... [more]
Study on Flow Characteristics of Hydraulic Suction of Seabed Ore Particles
Qiu Xia, Hao Jia, Jiuchun Sun, Xiaoguang Xi, Jingyu Cui
June 7, 2023 (v1)
Keywords: deep-sea mining, hydraulic suction, particle motion characteristics, solid–liquid two-phase flow, vertical force
Efficient and environmentally friendly ore collecting operation requires that the ore collecting head can provide just enough suction to start the ore particles in different working conditions. In this work, computational fluid dynamics and discrete element method (CFD-DEM) is used to simulate the hydraulic suction process of ore particles. After analyzing the pressure and velocity characteristics of the flow field, the effects of different suction velocities on the lateral displacement offset, drag coefficient Cd and Reynolds number Rep of particles are studied. It is determined that the lifting force is caused by the different flow velocities of the upper and lower flow fields; particle start-up time and the lateral offset are inversely proportional to suction speed. When h/d ≥ 2.25, the vertical force on particles is no longer affected by h/d. When S/d = 2.5, FZ decreases to 0 N; when h/d increases from 1.5 to 1.75, FZ decreases by nearly half. Three empirical equations for FZ repre... [more]
Examining Transit-Time Ultrasonic Flowmeter Inaccuracies during Changing Gas Velocity Profiles
Sameh Alsaqoor, Piotr Piechota, Ali Alahmer, Samer As’ad, Nabil Beithu, Wiesław Wędrychowicz, Artur Andruszkiewicz, Patryk Kotomski
June 7, 2023 (v1)
Keywords: flow measurement, flow stream, measurement error, shape factor, ultrasonic flowmeter
This study investigates the impact of changes in velocity profiles on the measurement inaccuracies of gas flow streams detected by an ultrasonic flowmeter. The cross-sectional velocity profile was influenced by the downhill flow rate, causing variations in the shape factor coefficient. The flowmeter processing equation should consider the factor of shape coefficient variations. Consideration for these variations can result in errors in the measurement of the flow stream. The processing equation assumes a single, constant value for the shape factor coefficient, which can lead to inaccuracies. This article covers the inaccuracies of the transit-time ultrasonic flowmeter caused by a change in the velocity profile of the flowing gas, such as air. A realistic flow system was established with measured flow rates ranging from 43 m3/h to 225 m3/h. The findings of this study can serve as a valuable reference for the design and implementation of more accurate and efficient flow measurement syste... [more]
Innovative Approaches to Solar Desalination: A Comprehensive Review of Recent Research
Ahmed E. Abu El-Maaty, Mohamed M. Awad, Gamal I. Sultan, Ahmed M. Hamed
May 24, 2023 (v1)
Keywords: desalination, direct, fog, HDH, indirect, solar, solar still
Solar desalination systems are a promising solution to the water scarcity problem since the majority of the earth’s water resources are salty. With the increasing focus on desalination research, many innovative methods are being developed to extract salts from saline water. Energy consumption is a significant concern in desalination, and renewable energy, particularly solar energy, is considered a viable alternative to fossil fuel energy. In this review, we will focus on direct and indirect solar desalination methods, specifically traditional direct solar desalination methods such as solar still and humidification dehumidification (HDH) desalination systems. We will also briefly discuss a recent advancement in the desalination method known as the fogging process, which is a development of the HDH desalination system.
