Gasification is considered a clean and effective way to convert low quality biomass to higher value gas and solve various waste utilization problems as well. However, only 80% of biomass is converted through thermal processes. The remaining part is char, which requires more time for conversion and in that case reduces the efficiency of gasifier. Seeking to optimize the process of gasification, this work focuses on the intensification of residual char gasification in a gasifier. For this purpose, three different types of char prepared from wood, sewage sludge and tire were examined under different conditions in a lab-scale gasification setup. Results showed that the air flux increase from 0.11 kg/(m2s) to 0.32 kg/(m2s) intensified the gasification process and the gasification rate increased from 0.8 to 2.61 g/min with the decrease of duration of wood char gasification by 72%. An additional introduction of pyrolysis gas into the char gasifier led to decreased bed temperatures, but the ga... [more]

Identifying a modeling procedure of biomass thermal decomposition that is not only simple enough to implement and use, and computationally efficient, but also sufficiently accurate for engineering design activities, and with a spectrum of applications as broad as possible is a very difficult task. The authors propose a procedure which consists of two main stages: (a) the static modeling phase with the purpose of generating the algorithm (macro functions) that supplies a Computational Fluid Dynamics (CFD) model with specific input data (source/sink terms and local material properties) and (b) the dynamic modeling phase, where the CFD model is bi-directionally coupled to the external biomass decomposition model in the form of a User-Defined Function (UDF). The modeling approach was successfully validated against data obtained from single particle decomposition experiments, demonstrating its applicability even to large biomass particles, under high heating rates and combusting conditions.

One of the tools to attain the goal of climate-neutrality by 2050 by the European Union is increasing the share of renewable energy sources (RESs) in the energy mix of member states. A major part of the future bioenergy mix is to be played by biomass. As many hazards have been pointed out when using forest biomass, particular attention is paid to the potential of agro biomass. However, as agro biomass is sourced mostly locally, the supply may not be sufficient to meet the growing demand. Therefore, international trade (including overseas) might become increasingly important to meet the EU renewable energy targets. In this context, it is seaports that may play a major part in developing biomass supply chains. The main purpose of the article is to fill the research gap by identifying the pros and cons for the development of biomass sea-based supply chains through secondary ports and specifying their relevance from the perspective of major stakeholders in the context of decarbonization pr... [more]

Tanzania has a high rural population, of which many rely on off-grid diesel generators to produce electricity. The focus of this paper is to assess if the waste biomass residues in Tanzania have sufficient energy potential to produce renewable electrical energy for small-scale electricity generation using off-grid diesel generators coupled with anaerobic digestion (AD) and/or gasification. The gaseous fuel produced can then be used to substitute diesel fuel used in small-scale dual fuel diesel gen-sets; thus, providing more affordable electricity whilst reducing dependency on fossil fuels. The biomass waste streams estimated are those arising from agriculture, forestry, livestock, and urban human waste. To answer this question, the energy potentials of each of these biomass waste streams are quantified, followed by further calculations to determine the electricity generation capacity per stream based on overall efficiencies of 10 and 25%. The results show that combined these waste stre... [more]

This paper deals with the state and perspectives of bioenergy development in the context of exploiting the potential of available natural resources. We analyse the economic benefits of transitioning to alternative biofuel within the research task in cooperation with the Vojany black coal power plant. Within the applied methodology, a non-parametric data envelopment analysis method was used to confirm the most economically efficient types of fuels used in the combustion process. The assumption of fuel efficiency was confirmed by testing fuel combustion combinations directly in the power plant. The transition to 100% combustion of solid recovered fuel creates the potential for sustainable production of the analysed power plant and compliance with the current emission values of basic pollutants and new stricter limits, which will be binding in the EU from August 2021. The proposed solutions were analysed by Monte Carlo simulation. An estimate of the economic results achieved by the power... [more]

