Fast forging of compacts made up of Mg and Ni powders is shown to be an effective method to induce severe plastic deformation with improved H2 sorption properties. Here, using such processed samples, a comprehensive analysis of the sorption properties reveals that the first hydrogenation sequence significantly depends on the forging temperature, through different microstructures. More in detail, no phase transformation occurs upon cold forging, while solid-state reaction leads to the formation of the Mg2Ni intermetallic compound upon forging above 400 °C. Forging below the brittle-to-ductile transition (225−250 °C) leads to faster H2 uptake upon first absorption owing to a more textured fiber along the c-axis and internal strains which promote hydrogen diffusion through the bulk material. Desorption kinetics remain slower with low-temperature forging, despite Ni recombining to form Mg2Ni during the first desorption. After several cycles, a two-step behavior is observed with a fast abso... [more]

The meaningful utilization of artificially created multiple fractures in tight formations is associated with the performance behavior of such flow channels, especially in the case of thermal energy extraction from sedimentary geothermal system. In this study, an innovative idea is presented to develop a numerical model for geothermal energy production based on concrete physical performance of an artificially created tensile multi-fracture system in a simplified manner. The state-of-the-art software FLAC3Dplus-TOUGH2MP-TMVOC are integrated to develop a coupled thermo-hydro-mechanical (THM) fictive model for constructing a multi-fracture scheme and estimating heat extraction performance. By incorporating the actual fracture width of newly created subsequent fracture under the effect of stress shadow, cubic law is implemented for fluid flow and geothermal energy production. The results depict that fracture spacing plays a vital role in the energy contribution through multiple fractures. A... [more]

Optimal scheduling of distributed energy resources (DERs) of a low-voltage utility-connected microgrid system is studied in this paper. DERs include both dispatchable fossil-fueled generators and non-dispatchable renewable energy resources. Various real constraints associated with adjustable loads, charging/discharging limitations of battery, and the start-up/shut-down time of the dispatchable DERs are considered during the scheduling process. Adjustable loads are assumed to the residential loads which either operates throughout the day or for a particular period during the day. The impact of these loads on the generation cost of the microgrid system is studied. A novel hybrid approach considers the grey wolf optimizer (GWO), sine cosine algorithm (SCA), and crow search algorithm (CSA) to minimize the overall generation cost of the microgrid system. It has been found that the generation costs rise 50% when the residential loads were included along with the fixed loads. Active participa... [more]

The effects of gravity on the heat transfer performance of supercritical CO2 flowing within a vertical tube with a diameter of 4.75 mm are numerically studied in this paper. The main objectives are to comprehensively investigate the action of gravity and buoyancy on the supercritical heat transfer. An effective numerical method, which employs a modified Shear Stress Transfer k-ω model (SST k-ω), is applied at various gravity conditions. It is found that, for both upward and downward flows, the heat transfer of supercritical CO2 is improved with increased gravity magnitude. The effect of gravity on heat transfer are more pronounced under a low mass flux condition than that under a high mass flux condition and it is closely related to the variations of thermal properties. For the upward flow, the increased gravity magnitude accelerates the near wall fluid and creates a classic “M-shaped” radial velocity distribution. For the downward flow, the increased gravity magnitude decelerates the... [more]

The octane number is a measure of the resistance of gasoline fuels to auto-ignition. Therefore, high octane numbers reduce the engine knocking risk, leading to higher compression threshold and, consequently, higher engine efficiencies. This allows higher compression ratios to be considered during the engine design stage. Current spark-ignited (SI) engines use knock sensors to protect the engine from knocking, usually adapting the operation parameters (boost pressure, spark timing, lambda). Moreover, some engines can move the settings towards optimized parameters if knock is not detected, leading to higher performance and fuel economy. In this work, three gasolines with different octane ratings (95, 98 and 100 RON (research octane number)) were fueled in a high-performance vehicle. Tests were performed in a chassis dyno at controlled ambient conditions, including a driving sequence composed of full-load accelerations and two steady-state modes. Vehicle power significantly increased with... [more]

To improve our understanding of the interactive effects in combustion of binary multicomponent fuel droplets at sub-atmospheric pressure, combustion experiments were conducted on two fibre-supported RP-3 kerosene droplets at pressures from 0.2 to 1.0 bar. The burning life of the interactive droplets was recorded by a high-speed camera and a mirrorless camera. The results showed that the flame propagation time from burning droplet to unburned droplet was proportional to the normalised spacing distance between droplets and the ambient pressure. Meanwhile, the maximum normalised spacing distance from which the left droplet can be ignited has been investigated under different ambient pressure. The burning rate was evaluated and found to have the same trend as the single droplet combustion, which decreased with the reduction in the pressure. For every experiment, the interactive coefficient was less than one owing to the oxygen competition, except for the experiment at L/D0 = 2.5 and P = 1.... [more]