Techno-Economic Analysis of Thermochemical Conversion of Waste Masks Generated in the EU during COVID-19 Pandemic into Energy Products
Samy Yousef, Vidas Lekavičius, Nerijus Striūgas
May 24, 2023 (v1)
Keywords: gasification, internal rate of return, pyrolysis, surgical mask waste, Technoeconomic Analysis
During the COVID-19 pandemic, more than 24 billion pieces of surgical mask waste (WM) were generated in the EU region, with an acute shortage of their management and recycling. Pyrolysis and gasification are among the most promising treatments that were proposed to dispose of WMs and convert them into pyrolysis oil and hydrogen-rich syngas. This work aimed to investigate the techno-economic analysis (TEA) of both treatments in order to assess the feasibility of scaling up. The TEA was carried out using a discounted cash flow model and its data were collected from practical experiments conducted using a fluidised bed pyrolysis reactor and bubbling fluidised bed gasifier system with a capacity of 0.2 kg/h and 1 kg/h, respectively, then upscaling to one tonne/h. The technological evaluation was made based on the optimal conditions that could produce the maximum amount of pyrolysis oil (42.3%) and hydrogen-rich syngas (89.7%). These treatments were also compared to the incineration of WMs... [more]
Numerical Simulation on the Influence of Inlet Flow Characteristics on the Performance of a Centrifugal Compressor
Xing Li, Ning Huang, Guanyan Chen, Yanli Zhang, Yang Zhao, Jie Zhang, Ding Tong
May 24, 2023 (v1)
Keywords: centrifugal compressor, distortion degree, inlet bent pipes, numerical simulation, reduction degree
Although inlet bent pipes are usually adopted due to limited installation space, the influences of different bend pipes on the inlet flow characteristics and performance of centrifugal compressors are still unclear. The numerical simulation of a centrifugal compressor is established and validated by experimental results with the case of a straight inlet pipe. Then, the internal flow characteristics of the centrifugal compressor with a 90-degree bent pipe (p90) and Z-shaped bent pipe (pz) are simulated and discussed. The results show that the adoption of two inlet bent pipes reduces the performance of the centrifugal compressor to a certain extent, which reduces more greatly with pz, with a maximum reduction of 6.82% in pressure ratio and 14.83% in efficiency, respectively. The pressure ratio and efficiency reduction of the centrifugal compressor both increase with the increment of distortion degree, which maintains the increasing trend as the flow rate increases, and the maximum distor... [more]
Flow Characteristics and Parameter Influence of the Under-Expansion Jet on Circulation Control Airfoil
Meng He, Liu Zhang, Chang Li, Lei Zhao
May 23, 2023 (v1)
Keywords: circulation control, flow control, shock structure, under-expansion jet
The enhancement in the jet pressure ratio and jet velocity contributes to expanding the control efficiency and control boundary of circulation control airfoil under high subsonic incoming flow. However, because of an excessive jet pressure ratio, the jet separates prematurely on the Coanda surface, resulting in control failure. In a bid to improve the adhesion capability of the jet under a high pressure ratio, a circulation control airfoil with a converging nozzle and back-facing step structure at the trailing edge was numerically simulated based on the Reynolds averaged Navier−Stokes equation (RANS), and a study was conducted on the complex flow structure of the under-expansion jet on the Coanda surface and the impact of design parameters such as jet pressure ratio, ellipticity, and nozzle height on the jet separation. The results show that the back-facing step provides an expansion space for the under-expansion jet and changes the shock-boundary layer interaction form. As the jet pre... [more]
Decarbonizing Telecommunication Sector: Techno-Economic Assessment and Optimization of PV Integration in Base Transceiver Stations in Telecom Sector Spreading across Various Geographically Regions
Muhammad Bilal Ali, Syed Ali Abbas Kazmi, Abdullah Altamimi, Zafar A. Khan, Mohammed A. Alghassab
May 23, 2023 (v1)
Keywords: base transceiver stations (BTS), decarbonization, hybrid energy systems, net present cost (NPC), real-time pricing, techno-economic assessment, telecommunication
Renewable energy is considered to be sustainable solution to the energy crisis and climate change. The transition to renewable energy needs to be considered on a sectoral basis and one such sector that can potentially decarbonized with renewable energy is the telecommunication sector. Several base transceiver stations (BTS) in remote regions have unstable electric supply systems. Diesel generators (DG) are a common solution to energy problems on such telecommunication sites. However, they have high fuel costs on the global market and contribute to high carbon emissions. Hybrid renewable energy systems may provide a stable power output by integrating multiple energy sources, essential for supplying a dependable and uninterrupted power supply in the context of the telecom sector, notably base transceiver stations (BTS). Deploying such a system might also help BTS, which relies mainly on diesel generators with battery storage backup, reduce operational costs and environmental problems. Th... [more]