Biomass chemical looping gasification (CLG) is a novel gasification technology for hydrogen production, where the oxygen carrier (OC) transfers lattice oxygen to catalytically oxidize fuel into syngas. However, the OC is gradually reduced, showing different reaction activities in the CLG process. Fully understanding the CLG reaction mechanism of fuel molecules on perfect and reduced OC surfaces is necessary, for which the CLG of ethanol using Fe2O3 as the OC was introduced as the probe reaction to perform density functional theory calculations to reveal the decomposition mechanism of ethanol into the synthesis gas (including H2, CH4, ethylene, formaldehyde, acetaldehyde, and CO) on perfect and reduced Fe2O3(001) surfaces. When Fe2O3(001) is reduced to FeO0.375(001), the calculated barrier energy decreases and then increases again, suggesting that the reduction state around FeO(001) favors the catalytic decomposition of ethanol to produce hydrogen, which proves that the degree of reduct... [more]

The demand for clean energy is a key global issue requiring global ideas to be implemented through local action. This is particularly important in Poland’s energy transition, since the country produces energy mainly from conventional sources, i.e., coal, gas, and crude oil. Adverse climate change caused by high emissions of the economy based on the combustion of hydrocarbons as well as the growing public awareness have made it necessary to look for new environmentally friendly energy sources. The aim of the paper is to demonstrate that the use of alternative energy sources, biomass in particular, is compatible with sustainable development policy. Eight indicators for the EU-28 and for Poland were analysed in order to verify the progress in modifying the energy mix between 2010 and 2018 in the context of implementing Sustainable Development Goals (SDGs). The analysis showed that both in the EU-28 and in Poland, the aggregated indicator taking into account the positive and negative chang... [more]

This paper addresses the solar thermochemical conversion of biomass or waste feedstocks based on pyro-gasification for the clean production of high-value and energy-intensive fuels. The utilization of solar energy for supplying the required process heat is attractive to lower the dependence of gasification processes on conventional energy resources and to reduce emissions of CO2 and other pollutants for the production of high-value chemical synthetic fuels (syngas). Using concentrated solar energy to drive the endothermal reactions further allows producing more syngas with a higher gas quality, since it has not been contaminated by combustion products, while saving biomass resources. The solar-driven process is thus a sustainable and promising alternative route, enabling syngas yield enhancement and CO2 mitigation, thereby potentially outperforming the performance of conventional processes for syngas production. This review presents relevant research studies in the field and provides t... [more]

Hydrothermal pretreatment of biomass can improve fuel characteristics based on the decomposition properties of subcritical water. Thus, this study used a hydrothermal treatment to improve the fuel characteristics of empty fruit bunches (EFBs), which are generated as waste after palm oil extraction. The experimental reaction temperature was increased from 180 °C to 250 °C at an interval of 10 °C and the mass ratios between the dry sample and water content were set to 1:8 and 1:16 so that the sample was sufficiently immersed. Additionally, the material properties of EFB under hydrothermal treatment conditions were investigated using mass and energy yields, elemental analysis, proximate analysis, thermogravimetric analysis, derivative thermogravimetry, and Fourier transform infrared spectroscopy analysis of the reaction products. As the reaction temperature increased, the fixed carbon content and heating value increased because volatile matter, including oxygen, was removed first, which i... [more]

The continued growth and evolving lifestyles of the human population require the urgent development of sustainable production in all its aspects. Microalgae have the potential of the sustainable production of various commodities; however, the energetic requirements of algae cultivation still largely contribute to the overall negative balance of many operation plants. Here, we evaluate energetic efficiency of biomass and lipids production by Chlorella pyrenoidosa in multi-tubular, helical-tubular, and flat-panel airlift pilot scale photobioreactors, placed in an indoor environment of greenhouse laboratory in Central Europe. Our results show that the main energy consumption was related to the maintenance of constant light intensity in the flat-panel photobioreactor and the culture circulation in the helical-tubular photobioreactor. The specific power input ranged between 0.79 W L−1 in the multi-tubular photobioreactor and 6.8 W L−1 in the flat-panel photobioreactor. The construction of m... [more]