In this study, rubber seed shell was used for the production of activated carbon by chemical activation using an ionic liquid, [C4Py][Tf2N] as an activating agent. Sample RSS-IL 800 shows the highest specific surface area of 393.99 m2/g, a total pore volume of 0.206 cm3/g, and a micropore volume of 0.172 cm3/g. The performance of AC samples as an adsorbent for CO2 was also studied using a static volumetric technique evaluated at a temperature of 25 °C and 1 bar pressure. The CO2 adsorption capacity for sample RSS-IL 800 was 2.436 mmol/g, comparable with reported data from the previous study. Results also show that the CO2 adsorption capacity decreased at a higher temperature between 50 and 100 °C and increased at elevated pressure due to its exothermic behavior. The Langmuir model fits the adsorption data well, and the isosteric heat of adsorption proved that the physisorption process and exothermic behavior occur.

Thermal degradation of lignin in nitrogen atmosphere is evaluated by linear heating and isothermal tests. While linear heating suggests that thermal decomposition in the 200−400 °C range mainly consists of a single step, a careful analysis of isothermal tests points to different lignin fractions having different stabilities. This is an important point for practical predictions, since kinetics obtained as if the degradations at different temperatures were the same would lack practical utility. Instead, stairway type tests are proposed to evaluate the degradation rates and sample quantities involved at the temperatures of interest.

The use of solar energy is an obvious choice; the energy of the sun is not only indispensable for most processes in nature but it is also a clean, abundant, sustainable, and—most importantly—universally available resource. Although the further spread of photovoltaic systems, which make use of this source of energy, is expected in the future all around the world, no comprehensive investigation has been conducted into the current situation of the small-scale photovoltaic power plants in Hungary, where this type of photovoltaic system is the most popular. By means of a case study, whose novelty lies in its focus on small-scale power plants and their complex examination, including economic and geographic indicators, this paper analyzes their status in Hungary. The study endeavors to establish the reasons for the popularity of this type of power plant and to identify some typical geographical locations with well-illustrated photovoltaic density. Residential, as well as business prosumers, w... [more]

This research work puts forward a hybrid AC/DC microgrid with renewable energy sources pertaining to consumer’s residential area for meeting the demand. Currently, the power generation and consumption have experienced key transformations. One such tendency would be integration of microgrids into the distribution network that is characterized by high penetration of renewable energy resources as well as operations in parallel. Traditional droop control can be employed in order to get an accurate steady state averaged active power sharing amongst parallel inverters pertaining to hybrid AC/DC microgrid. It is presumed that there would be similar transient average power responses, and there would be no circulating current flowing between the units for identical inverters possessing the same droop gain. However, the instantaneous power could be affected by different line impedances considerably and thus resulting in variation in circulating power that flows amongst inverters, especially duri... [more]

In many energy-intensive industrial process plants, significant improvements in energy efficiency can be achieved through increased heat recovery. However, retrofitting plants for heat integration purposes can affect process operability. The aim of this paper is to present a comprehensive overview of such issues by systematically relating different types of heat recovery retrofit measures to a range of technical barriers associated with process operability and practical implementation of the measures. The paper presents a new approach for this kind of study, which can be applied in the early-stage screening of heat integration retrofit measures. This approach accounts for the importance of a number of selected operability factors and their relative significance. The work was conducted in the form of a case study at a large oil refinery. Several conceptual heat exchanger network retrofit design proposals were prepared and discussed during semi-structured interviews with technical staff... [more]

Anaerobic digestion (AD) of chicken litter (CL) is a viable alternative to disposal. However, methane yields from this primarily organic waste are quite low when mono-digested. This paper discusses the effect of an enzyme cocktail, trace element (TE) supplementation and selenium (Se) addition in small-scale batch biomethane potential (BMP) assays to enhance the AD of CL. Eleven different assays were set up in triplicate including assays containing only inoculum (blank), only CL (negative control) and cellulose and inoculum (positive control). The results indicate that both enzyme treatment and trace element supplementation enhanced the biogas and methane yield. The highest specific biogas and methane yields were noted for 1% enzyme-treated CL of 835.2 L/kg volatile solids (VS) and 460.8 L/kg VS, respectively. Usually, mono-digestion of CL is low due to high nitrogen content and the presence of recalcitrant lignocellulosic material from the bedding material. Enzyme treatment performed b... [more]

Due to changes in wind, the torque obtained from the wind turbine always fluctuates. Here, the wind turbine and the rotor of the generator are connected by a shaft that is one elastic body, and each rotating body has different inertia. The difference in inertia between the wind turbine and the generator causes a torsion between the wind generator and the generator; metal fatigue and torsion can damage the shaft. Therefore, it is necessary to consider the axial torsional vibration suppression of a geared wind power generator using a permanent magnet synchronous generator (PMSG). In addition, errors in axis system parameters occur due to long-term operation of the generator, and it is important to estimate for accurate control. In this paper, we propose torque estimation using H ∞ observer and axial torsional vibration suppression control in a three inertia system. The H ∞ controller is introduced into the armature current control system (q-axis current control system) of... [more]