Sustainability of Biorefineries: Challenges and Perspectives
Juan Camilo Solarte-Toro, Carlos Ariel Cardona Alzate
May 23, 2023 (v1)
Keywords: bioeconomy, biomass upgrading, Carbon Dioxide Capture, decarbonization, multifeedstock biorefinery, process design
Biorefineries have been defined as complex systems where biomass is integrally processed to obtain value-added products and energy vectors, involving recent research advances, technological trends, and sustainable practices. These facilities are evolving since new pathways and challenges for biomass upgrading appear constantly aimed at increasing process sustainability. Nevertheless, few literature papers summarize how these new trends can improve biorefinery sustainability and boost the transition to renewable resources. This paper reviews several challenges and future perspectives before biorefinery implementation at the industrial level. Challenges related to waste stream valorization, multifeedstock use, biorefinery energy matrix diversification, and new products based on new biomass conversion pathways are reviewed. Thus, this paper provides an overview of the most recent trends and perspectives for improving biorefinery sustainability based on waste stream minimization, integral... [more]
Design Principles and Calculation Criteria for Skewed Notches in PM Motors
Siwei Ji, Yukai Li, Huanyu Ou, Wenlong Tian
May 23, 2023 (v1)
Keywords: cogging torque reduction, PM machine, skewed notch design
The stator structure is one of the main factors affecting the electromagnetic performance of permanent magnet (PM) motors. In this paper, an in-depth study and analysis of how to reduce the cogging torque is carried out from the perspective of the stator structure. According to the theory of cogging torque synthesis, this paper presents a unified calculation formula for different PM motor skewed notch designs. This theory is verified with a 20-pole, 60-slot motor and a 20-pole, 24-slot motor, respectively. The formula worked out proved to be highly applicable. The formula is intended to address how to quickly obtain key data (skew angle, notch depth) in a skewed notch study.
Energy Performance Comparison of a Chiller Plant Using the Conventional Staging and the Co-Design Approach in the Early Design Phase of Hotel Buildings
Yamile Díaz Torres, Paride Gullo, Hernán Hernández Herrera, Migdalia Torres del Toro, Roy Reyes Calvo, Jorge Iván Silva Ortega, Julio Gómez Sarduy
May 23, 2023 (v1)
Keywords: chiller plant, co-design, optimal chiller loading, optimal chiller sequencing, traditional staging
As part of the design process of a chiller plant, one of the final stages is the energy testing of the system in relation to future operating conditions. Recent studies have suggested establishing robust solutions, but a conservative approach still prevails at this stage. However, the results of some recent studies suggest the application of a new co-design (control−design) approach. The present research involves a comparative analysis between the use of conventional staging and the co-design approach in the design phase of a chiller plant. This paper analyzes the energy consumption estimations of six different chiller plant combinations for a Cuban hotel. For the conservative approach using on/off traditional staging, the results suggest that the best option would be the adoption of a chiller plant featuring a symmetrical configuration. However, the outcomes related to the co-design approach suggest that the best option would be an asymmetrical configuration. The energy savings result... [more]
Study on the Effect of Dedicated Microelement Mixture (DMM) on the Kick-Off Phase of the Digester and Stabilization of the Methane Fermentation Process
Sławomir Łazarski, Andrzej Butarewicz, Marcin Cichosz, Urszula Kiełkowska
May 23, 2023 (v1)
Keywords: anaerobic digestion, biogas, methane yield, microelements
The kick-off process is an important aspect of the proper operation of an agricultural biogas plant. At this stage, various operational problems may arise, mainly related to the stabilization of the fermentation process and reaching the full biogas production capacity. This paper presents the results of research on the kick-off of the fermentation process carried out on three selected biogas plants located in Poland. For the experiments, titration, potentiometric, and spectroscopic methods (ICP-MS) were used. The biogas plants during the kick-off period operated on the following substrates: a mixture of cattle and pig manure, corn silage, and whey liquor. Special attention was paid to the dosing process of the formulation developed by the authors (CMP-S1) containing Mo, Co, Ni, Se, and Mn for the fermentation chambers, to which the mixture of the selected microelements was not dosed. The study was carried out under real conditions on an engineering scale. The study showed that suppleme... [more]
Development of a Steam Generator Mock-Up for EU DEMO Fusion Reactor: Conceptual Design and Code Assessment