Formic acid is a liquid organic hydrogen carrier giving hydrogen on demand using catalysts. Metal complexes are known to be used as efficient catalysts for the hydrogen production from formic acid decomposition. Their performance could be better than those of supported catalysts with metal nanoparticles. However, difficulties to separate metal complexes from the reaction mixture limit their industrial applications. This problem can be resolved by supporting metal complexes on the surface of different supports, which may additionally provide some surface sites for the formic acid activation. The review analyzes the literature on the application of supported metal complexes in the hydrogen production from formic acid. It shows that the catalytic activity of some stable Ru and Ir supported metal complexes may exceed the activity of homogeneous metal complexes used for deposition. Non-noble metal-based complexes containing Fe demonstrated sufficiently high performance in the reaction; howe... [more]

In Thailand, Napier grass is expected to play an important role as an energy resource for future power generation. To accomplish this goal, numerous areas are required for Napier grass plantations. Before introducing crops, the land potential of the country and the impact of crops on the environment should be assessed. The soil and water assessment tool (SWAT) model is very useful in investigating crop impacts and land potential. Unfortunately, the crop growth parameters of Napier grass are yet to be identified and, thus, conducting effective analysis has not been possible. Accordingly, in this study, parameter calibration and SWAT model validation of Napier grass production in Thailand was carried out using datasets from eight sites with 93 samples. Parameter sensitivity analysis was performed prior to parameter calibration, the results of which suggest that the radiation use efficiency and potential harvested index are both highly sensitive. The crop growth parameters were calibrated... [more]

Energy-storage metabolites such as neutral lipids and carbohydrates are valuable compounds for liquid biofuel production. The aim of this work is to elucidate the main biological responses of two algae species known for their effective energy-rich compound accumulation in nitrogen limitation and day−night cycles: Nannochloropsis gaditana, a seawater species, and Parachlorella kessleri, a freshwater species. Lipid and carbohydrate production are investigated, as well as cell resistance to mechanical disruption for energy-rich compound release. Nitrogen-depleted N. gaditana showed only a low consumption of energy-storage molecules with a non-significant preference for neutral lipids (TAG) and carbohydrates in day−night cycles. However, it did accumulate significantly fewer carbohydrates than P. kessleri. Following this, the highest levels of productivity for N. gaditana in chemostat cultures at four levels of nitrogen limitation were found to be 3.4 and 2.2 × 10−3 kg/m2·d for carbohydrat... [more]

This study investigated the quantitative and qualitative attributes of liquid product and biochar obtained from pyrolysis of woody biomass (rubberwood sawdust (RWS)) and non-woody biomasses (oil palm trunk (OPT) and oil palm fronds (OPF)). The prepared biomass was pyrolyzed at temperatures of 500 °C, 550 °C, and 600 °C by using an agitated bed pyrolysis reactor, and then the yields and characteristics of liquid product and biochar were determined. The results showed that liquid product and biochar yields were in the respective ranges of 35.94−54.40% and 23.46−25.98% (wt.). Pyrolysis of RWS at 550 °C provided the highest liquid yield. The energy content of the water free liquid product was in the range 12.19−22.32 MJ/kg. The liquid product had a low pH and it mainly contained phenol groups as indicated by GC-MS. The biochars had high carbon contents (75.07−82.02%), while their oxygen contents were low (14.22−22%). The higher heating value (HHV) of biochar was in the range 26.42−29.33 MJ... [more]

Biomass residues are often considered as a resource if conveniently converted in fuel and alternative feedstock for chemical processes, and their conversion into valuable products may occur by different pathways. This work is focused on the thermochemical conversion at moderate temperature and in steam atmosphere, a mild process in comparison to hydrothermal liquefaction, followed by extraction of soluble products in a solvent. Such process has been already applied to various residues and here extended to the case of marc, the residual pomace from wine making, largely produced worldwide. A pressurized batch reactor was used for the quantitative determination of produced solid and liquid fractions, and their qualitative characterization was performed by instrumental analyses. The pressurized steam conversion of marc was effective, providing a yield in liquid fraction, upon extraction in solvent, up to 30% of the raw dried biomass. The use of polar and nonpolar solvent for the extraction... [more]