The park and ride (P&R) parking type is usually located near peripheral public transport stops. These parking places are dedicated to people who, after leaving their vehicle in the parking, continue their journey to the city center using some form of public transport such as bus, metro, rail or tram systems. This article aims to examine the features associated with P&R parking locations in use in Cracow (Poland). The analysis included the number of entries and exits to and from parking during particular periods of the day, week and year, parking time of vehicles, and parking space use. A parking peak hour factor was also calculated, which expresses the crowding degree of vehicle entries/exits in/out parking during a particular period. In addition, the paper presents an analysis of factors determining users to P&R parking use. In the modeling process, logit models were used, which, as stated after analyzing the literature on the subject, were already used in various countries around the... [more]

Disposal of vast agricultural residues has been a nerve-wracking social problem in many agriculture-intensive regions. Open-field combustion both squanders those biomass resources and causes severe atmospheric pollution and hazards. In addition, wood industries yield residues such as sanding powders without value application. Production of biofuels out of these biomass provides a multiple beneficial solution. To that end, this work focused on fabrication of biomass fuels using rice straws (Calorific value: 14.7 MJ/Kg) and wood residues from OSB industries (Calorific value: 17.3 MJ/Kg). Biofuel sticks from various proportions of biomass residues were made using an 18.5 KW industrial biomass extruder without adding bonding agents, achieving densities of 1.0−1.6 g/cm3 and comparative calorific values. The biofuel sticks exhibit moisture sensitivity when subjected to a ten-day conditioning. Release of residual stresses that were created during the densification process led to structural de... [more]

Within Li-ion batteries, lithium plating is considered as one of the main reasons behind the capacity fade that occurs during low temperature and fast charging conditions. Previous studies indicate that plating is influenced by the levels of loss of lithium inventory (LLI) and the loss of active material (LAM) present in a battery. However, it is not clear from the literature on how lithium plating influences battery degradation in terms of LAM and LLI. Quantifying the undesirable impacts of lithium plating can help in understanding its impact on battery degradation and feedback effects of previous lithium plating on the formation of present plating. This study aims to quantify the degradation modes of lithium plating: LLI, LAM at the electrode level. A commercial Li-ion cell was first, aged using two different cases: with and without lithium plating. Second, a degradation diagnostic method is developed to quantify the degradation modes based on their measurable effects on open-circuit... [more]

The volatility and uncertainty of high-penetration renewable energy (RE) challenge the stability of the power system. To tackle this challenge, an optimal dispatch of high-penetration RE based on flexible resources (FRs) is proposed to enhance the ability of the power system to cope with uncertain disturbances. Firstly, the flexibility of a high-penetration RE integrated power system is analyzed. The flexibility margin of power supply and flexible adaptability of RE are then introduced as the evaluation indices for optimal operation. Finally, a multi-objective optimal dispatch model for power system flexibility enhancement based on FRs under the constraint of flexibility indices is proposed. The simulation results show that the proposed optimal dispatch can effectively enhance the flexibility of the power system and the penetration of RE and reduce pollutant emissions. Compared with the conventional method, the daily average emissions of CO2, SO2, and NOx with the proposed method are r... [more]

Currently, ground source heat pump (GSHP) technology is being studied, as the use of the ground as a source of renewable energy allows significant energy savings to be obtained. Therefore, it is useful to quantify how these savings help to achieve the energy balance of a Net Zero Energy Building (NZEB) compared to an air source heat pump or a condensing boiler coupled to a chiller. This paper assesses how these savings affect the number of photovoltaic panels installed on the roof of a building to obtain the NZEB target. The study is conducted by dynamic simulation for a building used as a bed and breakfast, virtually placed in two Italian towns. The energy savings and reduction of CO2 emissions, the percentage of renewable energy used, and the photovoltaic surface needed are assessed. Finally, the discounted payback period is calculated. The results show that the GSHP, unlike the systems to which it is compared, allows an NZEB to be obtained by balancing yearly energy consumption with... [more]

A renewable and distributed generation (DG)-enabled modern electrified power network with/without energy storage (ES) helps the progress of microgrid development. Frequency regulation is a significant scheme to improve the dynamic response quality of the microgrid under unknown disturbances. This paper established a maiden load frequency regulation of a wind-driven generator (WG), solar tower (ST), bio-diesel power generator (BDPG) and thermostatically controllable load (heat pump and refrigerator)-based, isolated, single-area microgrid system. Hence, intelligent control strategies are important for this issue. A newly developed butterfly algorithmic technique (BOA) is leveraged to tune the controllers’ parameters. However, to attain a proper balance between net power generation and load power, a dual stage proportional-integral- one plus integral-derivative PI − (1 + ID) controller is developed. Comparative system responses (in MATLAB/SIMULINK software) for different scenarios under s... [more]