Alessandra Vannoni, Pierdomenico Lorusso, Marica Eboli, Fabio Giannetti, Cristiano Ciurluini, Amelia Tincani, Ranieri Marinari, Andrea Tarallo, Alessandro Del Nevo
May 23, 2023 (v1)
Keywords: DEMO, experimental installation, once through steam generator (OTSG), RELAP5, STEAM facility, water technologies
Recent R&D activities in nuclear fusion have identified the DEMO reactor as the ITER successor, aiming at demonstrating the technical feasibility of fusion plants, along with their commercial exploitation. However, the pulsed operation of the machine causes an “unconventional” operation of the system, posing unique challenges to the functional feasibility of the steam generator, for which it is necessary to define and qualify a reference configuration for DEMO. In order to facilitate the transitions between different operational regimes, the Once Through Steam Generator (OTSG) is considered to be a suitable choice for the DEMO primary heat transfer systems, being characterized by lower thermal inertia with respect to the most common U-tube steam generators. In this framework, the ENEA has undertaken construction of the STEAM facility at Brasimone R.C., aiming at characterizing the behavior of the DEMO OTSG and related water coolant systems in steady-state and transient conditions. A de... [more]
Pt-Fe-Co Ternary Metal Single Atom Catalyst for toward High Efficiency Alkaline Oxygen Reduction Reaction
Ruimin Zhang, Ke Wang, Peng Wang, Yan He, Zhiming Liu
May 23, 2023 (v1)
Keywords: electrocatalysts, kinetics, oxygen reduction reaction, single atom, ternary metal
Single-atom catalysts (SACs) within carbon matrix became one of the most promising alternatives to noble metal-based catalysts for oxygen reduction reaction (ORR). Although SACs have significant benefits in reducing the total catalyst cost, it also has the disadvantages of weak interaction between atoms and poor stability. Hence, there is still much room for improvement for the catalyst activity. In response, we designed a Fe-Co-Pt ternary metal single atom catalyst anchored on covalent organic framework (COF)-derived N-doped carbon nanospheres (Pt, Fe, Co/N-C). Due to effective charge transfer between Pt single atom and neighboring Fe-Co components, an intense electron interaction can be established within the Pt, Fe, Co/N-C catalyst. This is beneficial for enhancing charge transfer efficiency, modulating d electronic structure of Pt center and weakening oxygen intermediate adsorption, thus distinctly accelerating ORR catalytic kinetics. As expected, the half-wave potential of Pt, Fe,... [more]
Diffusion Absorption Refrigeration Systems: An Overview of Thermal Mechanisms and Models
Baby-Jean Robert Mungyeko Bisulandu, Rami Mansouri, Adrian Ilinca
May 23, 2023 (v1)
Keywords: ARS/DAR systems, energy performance, energy sources, generator/bubble pump design, hybrid ARS/DAR, thermal mechanisms
The energy transition, originating in the limitation of fossil resources and greenhouse gas (GHG) emission reduction, is the basis of many studies on renewable energies in different industrial applications. The diffusion absorption refrigeration machines are very promising insofar as they allow the use of renewable resources (solar, geothermal, waste gas, etc.). This technology is often considered an alternative to vapor compression systems in cooling and refrigeration applications. This paper aims to overview the thermal mechanisms related to modeling system energy sources and highlight the primary methodologies and techniques used. We study and analyze the technology’s current challenges and future directions and, finally, identify the gaps in the existing models to pave the way for future research. The paper also gives a classification of absorption refrigeration systems (ARS) to position and limit the scope of the study. The paper will help researchers who approach the various aspe... [more]
Investigation on Swelling Performance of Oil Sands and Its Impact on Oil Production during SAGD Processes
Xiuyu Wang, Chuanying Zhang, Guorui Sun
May 2, 2023 (v1)
Keywords: illite-montmorillonite mixed layer, mineral transformation, Oil Sands, particle migration, swelling rate
SAGD (Steam Assisted Gravity Drainage) is used in Canadian fields where there are interlayers that impede steam chamber development and thus impede production. Many experiments have been conducted on the effect of interlayers on oil recovery. However, the swelling characteristics of interlayers under different conditions, as well as the possible clay mineral transformation and particle migration of clay particles at high temperatures, are rarely studied. In this paper, the swelling characteristics of natural oil sands and artificial clay samples were studied by high temperature hydration swelling experiments to obtain a better comparison. The effects of temperature, pressure and solution type on the swelling rate of oil sand were studied. The uniaxial compressive strength of the core in the presence of clay was studied by the scribe test. In addition, before and after the aging test at 220 °C and 2.5 MPa, the clay mineral composition was studied by the X-ray diffraction method, and the... [more]
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