This study presents a combined cooling, heating, and power system powered by biogas, suitable for small scale communities in remote locations. To run such a system, in order to obtain the daily life essentials of electricity, hot water, and cooling, municipal waste can be considered as an option. Furthermore, the organic Rankine cycle part of the organic Rankine cycle powered vapor compression chiller can be used in times of need for additional electric production. The system comprises a medium temperature organic Rankine cycle utilizing M-xylene as its working fluid, and the cooling was covered by an Isobutane vapor compression cycle powered by an R245fa employing organic Rankine cycle. The system analyzed was designated to provide 250 kW of electricity. The energetic and exergetic analysis was performed, considering several system design parameters. The impact of the design parameters in the prime mover has a much greater effect on the whole system. The system proposed can deliver co... [more]

Increasingly stringent limits for NOx and SO2 emission are forcing the investigation of new reduction methods. This study was conducted to determine the combination of primary measures, i.e., flue gas recirculation (FGR) and excess air effects on sulfur, nitrogen and hydrocarbon emissions, in boiler flue gas. Experimental research was performed using an experimental, small-scale (20 kW) model of an industrial biofuel boiler. During combustion of sunflower seed hulls at different FGR ratios and incomplete combustion regimes, the composition of flue gas (NO, NO2, N2O, HCN, NH3, SO2, SO3, H2S, CO, and CxHy) was compared, allowing an explanation of the determinants of emission concentration changes to be provided. Increasing the flue gas recirculation ratio in the primary air had a positive effect on reducing NOX and CO with certain organic compounds. However, an opposite effect on SO2 was observed. NOX and SO2 concentrations were found to be approximately 500 mg/m3 and 150 mg/m3 under a r... [more]

Energy obtained from renewable sources is an important element of the sustainable development strategy of the European Union and its member states. The aim of this research is, therefore, to assess the potential and use of renewable energy sources and their effectiveness from the regional perspective in Poland. The research covered the years 2012 and 2018. The diversification of production and potential of renewable energy sources was defined on the basis of biogas and biomass. Calculations made using the data envelopment analysis (DEA) method showed that, in 2012, only three voivodeships achieved the highest efficiency in terms of the use of biogas and biomass resources; in 2018, this number increased to four. Comparing the effective units in 2012 and 2018, it can be seen that their efficiency frontier moved upwards by 56% in terms of biogas and 21% in terms of to biomass. Despite a large relative increase in the production of heat from biogas by 99% compared to the production of heat... [more]

In this study, a low-temperature drying plant based on renewable energies to dry food processing wastes is investigated. The demand-oriented heat supply is realized by a solar wall in combination with a biomass boiler. Due to the operational complexity of such a system with different sub-units and process parameters, steady-state simulations were performed in Aspen Plus to provide an insight into the process. Moreover, a time-resolved energetic evaluation was conducted to analyze the influence of varying capacity of the heat sources and operational strategy in addition to economic calculations. The simulations showed that an overall control strategy needs to consider the air properties as well as the flow rate of wet input material. In the reference case, the boiler must be operated at full load through the year to supply as much heat as possible. The revenue from the dried material was the most crucial parameter on the drying economics. Although the current plant configuration operati... [more]

Sugar cane bagasse and corn stalks are rich in lignocellulose, which can be degraded into monosaccharides through enzymatic hydrolysis. Appropriate pretreatment methods can effectively improve the efficiency of lignocellulose enzymatic hydrolysis. To enhance the efficiency of enzymatic hydrolysis, thread rolling pretreatment as a physical pretreatment was applied in this study. The influence of raw material meshes size after pretreatment was also taken as the research target. Specific surface area analysis, Scanning electron microscope (SEM), X-rays diffraction (XRD), and Fourier transform infrared (FT-IR) were used for characterizations. The results showed that, the total monosaccharide recovery rates of the raw materials, 20−40 mesh, 40−60 mesh, and 60−80 mesh enzymolysis substrates were 17.6%, 34.58%, 37.94%, and 50.69%, respectively. The sample after pretreatment showed a better recovery of monosaccharide than that of the raw material. Moreover, the enzymolysis substrates with a la... [more]