Chemical looping combustion (CLC) technology generates power while capturing CO2 inherently with no direct energy penalty. However, previous studies have shown significant energy penalties due to low turbine inlet temperature (TIT) relative to a standard natural gas combined cycle plant. The low TIT is limited by the oxygen carrier material used in the CLC process. Therefore, in the current study, an additional combustor is included downstream of the CLC air reactor to raise the TIT. The efficient production of clean hydrogen for firing the added combustor is key to the success of this strategy. Therefore, the highly efficient membrane-assisted chemical looping reforming (MA-CLR) technology was selected. Five different integrations between CLC and MA-CLR were investigated, capitalizing on the steam in the CLC fuel reactor outlet stream to achieve highly efficient reforming in MA-CLR. This integration reduced the energy penalty as low as 3.6%-points for power production only (case 2) an... [more]

The energy sector is currently undergoing a rapid transformation with the integration of power electronic converter (PEC)-interfaced renewable energy sources (RES), such as wind and solar photovoltaic (PV) systems, at both the transmission and distribution networks. Power system stability has been significantly influenced by this power grid transformation. This paper comprehensively reviews major power system stability issues affected due to large-scale integration of PEC-interfaced RES in power grids, with some example case studies relevant for each stability category. According to the review, stability issues are mainly originating from reduction in synchronous inertia, reduction in reactive power reserve, low short-circuit strength of the power network, and fault ride-through (FRT) strategy/capability of the PEC-interfaced RES. Decrease in synchronous inertia could affect both the rotor angle stability and the frequency stability, while decrease in short-circuit strength and reactiv... [more]

The ongoing diffusion of solid-state DC/DC converters makes possible a partial migration of electric power systems from the present AC paradigm to a future DC scenario. In addition, the power demand in the domestic environment is expected to grow considerably, for example, due to the progressive diffusion of electric vehicles, induction cooking and heat pumps. To face this evolution, the paper introduces a novel electric topology for a hybrid AC/DC smart house, based on the solid-state transformer technology. The electric scheme, voltage levels and converters types are thoroughly discussed to better integrate the spread of electric appliances, which are frequently based on internal DC buses, within the present AC distribution networks. Voltage levels are determined to guarantee high safety zones with negligible electric risk in the most exposed areas of the house. At the same time, the developed control schemes assure high power quality (voltage stability in the case of both load varia... [more]

In this work are presented experimental values of the burning velocity of iso-octane/air, n-heptane/air and n-heptane/toluene/air mixtures, gasoline surrogates valid over a range of pressures and temperatures similar to those obtained in internal combustion engines. The present work is based on a method to determine the burning velocities of liquid fuels in a spherical constant volume combustion bomb, in which the initial conditions of pressure, temperature and fuel/air equivalence ratios can be accurately established. A two-zone thermodynamic diagnostic model was used to analyze the combustion pressure trace and calculate thermodynamic variables that cannot be directly measured: the burning velocity and mass burning rate. This experimental facility has been used and validated before for the determination of the burning velocity of gaseous fuels and it is validated in this work for liquid fuels. The values obtained for the burning velocity are expressed as power laws of the pressure, t... [more]

As cities develop new interventions for climate change mitigation, incorporating renewable energy in urban public spaces becomes a common norm to address sustainability objectives. However, current built projects and assessment practices mainly uses a “techno-fixes” approach focusing on strategies that are related to the environmental benefits and neglecting other potential strategies instigating social and economic benefits of renewable energy. The purpose of this study is to present a potential sustainability assessment model introducing new strategies for public space renewable energy use where social and economic benefits of renewables become evident. Supplemented with theories and principles from ecology, the model’s economic strategies refer whether the project considers meaningful part of the produced electricity for generating a local economy; environmental strategy comprises embodied energy, energy storage and self-maintenance; social strategy includes whether the project cons... [more]

Improvement of the energy efficiency of public buildings appears to be one of the best ways to simultaneously reduce energy consumption as well as the negative impacts on the environment. The work is dedicated to the analysis of modernization process of the energy system in a sports facility in a way leading to design of smart energy system. The proposed solution, being a specific case study, offers optimal use of energy in the facility, significantly reducing the demand for energy derived from fossil fuels (heat providers and conventional power plants). The project, on its first step, consists of recovering energy from sewage that usually is irretrievably lost. This option allows to achieve the assumed goals simultaneously optimizing the investment costs. The proposed solution mitigates air pollution and harmful gas and dust emissions to the atmosphere, and contributes to an increase of both the attractiveness and competitiveness of the area in which the sports facility is located. Th... [more]