Finding a way for mitigating climate change is one of the main challenges of our generation. Sorption-enhanced gasification (SEG) is a process by which syngas as an important intermediate for the synthesis of e.g., dimethyl ether (DME), bio-synthetic natural gas (SNG) and Fischer−Tropsch (FT) products or hydrogen can be produced by using biomass as feedstock. It can, therefore, contribute to a replacement for fossil fuels to reduce greenhouse gas (GHG) emissions. SEG is an indirect gasification process that is operated in a dual-fluidized bed (DFB) reactor. By the use of a CO2-active sorbent as bed material, CO2 that is produced during gasification is directly captured. The resulting enhancement of the water−gas shift reaction enables the production of a syngas with high hydrogen content and adjustable H2/CO/CO2-ratio. Tests were conducted in a 200 kW DFB pilot-scale facility under industrially relevant conditions to analyze the influence of gasification temperature, steam to carbon (S... [more]

The chemical looping gasification of residual biomasses—operated in fluidized beds composed of oxygen-carriers—may allow the production of biofuels from syngas. This biomass-to-fuel chain can contribute to mitigate climate change, avoiding the accumulation of greenhouse gases in our atmosphere. The ongoing European research project Horizon2020 CLARA (G.A. 817841) investigates wheat-straw-pellets (WSP) and raw-pine-forest-residue (RPR) pellets as feedstocks for chemical looping gasification. This work presents experimental results from devolatilizations of WSP and RPR, in bubbling beds made of three different oxygen-carriers or sand (inert reference), at 700, 800, 900 °C. Devolatilization is a key step of gasification, influencing syngas quality and quantity. Tests were performed at laboratory-scale, by a quartz reactor (fluidizing agent: N2). For each pellet, collected data allowed the quantification of released gases (H2, CO, CO2, CH4, hydrocarbons) and mass balances, to obtain gas yi... [more]

The gasification process involves several reactions that occur simultaneously and are interrelated by several independent variables. Simulation tools can help us to understand the process behaviour and predict the efficiency and final composition of the products. In this work, two thermodynamic equilibrium models developed in Aspen Plus® software were assessed: a non-stoichiometric model based on the feedstock composition and on the most probable compounds expected from the results of the gasification process using minimisation of Gibbs free energy and a stoichiometric model based on a set of chemical reactions considered as the most relevant to describe the gasification process. Both models were validated with experimental data from a bubbling fluidised bed semi-pilot scale gasifier using pine kernel shells (PKS) as feedstock. The influence of temperature, stoichiometric ratio (SR) and steam to biomass ratio (SBR) were analysed. Overall, predictions of the gas composition and gasifica... [more]

The purpose of this work is to determine the impact of selected silage maize cultivation technologies, including energy inputs in the production chain (cultivation, harvesting, heap placing), on energy efficiency. The analysis of energy inputs, energy efficiency for the silage maize production technology were estimated. The research was performed for 13 farms producing silage maize. The data from the farms covered all the activities and the agrotechnical measures performed. The calculations of energy inputs made for the silage maize production for selected technologies were performed using the method developed by the Institute of Construction, Mechanization and Electrification for Agriculture (IBMER), once the method was verified and adapted to the needs and conditions of own research. Based on the accumulated energy production and the energy accumulated in the yield, energy efficiency index values for 13 silage maize cultivation technologies were calculated. The greatest impact on the... [more]

Maize forms the basis of Mexican food. As a result, approximately six million tons of corncob are produced each year, which represents an environmental issue, as well as a potential feedstock for biogas production. This research aimed to analyze the taxonomic and functional shift in the microbiome of the fermenters using a whole metagenome shotgun approach. Two strategies were used to understand the microbial community at the beginning and the end of anaerobic digestion: (i) phylogenetic analysis to infer the presence and coverage of clade-specific markers to assign taxonomy and (ii) the recovery of the individual genomes from the samples using the binning of the assembled scaffolds. The results showed that anaerobic digestion brought some noticeable changes and the main microbial community was composed of Corynebacterium variable, Desulfovibrio desulfuricans, Vibrio furnissii, Shewanella spp., Actinoplanes spp., Pseudoxanthomonas spp., Saccharomonospora azurea, Agromyces spp., Serinic... [more]